Herbicidal thiophenesulfonamides

ABSTRACT

Thiophenesulfonamides such as N-[(4,6-dimethylpyrimidin-2-yl)aminocarbonyl]-3-(isoxazol-3-yl)-2-thiophenesulfonamide are useful as herbicides and plant growth regulants.

RELATED APPLICATION

This application is a continuation of copending application Ser. No. 724,835 filed on Apr. 23, 1985, now U.S. Pat. No. 4,684,393, which in turn is a continuation-in-part of copending application Ser. No. 686,834 filed Dec. 27, 1984, now abandoned which in turn is a continuation-in-part of copending application Ser. No. 619,277 filed June 11, 1984, now abandoned.

BACKGROUND OF THE INVENTION

U.S. Pat. No. 4,398,939, issued Aug. 16, 1983 to Levitt, discloses herbicidal thiophenesulfonylureas such as ##STR1##

European Patent Application No. 30,142, published June 10, 1981, discloses herbicidal thiophene sulfonylureas such as ##STR2##

U.S. Pat. No. 4,378,991, issued Apr. 5, 1983 discloses o-phenyl sulfonylureas such as ##STR3##

European Patent Application No. 83,975, published July 20, 1983, and European Patent Application No. 85,476, published Aug. 10, 1983, disclose herbicidal benzenesulfonamides of the formula ##STR4## where Q is various 5- and 6-membered, saturated, unsaturated or partially unsaturated heterocyclic rings.

South African Patent Application No. 83/8416 (published May 12, 1984) discloses herbicidal sulfonamides of formula ##STR5## wherein A is an unsaturated or only partially saturated 5- or 6-membered heterocyclic ring system which is bonded through a carbon atom and contains 1, 2 or 3 heteroatoms and which may be substituted by C₁ -C₄ alkyl, C₁ -C₄ haloalkyl, C₁ -C₄ alkoxy, C₁ -C₄ alkylthio, C₂ -C₈ alkoxyalkyl, di(C₁ -C₄ alkyl)amino, halogen, cyano or nitro.

SUMMARY OF THE INVENTION

This invention relates to novel compounds of Formulas Ia, Ib, and Ic, agriculturally suitable compositions containing them, and their method-of-use as general or selective pre-emergent and post-emergent herbicides or as plant growth regulants. ##STR6## wherein R is H or CH₃ ;

n is 0, 1 or 2;

W is O or S;

Q is a phenyl ring or a saturated 5- or 6-membered ring containing 1 heteroatom selected from sulfur, nitrogen or oxygen or an unsaturated 5- or 6-membered ring containing 1-3 heteroatoms selected from 0-1 sulfur, 0-1 oxygen or 0-3 nitrogen and Q may optionally be substituted by one or more groups selected from SH, C₁ -C₄ alkyl, C₃ -C₄ alkenyl, C₁ -C₃ haloalkyl, halogen, C₁ -C₃ alkoxy, C₁ -C₄ alkylthio, C₃ -C₄ alkenylthio, C₃ -C₄ alkenyloxy, C₁ -C₂ haloalkoxy, C₁ -C₂ haloalkylthio, C₃ -C₄ alkynylthio, C₁ -C₄ cyanoalkylthio, C₁ -C₂ alkylcarbonylmethythio or C₁ -C₂ alkoxycarbonylmethylthio;

E is H, C₁ -C₂ alkyl, C₁ -C₂ alkoxy, halogen, NO₂, C₁ -C₂ haloalkyl, C₁ -C₂ alkylthio, C₁ -C₂ alkylsulfonyl, C₁ -C₂ alkoxycarbonyl, C₁ -C₂ dialkylaminosulfamoyl; ##STR7## X is H, C₁ -C₄ alkyl, C₁ -C₄ alkoxy, C₁ -C₄ haloalkoxy, C₁ -C₄ haloalkyl, C₁ -C₄ haloalkylthio, C₁ -C₄ alkylthio, halogen, C₂ -C₅ alkoxyalkyl, C₂ -C₅ alkoxyalkoxy, amino, C₁ -C₃ alkylamino or di(C₁ -C₃ alkyl)amino;

Y is H, C₁ -C₄ alkyl, C₁ -C₄ alkoxy, C₁ -C₄ haloalkoxy, C₁ -C₄ haloalkylthio, C₁ -C₄ alkylthio, halogen, C₂ -C₅ alkoxyalkyl, C₂ -C₅ alkoxyalkoxy, amino, C₁ -C₃ alkylamino, di(C₁ -C₃ alkyl)amino, C₃ -C₄ alkenyloxy, C₃ -C₄ alkynyloxy, C₂ -C₅ alkylthioalkyl, C₂ -C₅ alkylsulfinylalkyl, C₂ -C₅ alkylsulfonylalkyl, C₁ -C₄ haloalkyl, C₃ -C₅ cycloalkyl, C₂ -C₄ alkynyl, C(O)R_(c), ##STR8## m is 2 or 3; L₁ and L₂ are independently O or S;

R_(a) and R_(b) are independently C₁ -C₂ alkyl;

R_(c) is H or CH₃ ;

Z is CH or N;

Y₁ is O or CH₂ ;

X₁ is CH₃, OCH₃, OC₂ H₅ or OCF₂ H;

Y₂ is H or CH₃ ;

X₂ is CH₃, OCH₃ or SCH₃ ;

Y₃ is CH₃, CH₂ CH₃ or CH₂ CF₃ ; and

X₃ is CH₃ or OCH₃ ;

and their agriculturally suitable salts; provided that

(1) when X is F, Cl, Br or I, then Z is CH and Y is OCF₂ H, OCH₃ OC₂ H₅, NH₂, NHCH₃, N(CH₃)₂ ;

(2) the total number of carbon atoms of Q must be less than or equal to 8;

(3) when X or Y is OCF₂ H, then Z is CH;

(4) when Q is a saturated 5- or 6-membered ring containing one nitrogen atom, it is bonded to the thiophene ring through carbon; and

(5) when W is S, then A is A-1 and R₁ is CH₃, OCH₃, OC₂ H₅, CH₂ OCH₃, C₂ H₅, CF₃, SCH₃, OCH₂ CH═CH₂, OCH₂ C.tbd.CH, OCH₂ CH₂ OCH₃, CH(OCH₃)₂ or ##STR9##

In the above definitions, the term "alkyl", used either alone or in compound words such as "alkylthio" or "haloalkyl", denotes straight chain or branched alkyl, e.g. methyl, ethyl, n-propyl, isopropyl or the different butyl, pentyl, hexyl, heptyl, octyl, nonyl or decyl isomers.

Alkoxy denotes methoxy, ethoxy, n-propyloxy, isopropyloxy or the different butyl, pentyl, hexyl, heptyl, octyl or nonyl isomers.

Alkenyl denotes straight chain or branched alkenes, e.g. vinyl, 1-propenyl, 2-propenyl, isopropenyl or the different butenyl, pentenyl, hexenyl, heptenyl, octenyl, nonenyl or decenyl isomers.

Alkynyl denotes straight chain or branch alkynes, e.g., ethynyl, 1-propynyl, 2-propynyl or the different butynyl, pentynyl, hexynyl, heptynyl, octynyl, nonynyl and decynyl isomers.

Cycloalkyl denotes cyclopropyl, cyclobutyl or cyclopentyl.

The term "halogen", either alone or in compound words such as "haloalkyl", denotes fluorine, chlorine, bromine or iodine.

Alkylcarbonyl denotes acetyl or propionyl.

Alkoxycarbonyl denotes methoxycarbonyl or ethoxycarbonyl.

Alkylsulfonyl denotes methylsulfonyl or ethylsulfonyl.

Alkylthio, alkylamino, alkylsulfamoyl, etc. are defined in an analogous manner.

In terms such as C₂ -C₃ alkylthioalkyl, the specified number of carbon atoms is meant to define the total number of carbon atoms in that substituent group. For example, C₂ -C₃ alkylthioalkyl would designate CH₂ SCH₃, CH₂ SC₂ H₅, CH₂ CH₂ SCH₃ or CH(CH₃)SCH₃, and C₂ -C₅ alkoxyalkoxy would represent OCH₂ OCH₃, through O(CH₂)₄ OCH₃ or OCH₂ O(CH₂)₃ CH₃ and the various structural isomers embraced therein.

Preferred for their higher herbicidal activity, greater plant growth regulant activity and/or more favorable ease of synthesis are:

(1) Compounds of Formulas Ia-Ic where ##STR10## R₁ is H, Cl, CH₃ or OCH₃ ; R₂ is H, F, Cl, CH₃, OCH₃ or CF₃ ;

R₃, R₄, R₅, R₆, R₇, R₈, R₉ and R₁₀ are independently H or CH₃ ;

n' is 0 or 1;

R₃ ' is H, SH, C₁ -C₃ alkyl, C₁ -C₄ alkylthio, C₃ -C₄ alkenylthio, C₃ -C₄ alkynylthio, C₁ -C₃ cyanoalkylthio, SCH₂ CO₂ CH₃, SCH₂ CO₂ C₂ H₅, SCH₂ C(O)CH₃, halogen, C₁ -C₃ alkoxy or OCH₂ CH═CH₂ ;

R₃ " is H, CH₃, Cl or Br;

W' is O or S;

W" is O or S or NR₁₁ ;

R₁₁ is H, C₁ -C₃ alkyl or CH₂ CH═CH₂ ;

(2) Compounds of Preferred 1 where E is H; A is A-1; X is CH₃, OCH₃, OC₂ H₅, Cl or Br; Y is H, CH₃, OCH₃, C₂ H₅, OC₂ H₅, CH₂ OCH₃, CF₃, OCF₂ H, cyclopropyl, OCH₂ CF₃, NHCH₃, N(CH₃)₂, CH(OCH₃)₂ or ##STR11## n' is 0; and R₃ ' and R₃ " are independently H, CH₃ or Cl; R is H; and W is O;

(3) Compounds of Preferred 2 where n is O;

(4) Compounds of Preferred 3 where Y is C₁ -C₂ alkyl, OCH₃, or OCF₂ H;

(5) Compounds of Preferred 4 where R₁ is H, R₂ is H or Cl and Z is CH;

(6) Compounds of Preferred 5 of Formula Ia;

(7) Compounds of Preferred 5 of Formula Ib;

(8) Compounds of Preferred 5 of Formula Ic;

(9) Compounds of Preferred 6 where Q is Q-1;

(10) Compounds of Preferred 6 where Q is Q-2,

(11) Compounds of Preferred 6 where Q is Q-3;

(12) Compounds of Preferred 6 where Q is Q-5;

(13) Compounds of Preferred 6 where Q is Q-7;

(14) Compounds of Preferred 6 where Q is Q-10;

(15) Compounds of Preferred 6 where Q is Q-11;

(16) Compounds of Preferred 6 where Q is Q-15;

(17) Compounds of Preferred 6 where Q is Q-16;

(18) Compounds of Preferred 6 where Q is Q-20;

(19) Compounds of Preferred 6 where Q is Q-23;

(20) Compounds of Preferred 6 where Q is Q-28;

(21) Compounds of Preferred 6 where Q is Q-36;

(22) Compounds of Preferred 6 where Q is Q-39;

(23) Compounds of Preferred 7 where Q is Q-1;

(24) Compounds of Preferred 7 where Q is Q-2;

(25) Compounds of Preferred 7 where Q is Q-3;

(26) Compounds of Preferred 7 where Q is Q-5;

(27) Compounds of Preferred 7 where Q is Q-7;

(28) Compounds of Preferred 7 where Q is Q-10;

(29) Compounds of Preferred 7 where Q is Q-11;

(30) Compounds of Preferred 7 where Q is Q-15;

(31) Compounds of Preferred 7 where Q is Q-16;

(32) Compounds of Preferred 7 where Q is Q-20;

(33) Compounds of Preferred 7 where Q is Q-23;

(34) Compounds of Preferred 7 where Q is Q-28;

(35) Compounds of Preferred 7 where Q is Q-36;

(36) Compounds of Preferred 7 where Q is Q-39;

(37) Compounds of Preferred 8 where Q is Q-1;

(38) Compounds of Preferred 8 where Q is Q-2;

(39) Compounds of Preferred 8 where Q is Q-3;

(40) Compounds of Preferred 8 where Q is Q-5;

(41) Compounds of Preferred 8 where Q is Q-7;

(42) Compounds of Preferred 8 where Q is Q-10;

(43) Compounds of Preferred 8 where Q is Q-11;

(44) Compounds of Preferred 8 where Q is Q-15;

(45) Compounds of Preferred 8 where Q is Q-16;

(46) Compounds of Preferred 8 where Q is Q-20;

(47) Compounds of Preferred 8 where Q is Q-23;

(48) Compounds of Preferred 8 where Q is Q-28;

(49) Compounds of Preferred 8 where Q is Q-36;

(50) Compounds of Preferred 8 where Q is Q-39;

(51) Compounds of Preferred 16 where W" is S;

(52) Compounds of Preferred 30 where W" is S;

(53) Compounds of Preferred 44 where W" is S;

Specifically Preferred for their highest herbicidal activity, greatest plant growth regulant activity and/or most favorable ease of synthesis are:

N-[(4,6-dimethylpyrimidin-2-yl)aminocarbonyl]-3-(isoxazol-3-yl)-2-thiophenesulfonamide, m.p. 172.5°-173° C.

3-(isoxazol-3-yl)-N-[(4-methoxy-6-methylpyrimidin-2-yl)aminocarbonyl]-2-thiophenesulfonamide, m.p. 192° C. (d);

N-[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-3-(isoxazol-3-yl)-2-thiophenesulfonamide, m.p. 157°-158° C.;

3-(5-chloro-1H-1,2,4-triazol-1-yl)-N-[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-2-thiophenesulfonamide, m.p. 204°-205° C. (d);

N-[(4-methoxy-6-methylpyrimidin-2-yl)aminocarbonyl]-3-(1H-pyrrol-1-yl)-2-thiophenesulfonamide, m.p. 152°-155° C.;

N-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)aminocarbonyl]-3-(1H-pyrrol-1-yl)-2-thiophenesulfonamide, m.p. 144°-146° C.;

N-[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-3-(1H-pyrrol-1-yl)-2-thiophenesulfonamide, m.p. 142°-146° C.;

N-[(4,6-dimethylpyrimidin-2-yl)aminocarbonyl]-3-(1H-pyrrol-1-yl)-2-thiophenesulfonamide, m.p. 170°-173° C.;

N-[(4,6-dimethyl-1,3,5-triazin-2-yl)aminocarbonyl]-3-(1H-pyrrol-1-yl)-2-thiophenesulfonamide, m.p. 153°-156° C.;

N-[(4,6-dimethoxy-1,3,5-triazin-2-yl)aminocarbonyl]-3-(1H-pyrrol-1-yl)-2-thiophenesulfonamide, m.p. 156°-159° C.;

N-[(4-chloro-6-methoxypyridimin-2-yl)aminocarbonyl]-3-(2-methyl-4-thiazolyl)-2-thiophenesulfonamide. m.p. 146°-149° C.;

N-[(4-methoxy-6-methylpyrimidin-2-yl)aminocarbonyl]-3-(2-methyl-4-thiazolyl)-2-thiophenesulfonamide, m.p. 146°-149° C.;

N-[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-3-(2-methyl-4-thiazolyl)-2-thiophenesulfonamide, m.p. 164°-168° C.

SYNTHESIS

The compounds of Formula I can be prepared by one or more of the methods described below in Equations 1 through 4.

Many of the compounds of Formula I can be prepared by reaction of a sulfonamide of Formula 2 with an appropriate methyl carbamate of Formula 3 in the presence of at least an equimolar amount of trimethylaluminum, according to Equation 1.

EQUATION 1 ##STR12## These reactions are carried out at 25° to 40° C. under an inert atmosphere and in an inert, dipolar aprotic solvent such as methylene chloride for 10 to 96 hours. Details of this reaction as well as the preparation of the carbamates of Formula 3 can be found in EPO Publication No. 13,480.

Many of the compounds of Formula I also can be prepared by reacting a sulfonylcarbamate of Formula 4 with an appropriate heterocyclic amine of Formula 5, according to Equation 1a.

EQUATION 1a ##STR13## The reaction is carried out at 50° to 100° C. in a solvent such as 1,4-dioxane for 0.5 to 24 hours according to EPO Publication No. 44807. The required carbamates of Formula 4 are prepared by reacting the appropriate sulfonamide, 2, with diphenylcarbonate in the presence of equimolar quantities of a strong base, such as sodium or potassium hydride.

Some of the compounds of Formula I also can be prepared as shown in Equation 2.

EQUATION 2 ##STR14## wherein Y' is CH₃, C₂ H₅ or CH₂ CF₃.

This reaction series is performed according to the procedures disclosed by EPO Publication No. 30,140 and the requisite heterocyclic isocyanates of Formula 6 can be prepared according to methods described in Swiss Pat. No. 579,062, U.S. Pat. No. 3,919,228, U.S. Pat. No. 3,732,223 and U. von Gizycki, Angew. Chem. Int. Ed. Engl. 1976, 10, 402 and 403.

Compounds of Formula I also may be prepared by reaction of a thienylsulfonylisocyanate of Formula 8 with the appropriate heterocyclic amine, as shown in Equation 3.

EQUATION 3 ##STR15## The reaction of Equation 3 is most successful when performed in an inert dipolar aprotic solvent such as methylene chloride, tetrahydrofuran or acetonitrile at temperatures between 20° and 80° C. A catalytic amount of 1,4-diazabicyclo[2.2.2]octane (Dabco®) may be used to accelerate the reaction. In cases where the products are insoluble in the reaction solvent, isolation may be performed by simple filtration; when the products are soluble, isolation may be performed by evaporation of the solvent, trituration with a solvent such as 1-chlorobutane, diethyl ether or methanol and filtration.

Thienylsulfonylisocyanates of Formula 8, can be prepared from sulfonamides of Formula 2 by methods described in U.S. Pat. No. 4,238,621, as indicated in Equation 3a. Alternatively, these sulfonylisocyanates can be synthesized via a two-step procedure, consisting of (1) reacting sulfonamide 2 with n-butylisocyanate in the presence of one molar equivalent of a base such as potassium carbonate in a solvent such as 2-butanone or acetonitrile, to form n-butylsulfonylureas of Formula 9 and (2) reaction of 9 with phosgene using Dabco® as a catalyst in refluxing xylene as solvent. This method is similar to the preparation found in "Newer Methods of Preparative Organic Chemistry," W. Forest, Ed., Vol. VI, Academic Press, NY, 1967, pp. 223-241. Equation 3b illustrates the procedure.

EQUATION 3a ##STR16## EQUATION 3b ##STR17## wherein W is O.

Sulfonyl isothiocyanates of Formula 8, wherein W is S, can be prepared by treatment of sulfonamides of Formula 2 with carbon disulfide and potassium hydroxide followed by reaction of the dipotassium salt with phosgene according to K. Hartke, Arch. Pharm., 299, 174.

The compounds of Formula I also are available by the methodology described in South African Application No. 830441 and illustrated by Equation 4. Thienylsulfonamides of Formula 2 reacts with heterocyclic carbamates of Formula 10 in 1,4-dioxane at 20° to 80° C. for periods of 1 to 24 hours when 1 equivalent of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) is added to the reaction mixture. The resultant products are isolated by dilution of the reaction mixture with water, acidification and subsequent filtration. Heterocyclic carbamates of Formula 10 in turn are synthesized by reaction of heterocyclic amines of Formula 5 with diphenyl carbonate or phenyl chloroformate in pyridine at temperatures ranging from 20° to 80° C., as indicated in Equation 4a.

EQUATION 4 ##STR18## EQUATION 4a ##STR19##

The synthesis of thienylsulfonylureas of Formula I rely upon the requisite intermediate thiophenesulfonamides of Formula 2.

Some of the intermediate sulfonamides of Formula 2 described above can be prepared from amines of Formula 11 by a two-step procedure, as shown in Equation 5. This consists of (5a) diazotizing 11 and coupling the diazonium salt with sulfur dioxide to form a sulfonyl chloride of Formula 12; and (5b) aminating 12 with ammonium hydroxide or anhydrous ammonia to form 2.

EQUATION 5 ##STR20##

The reaction of Equation 5a is accomplished by treating a solution of amine 11 in a mixture of concentrated hydrochloric acid and glacial acetic acid with a solution of sodium nitrite in water at -5° to 5° C. After stirring for 10-30 minutes at about 0° C. to insure complete diazotization, the solution is added to a mixture of an excess of sulfur dioxide and a catalytic amount of copper(I) chloride or copper(II) chloride in glacial acetic acid at about 10° C. The temperature is kept at about 10° C. for 1/4 to 1 hour, then raised to 20° to 30° C. and held at that temperature for 2 to about 24 hours. This solution is then poured into a large excess of ice water. The sulfonyl chloride 12 can be isolated by filtration or by extraction into a solvent such as ethyl ether, methylene chloride or, preferably, 1-chlorobutane followed by evaporation of the solvent.

The amination described in the reaction of Equation 5b above is carried out conveniently by treating a solution of the sulfonyl chloride 12 with at least two mole equivalents of anhydrous ammonia in a solvent such as ethyl ether or methylene chloride at -20° to 30° C. If the sulfonamide product 2 is insoluble, it may be isolated by filtration followed by washing out the salts with water. If product 2 is soluble in the reaction solvent, it may be isolated by filtering off the precipitated ammonium chloride and evaporation of the solvent. Additionally, many sulfonamides 2 can be prepared by reaction of corresponding sulfonyl chlorides 12 with excess aqueous ammonium hydroxide in tetrahydrofuran at 0° to about 40° C. for 0.5 to 10 hours. The sulfonamide product 2 is isolated by evaporation of the tetrahydrofuran solvent, addition of water to the residue and filtration.

Alternatively, the intermediate sulfonyl chloride 12 can be prepared as shown below in Equation 6.

EQUATION 6 ##STR21##

According to Equation 6, a lithium salt, prepared by reaction of 13 with n-butyllithium in ether at about -70° C., is added to sulfuryl chloride in hexane at about -30° to -20° C. and stirred for 0.5 to 10 hours at -30° to 30° C. to yield sulfonyl chloride 12, according to teachings of S. N. Bhattacharya, C. Earborn and D. R. M. Walsh, J. Chem Soc. (C) 1968, 1265 and H. Quast and F. Kee, Synthesis 1974, 489. Subsequent reaction of 12 with ammonia or ammonium hydroxide as described above provides the corresponding sulfonamide.

Starting with an appropriate bromothiophene, and carrying out the procedures described in Equation 6, or simple modifications thereof, one skilled in the art may prepare some of the other sulfonyl chlorides of Formula 12 described above. Of necessity, the reactions are limited to those cases in which the substituent (CH₂)_(n) Q is inert to lithium reagents under the conditions of the reactions, which will be obvious to one skilled in the art. For a general review of metallation with lithium reagents, see H. W. Gschwend and H. R. Rodriguez, Org. Reactions 1979, 26, 1.

Some sulfonamides 2 are best prepared by the procedure of Equation 7 below.

EQUATION 7 ##STR22##

The preparation of sulfinic acid salts 14 by the procedure of Equation 7 is well known in the art; see U.S. 4,127,405 and H. W. Gschwend et al., loc. cit. . Sulfonamides 2 are best prepared by treatment of sulfinic acid salts with chloramine. In this procedure an ethereal solution or suspension of the salt 14 is treated at low temperature (25° to -30° C.) with a dry ethereal solution of chloramine. The reaction is stirred for a period of several minutes to several hours. After filtration, the reaction mixture is washed with aqueous bisulfite, dried and the solvent removed on a rotary evaporator. The crude product is further purified by usual methods such as crystallization or chromatography.

In the reaction shown in Equation 8, a thienylcopper compound of Formula 15 is reacted with an iodo- or bromoheterocycle (X(CH₂)nQ where X is I or Br and n is 0, 1 or 2) in a solvent such as pyridine or quinoline. The copper compounds of Formula 15 are prepared by reacting the corresponding lithium compounds with cuprous iodide or cuprous bromide in a solvent such a diethyl ether. The detailed procedures for this type of reactions are described in the following references: M. Nilsson and C. Ullenius, Acta Chem. Scand. 1970, 24, 2379-2388; C. Ullenius, Acta Chem. Scand. 1972, 26, 3383-3386.

EQUATION 8 ##STR23## Treatment of the compounds of Formula 16 with an acid catalyst in an alcohol solvent or in trifluoroacetic acid removes the t-butyl group to yield compounds of Formula 2 as shown in Equation 9. EQUATION 9 ##STR24##

In the syntheses outlined above, the generalized designation of compounds of Formula I is meant to imply the (CH₂)_(n) Q substituents and the sulfonylurea functional group are bonded to the thiophene ring in adjacent positions corresponding to one of the three possible combinations designated as Formulae Ia, Ib, or Ic in the summary of the invention. It will be convenient for purposes of expediency and clarity of this teaching to use this generalized formula further in this disclosure. All values of Q, n, N', R, R₁, R₂, R₃, R₃ ', R₃ ", R₄, R₅, R₆, R₇, R₈, R₉, R₁₀, R₁₁, n', W, W', W", A, X, Y, and Z are those described in the summary of the invention unless otherwise noted.

The heterocyclic thiophenesulfonamides of Formula 2 are important starting materials for the preparation of compounds of Formula I of this invention and specific examples are prepared by the following methods.

In the specific case where Q is Q-1 and n is O, compound 17 can be prepared by the reaction sequence shown in Equation 10.

EQUATION 10 ##STR25##

In this synthetic sequence, a 1-phenylpropyne of Formula 18 is metallated with excess base. Addition of carbon disulfide leads to a phenyl-substituted ketene dithiolate, which undergoes intramolecular cyclization to give 19 after proton quenching. The conditions necessary for this transformation are described by R. L. P. DeJong and L. Brandsma, J. Organometal. Chem. 1982, 238, C17. Mild oxidative chlorination of 19 leads to a sulfonyl chloride of Formula 20, which is converted to the sulfonamide 17 by treatment with ammonia in THF solution at temperatures of -35° to 25° C.

Alternatively, 17 can be prepared by route of Equation 11. 3-Phenylthiophene 21 reacts with n-butyllithium in diethyl ether at 25° C. for 0.5 hour to form lithiated intermediates which may be quenched using sulfuryl chloride. The resultant sulfonyl chlorides 20 and 20a then are treated with ammonia in THF solution as before to give 17 and isomeric 17a. The desired 17 can be isolated by chromatographic techniques known by one skilled in the art. Metallation of 21 has been described by R. Teardini, G. Martelli, P. Spagnolo, and M. Tiecco J. Chem. Soc., C. 1970, 1464. For further details, cf. Equation 13.

EQUATION 11 ##STR26##

Other useful intermediates are known in the art. 2-Phenyl-3-bromothiophene (Q-1, n is O) may be prepared by the procedure of N. Gjoca and S. Gronowitz Acta chem. Scand. 1972, 26, 1851; 3-bromo-2,2'-bithiophene (Q-2, W' is S, n is O) and 3-bromo-2,3'-bithiophene (Q-3, W' is S, n is O) by the procedure of, for instance, S. Gronowitz, J. Skramstad and B. Eriksson, Ark. Kemi 1967, 28, 99.

When n is 1 or 2, application of organocopper methodologies known to one in the art yield substituted thiophenes of Formula 21a, as shown in Equation 11a. Thus, a dithienylcopperlithium of Formula 21b can be reacted with alkylhalides of Formula H to yield 21a; conversion to sulfonamide 17b can be accomplished by means of Equation 11.

EQUATION 11a ##STR27##

For the isomeric compounds of Formula 17b with generic structures of Formulae 2b and 2c, similar chemistry as in Equation 11a beginning with 2,3-dibromo- or 3,4-dibromothiophene will provide the requisite intermediates.

Equation 12 describes the synthesis of 3-(2-furanyl)- and 3-(2-thienyl)thiophenes of structure 24 (Q-2, n is 0).

EQUATION 12 ##STR28##

According to the work described by H. Wynberg, A. Logothetis, and D. Verploeg J. Am. Chem. Soc. 1957, 79, 1972, 2-lithiofuran or 2-lithiothiophene is added to 3-ketotetrahydrothiophene in diethyl ether at a temperature of 0° C. The reaction is quenched with and distilled from sulfuric acid to afford 3-substituted dihydrothiophenes of Formula 22, which are dehydrogenated using 2,3-dichloro-5,6-dicyano 1,4-benzoquinone (DDQ), giving thiophenes of Formula 23. These thiophenes can be metallated in the 2-position selectively and can be added to sulfuryl chloride in hexane solution, resulting in sulfonyl chlorides of Formula 24a which are converted into the desired sulfonamides 24 by treatment with ammonia in THF solution.

For those cases in which n is 1 or 2, a procedure entirely analogous to that of Equation 12 may be used, beginning with Q-2 synthons of Formula 200 (available commercially or obtained by methods obvious to one skilled in the art); ##STR29## compounds of Formula 24b ultimately will be produced ##STR30##

Starting with the appropriate 3-substituted thiophene and following the metallation procedure indicated in Equation 12 or simple modifications thereof, one skilled in the art may prepare many of the sulfonamides of Formula 2a. Only those 3-substituents which are inert to metallating reagents relative to the desired 2-metallation of the thiophene nucleus are compatible with this synthetic strategy; such substituents will be obvious to one skilled in the art.

In complement to the metallation-sulfonation sequence illustrated by Equation 12, equivalent metallation-sulfination may be performed to obtain the sulfonamides of Formula 2a. The latter sequence is described by Equation 13 and is entirely analogous to that of Equation 7.

EQUATION 13 ##STR31##

Once sulfinate salts of Formula 26 have been made, they may be transformed into sulfonamides 2a directly by reaction with chloramine as described by G. H. Coleman and C. R. Hauser J. Am. Chem. Soc. 1928, 50, 1193. Sulfinate salts of Formula 26 also may be converted to 2a in a two-step process: chlorination to afford a sulfonyl chloride, as practiced by J. F. Sculley and E. V. Brown J. Org. Chem. 1954, 19, 894; W. E. Trull and E. Wellisch J. Am. Chem. Soc. 1952, 74, 5177 and Y. K. Yuriev and N. K. Sadavaya J. Gen. Chem. USSR 1964, 34, 1814 and treatment of that sulfonyl chloride with ammonia in an ethereal solvent such as THF. Any of these procedures also are compatible with those sulfinate salts of Formula 14 generated via Equation 7.

The use of the strategy of Equation 7 is especially appealing in those cases where metallation of the 3-substituted thiophene of Formula 25 in the 2-position is not possible due to the reactivity of the (CH₂)_(n) Q substituent under the conditions of metallation. Formation of the 2-brominated thiophene 27 allows for exceedingly facile, mild halogen-metal exchange conditions to be used, as shown in Equation 14.

EQUATION 14 ##STR32##

Electrophilic aromatic bromination of 3-substituted thiophenes of Formula 25 leads to the 2-brominated compound of Formula 27 selectively, as shown in the teachings of S. Gronowitz, P. Moses and A. B. Hornfeldt Ark. Kem. 1962, 17, 165. Subsequent halogen-metal exchange and sulfination with sulfur dioxide gives the sulfinate salt 26 or sulfonation with sulfuryl chloride leads to the sulfonyl chloride 28.

In still other cases where (CH₂)_(n) Q will suffer addition of most nucleophiles, (CH₂)_(n) Q can be placed at the 3-position of the thiophene nucleus after the sulfonamide moiety or its synthetic equivalent has been incorporated at the 2-position. This strategy is shown in Equation 15.

EQUATION 15 ##STR33##

2,3-Dibromothiophene, 29 can be lithiated preferentially at the 2-position and treated with sulfuryl chloride to give the sulfonyl halide 30. Treatment with tert-butylamine results in the tert-butyl-protected sulfonamide of Formula 31. A second lithiumhalogen exchange reaction allows for an addition of the substituent (CH₂)_(n) Q, which may be added as an intact entity or as a synthetically equivalent substructure.

Given the general techniques of Equations 12 through 15, sulfonamides of Formula 2a may be prepared by the methods described below.

Compounds of Formula 35 can be prepared by use of the reaction sequence illustrated in Equation 16.

EQUATION 16 ##STR34##

3(3-Furanyl)- and 3(3-thienyl)-2-bromothiophenes of Formula 33 may be prepared from the methods of Y. Tamaru, Y. Yoshimi and Z. Yoshida, Tetrahedron 1979, 35, 329 or straightforward modifications thereof. By route of Equation 14 sulfonyl chlorides of Formula 34, and consequently sulfonamides 35, are obtained.

Using the procedure of C. Ullenius, Acta. Chem. Scand. 1972, 26, 3383 and M. Nilsson and C. Ullenius, Acta. Chem. Scand. 1970, 24, 2379 compounds of Formula 36 (Q-2, W=O, n=0) and 37 (Q-3, W=O, n=0) can be prepared as shown in Equation 17. For those cases in which n is 1 or 2, straightforward modification of Equation 17 using the appropriate furanylcopper species will result in the desired thienylbromide of Formula 37a. ##STR35##

EQUATION 17 ##STR36##

Sulfonamides containing a tetrahydrofuran or tetrahydrothiophene group (Q-4, Q-5, Q-6, W'=O, S) can be prepared by catalytic reduction of the corresponding furan or thiophene compounds as shown in Equation 18.

EQUATION 18 ##STR37##

Selective reductions of the type shown in Equation 18 are well known in the literature. The choice of catalyst, solvent, pressure and temperature for reduction of furans has been reviewed by Samuel Sevadesh in "The Furans" by A. P. Dunlop and F. N. Peters, Reinhold Publishing Corporation, New York, N.Y. 1953, pp. 674-713; and by P. N. Rylander in "Catalytic Hydrogenation in Organic Synthesis"; Academic Press, 1979, pp. 227-234. The reduction of thiophenes is reviewed by H. D. Hartough in "Thiophene and Its Derivatives"; The Chemistry of Heterocyclic Compounds Series, Interscience Publishers, Inc., New York, N.Y. 1952, pp. 167-169.

Compounds of Formula 42 can be prepared as shown in Equation 19.

EQUATION 19 ##STR38## wherein ##STR39##

According to Equation 19, a lithiothiophene is reacted with lactone L at -78° to 0° C. in an ethereal solvent such as THF to form lactol 43. The lactol may be dehydrated using a strong acid such as sulfuric acid to form the thiophene of Formula 44. 44 may be lithiated by the route of Equation 13, Using n-butyllithium as lithiating agent and diethyl ether as solvent at a temperature of about 0° C. Quenching of the reaction gives lithium sulfinates of Formula 45, which are isolated by evaporation of the reaction solvent. The sulfinate is treated with chloramine to yield 42. If desired, selective hydrogenation will yield compounds of Formula 46 (R₄ ═H).

3-(2-Tetrahydrofuranyl)- and 3-(2-tetrahydrapyranyl)thiophenes of Formula 46 also can be prepared as illustrated in Equation 20.

EQUATION 20 ##STR40## wherein ##STR41##

Reaction of a lithiothiophene with haloaldehydes of Formula 47 in inert solvents such as THF at temperatures of -78° to 25° C. affords thienylalkoxides which undergo intramolecular cyclization yielding cyclic ethers 48. These in turn are converted to sulfonamides 46 via the methods of Equation 13: metallation in diethyl ether with n-butyllithium at a temperature of ca. 0° C., followed by sulfination using sulfur dioxide gives lithium sulfinate 49. 49 in turn is treated with chloramine to give the target compound 46.

Sulfonamides of Formula 50 are prepared in a manner analogous to that of Equation 12, as shown by Equation 21.

EQUATION 21 ##STR42## wherein ##STR43##

A lithiothiophene reacts with ketones of Formula K to give, after proton quench, tertiary alcohols of Formula 51. 51 is dehydrated, using a strong acid such as trifluoroacetic acid, resulting in compounds of Formula 52 as mixtures of double bond isomers that are selectively hydrogenated to give 53. Bromination using N-bromosuccinimide in acetic acid for ca. 1 hour at ambient temperatures results in bromides of Formula 54; these bromides undergo halogen-metal exchange as described in Equation 14 to lead to sulfonamides of Formula 50.

Compounds of Formula 56 (Q-7, n is O) can be prepared as shown in Equation 22 by the reaction of the sodium salt of pyrrole with the bromothiophenesulfonamide in DMF with copper oxide catalyst.

EQUATION 22 ##STR44## Alternatively, a 2-aminothiophene-3-sulfonamide can be prepared and reacted with 1,4-dicarbonyl compounds to give substituted compounds of Formula 60 as shown in Equation 23. EQUATION 23 ##STR45##

The tert-butyl sulfonamide of Formula 57 is treated with two equivalents of n-butyllithium at -50° to 80° C. in tetrahydrofuran to give the dilithio salt 58 by analogy with the teaching of J. G. Lombardion, J. Org. Chem., 1971, 36 1843. Treatment of 58 with tosylazide followed by reduction with sodium borohydride gives the aminothiophenesulfonamide 59 by the procedure of J. N. Reedy and V. Smeckus Tetrahedron Lett. 1983, 3795. Condensation with a 1,4-dicarbonyl compound gives the compound of Formula 60. Removal of the t-butyl group affords the free sulfonamide.

3-(1-Pyrrolyl)thiophene 61 can be synthesized by the methods of V. Effi, M. Cugnonde Sevricourt, S. Rault and M. Robba, Heterocycles 1981, 16, 1519. Its conversion to the sulfonamide 62 is described in Equation 24.

EQUATION 24 ##STR46##

Selective 2-bromination of 61 may be performed by the use of NBS in acetic acid at temperatures of around 0° to 25° C. for 1 hour, resulting in compound of Formula 63. Using the process described in Equation 14, halogen-metal exchange in THF at -78° C. and quenching with sulfur dioxide gives lithium sulfinate 64. Amination using chloramine subsequently yields the sulfonamides of Formula 62.

Compounds of Formula 61a can be prepared using the route of Equation 24a.

Equation 24a ##STR47##

Compounds of Formula 61b are prepared according to Equation 24b. ##STR48##

Both 61b and 61a may be converted to sulfonamides of Formula 62a by means of Equation 24. ##STR49##

The thiophene of Formula 70 (Q-9, n is 0) can be prepared as shown in Equation 26.

EQUATION 26 ##STR50##

The condensation reaction of Equation 26 is well known in the art and has been reviewed by A. R. Jones and G. P. Bean in "The Chemistry of Pyrroles"; Academic Press, New York, N.Y. 1977. 3-(1-Methylpyrrol-3-yl)-thiophenes of Formula 71 may be synthesized according to Equation 27.

EQUATION 27 ##STR51##

In a reaction similar to Equation 12, a lithiothiophene attacks the 1-methyl-3-pyrrolidinone, 72, in THF solution at temperatures of -78° to 0° C., resulting in tertiary alcohol 73. Dehydration of 73 by a strong acid such a trifluoroacetic acid results in dehydration products of Formula 74 as a mixture of regioisomers. Dehydrogenation of 74 in hot DMF with sulfur yields 71. Compounds of Formula 71 are converted to the respective sulfonamides of Formula 75 by route of the methods of Equation 14. ##STR52##

Certain methods of synthesis leading to the intermediate sulfonamides of this invention are similar for many values of Q in each of the three possible isomeric arrangements. ##STR53## It will be convenient to use the following generalized formulas in this disclosure when certain synthetic methods are applicable to all the necessary isomers.

In the outlined synthesis below, the use of X¹ and another substituent on the thiophene ring in undesignated positions is meant to imply that the values indicated are in adjacent positions and that when X¹ is in the 2-position, it is hydrogen and when in the 3-position it is bromine.

An example showing the preparation of certain (5-isoxazolyl)thiophenes of Formula 76 (Q-10, W"=O, n is 0) is shown in Equation 28.

EQUATION 28 ##STR54## wherein X' is 2-H or 3-Br ##STR55##

The lithiothiophene is reacted with an acylchloride in THF solution at temperatures of -78° to 25° C., yielding ketones of Formula 77. Treatment of these ketones with dimethyl alkanamide dimethylacetals in solvents such as toluene or DMF at temperatures of 50° to 140° C. for a period of 3 to 24 hours results in β-amino α,β-unsaturated ketones of Formula 78. Details of this class of reactions may be found in Technical Information Bulletin, "DMF Acetals"; Aldrich Chemical Co., December 1973 and Y. Lin and S. A. Lang, J. Org. Chem. 1980, 45, 4857. 78 is treated with hydroxylamine hydrochloride in solvents such as ethanol or aqueous 1,4-dioxane at temperatures of 25° to 100° C. for 1 to 48 hours and the product 76 is isolated by addition of water to the reaction medium and extraction into methylene chloride. Similar procedures are described by Y. Lin and S. A. Land, J. Heterocycl. Chem. 1977, 14, 345. Compounds of Formula 76 can be converted to the appropriate sulfonamides of Formula 79, by the procedures of Equation 13. ##STR56##

For those cases where n is 1 or 2, a modification of Equation 28 may be employed to yield sulfonamides of Formula 79a. Equation 28a illustrates this modification.

EQUATION 28a ##STR57##

The appropriate lithiothiophene is reacted with an alkyl bromide of Formula K to give the thienylketals of Formula 77a. Transketalization using acetone and anhydrous copper (II) sulfate yield ketones of Formula 77b, which are converted to isoxazoles of Formula 76d in a manner entirely analogous to that described for Equation 28. The compounds of Formula 76d are converted to the appropriate sulfonamides of Formula 79a by the procedures of Equation 13. ##STR58##

Similarly, 5-isothiazolylthiophenes (Q-10, W'=S, n is 0) of Formula 80 can be synthesized from the thioanalogoues of 78, as shown by Equation 29; those isothiazolylthiophenes (Q-10, W'=S, n is 1 or 2) of Formula 80a can be prepared in a similar fashion, as illustrated in Equation 29a.

EQUATION 29 ##STR59## wherein X' is 2-H or 3-Br. EQUATION 29a ##STR60##

Compounds of Formula 78 can be treated with phosphorous oxychloride in methylene chloride at 0° to 30° C. for 0.2 to 2 hours and followed by addition of sodium perchlorate in water at 0° to 10° C. for 0.2 to 1 hour to form perchlorate salts of Formula 81. Subsequently, 81 can be reacted with sodium sulfide monohydrate in DMF and water at 0° to 10° C. for periods of 0.2 to 1 hour to form thiones of Formula 82. Finally, these thiones will react with hydroxylamine-O-sulfonic acid and 2 equivalents of pyridine in methanol at temperatures of 20° to 30° C. for 0.2 to 1 hour to give 80. Thiophenes 80 and 80a may be converted to sulfonamides of Formula 83 and 83a by route of Equation 13. ##STR61##

The preparation of thiophenes of Formula 84 (Q=Q-11, W" is NR₁₁) and 85 (Q=Q-10, W" is NR₁₁) is illustrated in Equation 30.

EQUATION 30 ##STR62##

The α,β-unsaturated ketones of Formulae 78 and 78a from EQUATION 28 and 28a can be reacted with hydrazines in refluxing ethanol for periods of 1 to 16 hours. The product mixture of thiophenes of Formulae 84 and 85 are isolated by chromatographic methods which are well known to those skilled in the art. Conversion of either 84 or 85 to the corresponding sulfonamides of Formulae 86 and 87 proceeds by way of the processes described in Equation 14. ##STR63##

Equation 31 depicts the synthesis of 3-(3-isoxazolyl)thiophenes of Formula 91.

EQUATION 31 ##STR64##

The 3-thienylaldehyde is reacted with hydroxylamine hydrochloride in ethanol to form oximes of Formula 88. These oximes are chlorinated by means of N-chlorosuccinimide (NCS), yielding chlorides of Formula 89 which, when reacted with vinyl acetates in the presence of one molar equivalent of triethylamine, undergo addition-cyclization to form acetates of Formula 90. Oxidative extrusion of acetic acid in hot DBU transforms 90 into thiophenes of Formula 91. Conversion to sulfonamides of Formula 92 can be accomplished by application of the chemistry described by Equation 13. ##STR65##

Equation 32 below illustrates a method for preparing 3-(3-bromothienyl)isoxazoles of Formula 93.

EQUATION 32 ##STR66## where R₃ =H.

The reaction of Equation 32 is run by procedures similar to those taught by M. Lanella et al., Chim. Ind. (Milan) 1965, 47, 996 and by G. Gaudiano et al., Gazz. Chim. Ital. 1959, 89, 2466. Thus, a 3-bromo-2-thiophenehydroxamic acid chloride of Formula 94 is reacted with an appropriate acetylenic Grignard regent in tetrahydrofuran at 0° to 30° C. for 1 to about 16 hours. The product is isolated by addition of water and ammonium chloride and extraction with methylene chloride. The acetylenic Grignard reagents are prepared from substituted acetylenes by procedures described in the cited references.

Another method of preparation of compounds of Formula 93 is shown in Equation 33.

EQUATION 33 ##STR67##

The reactions of Equation 33 above can be run by procedures similar to those described in G. Bianchetti et al., Gazz. Chim. Ital. 1963, 93, 1714. Thus, in Equation 33, 94 is reacted with an equimolar amount of triethylamine and a N-alkenylmorpholine in chloroform at reflux for 0.2 to about 1 hour to form a 5-(N-morpholino)-3-substituted-isoxazoline of Formula 95, which then is reacted with 10% hydrochloric acid at reflux for about 0.2 to 0.5 hour to from 93. The product 93 is isolated by extraction with methylene chloride.

Similarly, a reaction of the hydroxamic acid chloride with a vinyl acetate rather than an enamine can yield compounds of Formula 93 by the procedure of R. Micetich. Can. J. Chem. 1970, 48, 467.

(3-Isothiazolyl)thiophenes of Formula 96 can be prepared according to Equation 34.

EQUATION 34 ##STR68##

In Equation 34, the cyanothiophene can be reacted with an appropriate alkyl nitrile and sodium in a solvent such as ether or toluene at 0° to 80° C. for approximately 5 to 25 hours, forming mononitriles of Formula 97. Similar transformations may be found in U.S. Pat. No. 3,479,365. Netherlands 6,608,094 and T. Naito, S. Nakagawa, J. Okumura, K. Takahashi, K. Masuka and Y. Narita, Bull. Chem. Soc. Japan 1968, 41, 965. 97 can be reacted with hydrogen sulfide in the presence of a catalytic amount of potassium hydroxide in methylene chloride at -60° to 80° C. in a sealed vessel for 24 to 96 hours to give iminothioamides of Formula 98. Such a reaction parallels the work of T. Naito, S. Nakagawa and K. Takahashi, Chem. Pharm. Bull. 1968, 16, 148 and J. Goerdeles and H. Pohland, Chem. Ber. 1961, 94, 2950. Compounds of Formula 98 are cyclized by treatment with iodine in ether, chloroform or ethanol solution with potassium carbonate used as base at temperatures of 20° to 40° C. for 0.5 to 4 h, giving amines of Formula 99 in a manner similar to ibid., Netherlands 6,608,094 and J. Goerdeler and H. Pohland, Angew. Chem. 1962, 72, 77. Diazotization of 99 by nitrous acid generated in situ and reaction of the resultant diazonium salt with copper(II) oxide in 50% phosphoric acid at 0° C. for 2 hours followed by optional selective metallation and alkylation forms 96, in analogy to M. Beringer, B. Prijs and H. Erlenmeyer, Helv. Chim. Acta 1966, 49, 2466. Conversion to the corresponding sulfonamide 100 is accomplished using the synthetic scheme described in Equation 13. ##STR69##

As shown in Equation 35 below, (3-bromothienyl)isoxazoles of Formula 101 (Q-12, W" is O) can be prepared by reacting compounds of Formula 102 with hydroxylamine hydrochloride.

EQUATION 35 ##STR70##

The reaction of Equation 35 is run in ethanol at 25° to 80° C. for 3 to 16 hours. The product is isolated by addition of water and extraction with methylene chloride. The product is purified by recrystallization or column chromatography. The starting materials are prepared by known methods, e.g., V. Hengartner et al., J. Org. Chem., 1979, 44, 3748. For compounds of Formula 101a with substituents on the isoxazole ring, the reactions of Equation 36 illustrate a procedure similar to those described by H. Yasuda, Yakugaku Zuschi, 1959, 79, 623 and Bobranski and Wojtowski, Roczniki Chem., 1964, 38, 1327.

EQUATION 36 ##STR71##

4-Substituted isothiazoles of Formula 105 can be prepared in a manner analagous to that of Equation 29, beginning with those compounds of Formula 102. Subsequent conversion to sulfonamides of Formula 106 can be achieved by means of Equation 8. ##STR72##

(1-Methylpyrazol-4-yl)thiophenes of Formula 107 (n=0) are prepared by the teachings of S. Liljefors and S. Gronowitz. Chem. Scr. 1979, 15, 102. The respective sulfonamides of Formula 108 may be synthesized by the methods described in Equation 8. When n is 1 or 2, the thiophenes of Formula 107, and their respective sulfonamides 108 are prepared in an analogous manner. ##STR73##

Equations 37 and 38 illustrate the preparation of (2-oxazolyl)thiophenes of Formula 109. Details of these preparations may be found in W. E. Cass, J. Am. Chem. Soc. 1942, 64, 785 and "Heterocyclic Compounds"; Vol. 5, R. C. Elderfield, Ed. J. Wiley and Sons, NY, 1957, Ch. 5.

EQUATION 37 ##STR74## wherein R₃ and R₄ are H. EQUATION 38 ##STR75##

Thiophenes of Formula 109 can be converted to the corresponding sulfonamides of Formula 112 by the methods described in Equation 13. ##STR76##

(2-Thiazolyl)thiophenes of Formula 113 can be prepared by the procedure of Equation 39.

EQUATION 39 ##STR77## For details concerning the synthetic methods involved, see ibid. Conversion to sulfonamides of Formula 114 is accomplished using the techniques illustrated in Equation 13. ##STR78##

(1-Methylimidazol-2-yl)thiophenes of Formula 115 can be prepared by the method shown in Equation 40.

EQUATION 40 ##STR79##

A condensation reaction between the thienylaldehyde, an α-diketone and an excess of an amine leads to imidazoles of Formula 115. For detailed discussion of such reactions, cf. ibid., Ch. 4, 5 and 8. Sulfonamides of Formula 116 can be prepared from 115 by means of Equation 13.

Equations 41, 42 and 43 show the synthetic approaches that can be taken to generate (5-oxazolyl)thiophenes of Formula 117.

EQUATION 41 ##STR80## EQUATION 42 ##STR81## EQUATIONS 43 ##STR82## wherein R₃ and R₄ are H and ##STR83##

Details of the reactions depicted in Equations 39 and 40 are found in ibid., Ch. 5. The procedural details for Equation 41 are described by A. M. Van Leusen, B. E. Hogenboom and H. Serderius, Tetrahedron Lett. 1972, 2369. Compounds of Formula 118 are available by a route identical to or closely resembling the preparation of compounds of Formula 103 and subsequent bromination of the appropriate methylene moeity; details of such brominations have been recorded by S. Gronowitz. Ark. Kem. 1958, 13, 295. α-Hydroxyketones of Formula 119 in Equation 42 may be prepared from the appropriate thienylcarboxylic acid chlorides and appropriate 1,1,2,-tris[(trimethylsilyl)oxy]alkenes; cf. A. Wissner, J. E. Birnbaum and D. E. Wilson, J. Med. Chem. 1980, 23, 715. In all cases, transformation to sulfonamides of Formula 120 can be accomplished via Equation 13. ##STR84##

The analagous (5-thiazolyl)thiophenes of Formula 121 are prepared according to the process indicated in Equation 44, which is a straight-forward modification of Equation 41, above. Like synthons of Formula 117, those Formula 121 are converted to sulfonamides of Formula 122 by means of Equation 13.

EQUATION 44 ##STR85##

(5-Imidazolyl)thiophenes of Formula 123 are prepared according to Equation 45.

EQUATION 45 ##STR86##

Reaction of the appropriate α-haloketone of Formula 119 with an amidine yields imidazoles of Formula 123 with R₁₁ =H. N-alkylation may be achieved using common procedures, evident to those skilled in the art, to give compounds of Formula 123 and 124. Sulfonamides of Formula 125 and 126 are prepared via Equation 14. ##STR87##

(4-Oxazolyl)thiophenes of Formula 127 can be prepared by procedures analogous to those described in Equations 41 to 42; substituent limitations and sulfonamide preparation to give compounds of Formula 128 via Equation 13 remain the same. ##STR88##

An alternative synthesis of the oxazoles of Formula 127 is shown in Equation 45a. It is analogous to that shown in Equation 41.

EQUATION 45a ##STR89## wherein B=C₁ -C₃ alkyl, amino.

In the case where B=amino for compounds of Formula 127b, Sandmeyer-type reaction conditions afford new 2-substituted oxazoles, as shown in Equation 45b.

EQUATION 45b ##STR90##

The (4-thiazolyl)thiophenes of Formula 129 are prepared in a manner analogous to that shown in Equation 45 using the thioamide of Equation 44. These thiazoles are transformed into sulfonamides of Formula 130 using the method of Equation 7. Analogously, the procedures using Equations 45a and 45b also will give thaizoles of Formula 129. ##STR91##

Compounds of Formula 131 or 132 (Q-16, W'=O) can be prepared by the procedures of the example shown in Equation 46.

EQUATION 46 ##STR92## The formation of the 1,3-oxazolines of Equation 46 are prepared by heating the carboxylic acid and the appropriate amino alcohol in toluene to remove water by the procedure of H. L. Wehrmeister, J. Org. Chem., 1961, 26, 3821. The product oxazoline 133 or 131 can be lithiated with n-butyllithium in ether solvent. Treatment with SO₂ and conversion to compounds of Formula 132 is carried out by the procedures outlined in Equation 13 or as shown in Equation 46 by oxidation of the sulfinate salt with NCS (N-chlorosuccinimide) followed by amination using NH₃.

Synthesis of intermediate oxazolines, thiazolines and imidazolines where Q is Q-16 (W is S), Q-17 and Q-41 can be prepared by procedures similar to Equation 46 or by methods known in the art. ##STR93## For supplementary methods see:

R. C. Elderfield, op. cit.

R. J. Fern and J. C. Riebsomer, Chem. Rev. 1954, 54, 543.

R. H. Wiley and L. L. Bennett, Jr., Chem. Rev. 1944, 44, 447.

Compounds of Formula 134 (Q-18, n is 0) can be prepared by the procedure of S. Gronowitz and S. Liljefors, Chem. Scr. 1979, 13, 157 as shown in Equation 47.

EQUATION 47 ##STR94## According to Equation 47, a bromothiophene is reacted with the sodium salt of a pyrazole in pyridine containing a copper catalyst. The thienylpyrazole is lithiated and can be reacted with sulfuryl chloride by the procedures of S. N. Bhattacharya et al., J. Chem. Soc., C, 1968, 1265 to give compounds of Formula 134.

In those cases for Q-18 where n=1 or 2, the appropriate thiophenes of Formula 134c are prepared according to Equation 47a.

EQUATION 47a ##STR95##

Conversion to the sulfonamides of Formula 134d is accomplished in a way identical to that shown in Equation 13.

In an analogous manner, compounds of Formula 135 or 136b (Q-19) can be prepared by the procedures shown in Equations 48 and 49.

EQUATION 48 ##STR96## EQUATION 49 ##STR97##

The reactions are conducted in the presence of the appropriate solvent such a dimethylformamide. N-methylpyrolidone, THF or pyridine at temperatures from ambient to reflux for a period of one to twenty-four hours.

Equation 50 indicates the synthesis of thiophenes of Formula 137, bearing a Q-20 substituent.

EQUATION 50 ##STR98##

A chloride of Formula 138, when reacted with hydrazine, will result in a hydrazide of Formula 139. According to U.S. Pat. No. 3,808,223, reaction of 139 with an orthoester at 100° to 150° C. for 5 to 24 hours will yield oxadiazoles of Formula 140. Deprotection of the sulfonamide moiety using a strong acid such as trifluoroacetic acid results in the desired sulfonamides of Formula 137. Synthesis of the starting thiophenes of Formula 138 can be accomplished by the methods taught in European Patent Application No. 30,142.

Equation 50a illustrates the preparation of thiophenes of Formula 137a where R₃ is SR₁₂.

EQUATION 50a ##STR99## wherein R₁₂ =C₁ -C₄ alkyl, C₃ -C₄ alkenyl, C₃ -C₄ alkynyl, C₁ -C₃ cyanoalkyl, methoxycarbonylmethyl, ethoxycarbonylmethyl, methylcarbonylmethyl, or halogen.

The reactions of Equation 50a are run according to similar procedures described in E. Hoggarth, J. Chem. Soc. 4811 (1952). Thus, the hydrazide is reacted with carbon disulfide in ethanol in the presence of a base, such as potassium hydroxide at reflux for 4-16 hours, followed by addition of water and acidification with hydrochloric acid to form compound 140a. Further reaction of compound 140a with R₁₂ I in ethanol in the presence of base gives compound 137a.

Compounds of Formula 141 (Q-21, W'=O) are prepared by the procedure of P. DuBus, B. Decroix, J. Moreland and P. Pastour, Ann. Chim. (Paris) 1975, S14 t10, p 331 as shown in Equation 51.

EQUATION 51 ##STR100##

Compound 142 is reacted with excess triethylorthoformate at 100° to 150° C. for 1 to 24 hours to afford 141 (R₃ "=H). R₃ " may be optionally substituted with Cl or Br by selective deprotonation and quenching with NCS or NBS, respectively.

For R₃ "=CH₃. Compound 142 is reacted with acetylchloride and BF₃.Et₂ O according to U.S. Pat. No. 3,270,029.

Analogously, 1,3,4-thiadiazol-5-ylthiophenes of Formula 143 may be prepared following the techniques described by C. Ainsworth and R. G. Jones, J. Am. Chem. Soc. 1955, 77, 621 and H. Weidinger and J. Kranz, Ber. 1963, 96 1059. ##STR101##

Equation 52 illustrates the preparation of 1,2,4-thiadiazol-3-ylthiophenes of Formula 144.

EQUATION 52 ##STR102##

The reactions of Equation 52 may be run following similar methods found in J. Goerdeler and M. Budnowski, M. Chem. Ber. 1961, 94, 1682. Thus, an amidine of Formula 145, obtained via the corresponding carboxylate is treated with dichloromethylsulfenyl chloride and sodium hydroxide in a solvent such as aqueous 1,4-dioxane at temperatures of about 0° C. for 0.2 to 11 hours to form thiophene of Formula 146. Deprotection with a strong acid affords sulfonamide of Formula 144.

Y. Lin, S. A. Land, M. F. Lovell and N. A. Perkinson, J. Org. Chem., 1979, 44, 4160 indicate methods for the formation of 1,2,4-oxadiazol-5-yl-thiophenes of Formula 148, as shown in Equation 53.

EQUATION 53 ##STR103##

An amide of Formula 149, available by amination of the corresponding carboxylate is reacted with an excess of an alkanamide dimethylacetal at 80° to 120° C. for 0.3 to 3 hours, forming compounds of Formula 150. These compounds can be dissolved in aqueous 1,4-dioxane-acetic acid and reacted with hydroxylamine at temperatures ranging between 25° to 90° C. over 0.5 to 3 hours to form oxadiazoles of Formula 151, which are subsequently (or perhaps concomitantly) deprotected using a strong acid to give sulfonamides of Formula 148.

In a strictly analogous manner, using conditions similar to those described by Equation 53, 1,2,4-thiadiazol-5-ylthiophenes of Formula 152 can be prepared: cf. Y. Lin and S. A. Lang, J. Org. Chem. 1980, 45, 3750. ##STR104##

The 1,2,4-thiadiazol-4-ylthiophenes of Formula 153 can be prepared by the teachings of U.S. Pat. No. 3,940,407 and C. D. Hund and R. I. Mori, J. Am. Chem. Soc. 1955, 77, 5359. Equation 54 illustrates this process.

EQUATION 54 ##STR105##

Ketones of Formula 154 react with ethyl carbazate to form the corresponding hydrazide; subsequent reaction with thionyl chloride results in compounds of Formula 155. Deprotection of these compounds using standard conditions leads to sulfonamides of Formula 153.

1,2,5-Thiadiazol-3-ylthiophenes of Formula 156 can be prepared from thiophenes of Formula 31 by several known methods, such as those of L. M. Weinstock, P. Davis, B. Handelsman and R. Tull, J. Org. Chem. 1967, 32, 2823; V. Bertini and P. Pino, Angew Chem. Int. Ed. Engl. 1966, 5, 514 and S. Mataka, A. Hosoki, K. Takahashi and M. Tashino, Synthesis 1979, 524. ##STR106##

The methyl-1,3,4-triazol-2-ylthiophenes of Formula 157 can be prepared by the method shown in Equation 55. ##STR107##

N-aminoamides of Formula 158 will react with isocyanates in solvents such as acetone or 2-butanone at reflux to afford adducts of Formula 158a. These in turn upon heating will cyclize with concomittant extrusion of water, yielding triazolones of Formula 159. Treatment with phosphorous pentachloride and phosphorous oxychloride at reflux gives 2-chlorotriazoles of Formula 160, which, upon treatment with a nuleophile R₃ 'M in a polar, aprotic solvent such as DMF, yields the substituted sulfonamide of Formula 157. Compounds of Formula 158 in turn are synthesized from the treatment of esters of Formula 161 with hydrazines. ##STR108##

Methyl-1,2,4-triazol-5-ylthiophenes of Formula 162 can be synthesized by the route shown in Equation 56.

EQUATION 56 ##STR109##

Y. Lin, S. A. Lang, M. F. Lovell and N. A. Perkinson, J. Org. Chem. 1979, 44, 460 have shown that reaction of a compound of Formula 150 with alkylhydrazines in acetic acid at temperatures of 50° to 90° C. for 0.5 to 2 hours will give triazoles of Formula 163. Deprotection to form sulfonamides of Formula 162 may be accomplished during cyclization, or may be removed afterwards by use of a strong acid.

Additionally, compounds of Formula 162 may be prepared in a manner analogous to that of Equation 55, using the appropriate cyanate or thiocyanate to give the required intermediate compounds of Formula 158b. ##STR110##

Methyl-1,2,4-triazol-3-ylthiophenes of Formula 164 where R₃ '=R₃ are produced by the techniques illustrated in Equation 57 and similar to those described by M. Atkinson and J. Polya, J. Chem. Soc. 1954, 3319.

EQUATION 57 ##STR111## The hydrazine of Formula 165 reacts with an anhydride at temperatures ranging from 25° to 100° C. for approximately 0.5 to 2 hours, forming triazoles of Formula 166. Standard deprotection affords sulfonamides of Formula 164. Hydrazine 165 may be prepared by reaction of nitrile 161 with alkylhydrazines.

Similar treatment of hydrazine of Formula 165 with diphenylcarbonate or phosgene will result in triazolones of Formula 166a, as indicated in Equation 57a. Conversion to sulfonamides of Formula 164b is performed in a manner analogous to that of Equation 57.

EQUATION 57a ##STR112##

1,2,4-Triazolylthiophenes of Formula 167 can be synthesized by the reaction sequence of Equation 58.

EQUATION 58 ##STR113## Similar to the preparation of thiophenes of Formula 134a, triazoles of Formula 170 can be formed by reaction of the bromothiophene of Formula 168 with a sodium 1,2,4-triazole salt of Formula 169. 170 then can be subjected to oxidative chlorination: amination of the intermediary sulfonyl chloride will result in sulfonamides of Formula 167.

Alternatively, sulfonamides of Formula 167 where R₄ =H can be prepared by the route illustrated in Equation 58a.

EQUATION 58a ##STR114##

3-Bromothiophene is coupled with the sodium salt of a 1,2,4-triazole of Formula 169 in refluxing DMF using copper(II) catalysis. The resultant biaryl of Formula 170a then is regioselectively lithiated at -100° C. using n-butyllithium in diethyl ether; quenching with an eletrophile, R₃ "X, results in biaryls of Formula 170b. Sulfonamidation of 170b in a manner analogous to that described in Equation 12 gives the desired 167.

Those cases where n is 1 or 2, the sodio salt of the appropriate triazole may be added to aldehydes of Formula 170c, which can be converted by means of Equation 58b to sulfonamides of Formula 167a.

EQUATION 58b ##STR115##

Compounds of Formula 171 can be prepared by reacting a 1-formyl-2-(3'-bromothienyl)hydrazine of Formula 172 with excess formamide at reflux for about 1 to 6 hours, according to the procedures described by C. Ainsworth et al., J. Med. Pharm. Chem. 1962, 5, 353 as shown in Equation 59 below.

EQUATION 59 ##STR116##

Alternatively, compounds of Formula 171 can be prepared from 2,3-dibromothiophene by reaction with the sodium salt of a 1,2,4-triazole of Formula 169 as shown in Equation 60.

EQUATION 60 ##STR117## The reaction can be run by the procedures described in Equations 47, 48, and 49.

Compounds of Formula 171 may also be prepared by a modified Ullmann reaction, according to the teachings of M. Kahn and J. Polya, J. Chem. Soc., C. 1970, 85.

Compounds of Formula 167a (Q-29) can be prepared by the procedures shown in Equation 61.

EQUATION 61 ##STR118##

The 2-amino-3-thiophene-t-butylsulfonamide 59, prepared by the procedures of Equation 23, is treated with N,N'-diacylhydrazine at 150° to 200° C. for 0.5 to 2 hours, according to methods known in the art, e.g., C. Ainsworth et al., op. cit. 1,3,4-Triazol-3-yl-thiophenes of Formula 167b are formed as shown in Equation 62. An aminothiophene of Formula 172 will react with diacylhydrazines at high temperatures (150° to 200° C.) over a period of ca. 0.5 to 2 hours to result in triazoles of Formula 173. Conversion of these triazoles to sulfonamides of Formula 167b can be accomplished as shown in Equations 58 and 61.

EQUATION 62 ##STR119##

In those cases where n is 1 or 2, a procedure entirely analogous to that of Equation 58b may be used to prepare sulfonamides of Formula 167e. ##STR120##

3-Pyridinylthiophenes of Formulae 174, 175 and 176 are available by the methods of H. Wynberg, T. J. Van Bergen and R. M. Kellogg, J. Org. Chem. 1969, 34, 3175. In the case of 177, sulfonamides of this Formula can be prepared by route of Equation 7; for sulfonamides of Formulas 178 and 179, preparation will be better achieved by way of Equation 14. ##STR121##

Pyridinylthiophenesulfonamides where n'=1 (pyridine N-oxides) can be prepared by treatment of the corresponding pyridinylthiophenesulfonamides with m-chloroperbenzoic acid in chloroform. The resulting N-oxide readily precipitates from solution.

In those cases where n is 1 or 2, a synthetic sequence similar to that depicted in Equation 58b will lead to the desired sulfonamides of Formulae 177-179.

3-Pyrimidin-2-ylthiophenes of Formula 180 are prepared according to the techniques described by S. Gronowitz and S. Liljefors, Acta Chem. Scand. 1977, B 31, 771 and straightforward modifications thereof. Sulfonamides of Formula 181 are formed by means of Equation 14. ##STR122##

3-Pyrimidin-4-ylthiophenes of Formula 182 are synthesized according to R. E. van der Stoel and H. C. van der Plas, J. Chem. Soc., Perkin I 1979, 2393. Conversion to sulfonamides of Formula 183 can be made by the synthetic sequence of Equation 14. ##STR123##

3-Pyrimidin-5-ylthiophenes of Formula 184 are available by use of the synthesis described by S. Gronowitz and S. Liljefors, Chem. Scr. 1978, 13, 39 and J. Org. Chem. 1982, 47, 3177 and modifications thereof. Again, the preparation of the corresponding sulfonamides of Formula 185 can be accomplished by means of Equation 14. ##STR124##

3-Pyrazinylthiophenes of Formula 186 are prepared by the method of J. Bourguignon, J.-M. Bouchy, J.-C. Clinet and G. Queguiner, C. R. Acad. Sci. Paris C 1975, 281, 1019. The synthesis of the sulfonamides of Formula 187 can be achieved by use of the route described in Equation 14.

3-Pyridazin-3-ylthiophenes of Formula 188 are available by the method described by J. Bourguignon, C. Becue and G. Queguiner, J. Chem. Res., Synop. 1981, 4, 104. Conversion to the sulfonamides of Formula 189 is accomplished by means of Equation 14. ##STR125##

3-(1,3,5-triazin-2-yl)thiophenes of Formula 190 can be prepared by the methods of J. K. Chakrabarti, R. W. Goulding and A. Todd, J. Chem. Soc., Perkin I 1973, 2499. The appropriate 1,3,5-triazines needed for the synthesis are described by Smolin, E. M. and Rapoport, L. "The Chemistry of Heterocyclic Compounds," Vol. 13, Wily-Interscience, NY. The corresponding sulfonamides of Formula 191 are formed by application of the chemistry described in Equation 14.

3-(1,2,4-triazin-3-yl)thiophenes of Formula 192 are available by a route essentially similar to the preparation of thiophenes of Formula 190, using the appropriate 1,2,4-triazines as made by the methods of A. Rybowski and H. C. van der Plas, J. Org. Chem. 1980, 45, 881. Again, the sulfonamides of Formula 193 are available by use of the synthetic procedure described in Equation 14. ##STR126##

3-(1,2,3-Thiadiazol-5-yl)thiophenes of Formula 195 can be prepared by a straightforward modification of the synthesis of 153 described by Equation 54, beginning with thiophenes of Formula 196. These thiophenes in turn are available from the corresponding ketones. ##STR127##

Compounds of Formula 2 where Q is Q-33, Q-34, Q-35, Q-37, Q-38, Q-39, Q-40, Q-43 and Q-44 can be prepared by the sequence of reactions outlined in Equations 8 and 9.

Pyrimidines and triazines of Formula 5 are necessary intermediates for the preparation of compounds of Formulas Ia, Ib and Ic of this invention. Such pyrimidines and triazines are either known compositions or may be prepared by methods obvious to those skilled in the art.

Agriculturally suitable salts of compounds of Formulas Ia, Ib and Ic can be prepared by a number of ways known in the art. For example, some such ways include (1) metal and quarternary ammonium salts made by treatment of compounds of Formulas Ia, Ib and Ic with solutions of metal or ammonium hydroxides, alkoxides or carbinates that are suffiently basic with respect to the substrates Ia, Ib and Ic; (2) cation exchange of those salts formed e.g. by (1) with an aqueous solution of a second cation; in particular, one whose resultant salt preferentially is sparingly soluble in aqueous solution and therefore precipitates from the solution; (3) cation exchange via passage through various cation exchange resins loaded with the cation to be exchanged; in particular, the exchange with cations whose resultant salts with Ia, Ib and Ic are water-soluble and (4) acid addition salts made by treatment of compounds of Formulas Ia, Ib and Ic with suitably strong acids such as trichloroacetic acid or p-toluenesulfonic acid.

The compounds described in this invention are further illustrated by the following Examples 1 through 6.

EXAMPLE 1 3-(3-Thienyl)-4,5-dihydro-5-acetoxyisoxazole

To an ice-cooled mixture of 100 g thiophene-3-carboxaldehyde, 100 mL methanol, 100 mL water, and 80 g hydroxylamine hydrochloride was added 50% aqueous NaOH to neutrality (ca. 40 mL). Methanol was removed by rotary evaporation and the mixture was extracted with ether. The ether extracts were washed with brine, dried (MgSO₄), and concentrated to afford 117 g of crude oxime. This was dissolved in 100 mL of DMF and 110 g of N-chlorosuccinimide was added in portions at 15° C. After the addition, the mixture was allowed to stir at 15° C. for 1 h, and then the cooling bath was removed. A rapid exotherm caused the temperature to rise to 50° C. and ice was immediately added to the reaction mixture, which then was partitioned between ether and water. The ether layer was washed several times with water, then washed with brine, dried (MgSO₄), and filtered.

Vinyl acetate (100 mL) then was added, and the solution was heated at reflux while adding a solution of 80 mL of triethylamine in 250 mL of ether over a 4 hour period. The mixture was cooled and filtered and the filter cake was washed several times with water and was air-dried. This material was combined with more product obtained by separating the filtrate, washing the Et₂ O layer with brine, drying (MgSO₄), and concentration and trituration with ether (total yield 88.6 g, mp 98°-99° C.).

EXAMPLE 2 3-(3-Thienyl)isoxazole

To a solution of 88.6 g of the dihydroisoxazole in 300 mL of methylene chloride was added 88 g of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) whereupon an exotherm caused the solvent to reflux. The solution was washed with aqueous HCl and with brine then was dried (Na₂ SO₄), concentrated, and distilled to afford 52 g of the isoxazole, bp 75°-80° C./1 mm.

EXAMPLE 3 '-(3-Isoxazolyl)-2-thiophenesulfonyl chloride

To a solution of the thienylisoxazole in 300 mL of ether was added 60 mL of n-butyllithium as a 1.6M solution in hexane at -78° C. under nitrogen. After stirring for 10 min at -78° C., liquid SO₂ (10 mL) was added and the mixture was allowed to stand overnight at room temperature. Filtration afforded the sulfinate salt which was hygroscopic. This was stirred in 100 mL of 50% aqueous acetic acid while adding 13 g of N-chlorosuccinimide in portions at 0° C. After stirring for 30 minutes at room temperature, the mixture was diluted with 200 mL of ice water, filtered, washed with ice water, and air dried to afford 20 g of sulfonyl chloride, mp 92°-92.5° C.

EXAMPLE 4 3-(3-Isoxazolyl)-2-thiophenesulfonamide

A solution of 19.5 g of the sulfonyl chloride in 150 mL of methylene chloride was saturated with gaseous ammonia and was stirred for 16 h at 25°. The precipitate was filtered and washed with CH₂ Cl₂, then with water and air-dried to afford 11.7 g of the title sulfonamide, mp 163°-164° C. Another 1.5 g of product was obtained by washing the CH₂ Cl₂ -soluble fraction with brine, drying (Na₂ SO₄), concentration, and trituration with ether.

EXAMPLE 5 3-(3-Isoxazolyl)-2-thiophenesulfonylisocyanate

A mixture of 10 g of the sulfonamide, 100 mL of 2-butanone, 6 mL of n-butyl isocyanate, and 5 g of potassium carbonate was heated at reflux for 1 h, then was concentrated, acidified with cold, aqueous HCl, and filtered. The solid was dissolved in CH₂ Cl₂, dried (MgSO₄) and concentrated to afford 12 g of the n-butyl urea. The butyl urea (11 g) was heated in 50 mL of xylene containing 0.2 g of 1,4-diazabicyclo[2.2.2]octane at 135° C. while adding a solution of 4 mL of phosgene in 6 mL of xylene over a 1 h period. The mixture was cooled, filtered, and concentrated to an orange oil which had a strong IR absorption at 2250 cm⁻¹ indicative of a sulfonylisocyanate. This oil (11 g) was dissolved in 40 mL of methylene chloride and was used for the next reaction.

EXAMPLE 6 N-[(4,6-Dimethyl-pyrimidin- 2-yl)aminocarbonyl]-3-(3-isoxazolyl)-2-thiophenesulfonamide

To 6 mL of the isocyanate/CH₂ Cl₂ solution (1.1 g of contained isocyanate) was added 0.4 g of 2-amino-4,6-dimethylpyrimidine in 5 mL of methylene chloride. The solvent was removed and the crude product was triturated with ether and filtered. Recrystallization from CH₃ CN/n-BuCl afforded 250 mg of product, mp 172.5°-173°. NMR (CDCl₃) δ2.4 (s, 6H), 6.76 (s, 1H), 7.0 (d, 1H), 7.5 (d, 1H), 8.2 (d, 1H) 9.0 (d, 1H), 8.1 (br s, 1H) 10.6 (br s, 1H).

Using techniques described in Equations 1 to 62 and Examples 1 to 6 or simple modifications thereof, the compounds in Tables 1-6 may be synthesized by one skilled in the art.

GENERAL STRUCTURES FOR TABLES ##STR128##

                                      TABLE 1a                                     __________________________________________________________________________     General Structure 1 wherein Q is Q-1.                                          R  R.sub.1                                                                            R.sub.2                                                                             X         Y        Z  m.p. °C.                              __________________________________________________________________________     H  H   H    CH.sub.3  CH.sub.3 CH                                              H  H   H    CH.sub.3  CH.sub.3 N                                               H  H   H    CH.sub.3  OCH.sub.3                                                                               CH 208-210                                      H  H   H    CH.sub.3  OCH.sub.3                                                                               N  179-181                                      H  H   H    OCH.sub.3 OCH.sub.3                                                                               CH 210-212                                      H  H   H    Cl        OCH.sub.3                                                                               CH                                              H  H   H    OCH.sub.3 OCH.sub.3                                                                               N  182-185                                      H  4-Cl                                                                               H    CH.sub.3  OCH.sub.3                                                                               CH                                              H  H   4-F  CH.sub.3  CH.sub.3 N                                               H  4-CH.sub.3                                                                         H    OCH.sub.3 OCH.sub.3                                                                               CH                                              H  H   4-OCH.sub.3                                                                         CH.sub.3  OCH.sub.3                                                                               N                                               H  H   4-CF.sub.3                                                                          CH.sub.3  OCH.sub.3                                                                               CH                                              CH.sub.3                                                                          3-CH.sub.3                                                                         5-CH.sub.3                                                                          CH.sub.3  CH.sub.3 N                                               H  H   H    OCH.sub.3 OCF.sub.2 H                                                                             CH                                              H  H   H    OCH.sub.3 cyclopropyl                                                                             N                                               H  H   H    OC.sub.2 H.sub.5                                                                         OCH.sub.3                                                                               N                                               H  H   H    O-- -n-C.sub.4 H.sub.9                                                                   CH.sub.3 CH                                              H  H   H    OCH.sub.2 CF.sub.3                                                                       OCH.sub.3                                                                               N                                               H  H   H    OCH.sub.2 CH.sub.2 CH.sub.2 F                                                            CH.sub.3 CH                                              H  H   H    SCH.sub.3 OCH.sub.3                                                                               CH                                              H  H   H    SCH(CH.sub.3).sub.2                                                                      CH.sub.3 N                                               H  H   H    CH.sub.2 CH.sub.2 OCH.sub.3                                                              CH.sub.3 CH                                              H  H   H    CH.sub.2 OCH.sub.2 CH.sub.3                                                              OCH.sub.3                                                                               N                                               H  H   H    N(CH.sub.2 CH.sub.3).sub.2                                                               CH.sub.3 CH                                              H  H   H    N(CH.sub.2 CH.sub.2 CH.sub.3)                                                            OCH.sub.3                                                                               N                                               H  H   H    CH.sub.3  OCH.sub.2 CH═CH.sub.2                                                               CH                                              H  H   H    OCH.sub.3 OCH.sub.2 CCCH.sub.3                                                                    N                                               H  H   H    CH.sub.3  cyclopentyl                                                                             CH                                              H  H   H    OCH.sub.3 CH.sub.2 SCH.sub.3                                                                      N                                               H  H   H    CH.sub.3  C(O)CH.sub.3                                                                            CH                                              H  H   H    CH.sub.3  1,3-dioxan-2-yl                                                                         N                                               H  H   H    OCH.sub.3 N(OCH.sub.3)CH.sub.3                                                                    CH                                              H  H   H    OCH.sub.3 OCH.sub.3                                                                               CH *                                            H  H   H    OCH.sub.3 CH.sub.3 N  *                                            H  4-Cl                                                                               H    OCH.sub.3 OCH.sub.3                                                                               CH *                                            __________________________________________________________________________      W is O, unless indicated by * where W is S in all Tables.                

                                      TABLE 1b                                     __________________________________________________________________________     General Structure 1                                                            Q  R  R.sub.3                                                                           R.sub.4                                                                           R.sub.5                                                                           X       Y      Z  W'                                                                               m.p. °C.                             __________________________________________________________________________     Q-2                                                                               H  H  H  H  CH.sub.3                                                                               OCH.sub.3                                                                             CH O                                             Q-2                                                                               H  H  H  H  CH.sub.3                                                                               OCH.sub.3                                                                             N  O                                             Q-2                                                                               H  H  H  H  OCH.sub.3                                                                              OCH.sub.3                                                                             CH O                                             Q-2                                                                               H  H  H  H  OCH.sub.3                                                                              OCH.sub.3                                                                             N  O                                             Q-2                                                                               H  CH.sub.3                                                                          H  H  CH.sub.3                                                                               CH.sub.3                                                                              CH O                                             Q-2                                                                               H  H  CH.sub.3                                                                          H  CH.sub.3                                                                               OCH.sub.3                                                                             N  O                                             Q-2                                                                               H  H  H  CH.sub.3                                                                          CH.sub.3                                                                               OCH.sub.3                                                                             CH O                                             Q-2                                                                               CH.sub.3                                                                          H  H  H  CH      CH.sub.3                                                                              CH O                                             Q-2                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          H  OCH.sub.3                                                                              OCH.sub.3                                                                             N  O                                             Q-2                                                                               H  H  H  H  Cl      OCH.sub.3                                                                             CH S                                             Q-2                                                                               H  H  H  H  CH.sub.3                                                                               OCH.sub.3                                                                             CH S                                             Q-2                                                                               H  H  H  H  CH.sub.3                                                                               OCH.sub.3                                                                             N  S                                             Q-2                                                                               H  H  H  H  OCH.sub.3                                                                              OCH.sub.3                                                                             CH S                                             Q-2                                                                               H  H  H  H  OCH.sub.3                                                                              OCH.sub.3                                                                             N  S                                             Q-2                                                                               H  H  H  H  CH.sub.3                                                                               CH.sub.3                                                                              CH S                                             Q-2                                                                               H  CH.sub.3                                                                          H  H  CH.sub.3                                                                               CH.sub.3                                                                              CH S                                             Q-2                                                                               H  H  CH.sub.3                                                                          H  CH.sub.3                                                                               CH.sub.3                                                                              N  S                                             Q-2                                                                               H  H  H  CH.sub.3                                                                          CH.sub.3                                                                               OCH.sub.3                                                                             CH S                                             Q-2                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                               OCH.sub.3                                                                             N  S                                             Q-2                                                                               H  H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                              OCH.sub.3                                                                             CH S                                             Q-2                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                          OCH.sub.3                                                                              OCH.sub.3                                                                             N  S                                             Q-2                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                               OCH.sub.3                                                                             CH S                                             Q-2                                                                               CH.sub.3                                                                          H  H  H  CH.sub.3                                                                               CH.sub.3                                                                              CH S                                             Q-2                                                                               H  H  H  H  Cl      OC.sub.2 H.sub.5                                                                      CH S                                             Q-3                                                                               H  H  H  H  CH.sub.3                                                                               CH.sub.3                                                                              CH O                                             Q-3                                                                               H  H  H  H  CH.sub.3                                                                               CH.sub.3                                                                              N  O                                             Q-3                                                                               H  H  H  H  CH.sub.3                                                                               OCH.sub.3                                                                             CH O                                             Q-3                                                                               H  H  H  H  CH.sub.3                                                                               OCH.sub.3                                                                             N  O                                             Q-3                                                                               H  H  H  H  OCH.sub.3                                                                              OCH.sub.3                                                                             CH O                                             Q-3                                                                               H  H  H  H  OCH.sub.3                                                                              OCH.sub.3                                                                             N  O                                             Q-3                                                                               H  CH.sub.3                                                                          H  H  CH.sub.3                                                                               CH.sub.3                                                                              CH O                                             Q-3                                                                               H  H  CH.sub.3                                                                          H  CH.sub.3                                                                               CH.sub.3                                                                              N  O                                             Q-3                                                                               H  H  H  CH.sub.3                                                                          CH.sub.3                                                                               OCH.sub.3                                                                             CH O                                             Q-3                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                               OCH.sub.3                                                                             N  O                                             Q-3                                                                               H  H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                              OCH.sub.3                                                                             CH O                                             Q-3                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                          OCH.sub.3                                                                              OCH.sub.3                                                                             N  O                                             Q-3                                                                               H  H  H  H  OCH.sub.3                                                                              OCH.sub.2 CF.sub.3                                                                    CH O                                             Q-3                                                                               H  H  H  H  OCH.sub.3                                                                              OCH.sub.2 CF.sub.3                                                                    CH O                                             Q-3                                                                               CH.sub.3                                                                          H  H  H  Cl      OCH.sub.3                                                                             CH O                                             Q-3                                                                               H  H  H  H  CH.sub.3                                                                               OCH.sub.3                                                                             CH S                                             Q-3                                                                               H  H  H  H  OCH.sub.3                                                                              OCH.sub.3                                                                             CH S                                             Q-3                                                                               H  H  H  H  OCH.sub.3                                                                              OCH.sub.3                                                                             N  S                                             Q-3                                                                               H  CH.sub.3                                                                          H  H  CH.sub.3                                                                               CH.sub.3                                                                              CH S                                             Q-3                                                                               H  H  CH.sub.3                                                                          H  CH.sub. 3                                                                              OCH.sub.3                                                                             N  S                                             Q-3                                                                               H  H  H  CH.sub.3                                                                          CH.sub.3                                                                               OCH.sub.3                                                                             CH S                                             Q-3                                                                               CH.sub.3                                                                          H  H  H  CH.sub.3                                                                               CH.sub.3                                                                              CH S                                             Q-3                                                                               H  H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                              OCH.sub.3                                                                             N  S                                             Q-3                                                                               H  H  H  H  OCH.sub.3                                                                              CF.sub.3                                                                              N  S                                             Q-4                                                                               H  H  H  H  CH.sub.3                                                                               OCH.sub.3                                                                             CH --                                            Q-4                                                                               H  H  H  H  OCH.sub.3                                                                              Cl     CH --                                            Q-4                                                                               H  H  H  H  CH.sub.3                                                                               OCH.sub.3                                                                             N  --                                            Q-4                                                                               H  H  H  H  CH.sub.3                                                                               CH.sub.3                                                                              CH --                                            Q-4                                                                               H  H  H  H  OCH.sub.3                                                                              OCH.sub.3                                                                             CH --                                            Q-4                                                                               H  H  H  H  OCH.sub.3                                                                              OCH.sub.3                                                                             N  --                                            Q-4                                                                               H  CH.sub.3                                                                          H  H  CH.sub.3                                                                               CH.sub.3                                                                              CH --                                            Q-4                                                                               H  H  CH.sub.3                                                                          H  CH.sub.3                                                                               OCH.sub.3                                                                             N  --                                            Q-4                                                                               H  H  H  CH.sub.3                                                                          CH.sub.3                                                                               OCH.sub.3                                                                             CH --                                            Q-4                                                                               CH.sub.3                                                                          H  H  H  OCH.sub.3                                                                              OCH.sub.3                                                                             CH --                                            Q-4                                                                               CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub. 3                                                                              OCH.sub.3                                                                             N  --                                            Q-4                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                               OCH.sub.3                                                                             CH --                                            Q-4                                                                               H  H  H  H  OCH.sub.3                                                                              OCH.sub.2 CF.sub.3                                                                    N  --                                            Q-4                                                                               H  H  H  H  CH.sub.3                                                                               NHCH.sub.3                                                                            CH --                                            Q-4                                                                               H  H  H  H  CH.sub.3                                                                               CH.sub.3                                                                              CH --                                            Q-4                                                                               H  H  H  H  CH.sub.3                                                                               CH.sub.3                                                                              N  --                                            Q-9                                                                               H  H  H  H  CH.sub.3                                                                               OCH.sub.3                                                                             CH --                                            Q-9                                                                               H  H  H  H  CH.sub.3                                                                               OCH.sub.3                                                                             N  --                                            Q-9                                                                               H  H  H  H  OCH.sub.3                                                                              OCH.sub.3                                                                             CH --                                            Q-9                                                                               H  H  H  H  OCH.sub.3                                                                              OCH.sub.3                                                                             N  --                                            Q-9                                                                               CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                               CH.sub.3                                                                              CH --                                            Q-9                                                                               H  H  CH.sub.3                                                                          H  CH.sub.3                                                                               OCH.sub.3                                                                             N  --                                            Q-9                                                                               H  H  H  CH.sub.3                                                                          OCH.sub.3                                                                              OCH.sub.3                                                                             CH --                                            Q-9                                                                               H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                               OCH.sub.3                                                                             CH --                                            Q-9                                                                               H  H  H  H  Cl      OCH.sub.2 CH.sub.3                                                                    CH --                                            Q-9                                                                               H  H  H  H  OCH.sub.3                                                                              CH(OCH.sub.3).sub.2                                                                   CH --                                            Q-9                                                                               H  H  H  H  NH.sub.2                                                                               CH.sub.3                                                                              CH --                                            Q-9                                                                               H  H  H  H  NHCH(CH.sub.3).sub.2                                                                   CH.sub.3                                                                              CH --                                            Q-9                                                                               H  H  H  H  CH.sub.2 O-- -n-C.sub.4 H.sub.9                                                        CH.sub.3                                                                              CH --                                            Q-9                                                                               H  H  H  H  S-- -n-C.sub.4 H.sub.9                                                                 CH.sub.3                                                                              CH --                                            Q-9                                                                               H  H  H  H  S-- -n-CH.sub.2 CH.sub.2 F                                                             CH.sub.3                                                                              CH --                                            __________________________________________________________________________

                                      TABLE 1c                                     __________________________________________________________________________     General Structure 1                                                            Q   R  R.sub.3, '                                                                        R.sub.4                                                                           X   Y       Z  W"  m.p. °C.                                __________________________________________________________________________     Q-10                                                                               H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                              CH O                                                  Q-10                                                                               H  H  H  CH.sub.3                                                                           CH.sub.3                                                                               CH O                                                  Q-10                                                                               H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              N  O                                                  Q-10                                                                               H  H  H  OCH.sub.3                                                                          Cl      CH O                                                  Q-10                                                                               H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              CH O                                                  Q-10                                                                               H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              N  O                                                  Q-10                                                                               H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                              CH S                                                  Q-10                                                                               H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                              N  S                                                  Q-10                                                                               H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              CH S                                                  Q-10                                                                               H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              N  S                                                  Q-10                                                                               H  H  H  OCH.sub.3                                                                          Cl      CH NCH.sub.3                                          Q-10                                                                               H  H  H  CH.sub.3                                                                           CH.sub.3                                                                               CH NCH.sub.3                                          Q-10                                                                               H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                              N  NCH.sub.3                                          Q-10                                                                               H  H  H  CH.sub.3                                                                           CH.sub.3                                                                               N  NCH.sub.3                                          Q-10                                                                               H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              CH NCH.sub.3                                          Q-10                                                                               H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              N  NCH.sub.3                                          Q-10                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                               CH O                                                  Q-10                                                                               H  H  CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                              N  O                                                  Q-10                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                              CH O                                                  Q-10                                                                               CH.sub.3                                                                          H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              N  O                                                  Q-10                                                                               H  H  H  CH.sub.3                                                                            ##STR129##                                                                            CH O                                                  Q-10                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                               CH S                                                  Q-10                                                                               H  H  CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                              N  S                                                  Q-10                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                              CH S                                                  Q-10                                                                               CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                              CH S                                                  Q-10                                                                               CH.sub.3                                                                          H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              N  S                                                  Q-10                                                                               H  H  H  CH.sub.3                                                                           OC.sub.2 H.sub.5                                                                       CH S                                                  Q-10                                                                               H  H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                               N  NCH.sub.3                                          Q-10                                                                               H  H  CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                              CH NCH.sub.3                                          Q-10                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                              N  NCH.sub.3                                          Q-10                                                                               CH.sub.3                                                                          H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              N  NCH.sub.3                                          Q-11                                                                               H  H  H  CH.sub.3                                                                           CH.sub.3                                                                               N  O                                                  Q-11                                                                               H  H  H  CH.sub.3                                                                           CH.sub.3                                                                               CH O   172.5-173                                      Q-11                                                                               H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                              N  O                                                  Q-11                                                                               H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                              CH O   192(d)                                         Q-11                                                                               H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              CH O   157-158                                        Q-11                                                                               H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              N  O                                                  Q-11                                                                               H  H  H  CH.sub.3                                                                           CH.sub.3                                                                               CH S                                                  Q-11                                                                               H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                              CH S                                                  Q-11                                                                               H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                              CH S                                                  Q-11                                                                               H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              CH S                                                  Q-11                                                                               H  H  H  CH.sub.3                                                                           CH.sub.3                                                                               CH NCH.sub.3                                          Q-11                                                                               H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                              CH NCH.sub.3                                          Q-11                                                                               H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              CH NCH.sub.3                                          Q-11                                                                               H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                              N  NCH.sub.3                                          Q-11                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                              N  O                                                  Q-11                                                                               H  H  CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                              N  O                                                  Q-11                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                              CH O                                                  Q-11                                                                               CH.sub.3                                                                          H  H  CH.sub.3                                                                           OCH.sub.3                                                                              CH O                                                  Q-11                                                                               H  H  H  CH.sub.3                                                                           C.sub.2 H.sub.5                                                                        N  O                                                  Q-11                                                                               H  H  H  CH.sub.3                                                                           CH.sub.2 OCH.sub.3                                                                     CH O                                                  Q-11                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                              N  S                                                  Q-11                                                                               H  H  CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                              N  S                                                  Q-11                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                              CH S                                                  Q-11                                                                               CH.sub.3                                                                          H  H  CH.sub.3                                                                           OCH.sub.3                                                                              CH S                                                  Q-11                                                                               H  H  H  CH.sub.3                                                                           C.sub.2 H.sub.5                                                                        N  S                                                  Q-11                                                                               CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                              N  S                                                  Q-11                                                                               H  H  H  Cl  OCH.sub.3                                                                              CH S                                                  Q-11                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                               CH NCH.sub.3                                          Q-11                                                                               H  H  CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                              N  NCH.sub.3                                          Q-11                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                              CH NCH.sub.3                                          Q-11                                                                               CH.sub.3                                                                          H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              N  NH                                                 Q-11                                                                               H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                              CH NH                                                 Q-11                                                                               H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              CH O*                                                 Q-11                                                                               H  H  H  OCH.sub.3                                                                          CH      N  O*                                                 Q-11                                                                               H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                              N  NCH.sub.3                                          Q-11                                                                               H  H  H  CH.sub.3                                                                           OCF.sub.2 H                                                                            CH NCH.sub.3                                          Q-11                                                                               H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.2 CF.sub.3                                                                     N  NCH.sub.3                                          Q-12                                                                               H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                              CH O                                                  Q-12                                                                               H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                              N  O                                                  Q-12                                                                               H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              CH O                                                  Q-12                                                                               H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              N  O                                                  Q-12                                                                               H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                              CH S                                                  Q-12                                                                               H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                              N  S                                                  Q-12                                                                               H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              CH S                                                  Q-12                                                                               H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              N  S                                                  Q-12                                                                               H  H  H  CH.sub.3                                                                           CH.sub.3                                                                               N  NCH.sub.3                                          Q-12                                                                               H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                              CH NCH.sub.3                                          Q-12                                                                               H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                              N  NCH.sub.3                                          Q-12                                                                               H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              CH NCH.sub.3                                          Q-12                                                                               H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              N  NCH.sub.3                                          Q-12                                                                               H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              N  NH                                                 Q-12                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                               CH O                                                  Q-12                                                                               H  H  CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                              N  O                                                  Q-12                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                              CH O                                                  Q-12                                                                               CH.sub.3                                                                          H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              N  O                                                  Q-12                                                                               CH.sub.3                                                                          H  H  CH.sub.3                                                                           CF.sub.3                                                                               CH O                                                  Q-12                                                                               H  H  H  OCH.sub.3                                                                          OCH.sub.2 CF.sub.3                                                                     N                                                     Q-12                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                              CH S                                                  Q-12                                                                               H  H  CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                              N  S                                                  Q-12                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                              CH S                                                  Q-12                                                                               CH.sub.3                                                                          H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              N  S                                                  Q-12                                                                               CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           NHCH.sub.3                                                                             CH S                                                  Q-12                                                                               H  H  H  Br  OC.sub.2 H.sub.5                                                                       CH S                                                  Q-12                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                               CH NH                                                 Q-12                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                               CH NCH.sub.3                                          Q-12                                                                               H  H  CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                              N  NCH.sub.3                                          Q-12                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                               CH.sub.3                                                                          NCH.sub.3                                          Q-12                                                                               CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                              N  NCH.sub.3                                          Q-12                                                                               CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                              CH NCH.sub.3                                          Q-12                                                                               H  H  H  Br  OCH.sub.3                                                                              CH NCH.sub.3                                          Q-12                                                                               H  H  H  OCH.sub.3                                                                          N(CH.sub.3).sub.2                                                                      CH NCH.sub.3                                          Q-13                                                                               H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                              CH O                                                  Q-13                                                                               H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                              CH O                                                  Q-13                                                                               H  H  H  CH.sub.3                                                                           CH.sub.3                                                                               CH O                                                  Q-13                                                                               H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                              N  O                                                  Q-13                                                                               H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              CH O                                                  Q-13                                                                               H  H  H  CH.sub.3                                                                           CH.sub.3                                                                               N  O                                                  Q-13                                                                               H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              N  O                                                  Q-13                                                                               H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                              CH S                                                  Q-13                                                                               H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                              N  S                                                  Q-13                                                                               H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              CH S                                                  Q-13                                                                               H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              N  S                                                  Q-13                                                                               H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                              CH NH                                                 Q-13                                                                               H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                              N  NH                                                 Q-13                                                                               H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              CH NCH.sub.3                                                                          150-152                                        Q-13                                                                               H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              N  NH                                                 Q-13                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                               CH O                                                  Q-13                                                                               H  H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                               N  O                                                  Q-13                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                              CH O                                                  Q-13                                                                               CH.sub.3                                                                          H  H  CH.sub.3                                                                           OCH.sub.3                                                                              N  O                                                  Q-13                                                                               H  H  H  CH.sub.3                                                                           CH(OCH.sub.3).sub.2                                                                    CH O                                                  Q-13                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                              CH S                                                  Q-13                                                                               H  H  CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                              CH S                                                  Q-13                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                              N  S                                                  Q-13                                                                               CH.sub.3                                                                          H  CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                              N  S                                                  Q-13                                                                               CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                               N  S                                                  Q-13                                                                               H  H  H  OCH.sub.3                                                                           ##STR130##                                                                            CH S                                                  Q-13                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                              N  NCH.sub.3                                          Q-13                                                                               H  H  CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                              N  NCH.sub.3                                          Q-13                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                              CH NCH.sub.3                                          Q-13                                                                               CH.sub.3                                                                          H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              CH NCH.sub.3                                          Q-13                                                                               H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                              N  NH                                                 Q-13                                                                               H  H  H  Br  OC.sub.2 H.sub.5                                                                       CH NH                                                 Q-13                                                                               H  H  H  OCH.sub.3                                                                          C.sub.2 H.sub.5                                                                        N  NH                                                 Q-13                                                                               H  H  H  CH.sub.3                                                                           CH.sub.3                                                                               CH NCH.sub.3                                          Q-13                                                                               H  H  H  CH.sub.3                                                                           CH.sub.3                                                                               N  NCH.sub.3                                          Q-13                                                                               H  H  H  Cl  OCH.sub.3                                                                              CH NCH.sub.3                                          Q-14                                                                               H  H  H  CH.sub.3                                                                           CH.sub.3                                                                               N  O                                                  Q-14                                                                               H  H  H  CH.sub.3                                                                           CH.sub.3                                                                               CH O                                                  Q-14                                                                               H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                              CH O                                                  Q-14                                                                               H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                              CH O                                                  Q-14                                                                               H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                              N  O                                                  Q-14                                                                               H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              CH O                                                  Q-14                                                                               H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                              CH S                                                  Q-14                                                                               H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                              N  S                                                  Q-14                                                                               H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              CH S                                                  Q-14                                                                               H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              CH S                                                  Q-14                                                                               H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              N  S                                                  Q-14                                                                               H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                              CH NCH.sub.3                                          Q-14                                                                               H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                              N  NCH.sub.3                                          Q-14                                                                               H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              CH NH                                                 Q-14                                                                               H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              N  NCH.sub.3                                          Q-14                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                               CH O                                                  Q-14                                                                               H  H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                               N  O                                                  Q-14                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                              CH O                                                  Q-14                                                                               CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                              N  O                                                  Q-14                                                                               H  H  H  CH.sub.3                                                                           C.sub.2 H.sub.5                                                                        N  O                                                  Q-14                                                                               H  H  H  CH.sub.3                                                                           OC.sub.2 H.sub.5                                                                       N  O                                                  Q-14                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                              CH S                                                  Q-14                                                                               H  H  CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                              N  S                                                  Q-14                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                              CH S                                                  Q-14                                                                               CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                              CH S                                                  Q-14                                                                               H  H  H  OCH.sub.3                                                                          C.sub.2 H.sub.5                                                                        N  S                                                  Q-14                                                                               H  H  H  OCH.sub.3                                                                          OC.sub.2 H.sub.5                                                                       N  S                                                  Q-14                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                              CH NCH.sub.3                                          Q-14                                                                               H  H  CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                              N  NCH.sub.3                                          Q-14                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                              CH NCH.sub.3                                          Q-14                                                                               CH.sub.3                                                                          CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                              N  NCH.sub.3                                          Q-14                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                              CH NH                                                 Q-14                                                                               H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                              N  NH                                                 Q-14                                                                               H  H  H  CH.sub.3                                                                           CH.sub.2 OCH.sub.3                                                                     CH NCH.sub.3                                          Q-15                                                                               H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                              CH O                                                  Q-15                                                                               H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                              N  O                                                  Q-15                                                                               H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              CH O                                                  Q-15                                                                               H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              N  O                                                  Q-15                                                                               H  C.sub.2 H.sub.5                                                                   H  OCH.sub.3                                                                          OCH.sub.3                                                                              CH O   134-136                                        Q-15                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                              CH O   150-152                                        Q-15                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                               CH O   177-179                                        Q-15                                                                               H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                              CH O   133-134                                        Q-15                                                                               H  H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                               N  O                                                  Q-15                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                              N  O   158-160                                        Q-15                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                              CH O                                                  Q-15                                                                               H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                              N  O   164-165                                        Q-15                                                                               CH.sub.3                                                                          H  H  CH.sub.3                                                                           OCH.sub.3                                                                              N  O                                                  Q-15                                                                               H  CH.sub.3                                                                          H  OCH.sub.3                                                                          Cl      CH O   154-156                                        Q-15                                                                               CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                              CH O                                                  Q-15                                                                               H  H  H  CH.sub.3                                                                           CF.sub.3                                                                               CH O                                                  Q-15                                                                               H  H  H  CH.sub.3                                                                           CF.sub.3                                                                               N  O                                                  Q-15                                                                               H  H  H  OCH.sub.3                                                                          OCF.sub.2 H                                                                            CH O                                                  Q-15                                                                               CH.sub.3                                                                          H  H  OCH.sub.3                                                                          OCF.sub.2 H                                                                            CH O                                                  Q-15                                                                               H  H  H  CH.sub.3                                                                           CH.sub.3                                                                               CH O                                                  Q-15                                                                               H  H  H  CH.sub.3                                                                           CH.sub.3                                                                               N  O                                                  Q-15                                                                               H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              CH O*                                                 Q-15                                                                               H  H  H  OCH.sub.3                                                                          CH.sub.3                                                                               N  O*                                                 Q-15                                                                               H  H  H  CH.sub.3                                                                           CH.sub.3                                                                               N  S                                                  Q-15                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                              CH S   146-149                                        Q-15                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                              N  S   148-151                                        Q-15                                                                               H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                              CH S   164-168                                        Q-15                                                                               H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                              N  S   170-173                                        Q-15                                                                               H  CH.sub.3                                                                          H  Cl  OCH.sub.3                                                                              CH S   141-149                                        Q-15                                                                               H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                              CH NCH.sub.3                                          Q-15                                                                               H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                              N  NCH.sub.3                                          Q-15                                                                               H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              CH NCH.sub.3                                          Q-15                                                                               H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              N  NCH.sub.3                                          Q-15                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                               CH S   172-175                                        Q-15                                                                               H  H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                               N  S                                                  Q-15                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                              CH S                                                  Q-15                                                                               CH.sub.3                                                                          H  H  CH.sub.3                                                                           OCH.sub.3                                                                              N  S                                                  Q-15                                                                               CH.sub.3                                                                          H  CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                              CH S                                                  Q-15                                                                               H  H  H  Cl  OC.sub.2 H.sub.5                                                                       CH S                                                  Q-15                                                                               H  H  H  OCH.sub.3                                                                          OCH.sub.2 CF.sub.3                                                                     CH S                                                  Q-15                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                               CH NCH.sub.3                                          Q-15                                                                               H  H  CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                              CH NCH.sub.3                                          Q-15                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                              N  NCH.sub.3                                          Q-15                                                                               CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                              N  NCH.sub.3                                          Q-15                                                                               CH.sub.3                                                                          H  H  CH.sub.3                                                                           OCH.sub.3                                                                              CH NH                                                 Q-15                                                                               H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              N  NH                                                 Q-15                                                                               H  H  H  CH.sub.3                                                                           NHCH.sub.3                                                                             CH NCH.sub.3                                          Q-15                                                                               H  H  H  OCH.sub.3                                                                          N(CH.sub.3).sub.2                                                                      CH NCH.sub.3                                          Q-15                                                                               H  H  H  CH.sub.3                                                                           OCH.sub.2 CCH                                                                          N  S                                                  Q-15                                                                               H  H  H  CH.sub.3                                                                           CH.sub.2 CCH.sub.3                                                                     CH S                                                  Q-15                                                                               H  H  H  CH.sub.3                                                                           CCH     N  S                                                  Q-15                                                                               H  C.sub. 2 H.sub.5                                                                  H  OCH.sub.3                                                                          OCH.sub.3                                                                              CH S   127-129                                        Q-15                                                                               H  H  H  OCH.sub.3                                                                          (CH.sub.2).sub.3 CH.sub.2 F                                                            CH S                                                  Q-15                                                                               H  H  H  OCH.sub.3                                                                          2-methyl-1,3-                                                                          N  S                                                                   dioxolan-2-yl                                                 Q-15                                                                               H  H  H  OCH.sub.3                                                                          2-methyl-1,3-                                                                          CH S                                                                   dithiolan-2-yl                                                Q-15                                                                               H  H  H  OCH.sub.3                                                                          2-methyl-1,3-                                                                          N  S                                                                   dithian-2-yl                                                  Q-15                                                                               H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              CH S*                                                 Q-15                                                                               H  H  H  OCH.sub.3                                                                          CH.sub.3                                                                               N  S*                                                 __________________________________________________________________________

                  TABLE 1d                                                         ______________________________________                                         General Structure 1                                                                                                       m.p.                                Q    R      R.sub.3                                                                               R.sub.4                                                                             R.sub.5                                                                             X     Y       Z°C.                         ______________________________________                                         Q-18 H      H      H    H    CH.sub.3                                                                             CH.sub.3                                                                               CH 188-190                          Q-18 H      H      H    H    CH.sub.3                                                                             OCH.sub.3                                                                              CH 159-163                          Q-18 H      H      H    H    CH.sub.3                                                                             OCH.sub.3                                                                              N133-136                            Q-18 CH.sub.3                                                                              H      H    H    CH.sub.3                                                                             OCH.sub.3                                                                              N                                   Q-18 H      H      H    H    OCH.sub.3                                                                            OCH.sub.3                                                                              CH 192-194                          Q-18 H      H      H    H    CH.sub.3                                                                             CH.sub.3                                                                               CH 165-167                          Q-18 H      H      H    H    OCH.sub.3                                                                            OCH.sub.3                                                                              N163-166                            Q-18 H      H      H    H    Cl    OCH.sub.3                                                                              CH                                  Q-18 H      CH.sub.3                                                                              H    H    CH.sub.3                                                                             OCH.sub.3                                                                              CH                                  Q-18 H      H      CH.sub.3                                                                            H    CH.sub.3                                                                             OCH.sub.3                                                                              N                                   Q-18 H      H      H    CH.sub.3                                                                            CH.sub.3                                                                             CH.sub.3                                                                               CH                                  Q-18 H      CH.sub.3                                                                              CH.sub.3                                                                            H    CH.sub.3                                                                             CH.sub.3                                                                               N                                   Q-18 H      H      CH.sub.3                                                                            CH.sub.3                                                                            OCH.sub.3                                                                            OCH.sub.3                                                                              CH                                  Q-18 H      CH.sub.3                                                                              H    CH.sub.3                                                                            OCH.sub.3                                                                            OCH.sub.3                                                                              N                                   Q-18 H      CH.sub.3                                                                              CH.sub.3                                                                            CH.sub.3                                                                            CH.sub.3                                                                             OCH.sub.3                                                                              CH                                  Q-18 H      H      H    H    OCH.sub.3                                                                            CH(OCH.sub.3).sub.2 CH                      Q-19 CH.sub.3                                                                              H      H    H    Cl    OCH.sub.3                                                                              CH                                  Q-19 H      H      H    H    CH.sub.3                                                                             OCH.sub.3                                                                              CH                                  Q-19 H      H      H    H    CH.sub.3                                                                             OCH.sub.3                                                                              N                                   Q-19 H      H      H    H    OCH.sub.3                                                                            OCH.sub.3                                                                              CH                                  Q-19 H      H      H    H    OCH.sub.3                                                                            OCH.sub.3                                                                              N                                   Q-19 H      CH.sub.3                                                                              H    H    CH.sub.3                                                                             CH.sub.3                                                                               CH                                  Q-19 H      H      CH.sub.3                                                                            H    CH.sub.3                                                                             CH.sub.3                                                                               N                                   Q-19 H      H      H    CH.sub.3                                                                            CH.sub.3                                                                             OCH.sub.3                                                                              CH                                  Q-19 H      CH.sub.3                                                                              CH.sub.3                                                                            H    CH.sub.3                                                                             OCH.sub.3                                                                              N                                   Q-19 H      H      CH.sub.3                                                                            CH.sub.3                                                                            OCH.sub.3                                                                            OCH.sub.3                                                                              CH                                  Q-19 H      CH.sub.3                                                                              H    CH.sub.3                                                                            OCH.sub.3                                                                            OCH.sub.3                                                                              N                                   Q-19 H      H      H    H    CH.sub.3                                                                             CH.sub.3                                                                               CH                                  Q-19 H      CH.sub.3                                                                              CH.sub.3                                                                            CH.sub.3                                                                            CH.sub.3                                                                             OCH.sub.3                                                                              CH                                  Q-19 CH.sub.3                                                                              H      H    H    CH.sub.3                                                                             OCH.sub.3                                                                              N                                   Q-19 H      H      H    H    OCH.sub.3                                                                             ##STR131##                                                                            CH                                  ______________________________________                                    

                                      TABLE 1e                                     __________________________________________________________________________     General Structure 1                                                            Q   R  R.sub.3 ',"                                                                            X   Y       Z  W' m.p. °C.                               __________________________________________________________________________     Q-21                                                                               H  H       CH.sub.3                                                                           OCH.sub.3                                                                              CH O                                                Q-21                                                                               H  H       CH.sub.3                                                                           OCH.sub.3                                                                              N  O                                                Q-21                                                                               H  H       OCH.sub.3                                                                          OCH.sub.3                                                                              CH O                                                Q-21                                                                               CH.sub.3                                                                          H       OCH.sub.3                                                                          OCH.sub.3                                                                              CH O                                                Q-21                                                                               H  H       OCH.sub.3                                                                          NHCH.sub.3                                                                             CH O                                                Q-21                                                                               H  H       OCH.sub.3                                                                          OCH.sub.3                                                                              N  O                                                Q-21                                                                               H  CH.sub.3                                                                               CH.sub.3                                                                           OCH.sub.3                                                                              CH O                                                Q-21                                                                               CH.sub.3                                                                          CH.sub.3                                                                               CH.sub.3                                                                           OCH.sub.3                                                                              CH O                                                Q-21                                                                               H  H       CH.sub.3                                                                           CH.sub.3                                                                               CH O                                                Q-21                                                                               H  H       CH.sub.3                                                                           CH.sub.3                                                                               N  O                                                Q-21                                                                               H  H       CH.sub.3                                                                           OCH.sub.3                                                                              CH S                                                Q-21                                                                               H  H       CH.sub.3                                                                           OCH.sub.3                                                                              N  S                                                Q-21                                                                               H  H       OCH.sub.3                                                                          OCH.sub.3                                                                              CH S                                                Q-21                                                                               H  H       OCH.sub.3                                                                          OCH.sub.3                                                                              N  S                                                Q-21                                                                               H  CH.sub.3                                                                               CH.sub.3                                                                           OCH.sub.3                                                                              CH S                                                Q-21                                                                               CH.sub.3                                                                          H       CH.sub.3                                                                           OCH.sub.3                                                                              CH S                                                Q-21                                                                               H  H       OCH.sub.3                                                                          N(CH.sub.3).sub.2                                                                      N  S                                                Q-22                                                                               H  H       CH.sub.3                                                                           OCH.sub.3                                                                              CH O                                                Q-22                                                                               H  H       CH.sub.3                                                                           OCH.sub.3                                                                              N  O                                                Q-22                                                                               H  H       OCH.sub.3                                                                          OCH.sub.3                                                                              CH O                                                Q-22                                                                               H  H       OCH.sub.3                                                                          OCH.sub.3                                                                              N  O                                                Q-22                                                                               H  CH.sub.3                                                                               CH.sub.3                                                                           OCH.sub.3                                                                              CH O                                                Q-22                                                                               H  CH.sub.3                                                                               CH.sub.3                                                                           OCH.sub.3                                                                              N  O                                                Q-22                                                                               CH.sub.3                                                                          CH.sub.3                                                                               CH.sub.3                                                                           CH.sub.3                                                                               CH O                                                Q-22                                                                               H  H       CH.sub.3                                                                           CH(OCH.sub.3).sub.2                                                                    CH O                                                Q-22                                                                               H  H       CH.sub.3                                                                           C.sub.2 H.sub.5                                                                        N  O                                                Q-22                                                                               H  H       CH.sub.3                                                                           CH.sub.3                                                                               CH S                                                Q-22                                                                               H  H       CH.sub.3                                                                           CH.sub.3                                                                               N  S                                                Q-22                                                                               H  H       CH.sub.3                                                                           OCH.sub.3                                                                              CH S                                                Q-22                                                                               H  H       CH.sub.3                                                                           OCH.sub.3                                                                              N  S                                                Q-22                                                                               H  H       OCH.sub.3                                                                          OCH.sub.3                                                                              CH S                                                Q-22                                                                               H  H       OCH.sub.3                                                                          OCH.sub.3                                                                              N  S                                                Q-22                                                                               H  CH.sub.3                                                                               CH.sub.3                                                                           OCH.sub.3                                                                              CH S                                                Q-22                                                                               CH.sub.3                                                                          CH.sub.3                                                                               CH.sub.3                                                                           OCH.sub.3                                                                              CH S                                                Q-22                                                                               CH.sub.3                                                                          H       CH.sub.3                                                                           OCH.sub.3                                                                              N  S                                                Q-22                                                                               H  H       CH.sub.3                                                                            ##STR132##                                                                            CH S                                                Q-22                                                                               H  H       OCH.sub.3                                                                          C.sub.2 H.sub.5                                                                        N  S                                                Q-23                                                                               H  H       CH.sub.3                                                                           OCH.sub.3                                                                              CH --                                               Q-23                                                                               H  H       CH.sub.3                                                                           OCH.sub.3                                                                              N  --                                               Q-23                                                                               H  H       OCH.sub.3                                                                          OCH.sub.3                                                                              CH --                                               Q-23                                                                               H  H       OCH.sub.3                                                                          OCH.sub.3                                                                              N  --                                               Q-23                                                                               H  CH.sub.3                                                                               CH.sub.3                                                                           CH.sub.3                                                                               CH --                                               Q-23                                                                               H  CH.sub.3                                                                               CH.sub.3                                                                           OCH.sub.3                                                                              N  --                                               Q-23                                                                               CH.sub.3                                                                          H       CH.sub.3                                                                           OCH.sub.3                                                                              N  --                                               Q-23                                                                               CH.sub.3                                                                          CH.sub.3                                                                               CH.sub.3                                                                           OCH.sub.3                                                                              CH --                                               Q-23                                                                               H  H       CH.sub.3                                                                           OC.sub.2 H.sub.5                                                                       N  --                                               Q-23                                                                               H  H       CH.sub.3                                                                           CH.sub.2 OCH.sub.3                                                                     CH --                                               Q-24                                                                               H  H       CH.sub.3                                                                           OCH.sub.3                                                                              CH --                                               Q-24                                                                               H  H       CH.sub.3                                                                           OCH.sub.3                                                                              N  --                                               Q-24                                                                               H  H       OCH.sub.3                                                                          OCH.sub.3                                                                              CH --                                               Q-24                                                                               H  H       OCH.sub.3                                                                          OCH.sub.3                                                                              N  --                                               Q-24                                                                               H  CH.sub.3                                                                               CH.sub.3                                                                           OCH.sub.3                                                                              CH --                                               Q-24                                                                               H  CH.sub.3                                                                               CH.sub.3                                                                           CH.sub.3                                                                               CH --                                               Q-24                                                                               CH.sub.3                                                                          H       CH.sub.3                                                                           CH.sub.3                                                                               N  --                                               Q-24                                                                               H  H       CH.sub.3                                                                           CF.sub.3                                                                               CH --                                               Q-24                                                                               H  H       OCH.sub.3                                                                          OCF.sub.2 H                                                                            N  --                                               Q-25                                                                               H  H       CH.sub.3                                                                           OCH.sub.3                                                                              CH -- **                                            Q-25                                                                               H  H       CH.sub.3                                                                           OCH.sub.3                                                                              N  -- **                                            Q-25                                                                               H  H       OCH.sub.3                                                                          OCH.sub.3                                                                              CH -- **                                            Q-25                                                                               H  H       OCH.sub.3                                                                          OCH.sub.3                                                                              N  -- **                                            Q-25                                                                               CH.sub.3                                                                          H       OCH.sub.3                                                                          OCH.sub.3                                                                              N  -- **                                            Q-25                                                                               H  H       CH.sub.3                                                                           CH.sub.3                                                                               CH -- **                                            Q-25                                                                               H  H       CH.sub.3                                                                           CH.sub.3                                                                               N  -- **                                            Q-25                                                                               H  CH.sub.3                                                                               CH.sub.3                                                                           OCH.sub.3                                                                              CH -- **                                            Q-25                                                                               H  CH.sub.3                                                                               CH.sub.3                                                                           OCH.sub.3                                                                              N  -- **                                            Q-25                                                                               CH.sub.3                                                                          CH.sub.3                                                                               OCH.sub.3                                                                          OCH.sub.3                                                                              N  -- **                                            Q-25                                                                               H  H       CH.sub.3                                                                           OCH.sub.2 CF.sub.3                                                                     CH -- **                                            Q-25                                                                               H  H       CH.sub.3                                                                           NHCH.sub.3                                                                             N  -- **                                            Q-26                                                                               H  H       CH.sub.3                                                                           OCH.sub.3                                                                              CH -- **                                            Q-26                                                                               H  H       CH.sub.3                                                                           OCH.sub.3                                                                              N  -- **                                            Q-26                                                                               H  H       OCH.sub.3                                                                          OCH.sub.3                                                                              CH -- **                                            Q-26                                                                               H  CH.sub.3                                                                               CH.sub.3                                                                           CH.sub.3                                                                               N  -- **                                            Q-26                                                                               H  CH.sub.3                                                                               CH.sub. 3                                                                          CH.sub.3                                                                               CH -- **                                            Q-26                                                                               H  CH.sub.3                                                                               CH.sub.3                                                                           OCH.sub.3                                                                              N  -- **                                            Q-26                                                                               H  CH.sub.3                                                                               CH.sub.3                                                                           OCH.sub.3                                                                              CH -- **                                            Q-26                                                                               H  CH.sub.3                                                                               CH.sub.3                                                                           OCH.sub.3                                                                              N  -- **                                            Q-26                                                                               H  H       CH.sub.3                                                                           CH.sub.3                                                                               CH -- **                                            Q-26                                                                               H  H       CH.sub.3                                                                           CH.sub.3                                                                               N  -- **                                            Q-26                                                                               H  CH.sub.3                                                                               OCH.sub.3                                                                          OCH.sub.3                                                                              CH -- **                                            Q-26                                                                               H  CH.sub.3                                                                               OCH.sub.3                                                                          OCH.sub.3                                                                              N  -- **                                            Q-26                                                                               CH.sub.3                                                                          H       CH.sub.3                                                                           OCH.sub.3                                                                              CH -- **                                            Q-26                                                                               H  H       CH.sub.3                                                                           N(CH.sub.3).sub.2                                                                      CH -- **                                            Q-26                                                                               H  H       CH.sub.3                                                                           N(CH.sub.3).sub.2                                                                      N  -- **                                            Q-27                                                                               H  H       CH.sub.3                                                                           OCH.sub.3                                                                              CH -- **                                            Q-27                                                                               H  H       CH.sub.3                                                                           OCH.sub.3                                                                              N  -- **                                            Q-27                                                                               H  H       OCH.sub.3                                                                          OCH.sub.3                                                                              CH -- **                                            Q-27                                                                               H  H       OCH.sub.3                                                                          OCH.sub.3                                                                              N  -- **                                            Q-27                                                                               H  H       CH.sub.3                                                                           CH.sub.3                                                                               CH -- **                                            Q-27                                                                               H  H       CH.sub.3                                                                           CH.sub.3                                                                               N  -- **                                            Q-27                                                                               H  CH.sub.3                                                                               CH.sub.3                                                                           CH.sub. 3                                                                              CH -- **                                            Q-27                                                                               H  H       Cl  OC.sub.2 H.sub.5                                                                       CH -- **                                            Q-27                                                                               H  CH.sub.3                                                                               CH.sub.3                                                                           CH.sub.3                                                                               N  -- **                                            Q-27                                                                               H  CH.sub.3                                                                               CH.sub.3                                                                           OCH.sub.3                                                                              CH -- **                                            Q-27                                                                               H  CH.sub.3                                                                               CH.sub.3                                                                           OCH.sub.3                                                                              N  -- **                                            Q-27                                                                               H  CH.sub.3                                                                               OCH.sub.3                                                                          OCH.sub.3                                                                              CH -- **                                            Q-27                                                                               H  CH.sub.3                                                                               OCH.sub.3                                                                          OCH.sub.3                                                                              N  -- **                                            Q-27                                                                               CH.sub.3                                                                          CH.sub.3                                                                               CH.sub.3                                                                           OCH.sub.3                                                                              N  -- **                                            Q-27                                                                               CH.sub.3                                                                          H       CH.sub.3                                                                           OCH.sub.3                                                                              N  -- **                                            Q-27                                                                               H  H       CH.sub.3                                                                           CH(OCH.sub.3).sub.2                                                                    CH -- **                                            Q-27                                                                               H  H       CH.sub.3                                                                           O(CH.sub.2).sub.3 CH.sub.2 Cl                                                          CH -- **                                            Q-25                                                                               H  SH      CH.sub.3                                                                           CH.sub.3                                                                               CH -- **                                            Q-25                                                                               H  SH      CH.sub.3                                                                           OCH.sub.3                                                                              CH -- **                                            Q-25                                                                               H  SH      OCH.sub.3                                                                          OCH.sub.3                                                                              CH -- **                                            Q-25                                                                               H  SH      OCH.sub.3                                                                          Cl      CH -- **                                            Q-25                                                                               H  SH      CH.sub.3                                                                           OCH.sub.3                                                                              N  -- **                                            Q-25                                                                               H  SH      OCH.sub.3                                                                          OCH.sub.3                                                                              N  -- **                                            Q-25                                                                               H  SCH.sub.3                                                                              CH.sub.3                                                                           CH.sub.3                                                                               CH -- **                                            Q-25                                                                               H  SCH.sub.3                                                                              CH.sub.3                                                                           OCH.sub.3                                                                              CH -- **                                            Q-25                                                                               H  SCH.sub.3                                                                              OCH.sub.3                                                                          OCH.sub.3                                                                              CH -- **                                            Q-25                                                                               H  SCH.sub.3                                                                              OCH.sub.3                                                                          Cl      CH -- **                                            Q-25                                                                               H  SCH.sub.3                                                                              CH  OCH.sub.3                                                                              N  -- **                                            Q-25                                                                               H  SCH.sub.3                                                                              OCH.sub.3                                                                          OCH.sub.3                                                                              N  -- **                                            Q-25                                                                               H  SCH.sub.2 CHCH.sub.2                                                                   CH.sub.3                                                                           CH.sub.3                                                                               CH -- **                                            Q-25                                                                               H  SCH.sub.2 CHCH.sub.2                                                                   CH.sub.3                                                                           OCH.sub.3                                                                              CH -- **                                            Q-25                                                                               H  SCH.sub.2 CHCH.sub.2                                                                   OCH.sub.3                                                                          OCH.sub.3                                                                              CH -- **                                            Q-25                                                                               H  SCH.sub.2 CHCH.sub.2                                                                   OCH.sub.3                                                                          Cl      CH -- **                                            Q-25                                                                               H  SCH.sub.2 CHCH.sub.2                                                                   CH.sub.3                                                                           OCH.sub.3                                                                              N  -- **                                            Q-25                                                                               H  SCH.sub.2 CHCH.sub.2                                                                   OCH.sub.3                                                                          OCH.sub.3                                                                              N  -- **                                            Q-25                                                                               CH.sub.3                                                                          SCH.sub.3                                                                              OCH.sub.3                                                                          OCH.sub.3                                                                              CH -- **                                            Q-25                                                                               CH SH      OCH.sub.3                                                                          OCH.sub.3                                                                              CH -- **                                            Q-25                                                                               CH.sub.3                                                                          SCH.sub.2 CHCH.sub.2                                                                   OCH.sub.3                                                                          OCH.sub.3                                                                              CH -- **                                            __________________________________________________________________________      R.sub.11  is --, unless indicated by ** where R.sub.11 is CH.sub.3 in all      Tables.                                                                  

                  TABLE 1f                                                         ______________________________________                                         General Structure 1                                                                                                         m.p.                              Q    R      R.sub.3 R.sub.4                                                                              R.sub.5                                                                             X     Y       Z°C.                       ______________________________________                                         Q-29 H      H       H     --   CH.sub.3                                                                             OCH.sub.3                                                                              CH                                Q-29 H      H       H     --   CH.sub.3                                                                             OCH.sub.3                                                                              N                                 Q-29 H      H       H     --   OCH.sub.3                                                                            OCH.sub.3                                                                              CH                                Q-29 H      H       H     --   OCH.sub.3                                                                            OCH.sub.3                                                                              N                                 Q-29 H      H       H     --   CH.sub.3                                                                             CH.sub.3                                                                               CH                                Q-29 H      H       H     --   CH.sub.3                                                                             CH.sub.3                                                                               N                                 Q-29 H      CH.sub.3                                                                               H     --   CH.sub.3                                                                             OCH.sub.3                                                                              CH                                Q-29 H      CH.sub.3                                                                               H     --   CH.sub.3                                                                             CH.sub.3                                                                               CH                                Q-29 H      CH.sub.3                                                                               CH.sub.3                                                                             --   CH.sub.3                                                                             OCH.sub.3                                                                              N                                 Q-29 CH.sub.3                                                                              CH.sub.3                                                                               CH.sub.3                                                                             --   CH.sub.3                                                                             CH.sub.3                                                                               N                                 Q-29 CH.sub.3                                                                              H       H     --   OCH.sub.3                                                                            OCH.sub.3                                                                              CH                                Q-29 H      H       H     --   CH.sub.3                                                                             OC.sub.2 H.sub.5                                                                       N                                 Q-29 H      H       H     --   Cl    OCH.sub.3                                                                              CH                                Q-36 H      H       H     H    CH.sub.3                                                                             OCH.sub.3                                                                              CH                                Q-36 CH.sub.3                                                                              H       H     H    CH.sub.3                                                                             OCH.sub.3                                                                              CH                                Q-36 H      H       H     H    CH.sub.3                                                                             OCH.sub.3                                                                              N                                 Q-36 H      H       H     H    OCH.sub.3                                                                            OCH.sub.3                                                                              CH                                Q-36 H      H       H     H    OCH.sub.3                                                                            OCH.sub.3                                                                              N                                 Q-36 H      H       H     H    OCH.sub.3                                                                            C.sub.2 H.sub.5                                                                        CH                                Q-36 H      H       H     H    CH.sub.3                                                                             CH.sub.3                                                                               CH                                Q-36 H      H       H     H    CH.sub.3                                                                             CH.sub.3                                                                               N                                 Q-36 H      CH.sub.3                                                                               H     H    CH.sub.3                                                                             CH.sub.3                                                                               CH                                Q-36 H      H       CH.sub.3                                                                             H    CH.sub.3                                                                             CH.sub.3                                                                               N                                 Q-36 H      CH.sub.3                                                                               H     CH.sub.3                                                                            CH.sub.3                                                                             OCH.sub.3                                                                              CH                                Q-36 H      CH.sub.3                                                                               CH.sub.3                                                                             H    CH.sub.3                                                                             OCH.sub.3                                                                              N                                 Q-36 H      CH.sub.3                                                                               CH.sub.3                                                                             CH.sub.3                                                                            OCH.sub.3                                                                            OCH.sub.3                                                                              CH                                Q-36 CH.sub.3                                                                              H       H     H    OCH.sub.3                                                                            OCH.sub.3                                                                              N                                 Q-36 H      H       H     H    CH.sub.3                                                                             NHCH.sub.3                                                                             CH                                Q-36 H      H       H     H    CH.sub.3                                                                             N(CH.sub.3).sub.2                                                                      CH                                Q-37 H      H       H     --   CH.sub.3                                                                             OCH.sub.3                                                                              CH                                Q-37 H      H       H     --   CH.sub.3                                                                             OCH.sub.3                                                                              N                                 Q-37 H      H       H     --   OCH.sub.3                                                                            OCH.sub.3                                                                              CH                                Q-37 H      H       H     --   OCH.sub.3                                                                            OCH.sub.3                                                                              N                                 Q-37 H      H       H     --   CH.sub.3                                                                             CH.sub.3                                                                               CH                                Q-37 H      2-CH.sub.3                                                                             H     --   CH.sub.3                                                                             CH.sub.3                                                                               CH                                Q-37 H      4-CH.sub.3                                                                             H     --   CH.sub.3                                                                             CH.sub.3                                                                               N                                 Q-37 H      5-CH.sub.3                                                                             H     --   CH.sub.3                                                                             OCH     CH                                Q-37 H      H       H     --   CH.sub.3                                                                             CH.sub.3                                                                               N                                 Q-37 H      2-CH.sub.3                                                                             4-CH.sub.3                                                                           --   CH.sub.3                                                                             OCH.sub.3                                                                              N                                 Q-37 H      2-CH.sub.3                                                                             5-CH.sub.3                                                                           --   OCH.sub.3                                                                            OCH.sub.3                                                                              CH                                Q-37 H      4-CH.sub.3                                                                             5-CH.sub.3                                                                           --   OCH.sub.3                                                                            OCH.sub.3                                                                              N                                 Q-37 CH.sub.3                                                                              H       H     --   CH.sub.3                                                                             OCH.sub.3                                                                              CH                                Q-37 H      H       H     --   CH.sub.3                                                                             CH(OCH.sub.3).sub.2 CH                    Q-37 H      H       H     --   Cl    OCH.sub.3                                                                              CH                                Q-38 H      H       H     --   CH.sub.3                                                                             OCH.sub.3                                                                              CH                                Q-38 H      H       H     --   CH.sub.3                                                                             OCH.sub.3                                                                              N                                 Q-38 H      H       H     --   OCH.sub.3                                                                            OCH.sub.3                                                                              CH                                Q-38 H      H       H     --   OCH.sub.3                                                                            OCH.sub.3                                                                              N                                 Q-38 H      2-CH.sub.3                                                                             H     --   CH.sub.3                                                                             CH.sub.3                                                                               CH                                Q-38 H      4-CH.sub.3                                                                             H     --   CH.sub.3                                                                             CH.sub.3                                                                               N                                 Q-38 H      2-CH.sub.3                                                                             4-CH.sub.3                                                                           --   CH.sub.3                                                                             OCH.sub.3                                                                              CH                                Q-38 H      4-CH.sub.3                                                                             4-CH.sub.3                                                                           --   CH.sub.3                                                                             OCH.sub.3                                                                              N                                 Q-38 H      H       H     --   CH.sub.3                                                                             CH.sub.3                                                                               N                                 Q-38 CH.sub.3                                                                              4-CH.sub.3                                                                             6-CH.sub.3                                                                           --   OCH.sub.3                                                                            OCH.sub.3                                                                              CH                                Q-38 H      H       H     --   CH.sub.3                                                                              ##STR133##                                                                            CH                                Q-38 H      H       H     --   CH.sub.3                                                                             CH.sub.3                                                                               CH                                Q-38 H      H       H     --   OCH.sub.3                                                                            C.sub.2 H.sub.5                                                                        N                                 Q-39 H      H       H     --   CH.sub.3                                                                             OCH.sub.3                                                                              CH                                Q-39 H      H       H     --   CH.sub.3                                                                             OCH.sub.3                                                                              N                                 Q-39 H      H       H     --   CH.sub.3                                                                             CH.sub.3                                                                               N                                 Q-39 H      H       H     --   OCH.sub.3                                                                            OCH.sub.3                                                                              CH                                Q-39 H      H       H     --   OCH.sub.3                                                                            OCH.sub.3                                                                              N                                 Q-39 CH.sub.3                                                                              H       H     --   OCH.sub.3                                                                            OCH.sub.3                                                                              N                                 Q-39 H      3-CH.sub.3                                                                             H     --   CH.sub.3                                                                             CH.sub.3                                                                               CH                                Q-39 H      H       H     --   CH.sub.3                                                                             CH.sub.3                                                                               CH                                Q-39 H      5-CH.sub.3                                                                             H     --   CH.sub.3                                                                             CH.sub.3                                                                               N                                 Q-39 H      H       H     --   Cl    OC.sub.2 H.sub. 5                                                                      CH                                Q-39 H      6-CH.sub.3                                                                             H     --   CH.sub.3                                                                             OCH.sub.3                                                                              CH                                Q-39 H      3-CH.sub.3                                                                             5-CH.sub.3                                                                           --   CH.sub.3                                                                             OCH.sub.3                                                                              N                                 Q-39 H      3-CH.sub.3                                                                             6-CH.sub.3                                                                           --   OCH.sub.3                                                                            OCH.sub.3                                                                              CH                                Q-39 H      5-CH.sub.3                                                                             6-CH.sub.3                                                                           --   OCH.sub.3                                                                            OCH.sub.3                                                                              N                                 Q-39 H      H       H     --   OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                       N                                 Q-39 H      H       H     --   OCH.sub.3                                                                            CH.sub.2 OCH.sub.3                                                                     N                                 Q-40 H      H       H     --   CH.sub.3                                                                             CH.sub.3                                                                               CH                                Q-40 H      H       H     --   CH.sub.3                                                                             OCH.sub.3                                                                              CH                                Q-40 H      H       H     --   CH.sub.3                                                                             OCH.sub.3                                                                              N                                 Q-40 H      H       H     --   OCH.sub.3                                                                            OCH.sub.3                                                                              CH                                Q-40 H      H       H     --   OCH.sub.3                                                                            OCH.sub.3                                                                              N                                 Q-40 H      H       H     --   CH.sub.3                                                                             CH.sub.3                                                                               N                                 Q-40 H      4-CH.sub.3                                                                             H     --   CH.sub.3                                                                             CH.sub.3                                                                               CH                                Q-40 H      5-CH.sub.3                                                                             H     --   CH.sub.3                                                                             CH.sub.3                                                                               N                                 Q-40 H      6-CH.sub.3                                                                             H     --   CH.sub.3                                                                             OCH.sub.3                                                                              CH                                Q-40 H      4-CH.sub.3                                                                             5-CH.sub.3                                                                           --   CH.sub.3                                                                             OCH.sub.3                                                                              N                                 Q-40 H      4-CH.sub.3                                                                             6-CH.sub.3                                                                           --   OCH.sub.3                                                                            OCH.sub.3                                                                              CH                                Q-40 H      5-CH.sub.3                                                                             6-CH.sub.3                                                                           --   OCH.sub.3                                                                            OCH.sub.3                                                                              N                                 Q-40 CH.sub.3                                                                              H       H     --   CH.sub.3                                                                             CH.sub.3                                                                               CH                                Q-40 H      H       H     --   OCH.sub.3                                                                            CF.sub.3                                                                               N                                 Q-40 H      H       H     --   OCH.sub.3                                                                            OCF.sub.2 H                                                                            N                                 Q-43 H      H       H     --   CH.sub.3                                                                             CH.sub.3                                                                               CH                                Q-43 H      H       H     --   CH.sub.3                                                                             OCH.sub.3                                                                              CH                                Q-43 H      H       H     --   CH.sub.3                                                                             OCH.sub.3                                                                              N                                 Q-43 H      H       H     --   OCH.sub.3                                                                            OCH.sub.3                                                                              CH                                Q-43 H      H       H     --   OCH.sub.3                                                                            OCH.sub.3                                                                              N                                 Q-43 CH.sub.3                                                                              H       H     --   OCH.sub.3                                                                            OCH.sub.3                                                                              CH                                Q-43 H      CH.sub.3                                                                               CH.sub.3                                                                             --   CH.sub.3                                                                             OCH.sub.3                                                                              CH                                Q-43 H      CH.sub.3                                                                               H     --   CH.sub.3                                                                             CH.sub.3                                                                               CH                                Q-43 H      H       H     --   CH.sub.3                                                                             CH.sub.3                                                                               N                                 Q-43 H      H       H     --   OCH.sub.3                                                                            OCH.sub.2 CF.sub.3                                                                     N                                 Q-43 H      H       H     --   OCH.sub.3                                                                            NHCH.sub.3                                                                             N                                 Q-44 H      H       H     --   CH.sub.3                                                                             OCH.sub.3                                                                              CH                                Q-44 H      H       H     --   CH.sub. 3                                                                            OCH.sub.3                                                                              N                                 Q-44 H      H       H     --   OCH.sub.3                                                                            OCH.sub.3                                                                              CH                                Q-44 H      H       H     --   OCH.sub.3                                                                            OCH.sub.3                                                                              N                                 Q-44 H      CH.sub.3                                                                               H     --   CH.sub.3                                                                             CH.sub.3                                                                               CH                                Q-44 H      H       CH.sub.3                                                                             --   CH.sub.3                                                                             CH.sub.3                                                                               N                                 Q-44 H      CH.sub.3                                                                               CH.sub.3                                                                             --   CH.sub.3                                                                             OCH.sub.3                                                                              N                                 Q-44 CH.sub.3                                                                              H       H     --   CH.sub.3                                                                             OCH.sub.3                                                                              N                                 Q-44 H      H       H     --   OCH.sub.3                                                                            N(CH.sub.3).sub.2                                                                      N                                 Q-44 H      H       H     --   Br    OCH.sub.3                                                                              CH                                Q-44 H      H       H     --   CH.sub.3                                                                             CH.sub.3                                                                               CH                                Q-44 H      H       H     --   CH.sub.3                                                                             CH.sub.3                                                                               N                                 Q-45 H      H       --    --   CH.sub.3                                                                             OCH.sub.3                                                                              CH                                Q-45 H      H       --    --   CH.sub.3                                                                             OCH.sub.3                                                                              N                                 Q-45 H      H       --    --   OCH.sub.3                                                                            OCH.sub.3                                                                              CH                                Q-45 H      H       --    --   OCH.sub.3                                                                            OCH.sub.3                                                                              N                                 Q-45 H      CH.sub.3                                                                               --    --   CH.sub.3                                                                             CH.sub.3                                                                               CH                                Q-45 CH.sub.3                                                                              H       --    --   CH.sub.3                                                                             CH.sub.3                                                                               N                                 Q-45 H      H       --    --   OCH.sub.3                                                                            CH(OCH.sub.3).sub.2 N                     Q-45 H      H       --    --   CH.sub.3                                                                             CH.sub.3                                                                               CH                                Q-45 H      H       --    --   CH.sub.3                                                                             CH.sub.3                                                                               N                                 Q-45 H      H       --    --   Cl    OCH.sub.3                                                                              CH                                ______________________________________                                          wherein W' is O.                                                         

                                      TABLE 2a                                     __________________________________________________________________________     General Structure 1 wherein Q is Q-5.                                          R  R.sub.3                                                                           R.sub.4                                                                           R.sub.5                                                                           R.sub.6                                                                           R.sub.7                                                                           R.sub.8                                                                           X   Y      Z  m.p. °C.                             __________________________________________________________________________     H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              N                                              H  H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             CH                                             H  H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N                                              H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH                                             H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             N                                              CH.sub.3                                                                          H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH                                             H  CH.sub.3                                                                          H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              CH                                             H  H  H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              N                                              H  H  H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                             CH                                             H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                             N                                              H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH                                             H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                             N                                              H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                              CH                                             H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                              N                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             CH                                             H  H  H  H  CH.sub.3                                                                          H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N                                              H  H  H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                             CH                                             H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             N                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                              CH                                             H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                              N                                              H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                             CH                                             H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                             N                                              H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                             CH                                             H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                              CH                                             H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                              CH                                             H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                              N                                              H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                             CH                                             CH.sub.3                                                                          H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N                                              H  H  H  H  H  H  H  OCH.sub.3                                                                          CH(OCH.sub.3).sub.2                                                                   N                                              H  H  H  H  H  H  H  OCH.sub.3                                                                           ##STR134##                                                                           N                                              H  H  H  H  H  H  H  Cl  OCH.sub.3                                                                             CH                                             H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              CH                                             __________________________________________________________________________      Wherein W" is O.                                                         

                                      TABLE 2b                                     __________________________________________________________________________     General Structure 1 wherein Q is Q-6.                                          Q  R  R.sub.3                                                                           R.sub.4                                                                           R.sub.5                                                                           R.sub.6                                                                           R.sub.7                                                                           R.sub.8                                                                           X   Y     Z  W" m.p. °C.                        __________________________________________________________________________     Q-6                                                                               H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             CH O                                         Q-6                                                                               H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             N  O                                         Q-6                                                                               H  CH.sub.3                                                                          H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH O                                         Q-6                                                                               H  H  H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N  O                                         Q-6                                                                               H  H  H  H  H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH O                                         Q-6                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N  O                                         Q-6                                                                               H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             CH O                                         Q-6                                                                               H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             N  O                                         Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH O                                         Q-6                                                                               H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N  O                                         Q-6                                                                               H  H  H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            CH O                                         Q-6                                                                               H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            N  O                                         Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             CH O                                         Q-6                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                             N  O                                         Q-6                                                                               H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            CH O                                         Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N  O                                         Q-6                                                                               H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH O                                         Q-6                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                            N  O                                         Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             CH O                                         Q-6                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                             N  O                                         Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH O                                         Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            N  O                                         Q-6                                                                               H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            CH O                                         Q-6                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            N  O                                         Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                             CH O                                         Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             N  O                                         Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            CH O                                         Q-6                                                                               CH.sub.3                                                                          H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N  O                                         Q-6                                                                               H  H  H  H  H  H  H  Br  OCH.sub.3                                                                            CH O                                         Q-6                                                                               H  H  H  H  H  H  H  Cl  OC.sub.2 H.sub.5                                                                     CH O                                         Q-6                                                                               H  H  H  H  H  H  H  OCH.sub. 3                                                                         C.sub.2 H.sub.5                                                                      CH O                                         Q-6                                                                               H  H  H  H  H  H  H  OCH.sub.3                                                                          OC.sub.2 H.sub.5                                                                     CH O                                         Q-6                                                                               H  H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH O                                         Q-6                                                                               H  H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N  O                                         Q-6                                                                               H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH O                                         Q-6                                                                               H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N  O                                         Q-6                                                                               CH.sub.3                                                                          H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH O                                         Q-6                                                                               H  H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH S                                         Q-6                                                                               H  H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N  S                                         Q-6                                                                               H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH S                                         Q-6                                                                               H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N  S                                         Q-6                                                                               H  H  H  H  H  H  H  OCH.sub.3                                                                          C.sub.2 H.sub.5                                                                      CH S                                         Q-6                                                                               H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             CH S                                         Q-6                                                                               H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             N  S                                         Q-6                                                                               H  CH.sub.3                                                                          H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH S                                         Q-6                                                                               H  H  H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N  S                                         Q-6                                                                               H  H  H  H  H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH S                                         Q-6                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N  S                                         Q-6                                                                               H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             CH S                                         Q-6                                                                               H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             N  S                                         Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH S                                         Q-6                                                                               H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N  S                                         Q-6                                                                               H  H  H  H  H  H  H  OCH.sub.3                                                                          CH.sub.2 OCH.sub.3                                                                   CH S                                         Q-6                                                                               H  H  H  H  H  H  H  OCH.sub.3                                                                          CF.sub.3                                                                             CH S                                         Q-6                                                                               H  H  H  H  H  H  H  OCH.sub.3                                                                          OCF.sub.2 H                                                                          CH S                                         Q-6                                                                               H  H  H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub. 3                                                                         OCH.sub.3                                                                            CH S                                         Q-6                                                                               H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            N  S                                         Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             CH S                                         Q-6                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                             N  S                                         Q-6                                                                               H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            CH S                                         Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N  S                                         Q-6                                                                               H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH S                                         Q-6                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                            N  S                                         Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             CH S                                         Q-6                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                             N  S                                         Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH S                                         Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            N  S                                         Q-6                                                                               H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            CH S                                         Q-6                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            N  S                                         Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                             CH S                                         Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             N  S                                         Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            CH S                                         Q-6                                                                               CH.sub.3                                                                          H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N  S                                         __________________________________________________________________________

                                      TABLE 2c                                     __________________________________________________________________________     General Structure 1                                                            Q  R  R.sub.3                                                                           R.sub.4                                                                           R.sub.5                                                                           R.sub.6                                                                           X   Y      Z  W'                                                                               m.p. °C.                              __________________________________________________________________________     Q-7                                                                               H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             CH --                                                                               152-155                                      Q-7                                                                               H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N  --                                                                               144-146                                      Q-7                                                                               H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH --                                                                               167-170                                      Q-7                                                                               H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             N  --                                                                               156-159                                      Q-7                                                                               H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              CH --                                                                               170-173                                      Q-7                                                                               H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              N  --                                                                               153-156                                      Q-7                                                                               H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             CH --                                             Q-7                                                                               H  H  CH.sub.3                                                                          H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N  --                                             Q-7                                                                               H  CH.sub.3                                                                          H  H  CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                             CH --                                             Q-7                                                                               H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                             N  --                                             Q-7                                                                               H  CH.sub. 3                                                                         CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                              CH --                                             Q-7                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                              N  --                                             Q-7                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                             CH --                                             Q-7                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                             N  --                                             Q-7                                                                               CH.sub.3                                                                          H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH --                                             Q-7                                                                               CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                             CH --                                             Q-7                                                                               H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.2 CF.sub.3                                                                    CH --                                             Q-7                                                                               H  H  H  H  H  OCH.sub.3                                                                          NHCH.sub.3                                                                            CH --                                             Q-7                                                                               H  H  H  H  H  Cl  OCH.sub.3                                                                             CH --                                                                               157-159                                      Q-7                                                                               H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH --                                                                               *                                            Q-7                                                                               H  H  H  H  H  OCH.sub.3                                                                          CH.sub.3                                                                              N  --                                                                               *                                            Q-7                                                                               H  H  H  H  H  OCH.sub.3                                                                          CH     CH --                                                                               *                                            Q-16                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           OCH.sub.3                                                                             CH O 157-160                                      Q-16                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N  O 137-140                                      Q-16                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                              Q-16                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             N  O 138-141                                      Q-16                                                                              CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                              Q-16                                                                              CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  Cl  OCH.sub.3                                                                             CH O                                              Q-16                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                              CH O 185-188                                      Q-16                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                              N  O 163-167                                      Q-16                                                                              H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                              Q-16                                                                              H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                              Q-16                                                                              H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                              Q-16                                                                              H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                              Q-16                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  OCH.sub.3                                                                          N(CH.sub.3).sub.2                                                                     CH O                                              Q-16                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  OCH.sub.3                                                                          CH(OCH.sub.3).sub.2                                                                   CH O                                              Q-16                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  Cl  OCH.sub.3                                                                             CH O 158-161                                      Q-16                                                                              H  CH.sub.3                                                                          CH.sub. 3                                                                         H  H  CH.sub.3                                                                           CH.sub.2 OCH.sub.3                                                                    N  O                                              Q-16                                                                              H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              CH O                                              Q-16                                                                              H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                              N  O                                              Q-16                                                                              H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                              Q-16                                                                              H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                              Q-16                                                                              H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                              Q-16                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                              Q-16                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                              CH O                                              Q-16                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                              N  O                                              Q-16                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                              CH S                                              Q-16                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                              N  S                                              Q-16                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                              Q-16                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                              Q-16                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                              Q-16                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                              Q-16                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  Cl  OCH.sub.3                                                                             CH S                                              Q-16                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           NHCH.sub.3                                                                            N  S                                              Q-16                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           N(CH.sub.3).sub.2                                                                     N  S                                              Q-16                                                                              H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                              Q-16                                                                              H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                              Q-16                                                                              H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                              Q-16                                                                              H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                              Q-16                                                                              CH.sub.3                                                                          H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              CH S                                              Q-16                                                                              H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              N  S                                              Q-16                                                                              H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                              Q-16                                                                              H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                              Q-16                                                                              H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                              Q-16                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                              Q-16                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                              CH S                                              Q-16                                                                              H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                              N  S                                              Q-16                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                              Q-17                                                                              H  H  H  H  H  Cl  OCH.sub.3                                                                             CH --                                             Q-17                                                                              H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              CH --                                             Q-17                                                                              H  H  H  H  H  Cl  OC.sub.2 H.sub.5                                                                      CH --                                             Q-17                                                                              H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              N  --                                             Q-17                                                                              H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH --                                             Q-17                                                                              H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             N  --                                             Q-17                                                                              H  H  H  H  H  OCH.sub.3                                                                          OC.sub.2 H.sub.5                                                                      CH --                                             Q-17                                                                              H  H  H  H  H  OCH.sub.3                                                                          OC.sub.2 H.sub.5                                                                      N  --                                             Q-17                                                                              H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              CH --                                             Q-17                                                                              H  H  H  H  H  CH.sub.3                                                                           CH(OCH.sub.3).sub.2                                                                   N  --                                             Q-17                                                                              H  H  H  H  H  CH.sub.3                                                                            ##STR135##                                                                           N  --                                             Q-17                                                                              H  H  H  CH.sub. 3                                                                         H  CH.sub.3                                                                           CH.sub.3                                                                              N  --                                             Q-17                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           OCH.sub.3                                                                             CH --                                             Q-17                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N  --                                             Q-17                                                                              H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                             CH --                                             Q-17                                                                              H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                             N  --                                             Q-17                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                              CH --                                             Q-17                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                              N  --                                             Q-17                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                             CH --                                             Q-17                                                                              CH.sub.3                                                                          H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N  --                                             __________________________________________________________________________

                                      TABLE 2d                                     __________________________________________________________________________     General Structure 1 wherein Q is Q-30                                          R  R.sub.3                                                                           R.sub.4                                                                           R.sub.5                                                                           R.sub.6                                                                           R.sub.7                                                                           R.sub.8                                                                           R.sub.9                                                                           X   Y     Z  m.p. °C.                           __________________________________________________________________________     H  H  H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                           H  H  H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N                                            H  H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                           H  H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N                                            H  H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             N                                            H  H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                           CH.sub.3                                                                          H  H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                           H  CH.sub.3                                                                          H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N                                            H  H  H  H  H  H  H  H  Cl  OCH.sub.3                                                                            CH                                           H  H  CH.sub.3                                                                          H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                           H  H  H  H  CH.sub.3                                                                          H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N                                            H  H  H  H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                           H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             N                                            H  CH.sub.3                                                                          H  H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                           H  CH.sub.3                                                                          H  H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            N                                            H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                           H  H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N                                            H  H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                           H  H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                             N                                            H  H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                           H  H  H  H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            N                                            H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                           H  CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N                                            H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                           H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                             N                                            H  CH.sub.3                                                                          H  H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                           H  CH.sub.3                                                                          H  H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            N                                            H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                           H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                            N                                            H  H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                           H  H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             N                                            H  H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            CH                                           H  H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            N                                            H  H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                           H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N                                            H  CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                           H  CH.sub.3                                                                          H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            N                                            H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                           H  CH.sub.3                                                                          H  H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            N                                            H  CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                           H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            N                                            H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                           H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             N                                            H  H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                           H  H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            N                                            H  H  H  H  CH.sub.3                                                                          CH.sub. 3                                                                         CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                           H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N                                            H  CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                           H  CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                             N                                            H  CH.sub.3                                                                          H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            CH                                           H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            N                                            H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                           H  H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            N                                            H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                           H  CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                             N                                            H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub. 3                                                                           CH                                           H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            N                                            H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                           H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            N                                            CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                             CH                                           H  H  H  H  H  H  H  H  CH.sub.3                                                                           OC.sub.2 H.sub.5                                                                     CH                                           H  H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.2 OCH.sub.3                                                                   CH                                           __________________________________________________________________________

                                      TABLE 2e                                     __________________________________________________________________________     General Structure 1 wherein Q is Q-31.                                         R  R.sub.3                                                                           R.sub.4                                                                           R.sub.5                                                                           R.sub.6                                                                           R.sub.7                                                                           R.sub.8                                                                           R.sub.9                                                                           R.sub.10                                                                          X   Y     Z  m.p. °C.                        __________________________________________________________________________     H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                        H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N                                         H  H  H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                        H  H  H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N                                         H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                        H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             N                                         H  H  H  H  H  H  H  H  H  Cl  OCH.sub.3                                                                            CH                                        H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           C.sub.2 H.sub.5                                                                      CH                                        H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           CF.sub.3                                                                             CH                                        H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           OCF.sub.2 H                                                                          CH                                        H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.2 CF.sub.3                                                                   CH                                        H  CH.sub.3                                                                          H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                        H  H  H  CH.sub.3                                                                          H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             N                                         H  H  H  H  H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                        H  H  H  H  H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            N                                         H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                        H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N                                         H  H  H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                        H  H  H  H  H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                             N                                         H  H  H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                        H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N                                         H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                        H  H  H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                            N                                         H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                        H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                             N                                         H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                        H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N                                         H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                        H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            N                                         H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                        H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             N                                         H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                        H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            N                                         H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                        H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                            N                                         H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                        H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             N                                         H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            CH                                        H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            N                                         H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                        CH.sub.3                                                                          H  H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N                                         H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH *                                      H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N  *                                      H  H  H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH *                                      H  H  H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N  *                                      H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             CH *                                      H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             N  *                                      H  H  H  H  H  H  H  H  H  Cl  OCH.sub.3                                                                            CH *                                      __________________________________________________________________________      ***Wherein W" is O, unless indicated by **** where W" is S in all Tables.

                                      TABLE 2f                                     __________________________________________________________________________     General Structure 1 wherein Q is Q-32.                                         R  R.sub.3                                                                           R.sub.4                                                                           R.sub.5                                                                           R.sub.6                                                                           R.sub.7                                                                           R.sub.8                                                                           R.sub.9                                                                           R.sub.10                                                                          X   Y      Z W"                                     __________________________________________________________________________     H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              CH                                                                               O                                      H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              N O                                      H  H  H  H  H  H  H  H  H  Cl  OCH.sub.3                                                                             CH                                                                               O                                      H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           NHCH.sub.3                                                                            CH                                                                               O                                      H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           N(CH.sub.3).sub.2                                                                     CH                                                                               O                                      H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           CH(OCH.sub.3).sub.2                                                                   CH                                                                               O                                      H  H  H  H  H  H  H  H  H  Br  OCH.sub.3                                                                             CH                                                                               O                                      H  CH.sub.3                                                                          H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              CH                                                                               O                                      H  H  H  CH.sub.3                                                                          H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              N O                                      H  H  H  H  H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             CH                                                                               O                                      H  H  H  H  H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                             N O                                      H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH                                                                               O                                      H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             N O                                      H  H  H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                              CH                                                                               O                                      H  H  H  H  H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                              N O                                      H  H  H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                             CH                                                                               O                                      H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N O                                      H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH                                                                               O                                      H  H  H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                             N O                                      H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              CH                                                                               O                                      H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                              N O                                      H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                             CH                                                                               O                                      H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N O                                      H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH                                                                               O                                      H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                             N O                                      H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                              CH                                                                               O                                      H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                              N O                                      H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           OCH.sub.3                                                                             CH                                                                               O                                      H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                             N O                                      H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH                                                                               O                                      H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                             N O                                      H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub. 3                                                                         H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                              CH                                                                               O                                      H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                              N O                                      H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                             CH                                                                               O                                      H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                             N O                                      H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH                                                                               O                                      CH.sub.3                                                                          H  H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             N O                                      H  CH.sub.3                                                                          H  H  H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                             CH                                                                               O                                      H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             CH                                                                               O                                      H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N O                                      H  H  H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH                                                                               O                                      H  H  H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             N O                                      H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             CH                                                                               S                                      H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N S                                      H  H  H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH                                                                               S                                      H  H  H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             N S                                      H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              CH                                                                               S                                      H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              N S                                      H  H  H  H  H  H  H  H  H  Cl  OCH.sub.3                                                                             CH                                                                               S                                      H  H  H  H  H  H  H  H  H  CH.sub.3                                                                            ##STR136##                                                                           CH                                                                               S                                      H  H  H  H  H  H  H  H  H  Cl  OC.sub.2 H.sub.5                                                                      CH                                                                               S                                      H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           C.sub.2 H.sub.5                                                                       N S                                      H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           OC.sub.2 H.sub.5                                                                      N S                                      H  CH.sub.3                                                                          H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              CH                                                                               S                                      H  H  H  CH.sub.3                                                                          H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              N S                                      H  H  H  H  H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             CH                                                                               S                                      H  H  H  H  H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                             N S                                      H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH                                                                               S                                      H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             N S                                      H  H  H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                              CH                                                                               S                                      H  H  H  H  H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                              N S                                      H  H  H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                             CH                                                                               S                                      H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N S                                      H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH                                                                               S                                      H  H  H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                             N S                                      H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              CH                                                                               S                                      H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                              N S                                      H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                             CH                                                                               S                                      H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N S                                      H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH                                                                               S                                      H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                             N S                                      H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                              CH                                                                               S                                      H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                              N S                                      H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N S                                      H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                             N S                                      H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH                                                                               S                                      H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                             N S                                      H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                              CH                                                                               S                                      H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                              N S                                      H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                             CH                                                                               S                                      H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                             N S                                      H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH                                                                               S                                      CH.sub.3                                                                          H  H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             N S                                      H  CH.sub.3                                                                          H  H  H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                             CH                                                                               S                                      __________________________________________________________________________

                                      TABLE 2g                                     __________________________________________________________________________     General Structure 1                                                            Q  R  R.sub.3                                                                           R.sub.4                                                                           R.sub.5                                                                           R.sub.6                                                                           R.sub.7                                                                           X   Y     Z  m.p. °C.                              __________________________________________________________________________     Q-41                                                                              H  H  H  H  H  H  Cl  OCH.sub.3                                                                            CH                                              Q-41                                                                              H  H  H  H  H  H  Br  OCH.sub.3                                                                            CH                                              Q-41                                                                              H  H  H  H  H  H  Cl  OC.sub.2 H.sub.5                                                                     CH                                              Q-41                                                                              H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             N                                               Q-41                                                                              H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                              Q-41                                                                              H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N                                               Q-41                                                                              H  H  H  H  H  H  OCH.sub.3                                                                          OC.sub.2 H.sub.5                                                                     CH                                              Q-41                                                                              H  H  H  H  H  H  OCH.sub.3                                                                          OC.sub.2 H.sub.5                                                                     N                                               Q-41                                                                              H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                              Q-41                                                                              H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N                                               Q-41                                                                              H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                              Q-41                                                                              H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.2 OCH.sub.3                                                                   CH                                              Q-41                                                                              H  H  H  H  H  H  CH.sub.3                                                                           CF.sub.3                                                                             N                                               Q-41                                                                              H  H  H  H  H  H  CH.sub.3                                                                           OCF.sub.2 H                                                                          N                                               Q-41                                                                              H  CH.sub.3                                                                          H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                              Q-41                                                                              H  H  H  CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                             N                                               Q-41                                                                              H  H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                              Q-41                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N                                               Q-41                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                              Q-41                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N                                               Q-41                                                                              H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                              Q-41                                                                              H  CH.sub.3                                                                          H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             N                                               Q-41                                                                              H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                              Q-41                                                                              H  H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            N                                               Q-41                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                              Q-41                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                            N                                               Q-41                                                                              H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                              Q-41                                                                              H  CH.sub.3                                                                          H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                             N                                               Q-41                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                              Q-41                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            N                                               Q-41                                                                              H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                              Q-41                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            N                                               Q-41                                                                              CH.sub.3                                                                          H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                              Q-41                                                                              CH.sub.3                                                                          H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                              __________________________________________________________________________

                                      TABLE 3a                                     __________________________________________________________________________     General Structure 1 wherein Q is Q-20                                          R  R'.sub.3      X   Y      Z  W' m.p. °C.                              __________________________________________________________________________     H  H             CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                               H  H             CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  H             OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  H             OCH.sub.3                                                                          Cl     CH O                                               H  H             OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                               H  H             CH.sub.3                                                                           CH.sub.3                                                                              CH O                                               H  CH.sub.3      CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                               CH.sub.3                                                                          H             CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               CH.sub.3                                                                          CH.sub.3      OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  H             CH.sub.3                                                                           OC.sub.2 H.sub.5                                                                      N  O                                               H  H             CH.sub.3                                                                           CH.sub.3                                                                              CH S                                               H  H             CH.sub.3                                                                           CH.sub.3                                                                              N  S                                               H  H             CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                               H  H             CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                               H  H             OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  H             OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               CH.sub.3                                                                          H             CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                               H  CH.sub.3      CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                               H  CH.sub.3      CH.sub.3                                                                           CH.sub.2 OCH.sub.3                                                                    N  S                                               H  C.sub.2 H.sub.5                                                                              CH.sub.3                                                                           CH.sub.3                                                                              CH O                                               H  C.sub.2 H.sub.5                                                                              CH.sub.3                                                                           CH.sub.3                                                                              N  O                                               H  C.sub.2 H.sub.5                                                                              CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                               H  C.sub.2 H.sub.5                                                                              CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  C.sub.2 H.sub.5                                                                              OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  C.sub.2 H.sub.5                                                                              OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                               H  C.sub.2 H.sub.5                                                                              OCH.sub.3                                                                          Cl     CH O                                               H  C.sub.2 H.sub.5                                                                              CH.sub.3                                                                           CH.sub.3                                                                              CH S                                               H  C.sub.2 H.sub.5                                                                              CH.sub.3                                                                           CH.sub.3                                                                              N  S                                               H  C.sub.2 H.sub.5                                                                              CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                               H  C.sub.2 H.sub.5                                                                              CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                               H  C.sub.2 H.sub.5                                                                              OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  C.sub.2 H.sub.5                                                                              OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               H  C.sub.2 H.sub.5                                                                              OCH.sub.3                                                                          Cl     CH S                                               H  C.sub.2 H.sub.5                                                                              OCH.sub.3                                                                          N(CH.sub.3).sub.2                                                                     N  S                                               CH.sub.3                                                                           -n-C.sub.3 H.sub.7                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               CH.sub.3                                                                           -n-C.sub.3 H.sub.7                                                                          CH.sub.3                                                                           CH.sub.3                                                                              CH O                                               CH.sub.3                                                                           -n-C.sub.3 H.sub.7                                                                          CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                               CH.sub.3                                                                           -n-C.sub.3 H.sub.7                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               CH.sub.3                                                                           -n-C.sub.3 H.sub.7                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                               CH.sub.3                                                                           -n-C.sub.3 H.sub.7                                                                          OCH.sub.3                                                                          Cl     CH O                                               CH.sub.3                                                                           -n-C.sub.3 H.sub.7                                                                          CH.sub.3                                                                           OCH.sub.2 CF.sub.3                                                                    CH O                                               H   -n-C.sub.3 H.sub.7                                                                          CH.sub.3                                                                           CH.sub.3                                                                              CH S                                               H   -n-C.sub.3 H.sub.7                                                                          CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                               H   -n-C.sub.3 H.sub.7                                                                          CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                               H   -n-C.sub.3 H.sub.7                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H   -n-C.sub.3 H.sub.7                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               H   -n-C.sub.3 H.sub.7                                                                          OCH.sub.3                                                                          Cl     CH S                                               H   -n-C.sub.3 H.sub.7                                                                          CH.sub.3                                                                           CH(OCH.sub.3).sub.2                                                                   CH S                                               H   .sub.-i-C.sub.3 H.sub.7                                                                     CH.sub.3                                                                           CH.sub.3                                                                              CH O                                               H   .sub.-i-C.sub.3 H.sub.7                                                                     CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                               H   .sub.-i-C.sub.3 H.sub.7                                                                     CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H   .sub.-i-C.sub.3 H.sub.7                                                                     OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H   .sub.-i-C.sub.3 H.sub.7                                                                     OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                               H   .sub.-i-C.sub.3 H.sub.7                                                                     OCH.sub.3                                                                          Cl     CH O                                               H   .sub.-i-C.sub.3 H.sub.7                                                                     CH.sub.3                                                                           CH.sub.3                                                                              N  O                                               H   .sub.-i-C.sub.3 H.sub.7                                                                     OCH.sub.3                                                                           ##STR137##                                                                           CH O                                               CH.sub.3                                                                           .sub.-i-C.sub.3 H.sub.7                                                                     OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H   .sub.-i-C.sub.3 H.sub.7                                                                     CH.sub.3                                                                           CH.sub.3                                                                              CH S                                               H   .sub.-i-C.sub.3 H.sub.7                                                                     CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                               H   .sub.-i-C.sub.3 H.sub.7                                                                     CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                               H   .sub.- i-C.sub.3 H.sub.7                                                                    OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H   .sub.-i-C.sub.3 H.sub.7                                                                     OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               H   .sub.-i-C.sub.3 H.sub.7                                                                     OCH.sub.3                                                                          Cl     CH S                                               H   .sub.-i-C.sub.3 H.sub.7                                                                     CH.sub.3                                                                           OC.sub.2 H.sub.5                                                                      N  S                                               H  SCH.sub.3     CH.sub.3                                                                           CH.sub.3                                                                              CH O                                               H  SCH.sub.3     CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                               H  SCH.sub.3     CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  SCH.sub.3     OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  SCH.sub.3     OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                               H  SCH.sub.3     OCH.sub.3                                                                          Cl     CH O                                               H  SCH.sub.3     OCH.sub.3                                                                          NHCH.sub.3                                                                            CH O                                               CH.sub.3                                                                          SCH.sub.3     OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  SCH.sub.3     CH.sub.3                                                                           CH.sub.3                                                                              CH S                                               H  SCH.sub.3     CH.sub.3                                                                           CH.sub.3                                                                              N  S                                               H  SCH.sub.3     CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                               H  SCH.sub.3     CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                               H  SCH.sub.3     OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  SCH.sub.3     OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               H  SCH.sub.3     OCH.sub.3                                                                          Cl     CH S                                               CH.sub.3                                                                          SC.sub.2 H.sub.5                                                                             OCH.sub. 3                                                                         OCH.sub.3                                                                             CH O                                               H  SC.sub.2 H.sub.5                                                                             CH.sub.3                                                                           CH.sub.3                                                                              CH O                                               H  SC.sub.2 H.sub.5                                                                             CH.sub.3                                                                           CH.sub.3                                                                              N  O                                               H  SC.sub.2 H.sub.5                                                                             CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                               H  SC.sub.2 H.sub.5                                                                             CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  SC.sub.2 H.sub.5                                                                             OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  SC.sub.2 H.sub.5                                                                             OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                               H  SC.sub.2 H.sub.5                                                                             OCH.sub.3                                                                          Cl     CH O                                               H  SC.sub.2 H.sub.5                                                                             CH.sub.3                                                                           CH.sub.3                                                                              CH S                                               H  SC.sub.2 H.sub.5                                                                             CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                               H  SC.sub.2 H.sub.5                                                                             CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                               H  SC.sub.2 H.sub.5                                                                             OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  SC.sub.2 H.sub.5                                                                             CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                               H  SC.sub.2 H.sub.5                                                                             OCH.sub.3                                                                          Cl     CH S                                               H  SC.sub.2 H.sub.5                                                                             CH.sub.3                                                                           OC.sub.2 H.sub.5                                                                      N  S                                               H  S -n-C.sub.3 H.sub.7                                                                         CH.sub.3                                                                           CH.sub.3                                                                              CH O                                               H  S -n-C.sub.3 H.sub.7                                                                         CH.sub.3                                                                           CH.sub.2 OCH.sub.3                                                                    CH O                                               H  S -n-C.sub. 3 H.sub.7                                                                        CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                               H  S -n-C.sub.3 H.sub.7                                                                         CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  S -n-C.sub.3 H.sub.7                                                                         OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  S -n-C.sub.3 H.sub.7                                                                         OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                               H  S -n-C.sub.3 H.sub.7                                                                         OCH.sub.3                                                                          Cl     CH O                                               CH.sub.3                                                                          S -n-C.sub.3 H.sub.7                                                                         OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  S -n-C.sub.3 H.sub.7                                                                         CH.sub.3                                                                           CH.sub.3                                                                              CH S                                               H  S -n-C.sub.3 H.sub.7                                                                         CH.sub.3                                                                           CH.sub.3                                                                              N  S                                               H  S -n-C.sub.3 H.sub.7                                                                         CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                               H  S -n-C.sub.3 H.sub.7                                                                         OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  S -n-C.sub.3 H.sub.7                                                                         OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               H  S -n-C.sub.3 H.sub.7                                                                         CH.sub.3                                                                           Cl     CH S                                               H  S -n-C.sub.3 H.sub.7                                                                         CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                               H  S -n-C.sub.3 H.sub.7                                                                         OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  S -n-C.sub.3 H.sub.7                                                                         CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                               CH.sub.3                                                                          S -n-C.sub.4 H.sub.9                                                                         OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  S -n-C.sub.4 H.sub.9                                                                         CH.sub.3                                                                           CH.sub.3                                                                              CH O                                               H  S -n-C.sub.4 H.sub.9                                                                         CH.sub.3                                                                           CH.sub.3                                                                              N  O                                               H  S -n-C.sub.4 H.sub.9                                                                         CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                               H  S -n-C.sub.4 H.sub.9                                                                         CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  S -n-C.sub.4 H.sub.9                                                                         OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  S -n-C.sub.4 H.sub.9                                                                         OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                               H  S -n-C.sub.4 H.sub.9                                                                         OCH.sub.3                                                                          Cl     CH O                                               H  S -n-C.sub.4 H.sub.9                                                                         CH.sub.3                                                                           CH.sub.3                                                                              CH S                                               H  S -n-C.sub.4 H.sub.9                                                                         CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                               H  S -n-C.sub.4 H.sub.9                                                                         CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                               H  S -n-C.sub.4 H.sub.9                                                                         OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               H  S -n-C.sub.4 H.sub.9                                                                         OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  S -n-C.sub.4 H.sub.9                                                                         OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               H  S -n-C.sub.4 H.sub.9                                                                         OCH.sub.3                                                                          OCF.sub.2 H                                                                           N  S                                               H  S -n-C.sub.4 H.sub.9                                                                         OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  S -n-C.sub.4 H.sub.9                                                                         CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  S -n-C.sub.4 H.sub.9                                                                         OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  S -n-C.sub.4 H.sub.9                                                                         CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                               H  S -n-C.sub.4 H.sub.9                                                                         CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  S -n-C.sub.4 H.sub.9                                                                         CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                               H  S -n-C.sub.4 H.sub.9                                                                         OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  S -n-C.sub.4 H.sub.9                                                                         OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               H  S -n-C.sub.4 H.sub.9                                                                         CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                               H  S -n-C.sub.4 H.sub.9                                                                         OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                               H  S -n-C.sub.4 H.sub.9                                                                         OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  S -n-C.sub.4 H.sub.9                                                                         CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                               H  SCH.sub.2 CHCH.sub.2                                                                         CH.sub.3                                                                           CH.sub.3                                                                              CH O                                               H  SCH.sub.2 CHCH.sub.2                                                                         CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  SCH.sub.2 CHCH.sub.2                                                                         CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                               H  SCH.sub.2 CHCH.sub.2                                                                         OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                               H  SCH.sub.2 CHCH.sub.2                                                                         OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  SCH.sub.2 CHCH.sub.2                                                                         OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                               H  SCH.sub.2 CHCH.sub.2                                                                         OCH.sub.3                                                                          Cl     CH O                                               H  SCH.sub.2 CHCH.sub.2                                                                         CH.sub.3                                                                           OCH.sub.2 CF.sub.3                                                                    CH O                                               CH.sub.3                                                                          SCH.sub.2 CHCH.sub.2                                                                         OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  SCH.sub.2 CHCH.sub.2                                                                         CH.sub.3                                                                           CH.sub.3                                                                              CH S                                               H  SCH.sub.2 CHCH.sub.2                                                                         CH.sub.3                                                                           CH.sub.3                                                                              N  S                                               H  SCH.sub.2 CHCH.sub.2                                                                         CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                               H  SCH.sub.2 CHCH.sub.2                                                                         CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                               H  SCH.sub.2 CHCH.sub.2                                                                         OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  SCH.sub.2 CHCH.sub.2                                                                         OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               H  SCH.sub.2 CHCH.sub.2                                                                         OCH.sub.3                                                                          Cl     CH S                                               H   .sub.--ESCHCHCH.sub.3                                                                       CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                               H   .sub.--ESCHCHCH.sub.3                                                                       CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H   .sub.--ESCHCHCH.sub.3                                                                       OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H   .sub.--ESCHCHCH.sub.3                                                                       OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                               H   .sub.--ESCHCHCH.sub.3                                                                       CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                               H   .sub.--ESCHCHCH.sub.3                                                                       CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                               H   .sub.--ESCHCHCH.sub.3                                                                       OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H   .sub.--ESCHCHCH.sub.3                                                                       OCH.sub.3                                                                          Cl     CH S                                               H   .sub.--ZSCHCHCH.sub.3                                                                       CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H   .sub.--ZSCHCHCH.sub.3                                                                       OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H   .sub.--ZSCHCHCH.sub.3                                                                       OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                               H   .sub.--ZSCHCHCH.sub.3                                                                       OCH.sub.3                                                                          Cl     CH O                                               H   .sub.--ZSCHCHCH.sub.3                                                                       CH.sub.3                                                                           CH.sub.3                                                                              CH S                                               H   .sub.--ZSCHCHCH.sub.3                                                                       OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H   .sub.--ZSCHCHCH.sub.3                                                                       CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                               H   .sub.--ZSCHCHCH.sub.3                                                                       OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               H  S(CH.sub.2).sub.2 CHCH.sub.2                                                                 OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  S(CH.sub.2).sub.2 CHCH.sub.2                                                                 OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                               H  S(CH.sub.2).sub.2 CHCH.sub.2                                                                 CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                               H  S(CH.sub.2).sub.2 CHCH.sub.2                                                                 OCH.sub.3                                                                          Cl     CH O                                               H  S(CH.sub.2).sub.2 CHCH.sub.2                                                                 OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  S(CH.sub.2).sub.2 CHCH.sub.2                                                                 CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                               H  S(CH.sub.2).sub.2 CHCH.sub.2                                                                 OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               H  S(CH.sub.2).sub.2 CHCH.sub.2                                                                 CH.sub.3                                                                           CH.sub.3                                                                              CH S                                               H   .sub.--ESCH.sub.2 CHCHCH.sub.3                                                              OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H   .sub.--ESCH.sub.2 CHCHCH.sub.3                                                              OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                               H   .sub.--ESCH.sub.2 CHCHCH.sub.3                                                              CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                               H   .sub.--ESCH.sub.2 CHCHCH.sub.3                                                              OCH.sub.3                                                                          Cl     CH O                                               H   .sub.--ESCH.sub.2 CHCHCH.sub.3                                                              OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H   .sub.--ESCH.sub.2 CHCHCH.sub.3                                                              CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                               H   .sub.--ESCH.sub.2 CHCHCH.sub.3                                                              CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                               H   .sub.--ESCH.sub.2 CHCHCH.sub.3                                                              CH.sub.3                                                                           CH.sub.3                                                                              CH S                                               H   .sub.--ZSCH.sub.2 CHCHCH.sub.3                                                              CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                               H   .sub.--ZSCH.sub.2 CHCHCH.sub.3                                                              CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H   .sub.--ZSCH.sub.2 CHCHCH.sub.3                                                              OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H   .sub.--ZSCH.sub.2 CHCHCH.sub.3                                                              OCH.sub.3                                                                          Cl     CH O                                               H   .sub.--ZSCH.sub.2 CHCHCH.sub.3                                                              CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                               H   .sub.--ZSCH.sub.2 CHCHCH.sub.3                                                              CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                               H   .sub.--ZSCH.sub.2 CHCHCH.sub.3                                                              OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H   .sub.--ZSCH.sub.2 CHCHCH.sub.3                                                              OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               H   .sub.--ESCHCHC.sub.2 H.sub.5                                                                OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H   .sub.--ESCHCHC.sub.2 H.sub.5                                                                OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                               H   .sub.--ESCHCHC.sub.2 H.sub.5                                                                CH.sub.3                                                                           OCh.sub.3                                                                             CH O                                               H   .sub.--ESCHCHC.sub.2 H.sub.5                                                                OCH.sub.3                                                                          Cl     CH O                                               H   .sub.--ESCHCHC.sub.2 H.sub.5                                                                OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H    .sub.--ESCHCHC.sub.2 H.sub.5                                                               CH.sub.3                                                                           CH.sub.3                                                                              CH S                                               H   .sub.--ESCHCHC.sub.2 H.sub.5                                                                CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                               H   .sub.--ESCHCHC.sub.2 H.sub.5                                                                CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                               H   .sub.--ZSCHCHC.sub.2 H.sub.5                                                                OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H   .sub.--ZSCHCHC.sub.2 H.sub.5                                                                OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                               H   .sub.--ZSCHCHC.sub.2 H.sub.5                                                                CH.sub.3                                                                           CH.sub.3                                                                              CH O                                               H   .sub.--ZSCHCHC.sub.2 H.sub.5                                                                CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H   .sub.--ZSCHCHC.sub.2 H.sub.5                                                                OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H   .sub.--ZSCHCHC.sub.2 H.sub.5                                                                CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                               H   .sub.--ZSCHCHC.sub.2 H.sub.5                                                                CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                               H   .sub.--ZSCHCHC.sub.2 H.sub.5                                                                OCH.sub.3                                                                          Cl     CH S                                               H  SCH.sub.2 C CH                                                                               CH.sub.3                                                                           OCh.sub.3                                                                             CH O                                               H  SCH.sub.2 CCH CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  SCH.sub.2 CCH OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  SCH.sub.2 CCH OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                               H  SCH.sub.2 CCH CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                               H  SCH.sub.2 CCH OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               H  SCH.sub.2 CCH OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  SCH.sub.2 CCH OCH.sub.3                                                                          Cl     CH S                                               CH.sub.3                                                                          SCH.sub.2 CCH OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  SCCCH.sub.3   CH.sub.3                                                                           CH.sub.3                                                                              CH O                                               H  SC CCH.sub.3  CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  SCCCH.sub.3   CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                               H  SCCCH.sub.3   OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                               H  SCCCH.sub.3   OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  SCCCH.sub.3   CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                               H  SCCCH.sub.3   CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                               H  SCCCH.sub.3   OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               H  S(CH.sub.2).sub.2 CCH                                                                        CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                               H  S(CH.sub.2).sub.2 CCH                                                                        CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  S(CH.sub.2).sub.2 CCH                                                                        OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  S(CH.sub.2).sub.2 C CH                                                                       OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                               H  S(CH.sub.2).sub.2 CCH                                                                        CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                               H  S(CH.sub.2).sub.2 CCH                                                                        CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                               H  S(CH.sub.2).sub.2 CCH                                                                        OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  S(CH.sub.2).sub.2 CCH                                                                        OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               H  SCH.sub.2 CCCH.sub.3                                                                         CH.sub.3                                                                           CH.sub.                                                                               CH O                                               H  SCH.sub.2 CCCH.sub.3                                                                         CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  SCH.sub.2 CCCH.sub.3                                                                         CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                               H  SCH.sub.2 CCCH.sub.3                                                                         OCH.sub.                                                                           OCH.sub.3                                                                             CH O                                               H  SCH.sub.2 C CCH.sub.3                                                                        OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  SCH.sub.2 CCCH.sub.3                                                                         OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               H  SCH.sub.2 CCCH.sub.3                                                                         CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                               H  SCH.sub.2 CCCH.sub.3                                                                         OCH.sub.3                                                                          Cl     CH S                                               H  SCCC.sub.2 H.sub.5                                                                           CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  SCCC.sub.2 H.sub.5                                                                           OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  SCCC.sub.2 H.sub.5                                                                           OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  SCCC.sub.2 H.sub.5                                                                           CH.sub.3                                                                           CH.sub.3                                                                              CH S                                               CH.sub.3                                                                          SCCC.sub.2 H.sub.5                                                                           CH.sub.3                                                                           OCH.sub.                                                                              CH O                                               H  CH.sub.2 CN   CH.sub.3                                                                           CH.sub.3                                                                              CH O                                               H  CH.sub.2 CN   CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  CH.sub.2 CN   CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                               H  CH.sub.2 CN   OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                               H  CH.sub.2 CN   OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  CH.sub.2 CN   OCH.sub.3                                                                          Cl     CH O                                               H  CH.sub.2 CN   CH.sub.3                                                                           NHCH.sub.3                                                                            N  O                                               CH.sub.3                                                                          CH.sub.2 CN   OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  CH.sub.2 CN   CH.sub.3                                                                           CH.sub.3                                                                              CH S                                               H  CH.sub.2 CN   CH.sub.3                                                                           CH.sub.3                                                                              N  S                                               H  CH.sub.2 CN   CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                               H  CH.sub.2 CN   CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                               H  CH.sub.2 CN   OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  CH.sub.2 CN   OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               H  CH.sub.2 CN   OCH.sub.3                                                                          Cl     CH S                                               CH.sub.3                                                                          CH.sub.2 CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                               H  CH.sub.2 CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                           CH.sub.3                                                                              CH O                                               H  CH.sub.2 CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                               H  CH.sub.2 CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  CH.sub.2 CO.sub.2 CH.sub.3                                                                   OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  CH.sub.2 CO.sub.2 CH.sub.3                                                                   OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                               H  CH.sub.2 CO.sub.2 CH.sub.3                                                                   OCH.sub.3                                                                          Cl     CH O                                               H  CH.sub.2 CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                           CH.sub.3                                                                              CH S                                               H  CH.sub.2 CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                               H  CH.sub.2 CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                               H  CH.sub.2 CO.sub.2 CH.sub.3                                                                   OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               H  CH.sub.2 CO.sub.2 CH.sub.3                                                                   OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  CH.sub.2 CO.sub.2 CH.sub.3                                                                   OCH.sub.3                                                                          Cl     CH S                                               H  CH.sub.2 CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                           N(CH.sub.3).sub.2                                                                     N  S                                               H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                                                            CH.sub.3                                                                           CH.sub.3                                                                              CH O                                               H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                                                            CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                                                            CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                               H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                                                            OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                               H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                                                            OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                                                            OCH.sub.3                                                                          Cl     CH O                                               H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                                                            OC.sub.2 H.sub.5                                                                   Cl     CH O                                               CH.sub.3                                                                          CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                                                            OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                                                            CH.sub.3                                                                           CH.sub.3                                                                              CH S                                               H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                                                            CH.sub.3                                                                           CH.sub.3                                                                              N  S                                               H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                                                            CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                               H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                                                            CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                               H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                                                            OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                                                            OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                                                            OCH.sub.3                                                                          Cl     CH S                                               CH.sub.3                                                                          CH.sub.2 OCH.sub.3                                                                           OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  CH.sub.2 OCH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                              CH O                                               H  CH.sub.2 OCH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                              N  O                                               H  CH.sub.2 OCH.sub.3                                                                           CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                               H  CH.sub.2 OCH.sub.3                                                                           CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  CH.sub.2 OCH.sub.3                                                                           OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  CH.sub.2 OCH.sub.3                                                                           OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                               H  CH.sub.2 OCH.sub.3                                                                           OCH.sub.3                                                                          Cl     CH O                                               H  CH.sub.2 OCH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                              CH S                                               H  CH.sub.2 OCH.sub.3                                                                           CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                               H  CH.sub.2 OCH.sub.3                                                                           CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                               H  CH.sub.2 OCH.sub.3                                                                           OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               H  CH.sub.2 OCH.sub.3                                                                           OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  CH.sub.2 OCH.sub.3                                                                           OCH.sub.3                                                                          Cl     CH S                                               H  CH.sub.2 OCH.sub.3                                                                           CH.sub.3                                                                           CH(OCH.sub.3).sub.2                                                                   CH S                                               H  CH.sub.2 OC.sub.2 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                              CH O                                               H  CH.sub.2 OC.sub.2 H.sub.5                                                                    CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  CH.sub.2 OC.sub.2 H.sub.5                                                                    CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                               H  CH.sub.2 OC.sub.2 H.sub.5                                                                    OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                               H  CH.sub.2 OC.sub.2 H.sub.5                                                                    OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  CH.sub.2 OC.sub.2 H.sub.5                                                                    OCH.sub.3                                                                          Cl     CH O                                               H  CH.sub.2 OC.sub.2 H.sub.5                                                                    OCH.sub.3                                                                          Br     CH O                                               CH.sub.3                                                                          CH.sub.2 OC.sub.2 H.sub.5                                                                    CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                               H  CH.sub.2 OC.sub.2 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                              CH S                                               H  CH.sub.2 OC.sub.2 H.sub.5                                                                    CH.sub.3                                                                           CH.sub.3                                                                              N  S                                               H  CH.sub.2 OC.sub.2 H.sub.5                                                                    CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                               H  CH.sub.2 OC.sub.2 H.sub.5                                                                    CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                               H  CH.sub.2 OC.sub.2 H.sub.5                                                                    OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  CH.sub.2 OC.sub.2 H.sub.5                                                                    OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               H  CH.sub.2 OC.sub.2 H.sub.5                                                                    OCH.sub.3                                                                          Cl     CH S                                               CH.sub.3                                                                          (CH.sub.2).sub.2 COCH.sub.3                                                                  OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  (CH.sub.2).sub.2 COCH.sub.3                                                                  CH.sub.3                                                                           CH.sub.3                                                                              CH O                                               H  (CH.sub.2).sub.2 COCH.sub.3                                                                  CH.sub.3                                                                           CH.sub.3                                                                              N  O                                               H  (CH.sub.2).sub.2 COCH.sub.3                                                                  CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                               H  (CH.sub.2).sub.2 COCH.sub.3                                                                  CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  (CH.sub.2).sub.2 COCH.sub.3                                                                  OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  (CH.sub.2).sub.2 COCH.sub.3                                                                  OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                               H  (CH.sub.2).sub.2 COCH.sub.3                                                                  OCH.sub.3                                                                          Cl     CH O                                               H  (CH.sub.2).sub. 2 COCH.sub.3                                                                 CH.sub.3                                                                           CH.sub.3                                                                              CH S                                               H  (CH.sub.2).sub.2 COCH.sub.3                                                                  CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                               H  (CH.sub.2).sub.2 COCH.sub.3                                                                  CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                               H  (CH.sub.2).sub.2 COCH.sub.3                                                                  OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               H  (CH.sub.2).sub.2 COCH.sub.3                                                                  OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  (CH.sub.2).sub.2 COCH.sub.3                                                                  OCH.sub.3                                                                          Cl     CH S                                               H  (CH.sub.2).sub.2 COCH.sub.3                                                                  CH.sub.3                                                                            ##STR138##                                                                           CH S                                               H  (CH.sub.2).sub.2 CN                                                                          CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                               H  (CH.sub.2).sub.2 CN                                                                          CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  (CH.sub.2).sub.2 CN                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  (CH.sub.2).sub.2 CN                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                               H  (CH.sub.2).sub.2 CN                                                                          CH.sub.3                                                                           CH.sub.3                                                                              CH S                                               H  (CH.sub.2).sub.2 CN                                                                          CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                               H  (CH.sub.2).sub.2 CN                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  (CH.sub.2).sub.2 CN                                                                          OCH.sub.3                                                                          Cl     CH S                                               H  CH(CH.sub. 3)CN                                                                              OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  CH(CH.sub.3)CN                                                                               OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                               H  CH(CH.sub.3)CN                                                                               CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                               H  CH(CH.sub.3)CN                                                                               CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                               H  (CH.sub.2).sub.3 CN                                                                          CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                               H  (CH.sub.2).sub.3 CN                                                                          CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  (CH.sub.2).sub.3 CN                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  (CH.sub.2).sub.3 CN                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                               H  (CH.sub.2).sub.3 CN                                                                          CH.sub.3                                                                           CH.sub.3                                                                              CH S                                               H  (CH.sub.2).sub.3 CN                                                                          CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                               H  (CH.sub.2).sub.3 CN                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                             CH.sub.3                                                                          S                                               H  (CH.sub.2).sub.3 CN                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               H  CH.sub.2 CH(CH.sub.3)CN                                                                      CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                               H  CH.sub.2 CH(CH.sub.3)CN                                                                      CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  CH.sub.2 CH(CH.sub.3)CN                                                                      OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  CH.sub.2 CH(CH.sub.3)CN                                                                      OCH.sub.3                                                                          Cl     CH S                                               H  CH.sub.2 CH(CH.sub.3)CN                                                                      CH.sub.3                                                                           CH.sub.3                                                                              CH O                                               H  CH.sub.2 CH(CH.sub.3)CN                                                                      CH.sub. 3                                                                          OCH.sub.3                                                                             N  O                                               H  CH.sub.2 CH(CH.sub.3)CN                                                                      OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  CH.sub.2 CH(CH.sub.3)CN                                                                      OCH.sub.3                                                                          CH.sub.3                                                                              CH S                                               CH.sub.3                                                                          CH.sub.2 CH(CH.sub.3)CN                                                                      OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  CH(CN)C.sub.2 H.sub.5                                                                        CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  CH(CN)C.sub.2 H.sub.5                                                                        OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  CH(CN)C.sub.2 H.sub.5                                                                        OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               H  CH(CN)C.sub.2 H.sub.5                                                                        OCH.sub.3                                                                          Cl     CH S                                               H  C(CH.sub.3).sub.2 CN                                                                         CH.sub.3                                                                           CH.sub.3                                                                              CH O                                               H  C(CH.sub.3).sub.2 CN                                                                         OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  C(CH.sub.3).sub.2 CN                                                                         OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               H  C(CH.sub.3).sub.2 CN                                                                         OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  CH(CH.sub.3)CO.sub.2 CH.sub.3                                                                OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  CH(CH.sub.3)CO.sub.2 CH.sub.3                                                                OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                               H  CH(CH.sub.3)CO.sub.2 CH.sub.3                                                                CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                               H  CH(CH.sub.3)CO.sub.2 CH.sub.3                                                                CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                               H  (CH.sub.2).sub.3 CO.sub.2 CH.sub.3                                                           CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                               H  (CH.sub.2).sub.3 CO.sub.2 CH.sub.3                                                           CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  (CH.sub.2).sub.3 CO.sub.2 CH.sub.3                                                           OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  (CH.sub.2).sub.3 CO.sub.2 CH.sub.3                                                           OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                               H  (CH.sub.2).sub.3 CO.sub.2 CH.sub.3                                                           CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                               H  (CH.sub.2).sub.3 CO.sub.2 CH.sub.3                                                           CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                               H  (CH.sub.2).sub.3 CO.sub.2 CH.sub.3                                                           OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  (CH.sub.2).sub.3 CO.sub.2 CH.sub.3                                                           OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               H  CH.sub.2 CH(CH.sub.3)CO.sub.2 CH.sub.3                                                       CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                               H  CH.sub.2 CH(CH.sub.3)CO.sub.2 CH.sub.3                                                       CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  CH.sub.2 CH(CH.sub.3)CO.sub.2 CH.sub.3                                                       OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  CH.sub.2 CH(CH.sub.3)CO.sub.2 CH.sub.3                                                       OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               H  CH.sub.2 CH(CH.sub.3)CO.sub.2 CH.sub.3                                                       CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                               H  CH.sub.2 CH(CH.sub.3)CO.sub.2 CH.sub.3                                                       CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  CH.sub.2 CH(CH.sub.3 )CO.sub.2 CH.sub.3                                                      OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  CH.sub.2 CH(CH.sub.3)CO.sub.2 CH.sub.3                                                       OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               H  CH(CO.sub.2 CH.sub.3)C.sub.2 H.sub.5                                                         CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  CH(CO.sub.2 CH.sub.3)C.sub.2 H.sub.5                                                         OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  CH(CO.sub.2 CH.sub.3)C.sub.2 H.sub.5                                                         OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               H  CH(CO.sub.2 CH.sub.3)C.sub.2 H.sub.5                                                         OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  C(CH.sub.3).sub.2 CO.sub.3 CH.sub.3                                                          CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  C(CH.sub.3).sub.2 CO.sub.3 CH.sub.3                                                          OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  C(CH.sub.3).sub.2 CO.sub.3 CH.sub.3                                                          CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                               H  C(CH.sub.3).sub.2 CO.sub.3 CH.sub.3                                                          OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  (CH.sub.2).sub.2 CO.sub.2 C.sub.2 H.sub.5                                                    CH.sub.3                                                                           CH.sub.3                                                                              CH O                                               H  (CH.sub.2).sub.2 CO.sub.2 C.sub.2 H.sub.5                                                    CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  (CH.sub.2).sub.2 CO.sub.2 C.sub.2 H.sub.5                                                    OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  (CH.sub.2).sub. 2 CO.sub.2 C.sub.2 H.sub.5                                                   OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                               H  (CH.sub.2).sub.2 CO.sub.2 C.sub.2 H.sub.5                                                    OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  (CH.sub.2).sub.2 CO.sub.2 C.sub.2 H.sub.5                                                    CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                               H  (CH.sub.2).sub.2 CO.sub.2 C.sub.2 H.sub.5                                                    OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  (CH.sub.2).sub.2 CO.sub.2 C.sub.2 H.sub.5                                                    OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               H  CH(CH.sub.3)CO.sub.2 C.sub.2 H.sub.5                                                         OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  CH(CH.sub.3)CO.sub.2 C.sub.2 H.sub.5                                                         OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                               H  CH(CH.sub.3)CO.sub.2 C.sub.2 H.sub.5                                                         CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                               H  CH(CH.sub.3)CO.sub.2 C.sub.2 H.sub.5                                                         CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                               H  (CH.sub.2).sub.3 CO.sub.2 C.sub.2 H.sub.5                                                    CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                               H  (CH.sub.2).sub.3 CO.sub.2 C.sub.2 H.sub.5                                                    CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  (CH.sub.2).sub.3 CO.sub.2 C.sub.2 H.sub.5                                                    OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  (CH.sub.2).sub.3 CO.sub.2 C.sub. 2 H.sub.5                                                   OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                               H  (CH.sub.2).sub.3 CO.sub.2 C.sub.2 H.sub.5                                                    CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                               H  (CH.sub.2).sub.3 CO.sub.2 C.sub.2 H.sub.5                                                    CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                               H  (CH.sub.2).sub.3 CO.sub.2 C.sub.2 H.sub.5                                                    OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  (CH.sub.2).sub.3 CO.sub.2 C.sub.2 H.sub.5                                                    OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               H  CH.sub.2 CH(CH.sub.3)CO.sub.2 C.sub.2 H.sub.5                                                CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                               H  CH.sub.2 CH(CH.sub.3)CO.sub.2 C.sub.2 H.sub.5                                                CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  CH.sub.2 CH(CH.sub.3)CO.sub.2 C.sub.2 H.sub.5                                                OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  CH.sub.2 CH(CH.sub.3)CO.sub.2 C.sub.2 H.sub.5                                                OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               H  CH.sub.2 CH(CH.sub.3)CO.sub.2 C.sub.2 H.sub.5                                                CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                               H  CH.sub.2 CH(CH.sub.3)CO.sub.2 C.sub.2 H.sub.5                                                CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  CH.sub.2 CH(CH.sub.3)CO.sub.2 C.sub.2 H.sub.5                                                CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                               H  CH.sub.2 CH(CH.sub. 3)CO.sub.2 C.sub.2 H.sub.5                                               OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               H  CH(CO.sub.2 C.sub.2 H.sub.5)C.sub.2 H.sub.5                                                  CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  CH(CO.sub.2 C.sub.2 H.sub.5)C.sub.2 H.sub.5                                                  OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  CH(CO.sub.2 C.sub.2 H.sub.5)C.sub.2 H.sub.5                                                  OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               H  CH(CO.sub.2 C.sub.2 H.sub.5)C.sub.2 H.sub.5                                                  OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  C(CH.sub.3).sub.2 CO.sub.2 C.sub.2 H.sub.5                                                   CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  C(CH.sub.3).sub.2 CO.sub.2 C.sub.2 H.sub.5                                                   OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  C(CH.sub.3).sub.2 CO.sub.2 C.sub.2 H.sub.5                                                   CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  C(CH.sub.3).sub.2 CO.sub.2 C.sub.2 H.sub.5                                                   OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  (CH.sub.2).sub.2 OCH.sub.3                                                                   CH.sub.3                                                                           CH.sub.3                                                                              CH O                                               H  (CH.sub.2).sub.2 OCH.sub.3                                                                   CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  (CH.sub.2).sub.2 OCH.sub.3                                                                   OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  (CH.sub.2).sub.2 OCH.sub.3                                                                   OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                               H  (CH.sub.2).sub.2 OCH.sub.3                                                                   OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  (CH.sub.2).sub.2 OCH.sub.3                                                                   CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                               H  (CH.sub.2).sub.2 OCH.sub.3                                                                   OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  (CH.sub.2).sub.2 OCH.sub.3                                                                   OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               H  CH(CH.sub.3)OCH.sub.3                                                                        OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  CH(CH.sub.3)OCH.sub.3                                                                        OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                               H  CH(CH.sub.3)OCH.sub.3                                                                        CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                               H  CH(CH.sub.3)OCH.sub.3                                                                        CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                               H  (CH.sub.2).sub.3 OCH.sub.3                                                                   CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                               H  (CH.sub.2).sub.3 OCH.sub.3                                                                   CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  (CH.sub.2).sub.3 OCH.sub.3                                                                   OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  (CH.sub.2).sub.3 OCH.sub.3                                                                   OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                               H  (CH.sub.2).sub.3 OCH.sub.3                                                                   CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                               H  (CH.sub.2).sub.3 OCH.sub.3                                                                   CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                               H  (CH.sub.2).sub.3 OCH.sub.3                                                                   OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  (CH.sub.2).sub.3 OCH.sub.3                                                                   OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               H  CH.sub.2 CH(CH.sub.3)OCH.sub.3                                                               CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                               H  CH.sub.2 CH(CH.sub.3)OCH.sub.3                                                               CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  CH.sub.2 CH(CH.sub.3)OCH.sub.3                                                               OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  CH.sub.2 CH(CH.sub.3)OCH.sub.3                                                               OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               H  CH.sub.2 CH(CH.sub.3)OCH.sub.3                                                               CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                               H  CH.sub.2 CH(CH.sub.3)OCH.sub.3                                                               CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  CH.sub.2 CH(CH.sub.3)OCH.sub.3                                                               CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                               H  CH.sub.2 CH(CH.sub.3)OCH.sub.3                                                               OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               H  CH(OCH.sub.3)C.sub.2 H.sub.5                                                                 CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  CH(OCH.sub.3)C.sub.2 H.sub.5                                                                 OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  CH(OCH.sub.3)C.sub.2 H.sub.5                                                                 OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               H  CH(OCH.sub.3)C.sub.2 H.sub.5                                                                 OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  C(CH.sub.3).sub.2 OCH.sub.3                                                                  CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  C(CH.sub.3).sub.2 OCH.sub.3                                                                  OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  C(CH.sub.3).sub.2 OCH.sub.3                                                                  CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  C(CH.sub.3).sub.2 OCH.sub.3                                                                  OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  (CH.sub.2).sub.2 OC.sub.2 H.sub.5                                                            CH.sub.3                                                                           CH.sub.3                                                                              CH O                                               H  (CH.sub.2).sub.2 OC.sub.2 H.sub.5                                                            CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  (CH.sub.2).sub.2 OC.sub.2 H.sub.5                                                            OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  (CH.sub.2).sub.2 OC.sub.2 H.sub.5                                                            OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                               H  (CH.sub.2).sub.2 OC.sub.2 H.sub.5                                                            OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  (CH.sub.2).sub.2 OC.sub.2 H.sub.5                                                            CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                               H  (CH.sub.2).sub.2 OC.sub.2 H.sub.5                                                            OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  (CH.sub.2).sub.2 OC.sub.2 H.sub.5                                                            OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               H  CH(CH.sub.3)OC.sub.2 H.sub.5                                                                 OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  CH(CH.sub.3)OC.sub.2 H.sub.5                                                                 OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                               H  CH(CH.sub.3)OC.sub.2 H.sub.5                                                                 CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                               H  CH(CH.sub.3)OC.sub.2 H.sub.5                                                                 CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                               H  (CH.sub.2).sub.3 OC.sub.2 H.sub.5                                                            CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                               H  (CH.sub.2).sub.3 OC.sub.2 H.sub.5                                                            CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  (CH.sub.2).sub.3 OC.sub.2 H.sub.5                                                            OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  (CH.sub.2).sub.3 OC.sub.2 H.sub.5                                                            OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                               H  (CH.sub.2).sub.3 OC.sub.2 H.sub.5                                                            CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                               H  (CH.sub.2).sub.3 OC.sub.2 H.sub.5                                                            CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                               H  (CH.sub.2).sub.3 OC.sub.2 H.sub.5                                                            OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  (CH.sub.2).sub.3 OC.sub.2 H.sub.5                                                            OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               H  CH.sub.2 CH(CH.sub.3)OC.sub.2 H.sub.5                                                        CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                               H  CH.sub.2 CH(CH.sub.3)OC.sub.2 H.sub.5                                                        CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  CH.sub.2 CH(CH.sub.3)OC.sub.2 H.sub.5                                                        OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  CH.sub.2 CH(CH.sub.3)OC.sub.2 H.sub.5                                                        OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               H  CH(CH.sub.3)CH.sub.2 OC.sub.2 H.sub.5                                                        CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                               H  CH(CH.sub.3)CH.sub.2 OC.sub.2 H.sub.5                                                        CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  CH(CH.sub.3)CH.sub.2 OC.sub.2 H.sub.5                                                        CH.sub. 3                                                                          OCH.sub.3                                                                             CH S                                               H  CH(CH.sub.3)CH.sub.2 OC.sub.2 H.sub.5                                                        OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               H  CH(OC.sub.2 H.sub.5)C.sub.2 H.sub.5                                                          CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  CH(OC.sub.2 H.sub.5)C.sub.2 H.sub.5                                                          OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  CH(OC.sub.2 H.sub.5)C.sub.2 H.sub.5                                                          OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               H  CH(OC.sub.2 H.sub.5)C.sub.2 H.sub.5                                                          OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  CH(CH.sub.3).sub.2 OC.sub.2 H.sub.5                                                          CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  CH(CH.sub.3).sub.2 OC.sub.2 H.sub.5                                                          OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  CH(CH.sub.3).sub.2 OC.sub.2 H.sub.5                                                          CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  C(CH.sub.3).sub.2 OC.sub.2 H.sub.5                                                           OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  (CH.sub.2)CH.sub.2 COCH.sub.3                                                                CH.sub.3                                                                           CH.sub.3                                                                              CH O                                               H  (CH.sub.2)CH.sub.2 COCH.sub.3                                                                CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  (CH.sub.2)CH.sub.2 COCH.sub.3                                                                OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  (CH.sub.2)CH.sub.2 COCH.sub.3                                                                OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                               H  (CH.sub.2)CH.sub.2 COCH.sub.3                                                                OCH.sub. 3                                                                         OCH.sub.3                                                                             CH S                                               H  (CH.sub.2)CH.sub.2 COCH.sub.3                                                                CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                               H  (CH.sub.2)CH.sub.2 COCH.sub.3                                                                OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  (CH.sub.2)CH.sub.2 COCH.sub.3                                                                OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               H  CH(CH.sub.3)CH.sub.2 COCH.sub.3                                                              OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  CH(CH.sub.3)CH.sub.2 COCH.sub.3                                                              OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                               H  CH(CH.sub.3)CH.sub.2 COCH.sub.3                                                              CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                               H  CH(CH.sub.3)CH.sub.2 COCH.sub.3                                                              CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                               H  (CH.sub.2).sub.3 CH.sub.2 COCH.sub.3                                                         CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                               H  (CH.sub.2).sub.3 CH.sub.2 COCH.sub.3                                                         CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  (CH.sub.2).sub.3 CH.sub.2 COCH.sub.3                                                         OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  (CH.sub.2).sub.3 CH.sub.2 COCH.sub.3                                                         OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                               H  (CH.sub.2).sub.3 CH.sub.2 COCH.sub.3                                                         CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                               H  (CH.sub.2).sub.3 CH.sub.2 COCH.sub.3                                                         CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                               H  (CH.sub.2).sub.3 CH.sub.2 COCH.sub.3                                                         OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  (CH.sub.2).sub.3 CH.sub.2 COCH.sub.3                                                         OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               H  CH.sub.2 CH(CH.sub.3)CH.sub.2 COCH.sub.3                                                     CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                               H  CH.sub.2 CH(CH.sub.3)CH.sub.2 COCH.sub.3                                                     CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  CH.sub.2 CH(CH.sub.3)CH.sub.2 COCH.sub.3                                                     OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  CH.sub.2 CH(CH.sub.3)CH.sub.2 COCH.sub.3                                                     OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               H  CH(CH.sub.3)CH.sub.2 CH.sub.2 COCH.sub.3                                                     CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                               H  CH(CH.sub.3)CH.sub.2 CH.sub.2 COCH.sub.3                                                     CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  CH(CH.sub.3)CH.sub.2 CH.sub.2 COCH.sub.3                                                     CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                               H  CH(CH.sub.3)CH.sub.2 CH.sub.2 COCH.sub.3                                                     OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               H  CH(C.sub.2 H.sub.5)CH.sub.2 COCH.sub.3                                                       CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  CH(C.sub.2 H.sub.5)CH.sub.2 OCH.sub.3                                                        OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  CH(C.sub.2 H.sub.5)CH.sub.2 OCH.sub.3                                                        OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                               H  CH(C.sub.2 H.sub.5)CH.sub.2 OCH.sub.3                                                        OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  CH(CH.sub.3).sub. 2 CH.sub.2 COCH.sub.3                                                      CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  CH(CH.sub.3).sub.2 CH.sub.2 COCH.sub.3                                                       OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                               H  CH(CH.sub.3).sub.2 CH.sub.2 COCH.sub.3                                                       CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                               H  C(CH.sub.3).sub.2 CH.sub.2 COCH.sub.3                                                        OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                               H  H             OCH.sub.3                                                                          OCH.sub.3                                                                             CH O*                                              H  H             OCH.sub.3                                                                          OCH.sub.3                                                                             CH S*                                              H  CH.sub.3      OCH.sub.3                                                                          OCH.sub.3                                                                             CH O*                                              H  CH.sub.3      OCH.sub.3                                                                          OCH.sub.3                                                                             CH S*                                              H  SCH.sub.3     OCH.sub.3                                                                          OCH.sub.3                                                                             CH O*                                              H  SCH.sub.3     OCH.sub.3                                                                          OCH.sub.3                                                                             CH S*                                              H  SCH.sub.2 CHCH.sub.2                                                                         OCH.sub.3                                                                          OCH.sub.3                                                                             CH O*                                              H  SCH.sub.2 CHCH.sub.2                                                                         OCH.sub.3                                                                          OCH.sub.3                                                                             CH S*                                              H  SH            OCH.sub.3                                                                          OCH.sub.3                                                                             CH O*                                              H  SH            OCH.sub.3                                                                          OCH.sub.3                                                                             CH S*                                              __________________________________________________________________________      W is O, unless indicated by * where W is S in all Tables.                

                  TABLE 3b                                                         ______________________________________                                         General Structure 1 wherein Q is Q-28.                                                                                     m.p.                               R     R.sub.3                                                                               R.sub.4 X     Y       Z        °C.                         ______________________________________                                         H     H      H       CH.sub.3                                                                             OCH.sub.3                                                                              CH                                          H     H      H       CH.sub.3                                                                             OCH.sub.3                                                                              N                                           H     H      H       OCH.sub.3                                                                            OCH.sub.3                                                                              CH                                          H     H      H       OCH.sub.3                                                                            OCH.sub.3                                                                              N                                           H     H      H       CH.sub.3                                                                             CH.sub.3                                                                               CH                                          H     H      H       CH.sub.3                                                                             CH.sub.3                                                                               N                                           H     CH.sub.3                                                                              H       CH.sub.3                                                                             OCH.sub.3                                                                              CH                                          H     H      H       Br    OCH.sub.3                                                                              CH                                          H     H      CH.sub.3                                                                               CH.sub.3                                                                             OCH.sub.3                                                                              N                                           H     CH.sub.3                                                                              CH.sub.3                                                                               OCH.sub.3                                                                            OCH.sub.3                                                                              CH                                          CH.sub.3                                                                             CH.sub.3                                                                              CH.sub.3                                                                               OCH.sub.3                                                                            OCH.sub.3                                                                              N                                           H     H      H       CH.sub.3                                                                              ##STR139##                                                                            CH                                          H     H      H       CH.sub.3                                                                             C.sub.2 H.sub.5                                                                        CH                                          H     CH.sub.3                                                                              H       CH.sub.3                                                                             CH.sub.3                                                                               CH       220-222                            H     CH.sub.3                                                                              H       CH.sub.3                                                                             OCH.sub.3                                                                              N        189-192                            H     CH.sub.3                                                                              H       OCH.sub.3                                                                            OCH.sub.3                                                                              CH       198-207                            H     CH.sub.3                                                                              H       OCH.sub.3                                                                            OCH.sub.3                                                                              N                                           H     CH.sub.3                                                                              H       OCH.sub.3                                                                            Cl      CH       217-218                            H     CH.sub.3                                                                              H       CH.sub.3                                                                             CH.sub.3                                                                               N                                           H     Cl     H       CH.sub.3                                                                             CH.sub.3                                                                               CH       211-213                            H     Cl     H       CH.sub.3                                                                             CH.sub.3                                                                               N        195-197                            H     Cl     H       CH.sub.3                                                                             OCH.sub.3                                                                              CH                                          H     Cl     H       CH.sub.3                                                                             OCH.sub.3                                                                              N        175-177                            H     Cl     H       OCH.sub.3                                                                            OCH.sub.3                                                                              CH       204-205                            H     Cl     H       OCH.sub.3                                                                            OCH.sub.3                                                                              N        187-188                            H     Cl     H       OCH.sub.3                                                                            Cl      CH       205-206                            H     Cl     CH.sub.3                                                                               CH.sub.3                                                                             OCH.sub.3                                                                              CH                                          H     Cl     CH.sub.3                                                                               CH.sub.3                                                                             OCH.sub.3                                                                              N                                           H     Cl     CH.sub.3                                                                               OCH.sub.3                                                                            OCH.sub.3                                                                              CH                                          H     Cl     CH.sub.3                                                                               OCH.sub.3                                                                            OCH.sub.3                                                                              N                                           H     Br     H       OCH.sub.3                                                                            OCH.sub.3                                                                              CH                                          H     Br     H       CH.sub.3                                                                             CH.sub.3                                                                               CH                                          H     Br     H       CH.sub.3                                                                             OCH.sub.3                                                                              N                                           H     Br     H       CH.sub.3                                                                             OCH.sub.3                                                                              CH                                          H     Br     H       OCH.sub.3                                                                            OCH.sub.3                                                                              N                                           H     Br     H       OCH.sub.3                                                                            OCH.sub.3                                                                              CH                                          H     Br     H       OCH.sub.3                                                                            Cl      CH                                          H     H      H       OCH.sub.3                                                                            OCH.sub.3                                                                              CH   *                                      H     CH.sub.3                                                                              H       OCH.sub.3                                                                            OCH.sub.3                                                                              CH   *                                      H     H      CH.sub.3                                                                               OCH.sub.3                                                                            OCH.sub.3                                                                              CH   *                                      H     CH.sub.3                                                                              CH.sub.3                                                                               OCH.sub.3                                                                            OCH.sub.3                                                                              CH   *                                      H     Cl     H       OCH.sub.3                                                                            OCH.sub.3                                                                              CH   *                                      H     Cl     CH.sub.3                                                                               OCH.sub.3                                                                            OCH.sub.3                                                                              CH   *                                      H     Br     H       OCH.sub.3                                                                            OCH.sub.3                                                                              CH   *                                      H     Br     CH.sub.3                                                                               OCH.sub.3                                                                            OCH.sub.3                                                                              CH   *                                      ______________________________________                                          *Wherein W is O, unless indicated by * where W is S in all Tables.       

                                      TABLE 3c                                     __________________________________________________________________________     General Structure 1                                                                                           m.p.                                            Q   R  R.sub.3                                                                            R.sub.4                                                                            X    Y     Z  n'                                                                               °C.                                      __________________________________________________________________________     Q-33                                                                               H  H   H   CH.sub.3                                                                            OCH.sub.3                                                                            CH 0                                                 Q-33                                                                               H  H   H   CH.sub.3                                                                            OCH.sub.3                                                                            N  0 173-176 (d)                                     Q-33                                                                               H  H   H   OCH.sub.3                                                                           OCH.sub.3                                                                            CH 0 198-203 (d)                                     Q-33                                                                               H  H   H   OCH.sub.3                                                                           OCH.sub.3                                                                            N  0 172-174                                         Q-33                                                                               H  H   H   CH.sub.3                                                                            CH.sub.3                                                                             CH 0 130-133                                         Q-33                                                                               H  3-CH.sub.3                                                                         H   CH.sub.3                                                                            OCH.sub.3                                                                            CH 0                                                 Q-33                                                                               H  4-CH.sub.3                                                                         H   CH.sub.3                                                                            OCH.sub.3                                                                            CH 0                                                 Q-33                                                                               H  5-CH.sub.3                                                                         H   CH.sub.3                                                                            OCH.sub.3                                                                            CH 0                                                 Q-33                                                                               H  H   H   CH.sub.3                                                                            CH.sub.3                                                                             N  0                                                 Q-33                                                                               H  6-CH.sub.3                                                                         H   CH.sub.3                                                                            OCH.sub.3                                                                            CH 0                                                 Q-33                                                                               H  3-CH.sub.3                                                                         5-CH.sub.3                                                                         CH.sub.3                                                                            OCH.sub.3                                                                            N  0                                                 Q-33                                                                               H  4-CH.sub.3                                                                         6-CH.sub.3                                                                         CH.sub.3                                                                            OCH.sub.3                                                                            N  0                                                 Q-33                                                                               CH.sub.3                                                                          H   H   OCH.sub.3                                                                           OCH.sub.3                                                                            CH 0                                                 Q-33                                                                               H  H   H   CH.sub.3                                                                            CH.sub.2 OCH.sub.3                                                                   CH 0                                                 Q-33                                                                               H  H   H   Cl   OC.sub.2 H.sub.5                                                                     CH 0                                                 Q-33                                                                               H  H   H   CH.sub.3                                                                            CF.sub.3                                                                             CH 0                                                 Q-33                                                                               H  H   H   Cl   OCH.sub.3                                                                            CH 1 180                                             Q-33                                                                               H  H   H   CH.sub.3                                                                            OCH.sub.3                                                                            CH 1 160-162                                         Q-33                                                                               H  H   H   CH.sub.3                                                                            OCH.sub.3                                                                            N  1 223-226                                         Q-33                                                                               H  H   H   OCH.sub.3                                                                           OCH.sub.3                                                                            CH 1 182-185                                         Q-33                                                                               H  H   H   OCH.sub.3                                                                           OCH.sub.3                                                                            N  1 218-220                                         Q-33                                                                               H  H   H   CH.sub.3                                                                            CH.sub.3                                                                             CH 1 159-161                                         Q-33                                                                               H  3-CH.sub.3                                                                         H   CH.sub.3                                                                            OCH.sub.3                                                                            CH 1                                                 Q-33                                                                               H  4-CH.sub.3                                                                         H   CH.sub.3                                                                            OCH.sub.3                                                                            CH 1                                                 Q-33                                                                               H  5-CH.sub.3                                                                         H   CH.sub.3                                                                            OCH.sub.3                                                                            CH 1                                                 Q-33                                                                               H  H   H   CH.sub.3                                                                            CH.sub.3                                                                             N  1                                                 Q-33                                                                               H  6-CH.sub.3                                                                         H   CH.sub.3                                                                            OCH.sub.3                                                                            CH 1                                                 Q-33                                                                               H  3-CH.sub.3                                                                         5-CH.sub.3                                                                         CH.sub.3                                                                            OCH.sub.3                                                                            N  1                                                 Q-33                                                                               H  4-CH.sub.3                                                                         6-CH.sub.3                                                                         CH.sub.3                                                                            OCH.sub.3                                                                            N  1                                                 Q-33                                                                               CH.sub.3                                                                          H   H   OCH.sub.3                                                                           OCH.sub.3                                                                            CH 1                                                 Q-33                                                                               H  H   H   CH.sub.3                                                                            CH.sub.2 OCH.sub.3                                                                   CH 1                                                 Q-33                                                                               H  H   H   Cl   OC.sub.2 H.sub.5                                                                     CH 1                                                 Q-33                                                                               H  H   H   CH.sub.3                                                                            CF.sub.3                                                                             CH 1                                                 Q-34                                                                               H  H   H   CH.sub.3                                                                            OCH.sub.3                                                                            CH 0                                                 Q-34                                                                               H  H   H   CH.sub.3                                                                            OCH.sub.3                                                                            N  0                                                 Q-34                                                                               H  H   H   OCH.sub.3                                                                           OCH.sub.3                                                                            CH 0                                                 Q-34                                                                               H  H   H   OCH.sub.3                                                                           OCH.sub.3                                                                            N  0                                                 Q-34                                                                               H  2-CH.sub.3                                                                         H   CH.sub.3                                                                            CH.sub.3                                                                             CH 0                                                 Q-34                                                                               H  4-CH.sub.3                                                                         H   CH.sub.3                                                                            CH.sub.3                                                                             N  0                                                 Q-34                                                                               H  5-CH.sub.3                                                                         H   CH.sub.3                                                                            OCH.sub.3                                                                            CH 0                                                 Q-34                                                                               H  6-CH.sub.3                                                                         H   CH.sub.3                                                                            OCH.sub.3                                                                            N  0                                                 Q-34                                                                               H  2-CH.sub.3                                                                         6-CH.sub.3                                                                         OCH.sub.3                                                                           OCH.sub.3                                                                            CH 0                                                 Q-34                                                                               H  4-CH.sub.3                                                                         6-CH.sub.3                                                                         OCH.sub.3                                                                           OCH.sub.3                                                                            N  0                                                 Q-34                                                                               H  H   H   CH.sub.3                                                                            CH.sub.3                                                                             N  0                                                 Q-34                                                                               CH.sub.3                                                                          H   H   CH.sub.3                                                                            CH.sub.3                                                                             CH 0                                                 Q-34                                                                               H  H   H   CH.sub.3                                                                            CH.sub.3                                                                             CH 0                                                 Q-34                                                                               H  H   H   CH.sub.3                                                                            OCF.sub.2 H                                                                          CH 0                                                 Q-34                                                                               H  H   H   CH.sub.3                                                                            OCH.sub.3                                                                            CH 1                                                 Q-34                                                                               H  H   H   CH.sub.3                                                                            OCH.sub.3                                                                            N  1                                                 Q-34                                                                               H  H   H   OCH.sub.3                                                                           OCH.sub. 3                                                                           CH 1                                                 Q-34                                                                               H  H   H   OCH.sub.3                                                                           OCH.sub.3                                                                            N  1                                                 Q-34                                                                               H  2-CH.sub.3                                                                         H   CH.sub.3                                                                            CH.sub.3                                                                             CH 1                                                 Q-34                                                                               H  4-CH.sub.3                                                                         H   CH.sub.3                                                                            CH.sub.3                                                                             N  1                                                 Q-34                                                                               H  5-CH.sub.3                                                                         H   CH.sub.3                                                                            OCH.sub.3                                                                            CH 1                                                 Q-34                                                                               H  6-CH.sub.3                                                                         H   CH.sub.3                                                                            OCH.sub.3                                                                            N  1                                                 Q-34                                                                               H  2-CH.sub.3                                                                         6-CH.sub.3                                                                         OCH.sub.3                                                                           OCH.sub.3                                                                            CH 1                                                 Q-34                                                                               H  4-CH.sub.3                                                                         6-CH.sub.3                                                                         OCH.sub.3                                                                           OCH.sub.3                                                                            N  1                                                 Q-34                                                                               H  H   H   CH.sub.3                                                                            CH.sub.3                                                                             N  1                                                 Q-34                                                                               CH.sub.3                                                                          H   H   CH.sub.3                                                                            CH.sub.3                                                                             CH 1                                                 Q-34                                                                               H  H   H   CH.sub.3                                                                            CH.sub.3                                                                             CH 1                                                 Q-34                                                                               H  H   H   CH.sub.3                                                                            OCF.sub.2 H                                                                          CH 1                                                 Q-35                                                                               H  H   H   CH.sub.3                                                                            OCH.sub.3                                                                            CH 0                                                 Q-35                                                                               H  H   H   CH.sub.3                                                                            OCH.sub.3                                                                            N  0                                                 Q-35                                                                               H  H   H   OCH.sub.3                                                                           OCH.sub.3                                                                            CH 0                                                 Q-35                                                                               H  H   H   OCH.sub.3                                                                           OCH.sub.3                                                                            N  0                                                 Q-35                                                                               H  2-CH.sub.3                                                                         H   CH.sub.3                                                                            CH.sub.3                                                                             CH 0                                                 Q-35                                                                               H  H   H   Cl   OCH.sub.3                                                                            CH 0                                                 Q-35                                                                               H  3-CH.sub.3                                                                         H   CH.sub.3                                                                            CH.sub.3                                                                             N  0                                                 Q-35                                                                               H  2-CH.sub.3                                                                         6-CH.sub.3                                                                         CH.sub.3                                                                            OCH.sub.3                                                                            CH 0                                                 Q-35                                                                               H  2-CH.sub.3                                                                         3-CH.sub.3                                                                         CH.sub.3                                                                            OCH.sub.3                                                                            N  0                                                 Q-35                                                                               H  3-CH.sub.3                                                                         5-CH.sub.3                                                                         CH.sub.3                                                                            OCH.sub.3                                                                            N  0                                                 Q-35                                                                               H  H   H   CH.sub.3                                                                            CH.sub.3                                                                             N  0                                                 Q-35                                                                               CH.sub.3                                                                          H   H   OCH.sub.3                                                                           OCH.sub.3                                                                            CH 0                                                 Q-35                                                                               H  H   H   CH.sub.3                                                                            OCH.sub.2 CF.sub.3                                                                   CH 0                                                 Q-35                                                                               H  H   H   CH.sub.3                                                                            CH.sub.3                                                                             CH 0                                                 Q-35                                                                               H  H   H   CH.sub.3                                                                            OCH.sub.3                                                                            CH 1                                                 Q-35                                                                               H  H   H   CH.sub.3                                                                            OCH.sub.3                                                                            N  1                                                 Q-35                                                                               H  H   H   OCH.sub.3                                                                           OCH.sub.3                                                                            CH 1                                                 Q-35                                                                               H  H   H   OCH.sub.3                                                                           OCH.sub.3                                                                            N  1                                                 Q-35                                                                               H  2-CH.sub.3                                                                         H   CH.sub.3                                                                            CH.sub.3                                                                             CH 1                                                 Q-35                                                                               H  H   H   Cl   OCH.sub.3                                                                            CH 1                                                 Q-35                                                                               H  3-CH.sub.3                                                                         H   CH.sub.3                                                                            CH.sub.3                                                                             N  1                                                 Q-35                                                                               H  2-CH.sub.3                                                                         6-CH.sub.3                                                                         CH.sub.3                                                                            OCH.sub.3                                                                            CH 1                                                 Q-35                                                                               H  2-CH.sub.3                                                                         3-CH.sub.3                                                                         CH.sub.3                                                                            OCH.sub.3                                                                            N  1                                                 Q-35                                                                               H  3-CH.sub.3                                                                         5-CH.sub.3                                                                         CH.sub.3                                                                            OCH.sub.3                                                                            N  1                                                 Q-35                                                                               H  H   H   CH.sub.3                                                                            CH.sub.3                                                                             N  1                                                 Q-35                                                                               CH.sub.3                                                                          H   H   OCH.sub.3                                                                           OCH.sub.3                                                                            CH 1                                                 Q-35                                                                               H  H   H   CH.sub.3                                                                            OCH.sub.2 CF.sub.3                                                                   CH 1                                                 Q-35                                                                               H  H   H   CH.sub.3                                                                            CH.sub.3                                                                             CH 1                                                 __________________________________________________________________________

                                      TABLE 4a                                     __________________________________________________________________________     General Structure 2 wherein Q is Q-1.                                                                          m.p.                                           R  R.sub.1                                                                            R.sub.2                                                                             X        Y       Z  °C.                                     __________________________________________________________________________     H  H   H    CH.sub.3 CH.sub.3                                                                               CH 165-170                                        H  H   H    CH.sub.3 CH.sub.3                                                                               N                                                 H  H   H    CH.sub.3 OCH.sub.3                                                                              CH 175-180                                        H  H   H    CH.sub.3 OCH.sub.3                                                                              N  179-182                                        H  H   H    OCH.sub.3                                                                               OCH.sub.3                                                                              CH 179-183                                        H  H   H    Cl       OCH.sub.3                                                                              CH 171-173                                        H  H   H    OCH.sub.3                                                                               OCH.sub.3                                                                              N  163-166                                        H  4-Cl                                                                               H    CH.sub.3 OCH.sub.3                                                                              CH                                                H  H   4-F  CH.sub.3 CH.sub.3                                                                               N                                                 H  4-CH.sub.3                                                                         H    OCH.sub.3                                                                               OCH.sub.3                                                                              CH                                                H  H   4-OCH.sub.3                                                                         CH.sub.3 OCH.sub.3                                                                              N                                                 H  H   4-CF.sub.3                                                                          CH.sub.3 OCH.sub.3                                                                              CH                                                CH.sub.3                                                                          3-CH.sub.3                                                                         5-CH.sub.3                                                                          CH.sub.3 CH.sub.3                                                                               N                                                 H  H   H    OCH.sub.3                                                                               OCF.sub.2 H                                                                            CH                                                H  H   H    OCH.sub.3                                                                               cyclopropyl                                                                            N                                                 H  H   H    OC.sub.2 H.sub.5                                                                        OCH.sub.3                                                                              N                                                 H  H   H    O- -n-C.sub.4 H.sub.9                                                                   CH.sub.3                                                                               CH                                                H  H   H    OCH.sub.2 CF.sub.3                                                                      OCH.sub.3                                                                              N                                                 H  H   H    OCH.sub.2 CH.sub.2 CH.sub.2 F                                                           CH.sub.3                                                                               CH                                                H  H   H    SCH.sub.3                                                                               OCH.sub.3                                                                              CH                                                H  H   H    SCH(CH.sub.3).sub.2                                                                     CH.sub.3                                                                               N                                                 H  H   H    CH.sub.2 CH.sub.2 OCH.sub.3                                                             CH.sub.3                                                                               CH                                                H  H   H    CH.sub.2 OCH.sub.2 CH.sub.3                                                             OCH.sub.3                                                                              N                                                 H  H   H    N(CH.sub.2 CH.sub.3).sub.2                                                              CH.sub.3                                                                               CH                                                H  H   H    N(CH.sub.2 CH.sub.2 CH.sub.3)                                                           OCH.sub.3                                                                              N                                                 H  H   H    CH.sub.3 OCH.sub.2 CH═CH.sub.2                                                              CH                                                H  H   H    OCH.sub.3                                                                               OCH.sub.2 C.tbd.CCH.sub.3                                                              N                                                 H  H   H    CH.sub.3 cyclopentyl                                                                            CH                                                H  H   H    OCH.sub.3                                                                               CH.sub.2 SCH.sub.3                                                                     N                                                 H  H   H    CH.sub.3 C(O)CH.sub.3                                                                           CH                                                H  H   H    CH.sub.3 1,3-dioxan-2-yl                                                                        N                                                 H  H   H    OCH.sub.3                                                                               N(OCH.sub.3)CH.sub.3                                                                   CH                                                H  H   H    OCH.sub.3                                                                               OCH.sub.3                                                                              CH *                                              H  H   H    OCH.sub.3                                                                               CH.sub.3                                                                               N  *                                              H  4-Cl                                                                               H    OCH.sub.3                                                                               OCH.sub.3                                                                              CH *                                              H  H   H    OCH.sub.3                                                                               OCH.sub.3                                                                              CH ** 155-158                                     H  H   H    OCH.sub.3                                                                               CH.sub.3                                                                               N  ** 100-104                                     __________________________________________________________________________      W is O, unless indicated by * where W is S in all Tables.                      E is H, unless indicated by ** where E is 4Br in all Tables.             

                                      TABLE 4b                                     __________________________________________________________________________     General Structure 2                                                                                               m.p.                                        Q  R  R.sub.3                                                                           R.sub.4                                                                           R.sub.5                                                                           X       Y      Z  W'                                                                               °C.                                  __________________________________________________________________________     Q-2                                                                               H  H  H  H  CH.sub.3                                                                               OCH.sub.3                                                                             CH O                                             Q-2                                                                               H  H  H  H  CH.sub.3                                                                               OCH.sub.3                                                                             N  O                                             Q-2                                                                               H  H  H  H  OCH.sub.3                                                                              OCH.sub.3                                                                             CH O                                             Q-2                                                                               H  H  H  H  OCH.sub.3                                                                              OCH.sub.3                                                                             N  O                                             Q-2                                                                               H  CH.sub.3                                                                          H  H  CH.sub.3                                                                               CH.sub.3                                                                              CH O                                             Q-2                                                                               H  H  CH.sub.3                                                                          H  CH.sub.3                                                                               OCH.sub.3                                                                             N  O                                             Q-2                                                                               H  H  H  CH.sub.3                                                                          CH.sub.3                                                                               OCH.sub.3                                                                             CH O                                             Q-2                                                                               CH.sub.3                                                                          H  H  H  CH      CH.sub.3                                                                              CH O                                             Q-2                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          H  OCH.sub.3                                                                              OCH.sub.3                                                                             N  O                                             Q-2                                                                               H  H  H  H  Cl      OCH.sub.3                                                                             CH S                                             Q-2                                                                               H  H  H  H  CH.sub.3                                                                               OCH.sub.3                                                                             CH S                                             Q-2                                                                               H  H  H  H  CH.sub.3                                                                               OCH.sub.3                                                                             N  S                                             Q-2                                                                               H  H  H  H  OCH.sub.3                                                                              OCH.sub.3                                                                             CH S                                             Q-2                                                                               H  H  H  H  OCH.sub.3                                                                              OCH.sub.3                                                                             N  S                                             Q-2                                                                               H  H  H  H  CH.sub.3                                                                               CH.sub.3                                                                              CH S                                             Q-2                                                                               H  CH.sub.3                                                                          H  H  CH.sub.3                                                                               CH.sub.3                                                                              CH S                                             Q-2                                                                               H  H  CH.sub.3                                                                          H  CH.sub.3                                                                               CH.sub.3                                                                              N  S                                             Q-2                                                                               H  H  H  CH.sub.3                                                                          CH.sub.3                                                                               OCH.sub.3                                                                             CH S                                             Q-2                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                               OCH.sub.3                                                                             N  S                                             Q-2                                                                               H  H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                              OCH.sub.3                                                                             CH S                                             Q-2                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                          OCH.sub.3                                                                              OCH.sub.3                                                                             N  S                                             Q-2                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                               OCH.sub.3                                                                             CH S                                             Q-2                                                                               CH.sub.3                                                                          H  H  H  CH.sub.3                                                                               CH.sub.3                                                                              CH S                                             Q-2                                                                               H  H  H  H  Cl      OC.sub.2 H.sub.5                                                                      CH S                                             Q-3                                                                               H  H  H  H  CH.sub.3                                                                               CH.sub.3                                                                              CH O                                             Q-3                                                                               H  H  H  H  CH.sub.3                                                                               CH.sub.3                                                                              N  O                                             Q-3                                                                               H  H  H  H  CH.sub.3                                                                               OCH.sub.3                                                                             CH O                                             Q-3                                                                               H  H  H  H  CH.sub.3                                                                               OCH.sub.3                                                                             N  O                                             Q-3                                                                               H  H  H  H  OCH.sub.3                                                                              OCH.sub.3                                                                             CH O                                             Q-3                                                                               H  H  H  H  OCH.sub.3                                                                              OCH.sub. 3                                                                            N  O                                             Q-3                                                                               H  CH.sub.3                                                                          H  H  CH.sub.3                                                                               CH.sub.3                                                                              CH O                                             Q-3                                                                               H  H  CH.sub.3                                                                          H  CH.sub.3                                                                               CH.sub.3                                                                              N  O                                             Q-3                                                                               H  H  H  CH.sub.3                                                                          CH.sub.3                                                                               OCH.sub.3                                                                             CH O                                             Q-3                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                               OCH.sub.3                                                                             N  O                                             Q-3                                                                               H  H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                              OCH.sub.3                                                                             CH O                                             Q-3                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                          OCH.sub.3                                                                              OCH.sub.3                                                                             N  O                                             Q-3                                                                               H  H  H  H  OCH.sub.3                                                                              OCH.sub.2 CF.sub.3                                                                    CH O                                             Q-3                                                                               H  H  H  H  OCH.sub.3                                                                              OCH.sub.2 CF.sub.3                                                                    CH O                                             Q-3                                                                               CH.sub.3                                                                          H  H  H  Cl      OCH.sub.3                                                                             CH O                                             Q-3                                                                               H  H  H  H  CH.sub.3                                                                               OCH.sub.3                                                                             CH S                                             Q-3                                                                               H  H  H  H  OCH.sub.3                                                                              OCH.sub.3                                                                             CH S 133-135                                     Q-3                                                                               H  H  H  H  OCH.sub.3                                                                              OCH.sub.3                                                                             N  S                                             Q-3                                                                               H  CH.sub.3                                                                          H  H  CH.sub.3                                                                               CH.sub.3                                                                              CH S                                             Q-3                                                                               H  H  CH.sub.3                                                                          H  CH.sub.3                                                                               OCH.sub.3                                                                             N  S                                             Q-3                                                                               H  H  H  CH.sub.3                                                                          CH.sub.3                                                                               OCH.sub.3                                                                             CH S                                             Q-3                                                                               CH.sub.3                                                                          H  H  H  CH.sub.3                                                                               CH.sub.3                                                                              CH S                                             Q-3                                                                               H  H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                              OCH.sub.3                                                                             N  S                                             Q-3                                                                               H  H  H  H  OCH.sub.3                                                                              CF.sub.3                                                                              N  S                                             Q-4                                                                               H  H  H  H  CH.sub.3                                                                               OCH.sub.3                                                                             CH --                                            Q-4                                                                               H  H  H  H  OCH.sub.3                                                                              Cl     CH --                                            Q-4                                                                               H  H  H  H  CH.sub.3                                                                               OCH.sub.3                                                                             N  --                                                                               192-199                                     Q-4                                                                               H  H  H  H  CH.sub.3                                                                               CH.sub.3                                                                              CH --                                            Q-4                                                                               H  H  H  H  OCH.sub.3                                                                              OCH.sub.3                                                                             CH --                                                                               140-144                                     Q-4                                                                               H  H  H  H  OCH.sub.3                                                                              OCH.sub.3                                                                             N  --                                            Q-4                                                                               H  CH.sub.3                                                                          H  H  CH.sub.3                                                                               CH.sub.3                                                                              CH --                                            Q-4                                                                               H  H  CH.sub.3                                                                          H  CH.sub.3                                                                               OCH.sub.3                                                                             N  --                                            Q-4                                                                               H  H  H  CH.sub.3                                                                          CH.sub.3                                                                               OCH.sub.3                                                                             CH --                                            Q-4                                                                               CH.sub.3                                                                          H  H  H  OCH.sub.3                                                                              OCH.sub.3                                                                             CH --                                            Q-4                                                                               CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                               OCH.sub.3                                                                             N  --                                            Q-4                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                               OCH.sub.3                                                                             CH --                                            Q-4                                                                               H  H  H  H  OCH.sub.3                                                                              OCH.sub.2 CF.sub.3                                                                    N  --                                            Q-4                                                                               H  H  H  H  CH.sub.3                                                                               NHCH.sub.3                                                                            CH --                                            Q-4                                                                               H  H  H  H  CH.sub.3                                                                               CH.sub.3                                                                              CH --                                            Q-4                                                                               H  H  H  H  CH.sub.3                                                                               CH.sub.3                                                                              N  --                                            Q-9                                                                               H  H  H  H  CH.sub.3                                                                               OCH.sub.3                                                                             CH --                                            Q-9                                                                               H  H  H  H  CH.sub.3                                                                               OCH.sub.3                                                                             N  --                                            Q-9                                                                               H  H  H  H  OCH.sub.3                                                                              OCH.sub.3                                                                             CH --                                            Q-9                                                                               H  H  H  H  OCH.sub.3                                                                              OCH.sub.3                                                                             N  --                                            Q-9                                                                               CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                               CH.sub.3                                                                              CH --                                            Q-9                                                                               H  H  CH.sub.3                                                                          H  CH.sub.3                                                                               OCH.sub.3                                                                             N  --                                            Q-9                                                                               H  H  H  CH.sub.3                                                                          OCH.sub.3                                                                              OCH.sub.3                                                                             CH --                                            Q-9                                                                               H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                               OCH.sub.3                                                                             CH --                                            Q-9                                                                               H  H  H  H  Cl      OCH.sub.2 CH.sub.3                                                                    CH --                                            Q-9                                                                               H  H  H  H  OCH.sub.3                                                                              CH(OCH.sub.3).sub.2                                                                   CH --                                            Q-9                                                                               H  H  H  H  NH.sub.2                                                                               CH.sub.3                                                                              CH --                                            Q-9                                                                               H  H  H  H  NHCH(CH.sub.3).sub.2                                                                   CH.sub.3                                                                              CH --                                            Q-9                                                                               H  H  H  H  CH.sub.2 O- -n-C.sub.4 H.sub.9                                                         CH.sub. 3                                                                             CH --                                            Q-9                                                                               H  H  H  H  S- -n-C.sub.4 H.sub.9                                                                  CH.sub.3                                                                              CH --                                            Q-9                                                                               H  H  H  H  S- -n-CH.sub.2 CH.sub.2 F                                                              CH.sub.3                                                                              CH --                                            __________________________________________________________________________

                                      TABLE 4c                                     __________________________________________________________________________     General Structure 2                                                            Q  R   R.sub.3                                                                            R.sub.4                                                                            X   Y       Z   W"  m.p. °C.                             __________________________________________________________________________     Q-10                                                                              H   H   H   CH.sub.3                                                                           OCH.sub.3                                                                              CH  O                                               Q-10                                                                              H   H   H   CH.sub.3                                                                           CH.sub.3                                                                               CH  O                                               Q-10                                                                              H   H   H   OCH.sub.3                                                                          OCH.sub.3                                                                              N   O                                               Q-10                                                                              H   H   H   OCH.sub.3                                                                          Cl      CH  O                                               Q-10                                                                              H   H   H   OCH.sub.3                                                                          OCH.sub.3                                                                              CH  O   157-161                                     Q-10                                                                              H   H   H   OCH.sub.3                                                                          OCH.sub.3                                                                              N   O                                               Q-10                                                                              H   H   H   CH.sub.3                                                                           OCH.sub.3                                                                              CH  S                                               Q-10                                                                              H   H   H   CH.sub.3                                                                           OCH.sub.3                                                                              N   S                                               Q-10                                                                              H   H   H   OCH.sub.3                                                                          OCH.sub.3                                                                              CH  S                                               Q-10                                                                              H   H   H   OCH.sub.3                                                                          OCH.sub.3                                                                              N   S                                               Q-10                                                                              H   H   H   OCH.sub.3                                                                          Cl      CH  NCH.sub.3                                                                          193-195                                     Q-10                                                                              H   H   H   CH.sub.3                                                                           CH.sub.3                                                                               CH  NCH.sub.3                                                                          112-115                                     Q-10                                                                              H   H   H   CH.sub.3                                                                           OCH.sub.3                                                                              N   NCH.sub.3                                                                          190-192                                     Q-10                                                                              H   H   H   CH.sub.3                                                                           CH.sub.3                                                                               N   NCH.sub.3                                                                          185-189                                     Q-10                                                                              H   H   H   OCH.sub. 3                                                                         OCH.sub.3                                                                              CH  NCH.sub.3                                                                          202-204                                     Q-10                                                                              H   H   H   OCH.sub.3                                                                          CH.sub.3                                                                               CH  NCH.sub.3                                                                          171-174                                     Q-10                                                                              H   CH.sub.3                                                                           H   CH.sub.3                                                                           CH.sub.3                                                                               CH  O                                               Q-10                                                                              H   H   CH.sub.3                                                                           CH.sub.3                                                                           OCH.sub.3                                                                              N   O                                               Q-10                                                                              H   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                           OCH.sub.3                                                                              CH  O                                               Q-10                                                                              CH.sub.3                                                                           H   H   OCH.sub.3                                                                          OCH.sub.3                                                                              N   O                                               Q-10                                                                              H   H   H   CH.sub.3                                                                            ##STR140##                                                                            CH  O                                               Q-10                                                                              H   CH.sub.3                                                                           H   CH.sub.3                                                                           CH.sub.3                                                                               CH  S                                               Q-10                                                                              H   H   CH.sub.3                                                                           CH.sub.3                                                                           OCH.sub.3                                                                              N   S                                               Q-10                                                                              H   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                           OCH.sub.3                                                                              CH  S                                               Q-10                                                                              CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                           OCH.sub.3                                                                              CH  S                                               Q-10                                                                              CH.sub.3                                                                           H   H   OCH.sub.3                                                                          OCH.sub.3                                                                              N   S                                               Q-10                                                                              H   H   H   CH.sub.3                                                                           OC.sub.2 H.sub.5                                                                       CH  S                                               Q-10                                                                              H   H   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                               N   NCH.sub.3                                       Q-10                                                                              H   H   CH.sub.3                                                                           CH.sub.3                                                                           OCH.sub.3                                                                              CH  NCH.sub.3                                       Q-10                                                                              H   CH.sub.3                                                                           CH.sub.3                                                                           OCH.sub.3                                                                          OCH.sub.3                                                                              N   NCH.sub.3                                       Q-10                                                                              CH.sub.3                                                                           H   H   OCH.sub.3                                                                          OCH.sub.3                                                                              N   NCH.sub.3                                       Q-11                                                                              H   H   H   CH.sub.3                                                                           CH.sub.3                                                                               N   O                                               Q-11                                                                              H   H   H   CH.sub.3                                                                           CH.sub.3                                                                               CH  O                                               Q-11                                                                              H   H   H   CH.sub.3                                                                           OCH.sub.3                                                                              N   O                                               Q-11                                                                              H   H   H   CH.sub.3                                                                           OCH.sub.3                                                                              CH  O                                               Q-11                                                                              H   H   H   OCH.sub.3                                                                          OCH.sub.3                                                                              CH  O                                               Q-11                                                                              H   H   H   OCH.sub.3                                                                          OCH.sub.3                                                                              N   O                                               Q-11                                                                              H   H   H   CH.sub.3                                                                           CH.sub.3                                                                               CH  S                                               Q-11                                                                              H   H   H   CH.sub.3                                                                           OCH.sub.3                                                                              CH  S                                               Q-11                                                                              H   H   H   CH.sub.3                                                                           OCH.sub.3                                                                              CH  S                                               Q-11                                                                              H   H   H   OCH.sub.3                                                                          OCH.sub.3                                                                              CH  S                                               Q-11                                                                              H   H   H   CH.sub.3                                                                           CH.sub.3                                                                               CH  NCH.sub.3                                       Q-11                                                                              H   H   H   CH.sub.3                                                                           OCH.sub.3                                                                              CH  NCH.sub.3                                       Q-11                                                                              H   H   H   OCH.sub.3                                                                          OCH.sub.3                                                                              CH  NCH.sub.3                                       Q-11                                                                              H   H   H   CH.sub.3                                                                           OCH.sub.3                                                                              N   NCH.sub.3                                       Q-11                                                                              H   CH.sub.3                                                                           H   CH.sub.3                                                                           OCH.sub.3                                                                              N   O                                               Q-11                                                                              H   H   CH.sub.3                                                                           OCH.sub.3                                                                          OCH.sub.3                                                                              N   O                                               Q-11                                                                              H   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                           OCH.sub.3                                                                              CH  O                                               Q-11                                                                              CH.sub.3                                                                           H   H   CH.sub.3                                                                           OCH.sub.3                                                                              CH  O                                               Q-11                                                                              H   H   H   CH.sub.3                                                                           C.sub.2 H.sub.5                                                                        N   O                                               Q-11                                                                              H   H   H   CH.sub.3                                                                           CH.sub.2 OCH.sub.3                                                                     CH  O                                               Q-11                                                                              H   CH.sub.3                                                                           H   CH.sub.3                                                                           OCH.sub.3                                                                              N   S                                               Q-11                                                                              H   H   CH.sub.3                                                                           OCH.sub.3                                                                          OCH.sub.3                                                                              N   S                                               Q-11                                                                              H   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                           OCH.sub.3                                                                              CH  S                                               Q-11                                                                              CH.sub.3                                                                           H   H   CH.sub.3                                                                           OCH.sub.3                                                                              CH  S                                               Q-11                                                                              H   H   H   CH.sub.3                                                                           C.sub.2 H.sub.5                                                                        N   S                                               Q-11                                                                              CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                           OCH.sub.3                                                                              N   S                                               Q-11                                                                              H   H   H   Cl  OCH.sub.3                                                                              CH  S                                               Q-11                                                                              H   CH.sub.3                                                                           H   CH.sub.3                                                                           CH.sub.3                                                                               CH  NCH.sub.3                                       Q-11                                                                              H   H   CH.sub.3                                                                           CH.sub.3                                                                           OCH.sub.3                                                                              N   NCH.sub.3                                       Q-11                                                                              H   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                           OCH.sub.3                                                                              CH  NCH.sub.3                                       Q-11                                                                              CH.sub.3                                                                           H   H   OCH.sub.3                                                                          OCH.sub.3                                                                              N   NH                                              Q-11                                                                              H   H   H   CH.sub.3                                                                           OCH.sub.3                                                                              CH  NH                                              Q-11                                                                              H   H   H   OCH.sub.3                                                                          OCH.sub.3                                                                              CH  O   *                                           Q-11                                                                              H   H   H   OCH.sub.3                                                                          CH      N   O   *                                           Q-11                                                                              H   H   H   CH.sub.3                                                                           OCH.sub.3                                                                              N   NCH.sub.3                                       Q-11                                                                              H   H   H   CH.sub.3                                                                           OCF.sub.2 H                                                                            CH  NCH.sub.3                                       Q-11                                                                              H   CH.sub.3                                                                           H   OCH.sub.3                                                                          OCH.sub.2 CF.sub.3                                                                     N   NCH.sub.3                                       Q-12                                                                              H   H   H   CH.sub.3                                                                           OCH.sub.3                                                                              CH  O                                               Q-12                                                                              H   H   H   CH.sub.3                                                                           OCH.sub.3                                                                              N   O                                               Q-12                                                                              H   H   H   OCH.sub.3                                                                          OCH.sub.3                                                                              CH  O                                               Q-12                                                                              H   H   H   OCH.sub.3                                                                          OCH.sub.3                                                                              N   O                                               Q-12                                                                              H   H   H   CH.sub.3                                                                           OCH.sub.3                                                                              CH  S                                               Q-12                                                                              H   H   H   CH.sub.3                                                                           OCH.sub.3                                                                              N   S                                               Q-12                                                                              H   H   H   OCH.sub.3                                                                          OCH.sub.3                                                                              CH  S                                               Q-12                                                                              H   H   H   OCH.sub.3                                                                          OCH.sub.3                                                                              N   S                                               Q-12                                                                              H   H   H   CH.sub.3                                                                           CH.sub.3                                                                               N   NCH.sub.3                                       Q-12                                                                              H   H   H   CH.sub.3                                                                           OCH.sub.3                                                                              CH  NCH.sub.3                                       Q-12                                                                              H   H   H   CH.sub.3                                                                           OCH.sub.3                                                                              N   NCH.sub.3                                       Q-12                                                                              H   H   H   OCH.sub.3                                                                          OCH.sub.3                                                                              CH  NCH.sub.3                                       Q-12                                                                              H   H   H   OCH.sub.3                                                                          OCH.sub.3                                                                              N   NCH.sub.3                                       Q-12                                                                              H   H   H   OCH.sub.3                                                                          OCH.sub.3                                                                              N   NH                                              Q-12                                                                              H   CH.sub.3                                                                           H   CH.sub.3                                                                           CH.sub.3                                                                               CH  O                                               Q-12                                                                              H   H   CH.sub.3                                                                           CH.sub.3                                                                           OCH.sub.3                                                                              N   O                                               Q-12                                                                              H   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                           OCH.sub.3                                                                              CH  O                                               Q-12                                                                              CH.sub.3                                                                           H   H   OCH.sub.3                                                                          OCH.sub.3                                                                              N   O                                               Q-12                                                                              CH.sub.3                                                                           H   H   CH.sub.3                                                                           CF.sub.3                                                                               CH  O                                               Q-12                                                                              H   H   H   OCH.sub.3                                                                          OCH.sub.2 CF.sub.3                                                                     N                                                   Q-12                                                                              H   CH.sub.3                                                                           H   CH.sub.3                                                                           OCH.sub.3                                                                              CH  S                                               Q-12                                                                              H   H   CH.sub.3                                                                           CH.sub.3                                                                           OCH.sub.3                                                                              N   S                                               Q-12                                                                              H   CH.sub.3                                                                           CH.sub.3                                                                           OCH.sub.3                                                                          OCH.sub.3                                                                              CH  S                                               Q-12                                                                              CH.sub.3                                                                           H   H   OCH.sub.3                                                                          OCH.sub.3                                                                              N   S                                               Q-12                                                                              CH.sub.3                                                                           CH.sub.3                                                                           H   CH.sub.3                                                                           NHCH.sub.3                                                                             CH  S                                               Q-12                                                                              H   H   H   Br  OC.sub.2 H.sub.5                                                                       CH  S                                               Q-12                                                                              H   CH.sub.3                                                                           H   CH.sub.3                                                                           CH.sub.3                                                                               CH  NH                                              Q-12                                                                              H   CH.sub.3                                                                           H   CH.sub.3                                                                           CH.sub.3                                                                               CH  NCH.sub.3                                       Q-12                                                                              H   H   CH.sub.3                                                                           CH.sub.3                                                                           OCH.sub.3                                                                              N   NCH.sub.3                                       Q-12                                                                              H   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                               CH.sub.3                                                                           NCH.sub.3                                       Q-12                                                                              CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                           OCH.sub.3                                                                              N   NCH.sub.3                                       Q-12                                                                              CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                           OCH.sub.3                                                                              CH  NCH.sub.3                                       Q-12                                                                              H   H   H   Br  OCH.sub.3                                                                              CH  NCH.sub.3                                       Q-12                                                                              H   H   H   OCH.sub.3                                                                          N(CH.sub.3).sub.2                                                                      CH  NCH.sub.3                                       Q-13                                                                              H   H   H   CH.sub.3                                                                           OCH.sub.3                                                                              CH  O                                               Q-13                                                                              H   H   H   CH.sub.3                                                                           OCH.sub.3                                                                              CH  O                                               Q-13                                                                              H   H   H   CH.sub.3                                                                           CH.sub.3                                                                               CH  O                                               Q-13                                                                              H   H   H   CH.sub.3                                                                           OCH.sub.3                                                                              N   O                                               Q-13                                                                              H   H   H   OCH.sub.3                                                                          OCH.sub.3                                                                              CH  O                                               Q-13                                                                              H   H   H   CH.sub.3                                                                           CH.sub.3                                                                               N   O                                               Q-13                                                                              H   H   H   OCH.sub.3                                                                          OCH.sub.3                                                                              N   O                                               Q-13                                                                              H   H   H   CH.sub.3                                                                           OCH.sub.3                                                                              CH  S                                               Q-13                                                                              H   H   H   CH.sub.3                                                                           OCH.sub.3                                                                              N   S                                               Q-13                                                                              H   H   H   OCH.sub.3                                                                          OCH.sub.3                                                                              CH  S                                               Q-13                                                                              H   H   H   OCH.sub.3                                                                          OCH.sub.3                                                                              N   S                                               Q-13                                                                              H   H   H   CH.sub.3                                                                           OCH.sub.3                                                                              CH  NH                                              Q-13                                                                              H   H   H   CH.sub.3                                                                           OCH.sub.3                                                                              N   NH                                              Q-13                                                                              H   H   H   OCH.sub.3                                                                          OCH.sub.3                                                                              CH  NCH.sub.3                                       Q-13                                                                              H   H   H   OCH.sub.3                                                                          OCH.sub.3                                                                              N   NH                                              Q-13                                                                              H   CH.sub.3                                                                           H   CH.sub.3                                                                           CH.sub.3                                                                               CH  O                                               Q-13                                                                              H   H   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                               N   O                                               Q-13                                                                              H   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                           OCH.sub.3                                                                              CH  O                                               Q-13                                                                              CH.sub.3                                                                           H   H   CH.sub.3                                                                           OCH.sub.3                                                                              N   O                                               Q-13                                                                              H   H   H   CH.sub.3                                                                           CH(OCH.sub. 3).sub.2                                                                   CH  O                                               Q-13                                                                              H   CH.sub.3                                                                           H   CH.sub.3                                                                           OCH.sub.3                                                                              CH  S                                               Q-13                                                                              H   H   CH.sub.3                                                                           CH.sub.3                                                                           OCH.sub.3                                                                              CH  S                                               Q-13                                                                              H   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                           OCH.sub.3                                                                              N   S                                               Q-13                                                                              CH.sub.3                                                                           H   CH.sub.3                                                                           OCH.sub.3                                                                          OCH.sub.3                                                                              N   S                                               Q-13                                                                              CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                               N   S                                               Q-13                                                                              H   H   H   OCH.sub.3                                                                           ##STR141##                                                                            CH  S                                               Q-13                                                                              H   CH.sub.3                                                                           H   CH.sub.3                                                                           OCH.sub.3                                                                              N   NCH.sub.3                                       Q-13                                                                              H   H   CH.sub.3                                                                           CH.sub.3                                                                           OCH.sub.3                                                                              N   NCH.sub.3                                       Q-13                                                                              H   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                           OCH.sub.3                                                                              CH  NCH.sub.3                                       Q-13                                                                              CH.sub.3                                                                           H   H   OCH.sub.3                                                                          OCH.sub.3                                                                              CH  NCH.sub.3                                       Q-13                                                                              H   H   H   CH.sub.3                                                                           OCH.sub.3                                                                              N   NH                                              Q-13                                                                              H   H   H   Br  OC.sub.2 H.sub.5                                                                       CH  NH                                              Q-13                                                                              H   H   H   OCH.sub.3                                                                          C.sub.2 H.sub.5                                                                        N   NH                                              Q-13                                                                              H   H   H   CH.sub.3                                                                           CH.sub.3                                                                               CH  NCH.sub.3                                       Q-13                                                                              H   H   H   CH.sub.3                                                                           CH.sub.3                                                                               N   NCH.sub.3                                       Q-13                                                                              H   H   H   Cl  OCH.sub. 3                                                                             CH  NCH.sub.3                                       Q-14                                                                              H   H   H   CH.sub.3                                                                           CH.sub.3                                                                               N   O                                               Q-14                                                                              H   H   H   CH.sub.3                                                                           CH.sub.3                                                                               CH  O                                               Q-14                                                                              H   H   H   CH.sub.3                                                                           OCH.sub.3                                                                              CH  O                                               Q-14                                                                              H   H   H   CH.sub.3                                                                           OCH.sub.3                                                                              CH  O                                               Q-14                                                                              H   H   H   CH.sub.3                                                                           OCH.sub.3                                                                              N   O                                               Q-14                                                                              H   H   H   OCH.sub.3                                                                          OCH.sub.3                                                                              CH  O                                               Q-14                                                                              H   H   H   CH.sub.3                                                                           OCH.sub.3                                                                              CH  S                                               Q-14                                                                              H   H   H   CH.sub.3                                                                           OCH.sub.3                                                                              N   S                                               Q-14                                                                              H   H   H   OCH.sub.3                                                                          OCH.sub.3                                                                              CH  S                                               Q-14                                                                              H   H   H   OCH.sub.3                                                                          OCH.sub.3                                                                              CH  S                                               Q-14                                                                              H   H   H   OCH.sub.3                                                                          OCH.sub.3                                                                              N   S                                               Q-14                                                                              H   H   H   CH.sub.3                                                                           OCH.sub.3                                                                              CH  NCH.sub.3                                       Q-14                                                                              H   H   H   CH.sub.3                                                                           OCH.sub.3                                                                              N   NCH.sub.3                                       Q-14                                                                              H   H   H   OCH.sub.3                                                                          OCH.sub.3                                                                              CH  NH                                              Q-14                                                                              H   H   H   OCH.sub.3                                                                          OCH.sub.3                                                                              N   NCH.sub.3                                       Q-14                                                                              H   CH.sub.3                                                                           H   CH.sub.3                                                                           CH.sub.3                                                                               CH  O                                               Q-14                                                                              H   H   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                               N   O                                               Q-14                                                                              H   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                           OCH.sub.3                                                                              CH  O                                               Q-14                                                                              CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                           OCH.sub.3                                                                              N   O                                               Q-14                                                                              H   H   H   CH.sub.3                                                                           C.sub.2 H.sub.5                                                                        N   O                                               Q-14                                                                              H   H   H   CH.sub.3                                                                           OC.sub.2 H.sub.5                                                                       N   O                                               Q-14                                                                              H   CH.sub.3                                                                           H   CH.sub.3                                                                           OCH.sub.3                                                                              CH  S                                               Q-14                                                                              H   H   CH.sub.3                                                                           CH.sub.3                                                                           OCH.sub.3                                                                              N   S                                               Q-14                                                                              H   CH.sub.3                                                                           CH.sub.3                                                                           OCH.sub.3                                                                          OCH.sub.3                                                                              CH  S                                               Q-14                                                                              CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                           OCH.sub.3                                                                          OCH.sub.3                                                                              CH  S                                               Q-14                                                                              H   H   H   OCH.sub.3                                                                          C.sub.2 H.sub.5                                                                        N   S                                               Q-14                                                                              H   H   H   OCH.sub.3                                                                          OC.sub.2 H.sub.5                                                                       N   S                                               Q-14                                                                              H   CH.sub.3                                                                           H   CH.sub.3                                                                           OCH.sub.3                                                                              CH  NCH.sub.3                                       Q-14                                                                              H   H   CH.sub.3                                                                           CH.sub.3                                                                           OCH.sub.3                                                                              N   NCH.sub.3                                       Q-14                                                                              H   CH.sub.3                                                                           CH.sub.3                                                                           OCH.sub.3                                                                          OCH.sub.3                                                                              CH  NCH.sub.3                                       Q-14                                                                              CH.sub.3                                                                           CH.sub.3                                                                           H   OCH.sub.3                                                                          OCH.sub.3                                                                              N   NCH.sub.3                                       Q-14                                                                              H   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                           OCH.sub.3                                                                              CH  NH                                              Q-14                                                                              H   H   H   CH.sub.3                                                                           OCH.sub.3                                                                              N   NH                                              Q-14                                                                              H   H   H   CH.sub.3                                                                           CH.sub.2 OCH.sub.3                                                                     CH  NCH.sub.3                                       Q-15                                                                              H   H   H   CH.sub.3                                                                           OCH.sub.3                                                                              CH  O                                               Q-15                                                                              H   H   H   CH.sub.3                                                                           OCH.sub.3                                                                              N   O                                               Q-15                                                                              H   H   H   OCH.sub.3                                                                          OCH.sub.3                                                                              CH  O                                               Q-15                                                                              H   H   H   OCH.sub.3                                                                          OCH.sub.3                                                                              N   O                                               Q-15                                                                              H   C.sub.2 H.sub.5                                                                    H   OCH.sub.3                                                                          OCH.sub.3                                                                              CH  O                                               Q-15                                                                              H   CH.sub.3                                                                           H   CH.sub.3                                                                           OCH.sub.3                                                                              CH  O                                               Q-15                                                                              H   CH.sub.3                                                                           H   CH.sub.3                                                                           CH.sub.3                                                                               CH  O                                               Q-15                                                                              H   CH.sub.3                                                                           H   OCH.sub.3                                                                          OCH.sub.3                                                                              CH  O                                               Q-15                                                                              H   H   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                               N   O                                               Q-15                                                                              H   CH.sub.3                                                                           H   CH.sub.3                                                                           OCH.sub.3                                                                              N   O                                               Q-15                                                                              H   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                           OCH.sub.3                                                                              CH  O                                               Q-15                                                                              H   CH.sub.3                                                                           H   OCH.sub.3                                                                          OCH.sub.3                                                                              N   O                                               Q-15                                                                              CH.sub.3                                                                           H   H   CH.sub.3                                                                           OCH.sub.3                                                                              N   O                                               Q-15                                                                              H   CH.sub.3                                                                           H   OCH.sub.3                                                                          Cl      CH  O                                               Q-15                                                                              CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                           OCH.sub.3                                                                          OCH.sub.3                                                                              CH  O                                               Q-15                                                                              H   H   H   CH.sub.3                                                                           CF.sub.3                                                                               CH  O                                               Q-15                                                                              H   H   H   CH.sub.3                                                                           CF.sub.3                                                                               N   O                                               Q-15                                                                              H   H   H   OCH.sub.3                                                                          OCF.sub.2 H                                                                            CH  O                                               Q-15                                                                              CH.sub.3                                                                           H   H   OCH.sub.3                                                                          OCF.sub.2 H                                                                            CH  O                                               Q-15                                                                              H   H   H   CH.sub.3                                                                           CH.sub.3                                                                               CH  O                                               Q-15                                                                              H   H   H   CH.sub.3                                                                           CH.sub.3                                                                               N   O                                               Q-15                                                                              H   H   H   OCH.sub.3                                                                          OCH.sub.3                                                                              CH  O   *                                           Q-15                                                                              H   H   H   OCH.sub.3                                                                          CH.sub.3                                                                               N   O   *                                           Q-15                                                                              H   H   H   CH.sub.3                                                                           CH.sub.3                                                                               N   S                                               Q-15                                                                              H   CH.sub.3                                                                           H   CH.sub.3                                                                           OCH.sub.3                                                                              CH  S                                               Q-15                                                                              H   CH.sub.3                                                                           H   CH.sub.3                                                                           OCH.sub.3                                                                              N   S                                               Q-15                                                                              H   CH.sub.3                                                                           H   OCH.sub.3                                                                          OCH.sub.3                                                                              CH  S                                               Q-15                                                                              H   CH.sub.3                                                                           H   OCH.sub.3                                                                          OCH.sub.3                                                                              N   S                                               Q-15                                                                              H   CH.sub.3                                                                           H   Cl  OCH.sub.3                                                                              CH  S                                               Q-15                                                                              H   H   H   CH.sub.3                                                                           OCH.sub.3                                                                              CH  NCH.sub.3                                       Q-15                                                                              H   H   H   CH.sub.3                                                                           OCH.sub.3                                                                              N   NCH.sub.3                                       Q-15                                                                              H   H   H   OCH.sub.3                                                                          OCH.sub.3                                                                              CH  NCH.sub.3                                       Q-15                                                                              H   H   H   OCH.sub.3                                                                          OCH.sub.3                                                                              N   NCH.sub.3                                       Q-15                                                                              H   CH.sub.3                                                                           H   CH.sub.3                                                                           CH.sub.3                                                                               CH  S                                               Q-15                                                                              H   H   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                               N   S                                               Q-15                                                                              H   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                           OCH.sub.3                                                                              CH  S                                               Q-15                                                                              CH.sub.3                                                                           H   H   CH.sub.3                                                                           OCH.sub.3                                                                              N   S                                               Q-15                                                                              CH.sub.3                                                                           H   CH.sub.3                                                                           OCH.sub.3                                                                          OCH.sub.3                                                                              CH  S                                               Q-15                                                                              H   H   H   Cl  OC.sub.2 H.sub.5                                                                       CH  S                                               Q-15                                                                              H   H   H   OCH.sub.3                                                                          OCH.sub.2 CF.sub.3                                                                     CH  S                                               Q-15                                                                              H   CH.sub.3                                                                           H   CH.sub.3                                                                           CH.sub.3                                                                               CH  NCH.sub.3                                       Q-15                                                                              H   H   CH.sub.3                                                                           CH.sub.3                                                                           OCH.sub.3                                                                              CH  NCH.sub.3                                       Q-15                                                                              H   CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                           OCH.sub.3                                                                              N   NCH.sub.3                                       Q-15                                                                              CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                           OCH.sub.3                                                                              N   NCH.sub.3                                       Q-15                                                                              CH.sub.3                                                                           H   H   CH.sub.3                                                                           OCH.sub.3                                                                              CH  NH                                              Q-15                                                                              H   H   H   OCH.sub.3                                                                          OCH.sub.3                                                                              N   NH                                              Q-15                                                                              H   H   H   CH.sub.3                                                                           NHCH.sub.3                                                                             CH  NCH.sub.3                                       Q-15                                                                              H   H   H   OCH.sub.3                                                                          N(CH.sub.3).sub.2                                                                      CH  NCH.sub.3                                       Q-15                                                                              H   H   H   CH.sub.3                                                                           OCH.sub.2 CCH                                                                          N   S                                               Q-15                                                                              H   H   H   CH.sub.3                                                                           CH.sub.2 CCH.sub.3                                                                     CH  S                                               Q-15                                                                              H   H   H   CH.sub.3                                                                           CCH     N   S                                               Q-15                                                                              H   C.sub.2 H.sub.5                                                                    H   OCH.sub.3                                                                          OCH.sub.3                                                                              CH  S                                               Q-15                                                                              H   H   H   OCH.sub.3                                                                          (CH.sub. 2).sub.3 CH.sub.2 F                                                           CH  S                                               Q-15                                                                              H   H   H   OCH.sub.3                                                                          2-methyl-1,3-                                                                          N   S                                                                  dioxolan-2-yl                                               Q-15                                                                              H   H   H   OCH.sub.3                                                                          2-methyl-1,3-                                                                          CH  S                                                                  dithiolan-2-yl                                              Q-15                                                                              H   H   H   OCH.sub.3                                                                          2-methyl-1,3-                                                                          N   S                                                                  dithian-2-yl                                                Q-15                                                                              H   H   H   OCH.sub.3                                                                          OCH.sub.3                                                                              CH  S   *                                           Q-15                                                                              H   H   H   OCH.sub.3                                                                          CH.sub.3                                                                               N   S   *                                           __________________________________________________________________________

                                      TABLE 4d                                     __________________________________________________________________________     General Structure 2                                                                                           m.p.                                            Q   R  R.sub.3                                                                           R.sub.4                                                                           R.sub.5                                                                            X   Y      Z  °C.                                      __________________________________________________________________________     Q-18                                                                               H  H  H  H   CH.sub.3                                                                           CH.sub.3                                                                              CH 198-200                                         Q-18                                                                               H  H  H  H   CH.sub.3                                                                           OCH.sub.3                                                                             CH                                                 Q-18                                                                               H  H  H  H   CH.sub.3                                                                           OCH.sub.3                                                                             N  177-179                                         Q-18                                                                               CH.sub.3                                                                          H  H  H   CH.sub.3                                                                           OCH.sub.3                                                                             N                                                  Q-18                                                                               H  H  H  H   OCH.sub.3                                                                          OCH.sub.3                                                                             CH 178-182                                         Q-18                                                                               H  H  H  H   CH.sub.3                                                                           CH.sub.3                                                                              CH                                                 Q-18                                                                               H  H  H  H   OCH.sub.3                                                                          OCH.sub.3                                                                             N  185-188                                         Q-18                                                                               H  H  H  H   Cl  OCH.sub.3                                                                             CH                                                 Q-18                                                                               H  CH.sub.3                                                                          H  H   CH.sub.3                                                                           OCH.sub.3                                                                             CH                                                 Q-18                                                                               H  H  CH.sub.3                                                                          H   CH.sub.3                                                                           OCH.sub.3                                                                             N                                                  Q-18                                                                               H  H  H  CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3                                                                              CH                                                 Q-18                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          H   CH.sub.3                                                                           CH.sub.3                                                                              N                                                  Q-18                                                                               H  H  CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                          OCH.sub.3                                                                             CH                                                 Q-18                                                                               H  CH.sub.3                                                                          H  CH.sub. 3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                             N                                                  Q-18                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           OCH.sub.3                                                                             CH                                                 Q-18                                                                               H  H  H  H   OCH.sub.3                                                                          CH(OCH.sub.3).sub.2                                                                   CH                                                 Q-19                                                                               CH.sub.3                                                                          H  H  H   Cl  OCH.sub.3                                                                             CH                                                 Q-19                                                                               H  H  H  H   CH.sub.3                                                                           OCH.sub.3                                                                             CH                                                 Q-19                                                                               H  H  H  H   CH.sub.3                                                                           OCH.sub.3                                                                             N                                                  Q-19                                                                               H  H  H  H   OCH.sub.3                                                                          OCH.sub.3                                                                             CH                                                 Q-19                                                                               H  H  H  H   OCH.sub.3                                                                          OCH.sub.3                                                                             N                                                  Q-19                                                                               H  CH.sub.3                                                                          H  H   CH.sub.3                                                                           CH.sub.3                                                                              CH                                                 Q-19                                                                               H  H  CH.sub.3                                                                          H   CH.sub.3                                                                           CH.sub.3                                                                              N                                                  Q-19                                                                               H  H  H  CH.sub.3                                                                           CH.sub.3                                                                           OCH.sub.3                                                                             CH                                                 Q-19                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          H   CH.sub.3                                                                           OCH.sub.3                                                                             N                                                  Q-19                                                                               H  H  CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                          OCH.sub.3                                                                             CH                                                 Q-19                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                          OCH.sub.3                                                                             N                                                  Q-19                                                                               H  H  H  H   CH.sub.3                                                                           CH.sub.3                                                                              CH                                                 Q-19                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                           OCH.sub.3                                                                             CH                                                 Q-19                                                                               CH.sub.3                                                                          H  H  H   CH.sub.3                                                                           OCH.sub.3                                                                             N                                                                       O                                                         Q-19                                                                               H  H  H  H   OCH.sub.3  CH                                                                      O                                                         __________________________________________________________________________

                                      TABLE 4e                                     __________________________________________________________________________     General Structure 2                                                                                                          m.p.                             Q    R    R.sub.3 ',"                                                                              X     Y         Z    W'   °C.                       __________________________________________________________________________     Q-21 H    H         CH.sub.3                                                                             OCH.sub.3 CH   O                                     Q-21 H    H         CH.sub.3                                                                             OCH.sub.3 N    O                                     Q-21 H    H         OCH.sub.3                                                                            OCH.sub.3 CH   O                                     Q-21 CH.sub.3                                                                            H         OCH.sub.3                                                                            OCH.sub.3 CH   O                                     Q-21 H    H         OCH.sub.3                                                                            NHCH.sub.3                                                                               CH   O                                     Q-21 H    H         OCH.sub.3                                                                            OCH.sub.3 N    O                                     Q-21 H    CH.sub.3  CH.sub.3                                                                             OCH.sub.3 CH   O                                     Q-21 CH.sub.3                                                                            CH.sub.3  CH.sub.3                                                                             OCH.sub.3 CH   O                                     Q-21 H    H         CH.sub.3                                                                             CH.sub.3  CH   O                                     Q-21 H    H         CH.sub.3                                                                             CH.sub.3  N    O                                     Q-21 H    H         CH.sub.3                                                                             OCH.sub.3 CH   S                                     Q-21 H    H         CH.sub.3                                                                             OCH.sub.3 N    S                                     Q-21 H    H         OCH.sub.3                                                                            OCH.sub.3 CH   S                                     Q-21 H    H         OCH.sub.3                                                                            OCH.sub.3 N    S                                     Q-21 H    CH.sub.3  CH.sub.3                                                                             OCH.sub.3 CH   S                                     Q-21 CH.sub.3                                                                            H         CH.sub.3                                                                             OCH.sub.3 CH   S                                     Q-21 H    H         OCH.sub.3                                                                            N(CH.sub.3).sub.2                                                                        N    S                                     Q-22 H    H         CH.sub.3                                                                             OCH.sub.3 CH   O                                     Q-22 H    H         CH.sub.3                                                                             OCH.sub.3 N    O                                     Q-22 H    H         OCH.sub.3                                                                            OCH.sub.3 CH   O                                     Q-22 H    H         OCH.sub.3                                                                            OCH.sub.3 N    O                                     Q-22 H    CH.sub.3  CH.sub.3                                                                             OCH.sub.3 CH   O                                     Q-22 H    CH.sub.3  CH.sub.3                                                                             OCH.sub.3 N    O                                     Q-22 CH.sub.3                                                                            CH.sub.3  CH.sub.3                                                                             CH.sub.3  CH   O                                     Q-22 H    H         CH.sub.3                                                                             CH(OCH.sub.3).sub.2                                                                      CH   O                                     Q-22 H    H         CH.sub.3                                                                             C.sub.2 H.sub.5                                                                          N    O                                     Q-22 H    H         CH.sub.3                                                                             CH.sub.3  CH   S                                     Q-22 H    H         CH.sub.3                                                                             CH.sub.3  N    S                                     Q-22 H    H         CH.sub.3                                                                             OCH.sub.3 CH   S                                     Q-22 H    H         CH.sub.3                                                                             OCH.sub.3 N    S                                     Q-22 H    H         OCH.sub.3                                                                            OCH.sub.3 CH   S                                     Q-22 H    H         OCH.sub.3                                                                            OCH.sub.3 N    S                                     Q-22 H    CH.sub.3  CH.sub.3                                                                             OCH.sub.3 CH   S                                     Q-22 CH.sub.3                                                                            CH.sub.3  CH.sub.3                                                                             OCH.sub.3 CH   S                                     Q-22 CH.sub.3                                                                            H         CH.sub.3                                                                             OCH.sub.3 N    S                                     Q-22 H    H         CH.sub.3                                                                              ##STR142##                                                                              CH   S                                     Q-22 H    H         OCH.sub.3                                                                            C.sub.2 H.sub.5                                                                          N    S                                     Q-23 H    H         CH.sub.3                                                                             OCH.sub.3 CH   --                                    Q-23 H    H         CH.sub.3                                                                             OCH.sub.3 N    --                                    Q-23 H    H         OCH.sub.3                                                                            OCH.sub.3 CH   --                                    Q-23 H    H         OCH.sub.3                                                                            OCH.sub.3 N    --                                    Q-23 H    CH.sub.3  CH.sub.3                                                                             CH.sub.3  CH   --                                    Q-23 H    CH.sub.3  CH.sub.3                                                                             OCH.sub.3 N    --                                    Q-23 CH.sub.3                                                                            H         CH.sub.3                                                                             OCH.sub.3 N    --                                    Q-23 CH.sub.3                                                                            CH.sub.3  CH.sub.3                                                                             OCH.sub.3 CH   --                                    Q-23 H    H         CH.sub.3                                                                             OC.sub.2 H.sub.5                                                                         N    --                                    Q-23 H    H         CH.sub.3                                                                             CH.sub.2 OCH.sub.3                                                                       CH   --                                    Q-24 H    H         CH.sub.3                                                                             OCH.sub.3 CH   --                                    Q-24 H    H         CH.sub.3                                                                             OCH.sub.3 N    --                                    Q-24 H    H         OCH.sub.3                                                                            OCH.sub.3 CH   --                                    Q-24 H    H         OCH.sub.3                                                                            OCH.sub.3 N    --                                    Q-24 H    CH.sub.3  CH.sub.3                                                                             OCH.sub.3 CH   --                                    Q-24 H    CH.sub.3  CH.sub.3                                                                             CH.sub.3  CH   --                                    Q-24 CH.sub.3                                                                            H         CH.sub.3                                                                             CH.sub.3  N    --                                    Q-24 H    H         CH.sub.3                                                                             CF.sub.3  CH   --                                    Q-24 H    H         OCH.sub.3                                                                            OCF.sub.2 H                                                                              N    --                                    Q-25 H    H         CH.sub.3                                                                             OCH.sub.3 CH   -- **                                 Q-25 H    H         CH.sub.3                                                                             OCH.sub.3 N    -- **                                 Q-25 H    H         OCH.sub.3                                                                            OCH.sub.3 CH   -- **                                 Q-25 H    H         OCH.sub.3                                                                            OCH.sub.3 N    -- **                                 Q-25 CH.sub.3                                                                            H         OCH.sub.3                                                                            OCH.sub.3 N    -- **                                 Q-25 H    H         CH.sub.3                                                                             CH.sub.3  CH   -- **                                 Q-25 H    H         CH.sub.3                                                                             CH.sub.3  N    -- **                                 Q-25 H    CH.sub.3  CH.sub.3                                                                             OCH.sub.3 CH   -- **                                 Q-25 H    CH.sub.3  CH.sub.3                                                                             OCH.sub.3 N    -- **                                 Q-25 CH.sub.3                                                                            CH.sub.3  OCH.sub.3                                                                            OCH.sub.3 N    -- **                                 Q-25 H    H         CH.sub.3                                                                             OCH.sub.2 CF.sub.3                                                                       CH   -- **                                 Q-25 H    H         CH.sub.3                                                                             NHCH.sub.3                                                                               N    -- **                                 Q-26 H    H         CH.sub.3                                                                             OCH.sub.3 CH   -- **                                 Q-26 H    H         CH.sub.3                                                                             OCH.sub.3 N    -- **                                 Q-26 H    H         OCH.sub.3                                                                            OCH.sub.3 CH   -- **                                 Q-26 H    CH.sub.3  CH.sub.3                                                                             CH.sub.3  N    -- **                                 Q-26 H    CH.sub.3  CH.sub.3                                                                             CH.sub.3  CH   -- **                                 Q-26 H    CH.sub.3  CH.sub.3                                                                             OCH.sub.3 N    -- **                                 Q-26 H    CH.sub.3  CH.sub.3                                                                             OCH.sub.3 CH   -- **                                 Q-26 H    CH.sub.3  CH.sub.3                                                                             OCH.sub.3 N    -- **                                 Q-26 H    H         CH.sub.3                                                                             CH.sub.3  CH   -- **                                 Q-26 H    H         CH.sub.3                                                                             CH.sub.3  N    -- **                                 Q-26 H    CH.sub.3  OCH.sub.3                                                                            OCH.sub.3 CH   -- **                                 Q-26 H    CH.sub.3  OCH.sub.3                                                                            OCH.sub.3 N    -- **                                 Q-26 CH.sub.3                                                                            H         CH.sub.3                                                                             OCH.sub.3 CH   -- **                                 Q-26 H    H         CH.sub.3                                                                             N(CH.sub.3).sub.2                                                                        CH   -- **                                 Q-26 H    H         CH.sub.3                                                                             N(CH.sub.3).sub.2                                                                        N    -- **                                 Q-27 H    H         CH.sub.3                                                                             OCH.sub.3 CH   -- **                                 Q-27 H    H         CH.sub.3                                                                             OCH.sub.3 N    -- **                                 Q-27 H    H         OCH.sub.3                                                                            OCH.sub.3 CH   -- **                                 Q-27 H    H         OCH.sub.3                                                                            OCH.sub.3 N    -- **                                 Q-27 H    H         CH.sub.3                                                                             CH.sub.3  CH   -- **                                 Q-27 H    H         CH.sub.3                                                                             CH.sub.3  N    --  **                                Q-27 H    CH.sub.3  CH.sub.3                                                                             CH.sub.3  CH   -- **                                 Q-27 H    H         Cl    OC.sub.2 H.sub.5                                                                         CH   -- **                                 Q-27 H    CH.sub.3  CH.sub.3                                                                             CH.sub.3  N    -- **                                 Q-27 H    CH.sub.3  CH.sub.3                                                                             OCH.sub.3 CH   -- **                                 Q-27 H    CH.sub.3  CH.sub.3                                                                             OCH.sub.3 N    -- **                                 Q-27 H    CH.sub.3  OCH.sub.3                                                                            OCH.sub.3 CH   -- **                                 Q-27 H    CH.sub.3  OCH.sub.3                                                                            OCH.sub.3 N    -- **                                 Q-27 CH.sub.3                                                                            CH.sub.3  CH.sub.3                                                                             OCH.sub.3 N    -- **                                 Q-27 CH.sub.3                                                                            H         CH.sub.3                                                                             OCH.sub.3 N    -- **                                 Q-27 H    H         CH.sub.3                                                                             CH(OCH.sub.3).sub.2                                                                      CH   -- **                                 Q-27 H    H         CH.sub.3                                                                             O(CH.sub.2).sub.3 CH.sub.2 Cl                                                            CH   -- **                                 Q-25 H    SH        CH.sub.3                                                                             CH.sub.3  CH   -- **                                                                               210-219                          Q-25 H    SH        CH.sub.3                                                                             OCH.sub.3 CH   -- **                                                                               220-222                          Q-25 H    SH        OCH.sub.3                                                                            OCH.sub.3 CH   -- **                                                                               171-173                          Q-25 H    SH        OCH.sub.3                                                                            Cl        CH   -- **                                                                               180-182                          Q-25 H    SH        CH.sub.3                                                                             OCH.sub.3 N    --  **                                                                              169-171                          Q-25 H    SH        OCH.sub.3                                                                            OCH.sub.3 N    -- **                                                                               209-213                          Q-25 H    SCH.sub.3 CH.sub.3                                                                             CH.sub.3  CH   -- **                                                                               154-160                          Q-25 H    SCH.sub.3 CH.sub.3                                                                             OCH.sub.3 CH   -- **                                                                               142-145                          Q-25 H    SCH.sub.3 OCH.sub.3                                                                            OCH.sub.3 CH   -- **                                                                               178-180                          Q-25 H    SCH.sub.3 OCH.sub.3                                                                            Cl        CH   -- **                                                                               192-195                          Q-25 H    SCH.sub.3 CH    OCH.sub.3 N    -- **                                                                               198-200                          Q-25 H    SCH.sub.3 OCH.sub.3                                                                            OCH.sub.3 N    -- **                                                                               152-153                          Q-25 H    SCH.sub.2 CHCH.sub.2                                                                     CH.sub.3                                                                             CH.sub.3  CH   -- **                                                                               173-175                          Q-25 H    SCH.sub.2 CHCH.sub.2                                                                     CH.sub.3                                                                             OCH.sub.3 CH   -- **                                                                               154-159                          Q-25 H    SCH.sub.2 CHCH.sub.2                                                                     OCH.sub.3                                                                            OCH.sub.3 CH   -- **                                                                               115-117                          Q-25 H    SCH.sub.2 CHCH.sub.2                                                                     OCH.sub.3                                                                            Cl        CH   -- **                                                                               114-116                          Q-25 H    SCH.sub.2 CHCH.sub.2                                                                     CH.sub.3                                                                             OCH.sub.3 N    -- **                                                                               142-145                          Q-25 H    SCH.sub.2 CHCH.sub.2                                                                     OCH.sub.3                                                                            OCH.sub.3 N    -- **                                                                               91-93                            Q-25 CH.sub.3                                                                            SCH.sub.3 OCH.sub.3                                                                            OCH.sub.3 CH   -- **                                 Q-25 CH.sub.3                                                                            SH        OCH.sub.3                                                                            OCH.sub.3 CH   -- **                                 Q-25 CH.sub.3                                                                            SCH.sub.2 CHCH.sub.2                                                                     OCH.sub.3                                                                            OCH.sub.3 CH   -- **                                 __________________________________________________________________________      R.sub.11 is --, unless indicated by ** where R.sub.11 is CH.sub.3 in all       Tables.                                                                  

                                      TABLE 4f                                     __________________________________________________________________________     General Structure 2                                                                                                         m.p.                              Q    R    R.sub.3                                                                              R.sub.4                                                                              R.sub.5                                                                             X     Y        Z  °C.                        __________________________________________________________________________     Q-29 H    H     H     --   CH.sub.3                                                                             OCH.sub.3                                                                               CH                                   Q-29 H    H     H     --   CH.sub.3                                                                             OCH.sub.3                                                                               N                                    Q-29 H    H     H     --   OCH.sub.3                                                                            OCH.sub.3                                                                               CH                                   Q-29 H    H     H     --   OCH.sub.3                                                                            OCH.sub.3                                                                               N                                    Q-29 H    H     H     --   CH.sub.3                                                                             CH.sub.3 CH                                   Q-29 H    H     H     --   CH.sub.3                                                                             CH.sub.3 N                                    Q-29 H    CH.sub.3                                                                             H     --   CH.sub.3                                                                             OCH.sub.3                                                                               CH                                   Q-29 H    CH.sub.3                                                                             H     --   CH.sub.3                                                                             CH.sub.3 CH                                   Q-29 H    CH.sub.3                                                                             CH.sub.3                                                                             --   CH.sub.3                                                                             OCH.sub.3                                                                               N                                    Q-29 CH.sub.3                                                                            CH.sub.3                                                                             CH.sub.3                                                                             --   CH.sub.3                                                                             CH.sub.3 N                                    Q-29 CH.sub.3                                                                            H     H     --   OCH.sub.3                                                                            OCH.sub.3                                                                               CH                                   Q-29 H    H     H     --   CH.sub.3                                                                             OC.sub.2 H.sub.5                                                                        N                                    Q-29 H    H     H     --   Cl    OCH.sub.3                                                                               CH                                   Q-36 H    H     H     H    CH.sub.3                                                                             OCH.sub.3                                                                               CH                                   Q-36 CH.sub.3                                                                            H     H     H    CH.sub.3                                                                             OCH.sub.3                                                                               CH                                   Q-36 H    H     H     H    CH.sub.3                                                                             OCH.sub.3                                                                               N                                    Q-36 H    H     H     H    OCH.sub.3                                                                            OCH.sub.3                                                                               CH                                   Q-36 H    H     H     H    OCH.sub.3                                                                            OCH.sub.3                                                                               N                                    Q-36 H    H     H     H    OCH.sub.3                                                                            C.sub.2 H.sub.5                                                                         CH                                   Q-36 H    H     H     H    CH.sub.3                                                                             CH.sub.3 CH                                   Q-36 H    H     H     H    CH.sub.3                                                                             CH.sub.3 N                                    Q-36 H    CH.sub.3                                                                             H     H    CH.sub.3                                                                             CH.sub.3 CH                                   Q-36 H    H     CH.sub.3                                                                             H    CH.sub.3                                                                             CH.sub.3 N                                    Q-36 H    CH.sub.3                                                                             H     CH.sub.3                                                                            CH.sub.3                                                                             OCH.sub.3                                                                               CH                                   Q-36 H    CH.sub.3                                                                             CH.sub.3                                                                             H    CH.sub.3                                                                             OCH.sub.3                                                                               N                                    Q-36 H    CH.sub.3                                                                             CH.sub.3                                                                             CH.sub.3                                                                            OCH.sub.3                                                                            OCH.sub.3                                                                               CH                                   Q-36 CH.sub.3                                                                            H     H     H    OCH.sub.3                                                                            OCH.sub.3                                                                               N                                    Q-36 H    H     H     H    CH.sub.3                                                                             NHCH.sub.3                                                                              CH                                   Q-36 H    H     H     H    CH.sub.3                                                                             N(CH.sub.3).sub.2                                                                       CH                                   Q-37 H    H     H     --   CH.sub.3                                                                             OCH.sub.3                                                                               CH                                   Q-37 H    H     H     --   CH.sub.3                                                                             OCH.sub.3                                                                               N                                    Q-37 H    H     H     --   OCH.sub.3                                                                            OCH.sub.3                                                                               CH                                   Q-37 H    H     H     --   OCH.sub.3                                                                            OCH.sub.3                                                                               N                                    Q-37 H    H     H     --   CH.sub.3                                                                             CH.sub.3 CH                                   Q-37 H    2-CH.sub.3                                                                           H     --   CH.sub.3                                                                             CH.sub.3 CH                                   Q-37 H    4-CH.sub.3                                                                           H     --   CH.sub.3                                                                             CH.sub.3 N                                    Q-37 H    5-CH.sub.3                                                                           H     --   CH.sub.3                                                                             OCH      CH                                   Q-37 H    H     H     --   CH.sub.3                                                                             CH.sub.3 N                                    Q-37 H    2-CH.sub.3                                                                           4-CH.sub.3                                                                           --   CH.sub.3                                                                             OCH.sub.3                                                                               N                                    Q-37 H    2-CH.sub.3                                                                           5-CH.sub.3                                                                           --   OCH.sub.3                                                                            OCH.sub.3                                                                               CH                                   Q-37 H    4-CH.sub.3                                                                           5-CH.sub.3                                                                           --   OCH.sub.3                                                                            OCH.sub.3                                                                               N                                    Q-37 CH.sub.3                                                                            H     H     --   CH.sub.3                                                                             OCH.sub.3                                                                               CH                                   Q-37 H    H     H     --   CH.sub.3                                                                             CH(OCH.sub.3).sub.2                                                                     CH                                   Q-37 H    H     H     --   Cl    OCH.sub.3                                                                               CH                                   Q-38 H    H     H     --   CH.sub.3                                                                             OCH.sub.3                                                                               CH                                   Q-38 H    H     H     --   CH.sub.3                                                                             OCH.sub.3                                                                               N                                    Q-38 H    H     H     --   OCH.sub.3                                                                            OCH.sub.3                                                                               CH                                   Q-38 H    H     H     --   OCH.sub.3                                                                            OCH.sub.3                                                                               N                                    Q-38 H    2-CH.sub.3                                                                           H     --   CH.sub.3                                                                             CH.sub.3 CH                                   Q-38 H    4-CH.sub.3                                                                           H     --   CH.sub.3                                                                             CH.sub.3 N                                    Q-38 H    2-CH.sub.3                                                                           4-CH.sub.3                                                                           --   CH.sub.3                                                                             OCH.sub.3                                                                               CH                                   Q-38 H    4-CH.sub.3                                                                           4-CH.sub.3                                                                           --   CH.sub.3                                                                             OCH.sub.3                                                                               N                                    Q-38 H    H     H     --   CH.sub.3                                                                             CH.sub.3 N                                    Q-38 CH.sub.3                                                                            4-CH.sub.3                                                                           6-CH.sub.3                                                                           --   OCH.sub.3                                                                            OCH.sub.3                                                                               CH                                   Q-38 H    H     H     --   CH.sub.3                                                                              ##STR143##                                                                             CH                                   Q-38 H    H     H     --   CH.sub.3                                                                             CH.sub.3 CH                                   Q-38 H    H     H     --   OCH.sub.3                                                                            C.sub.2 H.sub.5                                                                         N                                    Q-39 H    H     H     --   CH.sub.3                                                                             OCH.sub.3                                                                               CH                                   Q-39 H    H     H     --   CH.sub.3                                                                             OCH.sub.3                                                                               N                                    Q-39 H    H     H     --   CH.sub.3                                                                             CH.sub.3 N                                    Q-39 H    H     H     --   OCH.sub.3                                                                            OCH.sub.3                                                                               CH                                   Q-39 H    H     H     --   OCH.sub.3                                                                            OCH.sub.3                                                                               N                                    Q-39 CH.sub.3                                                                            H     H     --   OCH.sub.3                                                                            OCH.sub.3                                                                               N                                    Q-39 H    3-CH.sub.3                                                                           H     --   CH.sub.3                                                                             CH.sub.3 CH                                   Q-39 H    H     H     --   CH.sub.3                                                                             CH.sub.3 CH                                   Q-39 H    5-CH.sub.3                                                                           H     --   CH.sub.3                                                                             CH.sub.3 N                                    Q-39 H    H     H     --   Cl    OC.sub.2 H.sub.5                                                                        CH                                   Q-39 H    6-CH.sub.3                                                                           H     --   CH.sub.3                                                                             OCH.sub.3                                                                               CH                                   Q-39 H    3-CH.sub.3                                                                           5-CH.sub.3                                                                           --   CH.sub.3                                                                             OCH.sub.3                                                                               N                                    Q-39 H    3-CH.sub.3                                                                           6-CH.sub.3                                                                           --   OCH.sub.3                                                                            OCH.sub.3                                                                               CH                                   Q-39 H    5-CH.sub.3                                                                           6-CH.sub.3                                                                           --   OCH.sub.3                                                                            OCH.sub.3                                                                               N                                    Q-39 H    H     H     --   OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                        N                                    Q-39 H    H     H     --   OCH.sub.3                                                                            CH.sub.2 OCH.sub.3                                                                      N                                    Q-40 H    H     H     --   CH.sub.3                                                                             CH.sub.3 CH                                   Q-40 H    H     H     --   CH.sub.3                                                                             OCH.sub.3                                                                               CH                                   Q-40 H    H     H     --   CH.sub.3                                                                             OCH.sub.3                                                                               N                                    Q-40 H    H     H     --   OCH.sub.3                                                                            OCH.sub.3                                                                               CH                                   Q-40 H    H     H     --   OCH.sub.3                                                                            OCH.sub.3                                                                               N                                    Q-40 H    H     H     --   CH.sub.3                                                                             CH.sub.3 N                                    Q-40 H    4-CH.sub.3                                                                           H     --   CH.sub.3                                                                             CH.sub. 3                                                                               CH                                   Q-40 H    5-CH.sub.3                                                                           H     --   CH.sub.3                                                                             CH.sub.3 N                                    Q-40 H    6-CH.sub.3                                                                           H     --   CH.sub.3                                                                             OCH.sub.3                                                                               CH                                   Q-40 H    4-CH.sub.3                                                                           5-CH.sub.3                                                                           --   CH.sub.3                                                                             OCH.sub.3                                                                               N                                    Q-40 H    4-CH.sub.3                                                                           6-CH.sub.3                                                                           --   OCH.sub.3                                                                            OCH.sub.3                                                                               CH                                   Q-40 H    5-CH.sub.3                                                                           6-CH.sub.3                                                                           --   OCH.sub.3                                                                            OCH.sub.3                                                                               N                                    Q-40 CH.sub.3                                                                            H     H     --   CH.sub.3                                                                             CH.sub.3 CH                                   Q-40 H    H     H     --   OCH.sub.3                                                                            CF.sub.3 N                                    Q-40 H    H     H     --   OCH.sub.3                                                                            OCF.sub.2 H                                                                             N                                    Q-43 H    H     H     --   CH.sub.3                                                                             CH.sub.3 CH                                   Q-43 H    H     H     --   CH.sub.3                                                                             OCH.sub.3                                                                               CH                                   Q-43 H    H     H     --   CH.sub.3                                                                             OCH.sub.3                                                                               N                                    Q-43 H    H     H     --   OCH.sub.3                                                                            OCH.sub.3                                                                               CH                                   Q-43 H    H     H     --   OCH.sub.3                                                                            OCH.sub.3                                                                               N                                    Q-43 CH.sub.3                                                                            H     H     --   OCH.sub.3                                                                            OCH.sub.3                                                                               CH                                   Q-43 H    CH.sub.3                                                                             CH.sub.3                                                                             --   CH.sub.3                                                                             OCH.sub.3                                                                               CH                                   Q-43 H    CH.sub.3                                                                             H     --   CH.sub.3                                                                             CH.sub.3 CH                                   Q-43 H    H     H     --   CH.sub.3                                                                             CH.sub.3 N                                    Q-43 H    H     H     --   OCH.sub.3                                                                            OCH.sub.2 CF.sub.3                                                                      N                                    Q-43 H    H     H     --   OCH.sub.3                                                                            NHCH.sub.3                                                                              N                                    Q-44 H    H     H     --   CH.sub.3                                                                             OCH.sub.3                                                                               CH                                   Q-44 H    H     H     --   CH.sub.3                                                                             OCH.sub.3                                                                               N                                    Q-44 H    H     H     --   OCH.sub.3                                                                            OCH.sub.3                                                                               CH                                   Q-44 H    H     H     --   OCH.sub.3                                                                            OCH.sub.3                                                                               N                                    Q-44 H    CH.sub.3                                                                             H     --   CH.sub.3                                                                             CH.sub.3 CH                                   Q-44 H    H     CH.sub.3                                                                             --   CH.sub.3                                                                             CH.sub.3 N                                    Q-44 H    CH.sub.3                                                                             CH.sub.3                                                                             --   CH.sub.3                                                                             OCH.sub.3                                                                               N                                    Q-44 CH.sub.3                                                                            H     H     --   CH.sub.3                                                                             OCH.sub.3                                                                               N                                    Q-44 H    H     H     --   OCH.sub.3                                                                            N(CH.sub.3).sub.2                                                                       N                                    Q-44 H    H     H     --   Br    OCH.sub.3                                                                               CH                                   Q-44 H    H     H     --   CH.sub.3                                                                             CH.sub.3 CH                                   Q-44 H    H     H     --   CH.sub.3                                                                             CH.sub.3 N                                    Q-45 H    H     --    --   CH.sub.3                                                                             OCH.sub.3                                                                               CH                                   Q-45 H    H     --    --   CH.sub.3                                                                             OCH.sub.3                                                                               N                                    Q-45 H    H     --    --   OCH.sub.3                                                                            OCH.sub.3                                                                               CH                                   Q-45 H    H     --    --   OCH.sub.3                                                                            OCH.sub.3                                                                               N                                    Q-45 H    CH.sub.3                                                                             --    --   CH.sub.3                                                                             CH.sub.3 CH                                   Q-45 CH.sub.3                                                                            H     --    --   CH.sub.3                                                                             CH.sub.3 N                                    Q-45 H    H     --    --   OCH.sub.3                                                                            CH(OCH.sub.3).sub.2                                                                     N                                    Q-45 H    H     --    --   CH.sub.3                                                                             CH.sub.3 CH                                   Q-45 H    H     --    --   CH.sub.3                                                                             CH.sub.3 N                                    Q-45 H    H     --    --   Cl    OCH.sub.3                                                                               CH                                   __________________________________________________________________________      wherein W' is O.                                                         

                                      TABLE 5a                                     __________________________________________________________________________     General Structure 2 wherein Q is Q-5.                                                                             m.p.                                        R  R.sub.3                                                                           R.sub.4                                                                           R.sub.5                                                                           R.sub.6                                                                           R.sub.7                                                                           R.sub.8                                                                           X   Y      Z  °C.                                  __________________________________________________________________________     H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              N                                              H  H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             CH                                             H  H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N                                              H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH                                             H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             N                                              CH.sub.3                                                                          H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH                                             H  CH.sub.3                                                                          H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              CH                                             H  H  H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              N                                              H  H  H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                             CH                                             H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                             N                                              H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH                                             H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                             N                                              H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                              CH                                             H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                              N                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             CH                                             H  H  H  H  CH.sub.3                                                                          H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N                                              H  H  H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                             CH                                             H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             N                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                              CH                                             H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                              N                                              H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                             CH                                             H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                             N                                              H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                             CH                                             H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                              CH                                             H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                              CH                                             H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                              N                                              H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                             CH                                             CH.sub.3                                                                          H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N                                              H  H  H  H  H  H  H  OCH.sub.3                                                                          CH(OCH.sub.3).sub.2                                                                   N                                                                       O                                                     H  H  H  H  H  H  H  OCH.sub.3  N                                                                       O                                                     H  H  H  H  H  H  H  Cl  OCH.sub.3                                                                             CH                                             H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              CH                                             __________________________________________________________________________      Wherein W" is O.                                                         

                                      TABLE 5b                                     __________________________________________________________________________     General Structure 2 wherein Q is Q-6.                                                                                  m.p.                                   Q  R  R.sub.3                                                                           R.sub.4                                                                           R.sub.5                                                                           R.sub.6                                                                           R.sub.7                                                                           R.sub.8                                                                           X   Y     Z  W" °C.                             __________________________________________________________________________     Q-6                                                                               H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             CH O                                         Q-6                                                                               H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             N  O                                         Q-6                                                                               H  CH.sub.3                                                                          H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH O                                         Q-6                                                                               H  H  H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N  O                                         Q-6                                                                               H  H  H  H  H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH O                                         Q-6                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N  O                                         Q-6                                                                               H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             CH O                                         Q-6                                                                               H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             N  O                                         Q-6                                                                               H  CH.sub.3                                                                          CH.sub. 3                                                                         H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH O                                         Q-6                                                                               H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N  O                                         Q-6                                                                               H  H  H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            CH O                                         Q-6                                                                               H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            N  O                                         Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             CH O                                         Q-6                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                             N  O                                         Q-6                                                                               H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            CH O                                         Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N  O                                         Q-6                                                                               H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH O                                         Q-6                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                            N  O                                         Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             CH O                                         Q-6                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                             N  O                                         Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH O                                         Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            N  O                                         Q-6                                                                               H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            CH O                                         Q-6                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            N  O                                         Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                             CH O                                         Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             N  O                                         Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            CH O                                         Q-6                                                                               CH.sub.3                                                                          H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N  O                                         Q-6                                                                               H  H  H  H  H  H  H  Br  OCH.sub.3                                                                            CH O                                         Q-6                                                                               H  H  H  H  H  H  H  Cl  OC.sub.2 H.sub.5                                                                     CH O                                         Q-6                                                                               H  H  H  H  H  H  H  OCH.sub.3                                                                          C.sub.2 H.sub.5                                                                      CH O                                         Q-6                                                                               H  H  H  H  H  H  H  OCH.sub.3                                                                          OC.sub. 2 H.sub.5                                                                    CH O                                         Q-6                                                                               H  H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH O                                         Q-6                                                                               H  H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N  O                                         Q-6                                                                               H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH O                                         Q-6                                                                               H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N  O                                         Q-6                                                                               CH.sub.3                                                                          H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH O                                         Q-6                                                                               H  H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH S                                         Q-6                                                                               H  H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N  S                                         Q-6                                                                               H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH S                                         Q-6                                                                               H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N  S                                         Q-6                                                                               H  H  H  H  H  H  H  OCH.sub.3                                                                          C.sub.2 H.sub.5                                                                      CH S                                         Q-6                                                                               H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             CH S                                         Q-6                                                                               H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             N  S                                         Q-6                                                                               H  CH.sub.3                                                                          H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH S                                         Q-6                                                                               H  H  H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N  S                                         Q-6                                                                               H  H  H  H  H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH S                                         Q-6                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N  S                                         Q-6                                                                               H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             CH S                                         Q-6                                                                               H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             N  S                                         Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH S                                         Q-6                                                                               H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N  S                                         Q-6                                                                               H  H  H  H  H  H  H  OCH.sub.3                                                                          CH.sub.2 OCH.sub.3                                                                   CH S                                         Q-6                                                                               H  H  H  H  H  H  H  OCH.sub.3                                                                          CF.sub.3                                                                             CH S                                         Q-6                                                                               H  H  H  H  H  H  H  OCH.sub.3                                                                          OCF.sub.2 H                                                                          CH S                                         Q-6                                                                               H  H  H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            CH S                                         Q-6                                                                               H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            N  S                                         Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             CH S                                         Q-6                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                             N  S                                         Q-6                                                                               H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            CH S                                         Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N  S                                         Q-6                                                                               H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH S                                         Q-6                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                            N  S                                         Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             CH S                                         Q-6                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                             N  S                                         Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH S                                         Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            N  S                                         Q-6                                                                               H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            CH S                                         Q-6                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            N  S                                         Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                             CH S                                         Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             N  S                                         Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            CH S                                         Q-6                                                                               CH.sub.3                                                                          H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N  S                                         __________________________________________________________________________

                                      TABLE 5c                                     __________________________________________________________________________     General Structure 2                                                                                              m.p.                                         Q  R  R.sub.3                                                                           R.sub.4                                                                           R.sub.5                                                                           R.sub.6                                                                           X   Y      Z  W'                                                                               °C.                                   __________________________________________________________________________     Q-7                                                                               H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             CH --                                             Q-7                                                                               H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N  --                                             Q-7                                                                               H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH --                                             Q-7                                                                               H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             N  --                                             Q-7                                                                               H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              CH --                                             Q-7                                                                               H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              N  --                                             Q-7                                                                               H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             CH --                                             Q-7                                                                               H  H  CH.sub.3                                                                          H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N  --                                             Q-7                                                                               H  CH.sub.3                                                                          H  H  CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                             CH --                                             Q-7                                                                               H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  OCH.sub. 3                                                                         OCH.sub.3                                                                             N  --                                             Q-7                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                              CH --                                             Q-7                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                              N  --                                             Q-7                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                             CH --                                             Q-7                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                             N  --                                             Q-7                                                                               CH.sub.3                                                                          H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH --                                             Q-7                                                                               CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                             CH --                                             Q-7                                                                               H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.2 CF.sub.3                                                                    CH --                                             Q-7                                                                               H  H  H  H  H  OCH.sub.3                                                                          NHCH.sub.3                                                                            CH --                                             Q-7                                                                               H  H  H  H  H  Cl  OCH.sub.3                                                                             CH --                                             Q-7                                                                               H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH --                                                                               *                                            Q-7                                                                               H  H  H  H  H  OCH.sub.3                                                                          CH.sub.3                                                                              N  --                                                                               *                                            Q-7                                                                               H  H  H  H  H  OCH.sub.3                                                                          CH     CH --                                                                               *                                            Q-16                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           OCH.sub.3                                                                             CH O 181-183                                      Q-16                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N  O   175-176.5                                  Q-16                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH O 176-178                                      Q-16                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             N  O 174-176                                      Q-16                                                                              CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                              Q-16                                                                              CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  Cl  OCH.sub.3                                                                             CH O                                              Q-16                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                              CH O 175-182                                      Q-16                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                              N  O                                              Q-16                                                                              H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                              Q-16                                                                              H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                              Q-16                                                                              H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                              Q-16                                                                              H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                              Q-16                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  OCH.sub.3                                                                          N(CH.sub.3).sub.2                                                                     CH O                                              Q-16                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  OCH.sub.3                                                                          CH(OCH.sub.3).sub.2                                                                   CH O                                              Q-16                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  Cl  OCH.sub.3                                                                             CH O 168-171                                      Q-16                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.2 OCH.sub.3                                                                    N  O                                              Q-16                                                                              H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              CH O                                              Q-16                                                                              H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                              N  O                                              Q-16                                                                              H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                              Q-16                                                                              H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                              Q-16                                                                              H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                              Q-16                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                              Q-16                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                              CH O                                              Q-16                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                              N  O                                              Q-16                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                              CH S                                              Q-16                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                              N  S                                              Q-16                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                              Q-16                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                              Q-16                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                              Q-16                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                              Q-16                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  Cl  OCH.sub.3                                                                             CH S                                              Q-16                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           NHCH.sub.3                                                                            N  S                                              Q-16                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           N(CH.sub.3).sub.2                                                                     N  S                                              Q-16                                                                              H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                              Q-16                                                                              H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                              Q-16                                                                              H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                              Q-16                                                                              H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                              Q-16                                                                              CH.sub.3                                                                          H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              CH S                                              Q-16                                                                              H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              N  S                                              Q-16                                                                              H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                              Q-16                                                                              H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                              Q-16                                                                              H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                              Q-16                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                              Q-16                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                              CH S                                              Q-16                                                                              H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                              N  S                                              Q-16                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                              Q-17                                                                              H  H  H  H  H  Cl  OCH.sub.3                                                                             CH --                                             Q-17                                                                              H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              CH --                                             Q-17                                                                              H  H  H  H  H  Cl  OC.sub.2 H.sub.5                                                                      CH --                                             Q-17                                                                              H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              N  --                                             Q-17                                                                              H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH --                                             Q-17                                                                              H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             N  --                                             Q-17                                                                              H  H  H  H  H  OCH.sub.3                                                                          OC.sub.2 H.sub.5                                                                      CH --                                             Q-17                                                                              H  H  H  H  H  OCH.sub.3                                                                          OC.sub.2 H.sub.5                                                                      N  --                                             Q-17                                                                              H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              CH --                                             Q-17                                                                              H  H  H  H  H  CH.sub.3                                                                           CH(OCH.sub.3).sub.2                                                                   N  --                                                                   O                                                        Q-17                                                                              H  H  H  H  H  CH.sub.3   N  --                                                                   O                                                        Q-17                                                                              H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                              N  --                                             Q-17                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           OCH.sub.3                                                                             CH --                                             Q-17                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N  --                                             Q-17                                                                              H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                             CH --                                             Q-17                                                                              H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                             N  --                                             Q-17                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                              CH --                                             Q-17                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                              N  --                                             Q-17                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                             CH --                                             Q-17                                                                              CH.sub.3                                                                          H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N  --                                             __________________________________________________________________________

                                      TABLE 5d                                     __________________________________________________________________________     General Structure 2 wherein Q is Q-30                                                                                m.p.                                     R  R.sub.3                                                                           R.sub.4                                                                           R.sub.5                                                                           R.sub.6                                                                            R.sub.7                                                                           R.sub.8                                                                           R.sub.9                                                                           X   Y     Z  °C.                               __________________________________________________________________________     H  H  H  H  H   H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                          H  H  H  H  H   H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N                                           H  H  H  H  H   H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                          H  H  H  H  H   H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N                                           H  H  H  H  H   H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             N                                           H  H  H  H  H   H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                          CH.sub.3                                                                          H  H  H  H   H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                          H  CH.sub.3                                                                          H  H  H   H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N                                           H  H  H  H  H   H  H  H  Cl  OCH.sub.3                                                                            CH                                          H  H  CH.sub.3                                                                          H  H   H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                          H  H  H  H  CH.sub.3                                                                           H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N                                           H  H  H  H  H   H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                          H  CH.sub.3                                                                          CH.sub.3                                                                          H  H   H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             N                                           H  CH.sub.3                                                                          H  H  CH.sub.3                                                                           H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                          H  CH.sub.3                                                                          H  H  H   H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            N                                           H  H  CH.sub.3                                                                          CH.sub.3                                                                          H   H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                          H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N                                           H  H  CH.sub.3                                                                          H  H   H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                          H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                             N                                           H  H  H  H  CH.sub.3                                                                           H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                          H  H  H  H  H   H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            N                                           H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H   H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                          H  CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N                                           H  CH.sub.3                                                                          CH.sub.3                                                                          H  H   H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                          H  CH.sub.3                                                                          H  H  H   CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                             N                                           H  CH.sub.3                                                                          H  H  CH.sub.3                                                                           H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                          H  CH.sub.3                                                                          H  H  H   H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            N                                           H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                          H  H  CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                            N                                           H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                          H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             N                                           H  H  CH.sub.3                                                                          H  H   H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            CH                                          H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            N                                           H  H  H  H  CH.sub.3                                                                           H  CH.sub.3                                                                          CH.sub. 3                                                                         OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N                                           H  CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                          H  CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            N                                           H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                          H  CH.sub.3                                                                          H  H  CH.sub.3                                                                           H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            N                                           H  CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                          H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                          H  CH.sub.3                                                                          CH.sub.3                                                                          H  H   H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            N                                           H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                          H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             N                                           H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                          H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub. 3                                                                          OCH.sub.3                                                                            N                                           H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N                                           H  CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                          H  CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                             N                                           H  CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            CH                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H   H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            N                                           H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                          H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            N                                           H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                          H  CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                             N                                           H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            CH                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            N                                           H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            N                                           CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                             CH                                          H  H  H  H  H   H  H  H  CH.sub.3                                                                           OC.sub.2 H.sub.5                                                                     CH                                          H  H  H  H  H   H  H  H  CH.sub.3                                                                           CH.sub.2 OCH.sub.3                                                                   CH                                          __________________________________________________________________________

                                      TABLE 5e                                     __________________________________________________________________________     General Structure 2 wherein Q is Q-31.                                                                                m.p.                                    R  R.sub.3                                                                           R.sub.4                                                                           R.sub.5                                                                           R.sub.6                                                                           R.sub.7                                                                           R.sub.8                                                                           R.sub.9                                                                           R.sub.10                                                                          X   Y     Z °C.                              __________________________________________________________________________     H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                        H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N                                         H  H  H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                        H  H  H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N                                         H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                        H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             N                                         H  H  H  H  H  H  H  H  H  Cl  OCH.sub.3                                                                            CH                                        H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           C.sub.2 H.sub.5                                                                      CH                                        H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           CF.sub.3                                                                             CH                                        H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           OCF.sub.2 H                                                                          CH                                        H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.2 CF.sub.3                                                                   CH                                        H  CH.sub.3                                                                          H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                        H  H  H  CH.sub.3                                                                          H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             N                                         H  H  H  H  H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                        H  H  H  H  H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            N                                         H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                        H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N                                         H  H  H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                        H  H  H  H  H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                             N                                         H  H  H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                        H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N                                         H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                        H  H  H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                            N                                         H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                        H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                             N                                         H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                        H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N                                         H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                        H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            N                                         H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                        H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             N                                         H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub. 3                                                                         CH.sub.3                                                                          H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                        H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            N                                         H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                        H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                            N                                         H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                        H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             N                                         H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            CH                                        H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            N                                         H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                        CH.sub.3                                                                          H  H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N                                         H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                                                               *                                       H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N *                                       H  H  H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                                                               *                                       H  H  H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N *                                       H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                                                               *                                       H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             N *                                       H  H  H  H  H  H  H  H  H  Cl  OCH.sub.3                                                                            CH                                                                               *                                       __________________________________________________________________________      ***Wherein W" is O, unless indicated by **** where W" is S in all Tables.

                                      TABLE 5f                                     __________________________________________________________________________     General Structure 2 wherein Q is Q-32.                                         R  R.sub.3                                                                           R.sub.4                                                                           R.sub.5                                                                           R.sub.6                                                                           R.sub.7                                                                           R.sub.8                                                                           R.sub.9                                                                           R.sub.10                                                                          X   Y      Z W"                                     __________________________________________________________________________     H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              CH                                                                               O                                      H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              N O                                      H  H  H  H  H  H  H  H  H  Cl  OCH.sub.3                                                                             CH                                                                               O                                      H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           NHCH.sub.3                                                                            CH                                                                               O                                      H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           N(CH.sub.3).sub.2                                                                     CH                                                                               O                                      H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           CH(OCH.sub.3).sub.2                                                                   CH                                                                               O                                      H  H  H  H  H  H  H  H  H  Br  OCH.sub.3                                                                             CH                                                                               O                                      H  CH.sub.3                                                                          H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              CH                                                                               O                                      H  H  H  CH.sub.3                                                                          H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              N O                                      H  H  H  H  H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             CH                                                                               O                                      H  H  H  H  H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                             N O                                      H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH                                                                               O                                      H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             N O                                      H  H  H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                              CH                                                                               O                                      H  H  H  H  H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                              N O                                      H  H  H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                             CH                                                                               O                                      H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N O                                      H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH                                                                               O                                      H  H  H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                             N O                                      H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              CH                                                                               O                                      H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                              N O                                      H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                             CH                                                                               O                                      H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N O                                      H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH                                                                               O                                      H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                             N O                                      H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                              CH                                                                               O                                      H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                              N O                                      H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           OCH.sub.3                                                                             CH                                                                               O                                      H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                             N O                                      H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH                                                                               O                                      H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                             N O                                      H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                              CH                                                                               O                                      H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                              N O                                      H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                             CH                                                                               O                                      H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                             N O                                      H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH                                                                               O                                      CH.sub.3                                                                          H  H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             N O                                      H  CH.sub.3                                                                          H  H  H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                             CH                                                                               O                                      H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             CH                                                                               O                                      H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub. 3                                                                            N O                                      H  H  H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH                                                                               O                                      H  H  H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             N O                                      H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             CH                                                                               S                                      H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N S                                      H  H  H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH                                                                               S                                      H  H  H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             N S                                      H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              CH                                                                               S                                      H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              N S                                      H  H  H  H  H  H  H  H  H  Cl  OCH.sub.3                                                                             CH                                                                               S                                                                     O                                               H  H  H  H  H  H  H  H  H  CH.sub.3   CH                                                                               S                                                                     O                                               H  H  H  H  H  H  H  H  H  Cl  OC.sub.2 H.sub.5                                                                      CH                                                                               S                                      H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           C.sub.2 H.sub.5                                                                       N S                                      H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           OC.sub.2 H.sub.5                                                                      N S                                      H  CH.sub.3                                                                          H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              CH                                                                               S                                      H  H  H  CH.sub.3                                                                          H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              N S                                      H  H  H  H  H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             CH                                                                               S                                      H  H  H  H  H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                             N S                                      H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH                                                                               S                                      H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             N S                                      H  H  H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                              CH                                                                               S                                      H  H  H  H  H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                              N S                                      H  H  H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                             CH                                                                               S                                      H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N S                                      H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH                                                                               S                                      H  H  H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                             N S                                      H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              CH                                                                               S                                      H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                              N S                                      H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                             CH                                                                               S                                      H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N S                                      H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH                                                                               S                                      H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                             N S                                      H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                              CH                                                                               S                                      H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                              N S                                      H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub. 3                                                                         CH.sub.3                                                                          H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N S                                      H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                             N S                                      H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH                                                                               S                                      H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                             N S                                      H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                              CH                                                                               S                                      H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                              N S                                      H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                             CH                                                                               S                                      H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                             N S                                      H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH                                                                               S                                      CH.sub.3                                                                          H  H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             N S                                      H  CH.sub.3                                                                          H  H  H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                             CH                                                                               S                                      __________________________________________________________________________

                                      TABLE 5g                                     __________________________________________________________________________     General Structure 2                                                                                                 m.p.                                      Q  R  R.sub.3                                                                           R.sub.4                                                                           R.sub.5                                                                           R.sub.6                                                                           R.sub.7                                                                           X   Y      Z  W °C.                                __________________________________________________________________________     Q-41                                                                              H  H  H  H  H  H  Cl  OCH.sub.3                                                                             CH                                             Q-41                                                                              H  H  H  H  H  H  Br  OCH.sub.3                                                                             CH                                             Q-41                                                                              H  H  H  H  H  H  Cl  OC.sub.2 H.sub.5                                                                      CH                                             Q-41                                                                              H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              N                                              Q-41                                                                              H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH                                             Q-41                                                                              H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             N                                              Q-41                                                                              H  H  H  H  H  H  OCH.sub.3                                                                          OC.sub.2 H.sub.5                                                                      CH                                             Q-41                                                                              H  H  H  H  H  H  OCH.sub.3                                                                          OC.sub.2 H.sub.5                                                                      N                                              Q-41                                                                              H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              CH                                             Q-41                                                                              H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N                                              Q-41                                                                              H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             CH                                             Q-41                                                                              H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.2 OCH.sub.3                                                                    CH                                             Q-41                                                                              H  H  H  H  H  H  CH.sub.3                                                                           CF.sub.3                                                                              N                                              Q-41                                                                              H  H  H  H  H  H  CH.sub.3                                                                           OCF.sub.2 H                                                                           N                                              Q-41                                                                              H  CH.sub.3                                                                          H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              CH                                             Q-41                                                                              H  H  H  CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                              N                                              Q-41                                                                              H  H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                             CH                                             Q-41                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N                                              Q-41                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH                                             Q-41                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             N                                              Q-41                                                                              H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                              CH                                             Q-41                                                                              H  CH.sub.3                                                                          H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                              N                                              Q-41                                                                              H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                             CH                                             Q-41                                                                              H  H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                             N                                              Q-41                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH                                             Q-41                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                             N                                              Q-41                                                                              H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                              CH                                             Q-41                                                                              H  CH.sub.3                                                                          H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                              N                                              Q-41                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                             CH                                             Q-41                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                             N                                              Q-41                                                                              H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                             CH --                                          Q-41                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                             N  --                                          Q-41                                                                              CH.sub.3                                                                          H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              CH --                                          Q-41                                                                              CH.sub.3                                                                          H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             CH --                                          Q-42                                                                              H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              CH --                                          Q-42                                                                              H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              N  O                                           Q-42                                                                              H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.2 CF.sub.3                                                                    N  O                                           Q-42                                                                              H  H  H  H  H  H  CH.sub.3                                                                           NHCH.sub.3                                                                            N  O                                           Q-42                                                                              H  H  H  H  H  H  CH.sub.3                                                                           N(CH.sub.3).sub.2                                                                     N  O                                           Q-42                                                                              H  H  H  H  H  H  CH.sub.3                                                                           CH(OCH.sub.3).sub.2                                                                   N  O                                           Q-42                                                                              CH.sub.3                                                                          H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                           Q-42                                                                              CH.sub.3                                                                          H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                           Q-42                                                                              H  CH.sub.3                                                                          H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              CH O                                           Q-42                                                                              H  H  H  CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                              N  O                                           Q-42                                                                              H  H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                           Q-42                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                           Q-42                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                           Q-42                                                                              H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                           Q-42                                                                              H  CH.sub.3                                                                          H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                              CH O                                           Q-42                                                                              H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                              N  O                                           Q-42                                                                              H  H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                           Q-42                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                           Q-42                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                           Q-42                                                                              H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                           Q-42                                                                              H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                              CH O                                           Q-42                                                                              H  CH.sub.3                                                                          H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                              N  O                                           Q-42                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                           Q-42                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                           Q-42                                                                              H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                           Q-42                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                           Q-42                                                                              H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             CH O                                           Q-42                                                                              H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N  O                                           Q-42                                                                              H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH O                                           Q-42                                                                              H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             N  O                                           Q-42                                                                              H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                           Q-42                                                                              H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                           Q-42                                                                              H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                           Q-42                                                                              H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                           Q-42                                                                              H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              CH S                                           Q-42                                                                              H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              N  S                                           Q-42                                                                              H  H  H  H  H  H  CH.sub.3                                                                            ##STR144##                                                                           N  S                                           Q-42                                                                              H  H  H  H  H  H  Br  OC.sub.2 H.sub.5                                                                      CH S                                           Q-42                                                                              H  H  H  H  H  H  OCH.sub.3                                                                          CH.sub.2 OCH.sub.3                                                                    N  S                                           Q-42                                                                              CH.sub.3                                                                          H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                           Q-42                                                                              CH.sub.3                                                                          H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                           Q-42                                                                              H  CH.sub.3                                                                          H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              CH S                                           Q-42                                                                              H  H  H  CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                              N  S                                           Q-42                                                                              H  H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                           Q-42                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                           Q-42                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                           Q-42                                                                              H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                           Q-42                                                                              H  CH.sub.3                                                                          H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                              CH S                                           Q-42                                                                              H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                              N  S                                           Q-42                                                                              H  H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                           Q-42                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                           Q-42                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                           Q-42                                                                              H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                           Q-42                                                                              H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                              CH S                                           Q-42                                                                              H  CH.sub.3                                                                          H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                              N  S                                           Q-42                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                             CH S                                           Q-42                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                             N  S                                           Q-42                                                                              H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                             CH S                                           Q-42                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                             N  S                                           __________________________________________________________________________

                                      TABLE 6a                                     __________________________________________________________________________     General Structure 2 wherein Q is Q-20.                                         R  R'.sub.3      X    Y       Z  W'                                                                               m.p. °C.                             __________________________________________________________________________     H  H             CH.sub.3                                                                            OCH.sub.3                                                                              CH O                                             H  H             CH.sub.3                                                                            OCH.sub.3                                                                              N  O 150-153                                     H  H             OCH.sub.3                                                                           OCH.sub.3                                                                              CH O 186-188                                     H  H             OCH.sub.3                                                                           Cl      CH O                                             H  H             OCH.sub.3                                                                           OCH.sub.3                                                                              N  O                                             H  H             CH.sub.3                                                                            CH.sub.3                                                                               CH O                                             H  CH.sub.3      CH.sub.3                                                                            OCH.sub.3                                                                              CH O                                             CH.sub.3                                                                          H             CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             CH.sub.3                                                                          CH.sub.3      OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H  H             CH.sub.3                                                                            OC.sub.2 H.sub.5                                                                       N  O                                             H  H             CH.sub.3                                                                            CH.sub.3                                                                               CH S                                             H  H             CH.sub.3                                                                            CH.sub.3                                                                               N  S                                             H  H             CH.sub.3                                                                            OCH.sub.3                                                                              CH S                                             H  H             CH.sub.3                                                                            OCH.sub.3                                                                              N  S                                             H  H             OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  H             OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             CH.sub.3                                                                          H             CH.sub.3                                                                            OCH.sub.3                                                                              CH S                                             H  CH.sub.3      CH.sub.3                                                                            OCH.sub.3                                                                              N  S                                             H  CH.sub.3      CH.sub.3                                                                            CH.sub.2 OCH.sub.3                                                                     N  S                                             H  C.sub.2 H.sub.5                                                                              CH.sub.3                                                                            CH.sub.3                                                                               CH O                                             H  C.sub.2 H.sub.5                                                                              CH.sub.3                                                                            CH.sub.3                                                                               N  O                                             H  C.sub.2 H.sub.5                                                                              CH.sub.3                                                                            OCH.sub.3                                                                              CH O                                             H  C.sub.2 H.sub.5                                                                              CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  C.sub.2 H.sub.5                                                                              OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H  C.sub.2 H.sub.5                                                                              OCH.sub.3                                                                           OCH.sub.3                                                                              N  O                                             H  C.sub.2 H.sub.5                                                                              OCH.sub.3                                                                           Cl      CH O                                             H  C.sub.2 H.sub.5                                                                              CH.sub.3                                                                            CH.sub.3                                                                               CH S                                             H  C.sub.2 H.sub.5                                                                              CH.sub.3                                                                            CH.sub.3                                                                               N  S                                             H  C.sub.2 H.sub.5                                                                              CH.sub.3                                                                            OCH.sub.3                                                                              CH S                                             H  C.sub.2 H.sub.5                                                                              CH.sub.3                                                                            OCH.sub.3                                                                              N  S                                             H  C.sub.2 H.sub.5                                                                              OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  C.sub.2 H.sub.5                                                                              OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             H  C.sub.2 H.sub.5                                                                              OCH.sub.3                                                                           Cl      CH S                                             H  C.sub.2 H.sub.5                                                                              OCH.sub.3                                                                           N(CH.sub.3).sub.2                                                                      N  S                                             CH.sub.3                                                                           -n-C.sub.3 H.sub.7                                                                          OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             CH.sub.3                                                                           -n-C.sub.3 H.sub.7                                                                          CH.sub.3                                                                            CH.sub. 3                                                                              CH O                                             CH.sub.3                                                                           -n-C.sub.3 H.sub.7                                                                          CH.sub.3                                                                            OCH.sub.3                                                                              CH O                                             CH.sub.3                                                                           -n-C.sub.3 H.sub.7                                                                          OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             CH.sub.3                                                                           -n-C.sub.3 H.sub.7                                                                          OCH.sub.3                                                                           OCH.sub.3                                                                              N  O                                             CH.sub.3                                                                           -n-C.sub.3 H.sub.7                                                                          OCH.sub.3                                                                           Cl      CH O                                             CH.sub.3                                                                           -n-C.sub.3 H.sub.7                                                                          CH.sub.3                                                                            OCH.sub.2 CF.sub.3                                                                     CH O                                             H   -n-C.sub.3 H.sub.7                                                                          CH.sub.3                                                                            CH.sub.3                                                                               CH S                                             H   -n-C.sub.3 H.sub.7                                                                          CH.sub.3                                                                            OCH.sub.3                                                                              CH S                                             H   -n-C.sub.3 H.sub.7                                                                          CH.sub.3                                                                            OCH.sub.3                                                                              N  S                                             H   -n-C.sub.3 H.sub.7                                                                          OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H   -n-C.sub.3 H.sub.7                                                                          OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             H   -n-C.sub.3 H.sub.7                                                                          OCH.sub.3                                                                           Cl      CH S                                             H   -n-C.sub.3 H.sub.7                                                                          CH.sub.3                                                                            CH(OCH.sub.3).sub.2                                                                    CH S                                             H   .sub.-i-C.sub.3 H.sub. 7                                                                    CH.sub.3                                                                            CH.sub.3                                                                               CH O                                             H   .sub.-i-C.sub.3 H.sub.7                                                                     CH.sub.3                                                                            OCH.sub.3                                                                              CH O                                             H   .sub.-i-C.sub.3 H.sub.7                                                                     CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H   .sub.-i-C.sub.3 H.sub.7                                                                     OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H   .sub.-i-C.sub.3 H.sub.7                                                                     OCH.sub.3                                                                           OCH.sub.3                                                                              N  O                                             H   .sub.-i-C.sub.3 H.sub.7                                                                     OCH.sub.3                                                                           Cl      CH O                                             H   .sub.-i-C.sub.3 H.sub.7                                                                     CH.sub.3                                                                            CH.sub.3                                                                               N  O                                             H   .sub.-i-C.sub.3 H.sub.7                                                                     OCH.sub.3                                                                            ##STR145##                                                                            CH O                                             CH.sub.3                                                                           .sub.-i-C.sub.3 H.sub.7                                                                     OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H   .sub.-i-C.sub.3 H.sub.7                                                                     CH.sub.3                                                                            CH.sub.3                                                                               CH S                                             H   .sub.-i-C.sub.3 H.sub.7                                                                     CH.sub.3                                                                            OCH.sub.3                                                                              CH S                                             H   .sub.- i-C.sub.3 H.sub.7                                                                    CH.sub.3                                                                            OCH.sub.3                                                                              N  S                                             H   .sub.-i-C.sub.3 H.sub.7                                                                     OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H   .sub.-i-C.sub.3 H.sub.7                                                                     OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             H   .sub.-i-C.sub.3 H.sub.7                                                                     OCH.sub.3                                                                           Cl      CH S                                             H   .sub.-i-C.sub.3 H.sub.7                                                                     CH.sub.3                                                                            OC.sub.2 H.sub.5                                                                       N  S                                             H  SCH.sub.3     CH.sub.3                                                                            CH.sub.3                                                                               CH O 175-177                                     H  SCH.sub.3     CH.sub.3                                                                            OCH.sub.3                                                                              CH O 148-149                                     H  SCH.sub.3     CH.sub.3                                                                            OCH.sub.3                                                                              N  O 167-170                                     H  SCH.sub.3     OCH.sub.3                                                                           OCH.sub.3                                                                              CH O 178-180                                     H  SCH.sub.3     OCH.sub.3                                                                           OCH.sub.3                                                                              N  O 146-151                                     H  SCH.sub.3     OCH.sub.3                                                                           Cl      CH O 163-169                                     H  SCH.sub.3     OCH.sub.3                                                                           NHCH.sub.3                                                                             CH O                                             CH.sub.3                                                                          SCH.sub.3     OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  SCH.sub.3     CH.sub.3                                                                            CH.sub.3                                                                               CH S                                             H  SCH.sub.3     CH.sub.3                                                                            CH.sub.3                                                                               N  S                                             H  SCH.sub.3     CH.sub.3                                                                            OCH.sub.3                                                                              CH S                                             H  SCH.sub.3     CH.sub.3                                                                            OCH.sub.3                                                                              N  S                                             H  SCH.sub.3     OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  SCH.sub.3     OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             H  SCH.sub.3     OCH.sub.3                                                                           Cl      CH S                                             CH.sub.3                                                                          SC.sub.2 H.sub.5                                                                             OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H  SC.sub.2 H.sub.5                                                                             CH.sub.3                                                                            CH.sub.3                                                                               CH O 168-177                                     H  SC.sub.2 H.sub.5                                                                             CH.sub.3                                                                            CH.sub.3                                                                               N  O                                             H  SC.sub.2 H.sub.5                                                                             CH.sub.3                                                                            OCH.sub.3                                                                              CH O                                             H  SC.sub.2 H.sub.5                                                                             CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  SC.sub.2 H.sub.5                                                                             OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H  SC.sub.2 H.sub.5                                                                             OCH.sub.3                                                                           OCH.sub.3                                                                              N  O                                             H  SC.sub.2 H.sub.5                                                                             OCH.sub.3                                                                           Cl      CH O                                             H  SC.sub.2 H.sub.5                                                                             CH.sub.3                                                                            CH.sub.3                                                                               CH S                                             H  SC.sub.2 H.sub.5                                                                             CH.sub.3                                                                            OCH.sub.3                                                                              CH S                                             H  SC.sub.2 H.sub.5                                                                             CH.sub.3                                                                            OCH.sub.3                                                                              N  S                                             H  SC.sub.2 H.sub.5                                                                             OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  SC.sub.2 H.sub.5                                                                             CH.sub.3                                                                            OCH.sub.3                                                                              N  S                                             H  SC.sub.2 H.sub.5                                                                             OCH.sub.3                                                                           Cl      CH S                                             H  SC.sub.2 H.sub.5                                                                             CH.sub.3                                                                            OC.sub.2 H.sub.5                                                                       N  S                                             H  S - n-C.sub.3 H.sub.7                                                                        CH.sub.3                                                                            CH.sub.3                                                                               CH O                                             H  S -n-C.sub.3 H.sub.7                                                                         CH.sub.3                                                                            CH.sub.2 OCH.sub.3                                                                     CH O                                             H  S -n-C.sub.3 H.sub.7                                                                         CH.sub.3                                                                            OCH.sub.3                                                                              CH O                                             H  S -n-C.sub.3 H.sub.7                                                                         CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  S -n-C.sub.3 H.sub.7                                                                         OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H  S -n-C.sub.3 H.sub.7                                                                         OCH.sub.3                                                                           OCH.sub.3                                                                              N  O                                             H  S -n-C.sub.3 H.sub.7                                                                         OCH.sub.3                                                                           Cl      CH O                                             CH.sub.3                                                                          S -n-C.sub.3 H.sub.7                                                                         OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  S -n-C.sub.3 H.sub.7                                                                         CH.sub.3                                                                            CH.sub.3                                                                               CH S                                             H  S -n-C.sub.3 H.sub.7                                                                         CH.sub.3                                                                            CH.sub.3                                                                               N  S                                             H  S -n-C.sub.3 H.sub.7                                                                         CH.sub.3                                                                            OCH.sub.3                                                                              CH S                                             H  S -n-C.sub.3 H.sub.7                                                                         OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  S -n-C.sub.3 H.sub.7                                                                         OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             H  S -n-C.sub.3 H.sub.7                                                                         CH.sub.3                                                                            Cl      CH S                                             H  S -n-C.sub.3 H.sub.7                                                                         CH.sub.3                                                                            OCH.sub.3                                                                              CH O                                             H  S -n-C.sub.3 H.sub.7                                                                         OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  S -n-C.sub.3 H.sub.7                                                                         CH.sub.3                                                                            OCH.sub.3                                                                              N  S                                             CH.sub.3                                                                          S -n-C.sub.4 H.sub.9                                                                         OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H  S -n-C.sub.4 H.sub.9                                                                         CH.sub.3                                                                            CH.sub.3                                                                               CH O                                             H  S -n-C.sub.4 H.sub.9                                                                         CH.sub.3                                                                            CH.sub.3                                                                               N  O                                             H  S -n-C.sub.4 H.sub.9                                                                         CH.sub.3                                                                            OCH.sub.3                                                                              CH O                                             H  S -n-C.sub.4 H.sub.9                                                                         CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  S -n-C.sub.4 H.sub.9                                                                         OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H  S -n-C.sub.4 H.sub.9                                                                         OCH.sub.3                                                                           OCH.sub.3                                                                              N  O                                             H  S -n-C.sub.4 H.sub.9                                                                         OCH.sub.3                                                                           Cl      CH O                                             H  S - n-C.sub.4 H.sub.9                                                                        CH.sub.3                                                                            CH.sub.3                                                                               CH S                                             H  S -n-C.sub.4 H.sub.9                                                                         CH.sub.3                                                                            OCH.sub.3                                                                              N  S                                             H  S -n-C.sub.4 H.sub.9                                                                         CH.sub.3                                                                            OCH.sub.3                                                                              CH S                                             H  S -n-C.sub.4 H.sub.9                                                                         OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             H  S -n-C.sub.4 H.sub.9                                                                         OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  S -n-C.sub.4 H.sub.9                                                                         OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             H  S -n-C.sub.4 H.sub.9                                                                         OCH.sub.3                                                                           OCF.sub.2 H                                                                            N  S                                             H  S -n-C.sub.4 H.sub.9                                                                         OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H  S -n-C.sub.4 H.sub.9                                                                         CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  S -n-C.sub.4 H.sub.9                                                                         OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  S -n-C.sub.4 H.sub.9                                                                         CH.sub.3                                                                            OCH.sub.3                                                                              CH S                                             H  S -n-C.sub.4 H.sub.9                                                                         CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  S -n-C.sub.4 H.sub.9                                                                         CH.sub.3                                                                            OCH.sub.3                                                                              CH O                                             H  S -n-C.sub.4 H.sub.9                                                                         OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  S -n-C.sub.4 H.sub.9                                                                         OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             H  S -n-C.sub.4 H.sub.9                                                                         CH.sub.3                                                                            OCH.sub.3                                                                              CH O                                             H  S -n-C.sub.4 H.sub.9                                                                         OCH.sub.3                                                                           OCH.sub.3                                                                              N  O                                             H  S -n-C.sub.4 H.sub.9                                                                         OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  S -n-C.sub.4 H.sub.9                                                                         CH.sub.3                                                                            OCH.sub.3                                                                              N  S                                             H  SCH.sub.2 CHCH.sub.2                                                                         CH.sub.3                                                                            CH.sub.3                                                                               CH O 169-170                                     H  SCH.sub.2 CHCH.sub.2                                                                         CH.sub.3                                                                            OCH.sub.3                                                                              N  O 148-151                                     H  SCH.sub.2 CHCH.sub.2                                                                         CH.sub.3                                                                            OCH.sub.3                                                                              CH O 134-138                                     H  SCH.sub.2 CHCH.sub.2                                                                         OCH.sub.3                                                                           OCH.sub.3                                                                              N  O 149-152                                     H  SCH.sub.2 CHCH.sub.2                                                                         OCH.sub.3                                                                           OCH.sub.3                                                                              CH O 165-168                                     H  SCH.sub.2 CHCH.sub.2                                                                         OCH.sub.3                                                                           OCH.sub.3                                                                              N  O                                             H  SCH.sub.2 CHCH.sub.2                                                                         OCH.sub.3                                                                           Cl      CH O 144-146                                     H  SCH.sub.2 CHCH.sub. 2                                                                        CH.sub.3                                                                            OCH.sub.2 CF.sub.3                                                                     CH O                                             CH.sub.3                                                                          SCH.sub.2 CHCH.sub.2                                                                         OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  SCH.sub.2 CHCH.sub.2                                                                         CH.sub.3                                                                            CH.sub.3                                                                               CH S                                             H  SCH.sub.2 CHCH.sub.2                                                                         CH.sub.3                                                                            CH.sub.3                                                                               N  S                                             H  SCH.sub.2 CHCH.sub.2                                                                         CH.sub.3                                                                            OCH.sub.3                                                                              CH S                                             H  SCH.sub.2 CHCH.sub.2                                                                         CH.sub.3                                                                            OCH.sub.3                                                                              N  S                                             H  SCH.sub.2 CHCH.sub.2                                                                         OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  SCH.sub.2 CHCH.sub.2                                                                         OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             H  SCH.sub.2 CHCH.sub.2                                                                         OCH.sub.3                                                                           Cl      CH S                                             H   .sub.--ESCHCHCH.sub.3                                                                       CH.sub.3                                                                            OCH.sub.3                                                                              CH O                                             H   .sub.--ESCHCHCH.sub.3                                                                       CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H   .sub.--ESCHCHCH.sub.3                                                                       OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H   .sub.--ESCHCHCH.sub.3                                                                       OCH.sub.3                                                                           OCH.sub.3                                                                              N  O                                             H   .sub.--ESCHCHCH.sub.3                                                                       CH.sub.3                                                                            OCH.sub.3                                                                              N  S                                             H   .sub.--ESCHCHCH.sub.3                                                                       CH.sub.3                                                                            OCH.sub.3                                                                              CH S                                             H   .sub.--ESCHCHCH.sub.3                                                                       OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H   .sub.--ESCHCHCH.sub.3                                                                       OCH.sub.3                                                                           Cl      CH S                                             H   .sub.--ZSCHCHCH.sub.3                                                                       CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H   .sub.--ZSCHCHCH.sub.3                                                                       OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H   .sub.--ZSCHCHCH.sub.3                                                                       OCH.sub.3                                                                           OCH.sub.3                                                                              N  O                                             H   .sub.--ZSCHCHCH.sub.3                                                                       OCH.sub.3                                                                           Cl      CH O                                             H   .sub.--ZSCHCHCH.sub.3                                                                       CH.sub.3                                                                            CH.sub.3                                                                               CH S                                             H   .sub.--ZSCHCHCH.sub.3                                                                       OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H   .sub.--ZSCHCHCH.sub.3                                                                       CH.sub.3                                                                            OCH.sub.3                                                                              N  S                                             H   .sub.--ZSCHCHCH.sub.3                                                                       OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             H  S(CH.sub.2).sub.2 CHCH.sub.2                                                                 OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H  S(CH.sub.2).sub.2 CHCH.sub.2                                                                 OCH.sub.3                                                                           OCH.sub.3                                                                              N  O                                             H  S(CH.sub.2).sub.2 CHCH.sub.2                                                                 CH.sub.3                                                                            OCH.sub.3                                                                              CH O                                             H  S(CH.sub.2).sub.2 CHCH.sub.2                                                                 OCH.sub.3                                                                           Cl      CH O                                             H  S(CH.sub.2).sub.2 CHCH.sub.2                                                                 OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  S(CH.sub.2).sub.2 CHCH.sub.2                                                                 CH.sub.3                                                                            OCH.sub.3                                                                              N  S                                             H  S(CH.sub.2).sub.2 CHCH.sub.2                                                                 OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             H  S(CH.sub.2).sub.2 CHCH.sub.2                                                                 CH.sub.3                                                                            CH.sub.3                                                                               CH S                                             H   .sub.--ESCH.sub.2 CHCHCH.sub.3                                                              OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H   .sub.--ESCH.sub.2 CHCHCH.sub.3                                                              OCH.sub.3                                                                           OCH.sub.3                                                                              N  O                                             H   .sub.--ESCH.sub.2 CHCHCH.sub.3                                                              CH.sub.3                                                                            OCH.sub.3                                                                              CH O                                             H   .sub.--ESCH.sub.2 CHCHCH.sub.3                                                              OCH.sub.3                                                                           Cl      CH O                                             H   .sub.--ESCH.sub.2 CHCHCH.sub.3                                                              OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H   .sub.--ESCH.sub.2 CHCHCH.sub.3                                                              CH.sub.3                                                                            OCH.sub.3                                                                              N  S                                             H   .sub.--ESCH.sub.2 CHCHCH.sub.3                                                              CH.sub.3                                                                            OCH.sub.3                                                                              CH S                                             H   .sub.-- ESCH.sub.2 CHCHCH.sub.3                                                             CH.sub.3                                                                            CH.sub.3                                                                               CH S                                             H   .sub.--ZSCH.sub.2 CHCHCH.sub.3                                                              CH.sub.3                                                                            OCH.sub.3                                                                              CH O                                             H   .sub.--ZSCH.sub.2 CHCHCH.sub.3                                                              CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H   .sub.--ZSCH.sub.2 CHCHCH.sub.3                                                              OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H   .sub.--ZSCH.sub.2 CHCHCH.sub.3                                                              OCH.sub.3                                                                           Cl      CH O                                             H   .sub.--ZSCH.sub.2 CHCHCH.sub.3                                                              CH.sub.3                                                                            OCH.sub.3                                                                              CH S                                             H   .sub.--ZSCH.sub.2 CHCHCH.sub.3                                                              CH.sub.3                                                                            OCH.sub.3                                                                              N  S                                             H   .sub.--ZSCH.sub.2 CHCHCH.sub.3                                                              OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H   .sub.--ZSCH.sub.2 CHCHCH.sub.3                                                              OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             H   .sub.--ESCHCHC.sub.2 H.sub.5                                                                OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H   .sub.--ESCHCHC.sub.2 H.sub.5                                                                OCH.sub.3                                                                           OCH.sub.3                                                                              N  O                                             H   .sub.--ESCH CHC.sub.2 H.sub.5                                                               CH.sub.3                                                                            OCH.sub.3                                                                              CH O                                             H   .sub.--ESCHCHC.sub.2 H.sub.5                                                                OCH.sub.3                                                                           Cl      CH O                                             H   .sub.--ESCHCHC.sub.2 H.sub.5                                                                OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H   .sub.--ESCHCHC.sub.2 H.sub.5                                                                CH.sub.3                                                                            CH.sub.3                                                                               CH S                                             H   .sub.--ESCHCHC.sub.2 H.sub.5                                                                CH.sub.3                                                                            OCH.sub.3                                                                              N  S                                             H   .sub.--ESCHCHC.sub.2 H.sub.5                                                                CH.sub.3                                                                            OCH.sub.3                                                                              CH S                                             H   .sub.--ZSCHCHC.sub.2 H.sub.5                                                                OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H   .sub.--ZSCHCHC.sub.2 H.sub.5                                                                OCH.sub.3                                                                           OCH.sub.3                                                                              N  O                                             H   .sub.--ZSCHCHC.sub.2 H.sub.5                                                                CH.sub.3                                                                            CH.sub.3                                                                               CH O                                             H   .sub.--ZSCHCHC.sub.2 H.sub.5                                                                CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H   .sub.--ZSCHCHC.sub.2 H.sub.5                                                                OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H   .sub.--ZSCHCHC.sub.2 H.sub. 5                                                               CH.sub.3                                                                            OCH.sub.3                                                                              CH S                                             H   .sub.--ZSCHCHC.sub.2 H.sub.5                                                                CH.sub.3                                                                            OCH.sub.3                                                                              N  S                                             H   .sub.--ZSCHCHC.sub.2 H.sub.5                                                                OCH.sub.3                                                                           Cl      CH S                                             H  SCH.sub.2 CCH CH.sub.3                                                                            OCH.sub.3                                                                              CH O                                             H  SCH.sub.2 CCH CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  SCH.sub.2 CCH OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H  SCH.sub.2 CCH OCH.sub.3                                                                           OCH.sub.3                                                                              N  O                                             H  SCH.sub.2 CCH CH.sub.3                                                                            OCH.sub.3                                                                              CH S                                             H  SCH.sub.2 CCH OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             H  SCH.sub.2 CCH OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  SCH.sub.2 CCH OCH.sub.3                                                                           Cl      CH S                                             CH.sub.3                                                                          SCH.sub.2 CCH OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  SCCCH.sub.3   CH.sub.3                                                                            CH.sub.3                                                                               CH O                                             H  SCCCH.sub.3   CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  SCCCH.sub.3   CH.sub.3                                                                            OCH.sub.3                                                                              CH O                                             H  SCCCH.sub.3   OCH.sub.3                                                                           OCH.sub.3                                                                              N  O                                             H  SCCCH.sub.3   OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  SCCCH.sub.3   CH.sub.3                                                                            OCH.sub.3                                                                              N  S                                             H  SCCCH.sub.3   CH.sub.3                                                                            OCH.sub.3                                                                              CH S                                             H  SCCCH.sub.3   OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             H  S(CH.sub.2).sub.2 CCH                                                                        CH.sub.3                                                                            OCH.sub.3                                                                              CH O                                             H  S(CH.sub.2).sub.2 CCH                                                                        CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  S(CH.sub.2).sub.2 CCH                                                                        OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H  S(CH.sub.2).sub.2 CCH                                                                        OCH.sub.3                                                                           OCH.sub.3                                                                              N  O                                             H  S(CH.sub.2).sub.2 CCH                                                                        CH.sub.3                                                                            OCH.sub.3                                                                              CH S                                             H  S(CH.sub.2).sub.2 CCH                                                                        CH.sub.3                                                                            OCH.sub.3                                                                              N  S                                             H  S(CH.sub.2).sub.2 CCH                                                                        OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  S(CH.sub.2).sub.2 CCH                                                                        OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             H  SCH.sub.2 CCCH.sub.3                                                                         CH.sub.3                                                                            CH.sub.3                                                                               CH O                                             H  SCH.sub.2 CCCH.sub.3                                                                         CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  SCH.sub.2 C CCH.sub.3                                                                        CH.sub.3                                                                            OCH.sub.3                                                                              CH O                                             H  SCH.sub.2 CCCH.sub.3                                                                         OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H  SCH.sub.2 CCCH.sub.3                                                                         OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  SCH.sub.2 CCCH.sub.3                                                                         OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             H  SCH.sub.2 CCCH.sub.3                                                                         CH.sub.3                                                                            OCH.sub.3                                                                              CH S                                             H  SCH.sub.2 CCCH.sub.3                                                                         OCH.sub.3                                                                           Cl      CH S                                             H  SCCC.sub.2 H.sub.5                                                                           CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  SCCC.sub.2 H.sub.5                                                                           OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H  SCCC.sub.2 H.sub.5                                                                           OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  SCCC.sub.2 H.sub.5                                                                           CH.sub.3                                                                            CH.sub.3                                                                               CH S                                             CH.sub.3                                                                          SCCC.sub.2 H.sub.5                                                                           CH.sub.3                                                                            OCH.sub.3                                                                              CH O                                             H  CH.sub.2 CN   CH.sub.3                                                                            CH.sub.3                                                                               CH O                                             H  CH.sub.2 CN   CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  CH.sub.2 CN   CH.sub.3                                                                            OCH.sub.3                                                                              CH O                                             H  CH.sub.2 CN   OCH.sub.3                                                                           OCH.sub.3                                                                              N  O                                             H  CH.sub.2 CN   OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H  CH.sub.2 CN   OCH.sub.3                                                                           Cl      CH O                                             H  CH.sub.2 CN   CH.sub.3                                                                            NHCH.sub.3                                                                             N  O                                             CH.sub.3                                                                          CH.sub.2 CN   OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  CH.sub.2 CN   CH.sub.3                                                                            CH.sub.3                                                                               CH S                                             H  CH.sub.2 CN   CH.sub.3                                                                            CH.sub.3                                                                               N  S                                             H  CH.sub.2 CN   CH.sub.3                                                                            OCH.sub.3                                                                              CH S                                             H  CH.sub.2 CN   CH.sub.3                                                                            OCH.sub.3                                                                              N  S                                             H  CH.sub.2 CN   OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  CH.sub.2 CN   OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             H  CH.sub.2 CN   OCH.sub.3                                                                           Cl      CH S                                             CH.sub.3                                                                          CH.sub.2 CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                            OCH.sub.3                                                                              CH O                                             H  CH.sub.2 CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                            CH.sub.3                                                                               CH O                                             H  CH.sub. 2 CO.sub.2 CH.sub.3                                                                  CH.sub.3                                                                            OCH.sub.3                                                                              CH O                                             H  CH.sub.2 CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  CH.sub.2 CO.sub.2 CH.sub.3                                                                   OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H  CH.sub.2 CO.sub.2 CH.sub.3                                                                   OCH.sub.3                                                                           OCH.sub.3                                                                              N  O                                             H  CH.sub.2 CO.sub.2 CH.sub.3                                                                   OCH.sub.3                                                                           Cl      CH O                                             H  CH.sub.2 CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                            CH.sub.3                                                                               CH S                                             H  CH.sub.2 CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                            OCH.sub.3                                                                              N  S                                             H  CH.sub.2 CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                            OCH.sub.3                                                                              CH S                                             H  CH.sub.2 CO.sub.2 CH.sub.3                                                                   OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             H  CH.sub.2 CO.sub.2 CH.sub.3                                                                   OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  CH.sub.2 CO.sub.2 CH.sub.3                                                                   OCH.sub.3                                                                           Cl      CH S                                             H  CH.sub.2 CO.sub.2 CH.sub.3                                                                   CH.sub.3                                                                            N(CH.sub.3).sub.2                                                                      N  S                                             H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                                                            CH.sub.3                                                                            CH.sub.3                                                                               CH O                                             H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                                                            CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                                                            CH.sub.3                                                                            OCH.sub.3                                                                              CH O                                             H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                                                            OCH.sub.3                                                                           OCH.sub.3                                                                              N  O                                             H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                                                            OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                                                            OCH.sub.3                                                                           Cl      CH O                                             H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                                                            OC.sub.2 H.sub.5                                                                    Cl      CH O                                             CH.sub.3                                                                          CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                                                            OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                                                            CH.sub.3                                                                            CH.sub.3                                                                               CH S                                             H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                                                            CH.sub.3                                                                            CH.sub.3                                                                               N  S                                             H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                                                            CH.sub.3                                                                            OCH.sub.3                                                                              CH S                                             H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                                                            CH.sub.3                                                                            OCH.sub.3                                                                              N  S                                             H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                                                            OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                                                            OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                                                            OCH.sub.3                                                                           Cl      CH S                                             CH.sub.3                                                                          CH.sub.2 OCH.sub.3                                                                           OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H  CH.sub.2 OCH.sub.3                                                                           CH.sub.3                                                                            CH.sub.3                                                                               CH O                                             H  CH.sub.2 OCH.sub.3                                                                           CH.sub.3                                                                            CH.sub.3                                                                               N  O                                             H  CH.sub.2 OCH.sub.3                                                                           CH.sub.3                                                                            OCH.sub.3                                                                              CH O                                             H  CH.sub.2 OCH.sub.3                                                                           CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  CH.sub.2 OCH.sub.3                                                                           OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H  CH.sub.2 OCH.sub.3                                                                           OCH.sub.3                                                                           OCH.sub.3                                                                              N  O                                             H  CH.sub.2 OCH.sub.3                                                                           OCH.sub.3                                                                           Cl      CH O                                             H  CH.sub.2 OCH.sub.3                                                                           CH.sub.3                                                                            CH.sub.3                                                                               CH S                                             H  CH.sub.2 OCH.sub.3                                                                           CH.sub.3                                                                            OCH.sub.3                                                                              N  S                                             H  CH.sub.2 OCH.sub.3                                                                           CH.sub.3                                                                            OCH.sub.3                                                                              CH S                                             H  CH.sub.2 OCH.sub.3                                                                           OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             H  CH.sub.2 OCH.sub.3                                                                           OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  CH.sub.2 OCH.sub.3                                                                           OCH.sub.3                                                                           Cl      CH S                                             H  CH.sub.2 OCH.sub.3                                                                           CH.sub.3                                                                            CH(OCH.sub.3).sub.2                                                                    CH S                                             H  CH.sub.2 OC.sub.2 H.sub.5                                                                    CH.sub.3                                                                            CH.sub.3                                                                               CH S                                             H  CH.sub.2 OC.sub.2 H.sub.5                                                                    CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  CH.sub.2 OC.sub.2 H.sub.5                                                                    CH.sub.3                                                                            OCH.sub.3                                                                              CH O                                             H  CH.sub.2 OC.sub.2 H.sub.5                                                                    OCH.sub.3                                                                           OCH.sub.3                                                                              N  O                                             H  CH.sub.2 OC.sub.2 H.sub.5                                                                    OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H  CH.sub.2 OC.sub.2 H.sub.5                                                                    OCH.sub.3                                                                           Cl      CH O                                             H  CH.sub.2 OC.sub.2 H.sub.5                                                                    OCH.sub.3                                                                           Br      CH O                                             CH.sub.3                                                                          CH.sub.2 OC.sub.2 H.sub.5                                                                    CH.sub.3                                                                            OCH.sub.3                                                                              CH S                                             H  CH.sub.2 OC.sub.2 H.sub.5                                                                    CH.sub.3                                                                            CH.sub.3                                                                               CH S                                             H  CH.sub.2 OC.sub.2 H.sub.5                                                                    CH.sub.3                                                                            CH.sub.3                                                                               N  S                                             H  CH.sub.2 OC.sub.2 H.sub.5                                                                    CH.sub.3                                                                            OCH.sub.3                                                                              CH S                                             H  CH.sub.2 OC.sub.2 H.sub.5                                                                    CH.sub.3                                                                            OCH.sub.3                                                                              N  S                                             H  CH.sub.2 OC.sub.2 H.sub.5                                                                    OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  CH.sub.2 OC.sub.2 H.sub.5                                                                    OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             H  CH.sub.2 OC.sub.2 H.sub.5                                                                    OCH.sub.3                                                                           Cl      CH S                                             CH.sub.3                                                                          (CH.sub.2).sub.2 COCH.sub.3                                                                  OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H  (CH.sub.2).sub.2 COCH.sub.3                                                                  CH.sub.3                                                                            CH.sub.3                                                                               CH O                                             H  (CH.sub.2).sub.2 COCH.sub.3                                                                  CH.sub.3                                                                            CH.sub.3                                                                               N  O                                             H  (CH.sub.2).sub.2 COCH.sub.3                                                                  CH.sub.3                                                                            OCH.sub.3                                                                              CH O                                             H  (CH.sub.2).sub.2 COCH.sub.3                                                                  CH.sub. 3                                                                           OCH.sub.3                                                                              N  O                                             H  (CH.sub.2).sub.2 COCH.sub.3                                                                  OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H  (CH.sub.2).sub.2 COCH.sub.3                                                                  OCH.sub.3                                                                           OCH.sub.3                                                                              N  O                                             H  (CH.sub.2).sub.2 COCH.sub.3                                                                  OCH.sub.3                                                                           Cl      CH O                                             H  (CH.sub.2).sub.2 COCH.sub.3                                                                  CH.sub.3                                                                            CH.sub.3                                                                               CH S                                             H  (CH.sub.2).sub.2 COCH.sub.3                                                                  CH.sub.3                                                                            OCH.sub.3                                                                              N  S                                             H  (CH.sub.2).sub.2 COCH.sub.3                                                                  CH.sub.3                                                                            OCH.sub.3                                                                              CH S                                             H  (CH.sub.2).sub.2 COCH.sub.3                                                                  OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             H  (CH.sub.2).sub.2 COCH.sub.3                                                                  OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  (CH.sub.2).sub.2 COCH.sub.3                                                                  OCH.sub.3                                                                           Cl      CH S                                                                   O                                                        H  (CH.sub.2).sub.2 COCH.sub.3                                                                  CH.sub.3     CH S                                                                   O                                                        H  (CH.sub.2).sub.2 CN                                                                          CH.sub.3                                                                            OCH.sub.3                                                                              CH O                                             H  (CH.sub.2).sub.2 CN                                                                          CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  (CH.sub.2).sub.2 CN                                                                          OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H  (CH.sub.2).sub.2 CN                                                                          OCH.sub.3                                                                           OCH.sub.3                                                                              N  O                                             H  (CH.sub.2).sub.2 CN                                                                          CH.sub.3                                                                            CH.sub.3                                                                               CH S                                             H  (CH.sub.2).sub.2 CN                                                                          CH.sub.3                                                                            OCH.sub.3                                                                              N  S                                             H  (CH.sub.2).sub.2 CN                                                                          OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  (CH.sub.2).sub.2 CN                                                                          OCH.sub.3                                                                           Cl      CH S                                             H  CH(CH.sub.3)CN                                                                               OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H  CH(CH.sub.3)CN                                                                               OCH.sub.3                                                                           OCH.sub.3                                                                              N  O                                             H  CH(CH.sub.3)CN                                                                               CH.sub.3                                                                            OCH.sub.3                                                                              CH S                                             H  CH(CH.sub.3)CN                                                                               CH.sub.3                                                                            OCH.sub.3                                                                              N  S                                             H  (CH.sub.2).sub.3 CN                                                                          CH.sub.3                                                                            OCH.sub.3                                                                              CH O                                             H  (CH.sub.2).sub.3 CN                                                                          CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  (CH.sub.2).sub.3 CN                                                                          OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H  (CH.sub.2).sub.3 CN                                                                          OCH.sub.3                                                                           OCH.sub.3                                                                              N  O                                             H  (CH.sub.2).sub.3 CN                                                                          CH.sub.3                                                                            CH.sub.3                                                                               CH S                                             H  (CH.sub.2).sub.3 CN                                                                          CH.sub.3                                                                            OCH.sub.3                                                                              N  S                                             H  (CH.sub.2).sub.3 CN                                                                          OCH.sub.3                                                                           OCH.sub.3                                                                              CH.sub.3                                                                          S                                             H  (CH.sub.2).sub.3 CN                                                                          OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             H  CH.sub.2 CH(CH.sub.3)CN                                                                      CH.sub.3                                                                            OCH.sub.3                                                                              CH O                                             H  CH.sub.2 CH(CH.sub.3)CN                                                                      CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  CH.sub.2 CH(CH.sub.3)CN                                                                      OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  CH.sub.2 CH(CH.sub.3)CN                                                                      OCH.sub.3                                                                           Cl      CH S                                             H  CH.sub.2 CH(CH.sub.3)CN                                                                      CH.sub.3                                                                            CH.sub.3                                                                               CH O                                             H  CH.sub.2 CH(CH.sub.3)CN                                                                      CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  CH.sub.2 CH(CH.sub.3)CN                                                                      OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  CH.sub.2 CH(CH.sub.3)CN                                                                      OCH.sub.3                                                                           CH.sub.3                                                                               CH S                                             CH.sub.3                                                                          CH.sub.2 CH(CH.sub.3)CN                                                                      OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  CH(CN)C.sub.2 H.sub.5                                                                        CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  CH(CN)C.sub.2 H.sub.5                                                                        OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H  CH(CN)C.sub.2 H.sub.5                                                                        OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             H  CH(CN)C.sub.2 H.sub.5                                                                        OCH.sub.3                                                                           Cl      CH S                                             H  C(CH.sub.3).sub.2 CN                                                                         CH.sub.3                                                                            CH.sub.3                                                                               CH O                                             H  C(CH.sub.3).sub.2 CN                                                                         OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H  C(CH.sub.3).sub.2 CN                                                                         OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             H  C(CH.sub.3).sub.2 CN                                                                         OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  CH(CH.sub.3)CO.sub.2 CH.sub.3                                                                OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H  CH(CH.sub.3)CO.sub.2 CH.sub.3                                                                OCH.sub.3                                                                           OCH.sub.3                                                                              N  O                                             H  CH(CH.sub. 3)CO.sub.2 CH.sub.3                                                               CH.sub.3                                                                            OCH.sub.3                                                                              CH S                                             H  CH(CH.sub.3)CO.sub.2 CH.sub.3                                                                CH.sub.3                                                                            OCH.sub.3                                                                              N  S                                             H  (CH.sub.2).sub.3 CO.sub.2 CH.sub.3                                                           CH.sub.3                                                                            OCH.sub.3                                                                              CH O                                             H  (CH.sub.2).sub.3 CO.sub.2 CH.sub.3                                                           CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  (CH.sub.2).sub.3 CO.sub.2 CH.sub.3                                                           OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H  (CH.sub.2).sub.3 CO.sub.2 CH.sub.3                                                           OCH.sub.3                                                                           OCH.sub.3                                                                              N  O                                             H  (CH.sub.2).sub.3 CO.sub.2 CH.sub.3                                                           CH.sub.3                                                                            OCH.sub.3                                                                              CH S                                             H  (CH.sub.2).sub.3 CO.sub.2 CH.sub.3                                                           CH.sub.3                                                                            OCH.sub.3                                                                              N  S                                             H  (CH.sub.2).sub.3 CO.sub.2 CH.sub.3                                                           OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  (CH.sub.2).sub.3 CO.sub.2 CH.sub.3                                                           OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             H  CH.sub.2 CH(CH.sub.3)CO.sub.2 CH.sub.3                                                       CH.sub.3                                                                            OCH.sub.3                                                                              CH O                                             H  CH.sub.2 CH(CH.sub.3)CO.sub.2 CH.sub.3                                                       CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  CH.sub.2 CH(CH.sub.3)CO.sub.2 CH.sub.3                                                       OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  CH.sub.2 CH(CH.sub.3)CO.sub.2 CH.sub.3                                                       OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             H  CH.sub.2 CH(CH.sub.3)CO.sub.2 CH.sub.3                                                       CH.sub.3                                                                            OCH.sub.3                                                                              CH O                                             H  CH.sub.2 CH(CH.sub.3)CO.sub.2 CH.sub.3                                                       CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  CH.sub.2 CH(CH.sub.3)CO.sub.2 CH.sub.3                                                       OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  CH.sub.2 CH(CH.sub.3)CO.sub.2 CH.sub.3                                                       OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             H  CH(CO.sub.2 CH.sub.3)C.sub.2 H.sub.5                                                         CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  CH(CO.sub.2 CH.sub.3)C.sub.2 H.sub.5                                                         OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H  CH(CO.sub.2 CH.sub.3)C.sub.2 H.sub.5                                                         OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             H  CH(CO.sub.2 CH.sub.3)C.sub.2 H.sub.5                                                         OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  C(CH.sub.3).sub.2 CO.sub.3 CH.sub.3                                                          CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  C(CH.sub.3).sub.2 CO.sub.3 CH.sub.3                                                          OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H  C(CH.sub.3).sub.2 CO.sub.3 CH.sub.3                                                          CH.sub.3                                                                            OCH.sub.3                                                                              N  S                                             H  C(CH.sub.3).sub.2 CO.sub.3 CH.sub.3                                                          OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  (CH.sub.2).sub.2 CO.sub.2 C.sub.2 H.sub.5                                                    CH.sub.3                                                                            CH.sub.3                                                                               CH O                                             H  (CH.sub.2).sub.2 CO.sub.2 C.sub.2 H.sub.5                                                    CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  (CH.sub.2).sub.2 CO.sub.2 C.sub.2 H.sub.5                                                    OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H  (CH.sub.2).sub.2 CO.sub.2 C.sub.2 H.sub.5                                                    OCH.sub.3                                                                           OCH.sub.3                                                                              N  O                                             H  (CH.sub.2).sub.2 CO.sub.2 C.sub.2 H.sub.5                                                    OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  (CH.sub.2).sub.2 CO.sub.2 C.sub.2 H.sub.5                                                    CH.sub.3                                                                            OCH.sub.3                                                                              N  S                                             H  (CH.sub.2).sub.2 CO.sub.2 C.sub.2 H.sub.5                                                    OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  (CH.sub.2).sub.2 CO.sub.2 C.sub.2 H.sub.5                                                    OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             H  CH(CH.sub.3)CO.sub.2 C.sub.2 H.sub.5                                                         OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H  CH(CH.sub.3)CO.sub.2 C.sub.2 H.sub.5                                                         OCH.sub.3                                                                           OCH.sub.3                                                                              N  O                                             H  CH(CH.sub.3)CO.sub.2 C.sub.2 H.sub.5                                                         CH.sub.3                                                                            OCH.sub.3                                                                              CH S                                             H  CH(CH.sub.3)CO.sub.2 C.sub.2 H.sub.5                                                         CH.sub.3                                                                            OCH.sub.3                                                                              N  S                                             H  (CH.sub.2).sub.3 CO.sub.2 C.sub.2 H.sub.5                                                    CH.sub.3                                                                            OCH.sub.3                                                                              CH O                                             H  (CH.sub.2 ).sub.3 CO.sub.2 C.sub.2 H.sub.5                                                   CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  (CH.sub.2).sub.3 CO.sub.2 C.sub.2 H.sub.5                                                    OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H  (CH.sub.2).sub.3 CO.sub.2 C.sub.2 H.sub.5                                                    OCH.sub.3                                                                           OCH.sub.3                                                                              N  O                                             H  (CH.sub.2).sub.3 CO.sub.2 C.sub.2 H.sub.5                                                    CH.sub.3                                                                            OCH.sub.3                                                                              CH S                                             H  (CH.sub.2).sub.3 CO.sub.2 C.sub.2 H.sub.5                                                    CH.sub.3                                                                            OCH.sub.3                                                                              N  S                                             H  (CH.sub.2).sub.3 CO.sub.2 C.sub.2 H.sub.5                                                    OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  (CH.sub.2).sub.3 CO.sub.2 C.sub.2 H.sub.5                                                    OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             H  CH.sub.2 CH(CH.sub.3)CO.sub.2 C.sub.2 H.sub.5                                                CH.sub.3                                                                            OCH.sub.3                                                                              CH O                                             H  CH.sub.2 CH(CH.sub.3)CO.sub.2 C.sub.2 H.sub.5                                                CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  CH.sub.2 CH(CH.sub.3)CO.sub.2 C.sub.2 H.sub.5                                                OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  CH.sub.2 CH(CH.sub.3)CO.sub.2 C.sub.2 H.sub.5                                                OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             H  CH.sub.2 CH(CH.sub.3)CO.sub.2 C.sub.2 H.sub.5                                                CH.sub.3                                                                            OCH.sub.3                                                                              CH O                                             H  CH.sub.2 CH(CH.sub.3)CO.sub.2 C.sub.2 H.sub.5                                                CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  CH.sub.2 CH(CH.sub.3)CO.sub.2 C.sub.2 H.sub.5                                                CH.sub.3                                                                            OCH.sub.3                                                                              CH S                                             H  CH.sub.2 CH(CH.sub.3)CO.sub.2 C.sub.2 H.sub.5                                                OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             H  CH(CO.sub.2 C.sub.2 H.sub.5)C.sub.2 H.sub.5                                                  CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  CH(CO.sub.2 C.sub.2 H.sub.5)C.sub.2 H.sub.5                                                  OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H  CH(CO.sub.2 C.sub.2 H.sub.5)C.sub.2 H.sub.5                                                  OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             H  CH(CO.sub.2 C.sub.2 H.sub.5)C.sub.2 H.sub.5                                                  OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  C(CH.sub.3).sub.2 CO.sub.2 C.sub.2 H.sub.5                                                   CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  C(CH.sub.3).sub.2 CO.sub.2 C.sub.2 H.sub.5                                                   OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H  C(CH.sub.3).sub.2 CO.sub.2 C.sub.2 H.sub.5                                                   CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  C(CH.sub.3).sub.2 CO.sub.2 C.sub.2 H.sub.5                                                   OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  (CH.sub.2).sub.2 OCH.sub.3                                                                   CH.sub.3                                                                            CH.sub.3                                                                               CH O                                             H  (CH.sub.2).sub.2 OCH.sub.3                                                                   CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  (CH.sub.2).sub.2 OCH.sub.3                                                                   OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H  (CH.sub.2).sub.2 OCH.sub.3                                                                   OCH.sub.3                                                                           OCH.sub.3                                                                              N  O                                             H  (CH.sub.2).sub.2 OCH.sub.3                                                                   OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  (CH.sub.2).sub.2 OCH.sub.3                                                                   CH.sub.3                                                                            OCH.sub.3                                                                              N  S                                             H  (CH.sub.2).sub.2 OCH.sub.3                                                                   OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  (CH.sub.2).sub.2 OCH.sub.3                                                                   OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             H  CH(CH.sub.3)OCH.sub.3                                                                        OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H  CH(CH.sub.3)OCH.sub.3                                                                        OCH.sub.3                                                                           OCH.sub.3                                                                              N  O                                             H  CH(CH.sub.3)OCH.sub.3                                                                        CH.sub.3                                                                            OCH.sub.3                                                                              CH S                                             H  CH(CH.sub.3)OCH.sub.3                                                                        CH.sub.3                                                                            OCH.sub.3                                                                              N  S                                             H  (CH.sub.2).sub.3 OCH.sub.3                                                                   CH.sub.3                                                                            OCH.sub.3                                                                              CH O                                             H  (CH.sub.2).sub.3 OCH.sub.3                                                                   CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  (CH.sub.2).sub.3 OCH.sub.3                                                                   OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H  (CH.sub.2).sub.3 OCH.sub.3                                                                   OCH.sub.3                                                                           OCH.sub.3                                                                              N  O                                             H  (CH.sub.2).sub.3 OCH.sub.3                                                                   CH.sub.3                                                                            OCH.sub.3                                                                              CH S                                             H  (CH.sub.2).sub.3 OCH.sub.3                                                                   CH.sub.3                                                                            OCH.sub.3                                                                              N  S                                             H  (CH.sub.2).sub.3 OCH.sub.3                                                                   OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  (CH.sub.2).sub.3 OCH.sub.3                                                                   OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             H  CH.sub.2 CH(CH.sub.3)OCH.sub.3                                                               CH.sub.3                                                                            OCH.sub.3                                                                              CH O                                             H  CH.sub.2 CH(CH.sub.3)OCH.sub.3                                                               CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  CH.sub.2 CH(CH.sub.3)OCH.sub.3                                                               OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  CH.sub.2 CH(CH.sub.3)OCH.sub.3                                                               OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             H  CH.sub.2 CH(CH.sub.3)OCH.sub.3                                                               CH.sub.3                                                                            OCH.sub.3                                                                              CH O                                             H  CH.sub.2 CH(CH.sub.3)OCH.sub.3                                                               CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  CH.sub.2 CH(CH.sub.3)OCH.sub.3                                                               CH.sub.3                                                                            OCH.sub.3                                                                              CH S                                             H  CH.sub.2 CH(CH.sub.3)OCH.sub.3                                                               OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             H  CH(OCH.sub.3)C.sub.2 H.sub.5                                                                 CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  CH(OCH.sub.3)C.sub.2 H.sub.5                                                                 OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H  CH(OCH.sub.3)C.sub.2 H.sub.5                                                                 OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             H  CH(OCH.sub.3)C.sub.2 H.sub.5                                                                 OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  C(CH.sub.3).sub. 2 OCH.sub.3                                                                 CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  C(CH.sub.3).sub.2 OCH.sub.3                                                                  OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H  C(CH.sub.3).sub.2 OCH.sub.3                                                                  CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  C(CH.sub.3).sub.2 OCH.sub.3                                                                  OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  (CH.sub.2).sub.2 OC.sub.2 H.sub.5                                                            CH.sub.3                                                                            CH.sub.3                                                                               CH O                                             H  (CH.sub.2).sub.2 OC.sub.2 H.sub.5                                                            CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  (CH.sub.2).sub.2 OC.sub.2 H.sub.5                                                            OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H  (CH.sub.2).sub.2 OC.sub.2 H.sub.5                                                            OCH.sub.3                                                                           OCH.sub.3                                                                              N  O                                             H  (CH.sub.2).sub.2 OC.sub.2 H.sub.5                                                            OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  (CH.sub.2).sub.2 OC.sub.2 H.sub.5                                                            CH.sub.3                                                                            OCH.sub.3                                                                              N  S                                             H  (CH.sub.2).sub.2 OC.sub.2 H.sub.5                                                            OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  (CH.sub.2).sub.2 OC.sub.2 H.sub.5                                                            OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             H  CH(CH.sub.3)OC.sub.2 H.sub.5                                                                 OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H  CH(CH.sub.3)OC.sub.2 H.sub.5                                                                 OCH.sub.3                                                                           OCH.sub.3                                                                              N  O                                             H  CH(CH.sub.3)OC.sub.2 H.sub. 5                                                                CH.sub.3                                                                            OCH.sub.3                                                                              CH S                                             H  CH(CH.sub.3)OC.sub.2 H.sub.5                                                                 CH.sub.3                                                                            OCH.sub.3                                                                              N  S                                             H  (CH.sub.2).sub.3 OC.sub.2 H.sub.5                                                            CH.sub.3                                                                            OCH.sub.3                                                                              CH O                                             H  (CH.sub.2).sub.3 OC.sub.2 H.sub.5                                                            CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  (CH.sub.2).sub.3 OC.sub.2 H.sub.5                                                            OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H  (CH.sub.2).sub.3 OC.sub.2 H.sub.5                                                            OCH.sub.3                                                                           OCH.sub.3                                                                              N  O                                             H  (CH.sub.2).sub.3 OC.sub.2 H.sub.5                                                            CH.sub.3                                                                            OCH.sub.3                                                                              CH S                                             H  (CH.sub.2).sub.3 OC.sub.2 H.sub.5                                                            CH.sub.3                                                                            OCH.sub.3                                                                              N  S                                             H  (CH.sub.2).sub.3 OC.sub.2 H.sub.5                                                            OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  (CH.sub.2).sub.3 OC.sub.2 H.sub.5                                                            OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             H  CH.sub.2 CH(CH.sub.3)OC.sub.2 H.sub.5                                                        CH.sub.3                                                                            OCH.sub.3                                                                              CH O                                             H  CH.sub.2 CH(CH.sub.3)OC.sub.2 H.sub.5                                                        CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  CH.sub.2 CH(CH.sub.3)OC.sub.2 H.sub.5                                                        OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  CH.sub.2 CH(CH.sub.3)OC.sub.2 H.sub.5                                                        OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             H  CH(CH.sub.3)CH.sub.2 OC.sub.2 H.sub.5                                                        CH.sub.3                                                                            OCH.sub.3                                                                              CH O                                             H  CH(CH.sub.3)CH.sub.2 OC.sub.2 H.sub.5                                                        CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  CH(CH.sub.3)CH.sub.2 OC.sub.2 H.sub.5                                                        CH.sub.3                                                                            OCH.sub.3                                                                              CH S                                             H  CH(CH.sub.3)CH.sub.2 OC.sub.2 H.sub.5                                                        OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             H  CH(OC.sub.2 H.sub.5)C.sub.2 H.sub.5                                                          CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  CH(OC.sub.2 H.sub.5)C.sub.2 H.sub.5                                                          OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H  CH(OC.sub.2 H.sub.5)C.sub.2 H.sub.5                                                          OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             H  CH(OC.sub.2 H.sub.5)C.sub.2 H.sub.5                                                          OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  CH(CH.sub.3).sub.2 OC.sub.2 H.sub.5                                                          CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  CH(CH.sub.3).sub.2 OC.sub.2 H.sub.5                                                          OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H  CH(CH.sub.3).sub.2 OC.sub.2 H.sub.5                                                          CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  C(CH.sub.3).sub.2 OC.sub.2 H.sub.5                                                           OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  (CH.sub.2)CH.sub.2 COCH.sub.3                                                                CH.sub.3                                                                            CH.sub.3                                                                               CH O                                             H  (CH.sub.2)CH.sub.2 COCH.sub.3                                                                CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  (CH.sub.2)CH.sub.2 COCH.sub.3                                                                OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H  (CH.sub.2)CH.sub.2 COCH.sub.3                                                                OCH.sub.3                                                                           OCH.sub.3                                                                              N  O                                             H  (CH.sub.2)CH.sub.2 COCH.sub.3                                                                OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  (CH.sub.2)CH.sub.2 COCH.sub.3                                                                CH.sub.3                                                                            OCH.sub.3                                                                              N  S                                             H  (CH.sub.2)CH.sub.2 COCH.sub.3                                                                OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  (CH.sub.2)CH.sub.2 COCH.sub.3                                                                OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             H  CH(CH.sub.3)CH.sub.2 COCH.sub.3                                                              OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H  CH(CH.sub.3)CH.sub.2 COCH.sub.3                                                              OCH.sub.3                                                                           OCH.sub.3                                                                              N  O                                             H  CH(CH.sub.3)CH.sub.2 COCH.sub.3                                                              CH.sub.3                                                                            OCH.sub.3                                                                              CH S                                             H  CH(CH.sub.3)CH.sub.2 COCH.sub.3                                                              CH.sub.3                                                                            OCH.sub.3                                                                              N  S                                             H  (CH.sub.2).sub.3 CH.sub.2 COCH.sub.3                                                         CH.sub.3                                                                            OCH.sub.3                                                                              CH O                                             H  (CH.sub.2).sub.3 CH.sub.2 COCH.sub.3                                                         CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  (CH.sub.2).sub.3 CH.sub.2 COCH.sub.3                                                         OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H  (CH.sub.2).sub.3 CH.sub.2 COCH.sub.3                                                         OCH.sub.3                                                                           OCH.sub.3                                                                              N  O                                             H  (CH.sub.2).sub.3 CH.sub.2 COCH.sub.3                                                         CH.sub.3                                                                            OCH.sub.3                                                                              CH S                                             H  (CH.sub.2).sub.3 CH.sub.2 COCH.sub.3                                                         CH.sub.3                                                                            OCH.sub.3                                                                              N  S                                             H  (CH.sub.2).sub.3 CH.sub.2 COCH.sub.3                                                         OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  (CH.sub.2).sub.3 CH.sub.2 COCH.sub.3                                                         OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             H  CH.sub.2 CH(CH.sub.3)CH.sub.2 COCH.sub.3                                                     CH.sub.3                                                                            OCH.sub.3                                                                              CH O                                             H  CH.sub.2 CH(CH.sub.3)CH.sub.2 COCH.sub.3                                                     CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  CH.sub.2 CH(CH.sub.3)CH.sub.2 COCH.sub.3                                                     OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  CH.sub.2 CH(CH.sub.3)CH.sub.2 COCH.sub.3                                                     OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             H  CH(CH.sub.3)CH.sub.2 CH.sub.2 COCH.sub.3                                                     CH.sub.3                                                                            OCH.sub.3                                                                              CH O                                             H  CH(CH.sub.3)CH.sub.2 CH.sub.2 COCH.sub.3                                                     CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  CH(CH.sub.3)CH.sub.2 CH.sub.2 COCH.sub.3                                                     CH.sub.3                                                                            OCH.sub.3                                                                              CH S                                             H  CH(CH.sub.3)CH.sub.2 CH.sub.2 COCH.sub.3                                                     OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             H  CH(C.sub.2 H.sub.5)CH.sub.2 COCH.sub.3                                                       CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  CH(C.sub.2 H.sub.5)CH.sub.2 OCH.sub.3                                                        OCH.sub. 3                                                                          OCH.sub.3                                                                              CH O                                             H  CH(C.sub.2 H.sub.5)CH.sub.2 OCH.sub.3                                                        OCH.sub.3                                                                           OCH.sub.3                                                                              N  S                                             H  CH(C.sub.2 H.sub.5)CH.sub.2 OCH.sub.3                                                        OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  CH(CH.sub.3).sub.2 COCH.sub.3                                                                CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  CH(CH.sub.3).sub.2 COCH.sub.3                                                                OCH.sub.3                                                                           OCH.sub.3                                                                              CH O                                             H  CH(CH.sub.3).sub.2 CH.sub.2 COCH.sub.3                                                       CH.sub.3                                                                            OCH.sub.3                                                                              N  O                                             H  C(CH.sub.3).sub.2 CH.sub.2 COCH.sub.3                                                        OCH.sub.3                                                                           OCH.sub.3                                                                              CH S                                             H  H             OCH.sub.3                                                                           OCH.sub.3                                                                              CH O*                                            H  H             OCH.sub.3                                                                           OCH.sub.3                                                                              CH S*                                            H  CH.sub.3      OCH.sub.3                                                                           OCH.sub.3                                                                              CH O*                                            H  CH.sub.3      OCH.sub.3                                                                           OCH.sub.3                                                                              CH S*                                            H  SCH.sub.3     OCH.sub.3                                                                           OCH.sub.3                                                                              CH O*                                            H  SCH.sub.3     OCH.sub.3                                                                           OCH.sub.3                                                                              CH S*                                            H  SCH.sub.2 CHCH.sub.2                                                                         OCH.sub.3                                                                           OCH.sub.3                                                                              CH O*                                            H  SCH.sub.3 CHCH.sub.2                                                                         OCH.sub.3                                                                           OCH.sub.3                                                                              CH S*                                            H  SH            OCH.sub.3                                                                           OCH.sub.3                                                                              CH O*                                            H  SH            OCH.sub.3                                                                           OCH.sub.3                                                                              CH S*                                            __________________________________________________________________________      W is O, unless indicated by * where W is S in all Tables.                

                  TABLE 6b                                                         ______________________________________                                         General Structure 2 wherein Q is Q-28.                                                                                     m.p.                               R     R.sub.3                                                                               R.sub.4 X     Y       Z        °C.                         ______________________________________                                         H     H      H       CH.sub.3                                                                             OCH.sub.3                                                                              CH       216-218                            H     H      H       CH.sub.3                                                                             OCH.sub.3                                                                              N        197-200                            H     H      H       OCH.sub.3                                                                            OCH.sub.3                                                                              CH       180-186                            H     H      H       OCH.sub.3                                                                            OCH.sub.3                                                                              N        196-198                            H     H      H       CH.sub.3                                                                             CH.sub.3                                                                               CH       242-244                            H     H      H       CH.sub.3                                                                             CH.sub.3                                                                               N                                           H     CH.sub.3                                                                              H       CH.sub.3                                                                             OCH.sub.3                                                                              CH                                          H     H      H       Cl    OCH.sub.3                                                                              CH       206-208                            H     H      CH.sub.3                                                                               CH.sub.3                                                                             OCH.sub.3                                                                              N                                           H     CH.sub.3                                                                              CH.sub.3                                                                               OCH.sub.3                                                                            OCH.sub.3                                                                              CH                                          CH.sub.3                                                                             CH.sub.3                                                                              CH.sub.3                                                                               OCH.sub.3                                                                            OCH.sub.3                                                                              N                                           H     H      H       CH.sub.3                                                                              ##STR146##                                                                            CH                                          H     H      H       CH.sub.3                                                                             C.sub.2 H.sub.5                                                                        CH                                          H     CH.sub.3                                                                              H       CH.sub. 3                                                                            CH.sub.3                                                                               CH                                          H     CH.sub.3                                                                              H       CH.sub.3                                                                             OCH.sub.3                                                                              N                                           H     CH.sub.3                                                                              H       OCH.sub.3                                                                            OCH.sub.3                                                                              CH                                          H     CH.sub.3                                                                              H       OCH.sub.3                                                                            OCH.sub.3                                                                              N                                           H     CH.sub.3                                                                              H       OCH.sub.3                                                                            Cl      CH                                          H     CH.sub.3                                                                              H       CH.sub.3                                                                             CH.sub.3                                                                               N                                           H     Cl     H       CH.sub.3                                                                             CH.sub.3                                                                               CH                                          H     Cl     H       CH.sub.3                                                                             CH.sub.3                                                                               N                                           H     Cl     H       CH.sub.3                                                                             OCH.sub.3                                                                              CH                                          H     Cl     H       CH.sub.3                                                                             OCH.sub.3                                                                              N                                           H     Cl     H       OCH.sub.3                                                                            OCH.sub.3                                                                              CH                                          H     Cl     H       OCH.sub.3                                                                            OCH.sub.3                                                                              N                                           H     Cl     H       OCH.sub.3                                                                            Cl      CH                                          H     Cl     CH.sub.3                                                                               CH.sub.3                                                                             OCH.sub.3                                                                              CH                                          H     Cl     CH.sub.3                                                                               CH.sub.3                                                                             OCH.sub.3                                                                              N                                           H     Cl     CH.sub.3                                                                               OCH.sub.3                                                                            OCH.sub.3                                                                              CH                                          H     Cl     CH.sub.3                                                                               OCH.sub.3                                                                            OCH.sub.3                                                                              N                                           H     Br     H       OCH.sub.3                                                                            OCH.sub.3                                                                              CH                                          H     Br     H       CH.sub.3                                                                             CH.sub.3                                                                               CH                                          H     Br     H       CH.sub.3                                                                             OCH.sub.3                                                                              N                                           H     Br     H       CH.sub.3                                                                             OCH.sub.3                                                                              CH                                          H     Br     H       OCH.sub.3                                                                            OCH.sub.3                                                                              N                                           H     Br     H       OCH.sub.3                                                                            OCH.sub.3                                                                              CH                                          H     Br     H       OCH.sub.3                                                                            Cl      CH                                          H     H      H       OCH.sub.3                                                                            OCH.sub. 3                                                                             CH   *                                      H     CH.sub.3                                                                              H       OCH.sub.3                                                                            OCH.sub.3                                                                              CH   *                                      H     H      CH.sub.3                                                                               OCH.sub.3                                                                            OCH.sub.3                                                                              CH   *                                      H     CH.sub.3                                                                              CH.sub.3                                                                               OCH.sub.3                                                                            OCH.sub.3                                                                              CH   *                                      H     Cl     H       OCH.sub.3                                                                            OCH.sub.3                                                                              CH   *                                      H     Cl     CH.sub.3                                                                               OCH.sub.3                                                                            OCH.sub.3                                                                              CH   *                                      H     Br     H       OCH.sub.3                                                                            OCH.sub.3                                                                              CH   *                                      H     Br     CH.sub.3                                                                               OCH.sub.3                                                                            OCH.sub.3                                                                              CH   *                                      ______________________________________                                          *Wherein W is O, unless indicated by * where W is S in all Tables.       

                  TABLE 6c                                                         ______________________________________                                         General Structure 2                                                                                                            m.p.                           Q    R      R.sub.3 R.sub.4                                                                              X     Y       Z   n'  °C.                     ______________________________________                                         Q-33 H      H       H     CH.sub.3                                                                             OCH.sub.3                                                                              CH  0   168-                                                                           173                            Q-33 H      H       H     CH.sub.3                                                                             OCH.sub.3                                                                              N   0   189-                                                                           190                            Q-33 H      H       H     OCH.sub.3                                                                            OCH.sub.3                                                                              CH  0   195-                                                                           196                            Q-33 H      H       H     OCH.sub.3                                                                            OCH.sub.3                                                                              N   0   183-                                                                           185                            Q-33 H      H       H     CH.sub.3                                                                             CH.sub.3                                                                               CH  0   164-                                                                           167                            Q-33 H      3-CH.sub.3                                                                             H     CH.sub.3                                                                             OCH.sub.3                                                                              CH  0                                  Q-33 H      4-CH.sub.3                                                                             H     CH.sub.3                                                                             OCH.sub.3                                                                              CH  0                                  Q-33 H      5-CH.sub.3                                                                             H     CH.sub.3                                                                             OCH.sub.3                                                                              CH  0                                  Q-33 H      H       H     CH.sub.3                                                                             CH.sub.3                                                                               N   0                                  Q-33 H      6-CH.sub.3                                                                             H     CH.sub.3                                                                             OCH.sub.3                                                                              CH  0                                  Q-33 H      3-CH.sub.3                                                                             5-CH.sub.3                                                                           CH.sub.3                                                                             OCH.sub.3                                                                              N   0                                  Q-33 H      4-CH.sub.3                                                                             6-CH.sub.3                                                                           CH.sub.3                                                                             OCH.sub.3                                                                              N   0                                  Q-33 CH.sub.3                                                                              H       H     OCH.sub.3                                                                            OCH.sub.3                                                                              CH  0                                  Q-33 H      H       H     CH.sub.3                                                                             CH.sub.2 OCH.sub.3                                                                     CH  0                                  Q-33 H      H       H     Cl    OCH.sub.3                                                                              CH  0   183-                                                                           184                            Q-33 H      H       H     CH.sub.3                                                                             CF.sub.3                                                                               CH  0                                  Q-33 H      H       H     Cl    OCH.sub.3                                                                              CH  1   184-                                                                           187                            Q-33 H      H       H     CH.sub.3                                                                             OCH.sub.3                                                                              CH  1   185-                                                                           187                            Q-33 H      H       H     CH.sub.3                                                                             OCH.sub.3                                                                              N   1   200                            Q-33 H      H       H     OCH.sub.3                                                                            OCH.sub.3                                                                              CH  1   191-                                                                           192                            Q-33 H      H       H     OCH.sub.3                                                                            OCH.sub.3                                                                              N   1   190                            Q-33 H      H       H     CH.sub.3                                                                             CH.sub.3                                                                               CH  1   171-                                                                           174                            Q-33 H      3-CH.sub.3                                                                             H     CH.sub.3                                                                             OCH.sub.3                                                                              CH  1                                  Q-33 H      4-CH.sub.3                                                                             H     CH.sub.3                                                                             OCH.sub.3                                                                              CH  1                                  Q-33 H      5-CH.sub.3                                                                             H     CH.sub.3                                                                             OCH.sub.3                                                                              CH  1                                  Q-33 H      H       H     CH.sub.3                                                                             CH.sub.3                                                                               N   1                                  Q-33 H      6-CH.sub.3                                                                             H     CH.sub.3                                                                             OCH.sub.3                                                                              CH  1                                  Q-33 H      3-CH.sub.3                                                                             5-CH.sub.3                                                                           CH.sub.3                                                                             OCH.sub.3                                                                              N   1                                  Q-33 H      4-CH.sub.3                                                                             6-CH.sub.3                                                                           CH.sub.3                                                                             OCH.sub.3                                                                              N   1                                  Q-33 CH.sub.3                                                                              H       H     OCH.sub.3                                                                            OCH.sub.3                                                                              CH  1                                  Q-33 H      H       H     CH.sub.3                                                                             CH.sub.2 OCH.sub.3                                                                     CH  1                                  Q-33 H      H       H     Cl    OC.sub.2 H.sub.5                                                                       CH  1                                  Q-33 H      H       H     CH.sub.3                                                                             CF.sub.3                                                                               CH  1                                  Q-34 H      H       H     CH.sub.3                                                                             OCH.sub.3                                                                              CH  0                                  Q-34 H      H       H     CH.sub.3                                                                             OCH.sub.3                                                                              N   0                                  Q-34 H      H       H     OCH.sub.3                                                                            OCH.sub.3                                                                              CH  0                                  Q-34 H      H       H     OCH.sub.3                                                                            OCH.sub.3                                                                              N   0                                  Q-34 H      2-CH.sub.3                                                                             H     CH.sub.3                                                                             CH.sub.3                                                                               CH  0                                  Q-34 H      4-CH.sub.3                                                                             H     CH.sub.3                                                                             CH.sub.3                                                                               N   0                                  Q-34 H      5-CH.sub.3                                                                             H     CH.sub.3                                                                             OCH.sub.3                                                                              CH  0                                  Q-34 H      6-CH.sub.3                                                                             H     CH.sub.3                                                                             OCH.sub.3                                                                              N   0                                  Q-34 H      2-CH.sub.3                                                                             6-CH.sub.3                                                                           OCH.sub.3                                                                            OCH.sub.3                                                                              CH  0                                  Q-34 H      4-CH.sub.3                                                                             6-CH.sub.3                                                                           OCH.sub.3                                                                            OCH.sub.3                                                                              N   0                                  Q-34 H      H       H     CH.sub.3                                                                             CH.sub.3                                                                               N   0                                  Q-34 CH.sub.3                                                                              H       H     CH.sub.3                                                                             CH.sub.3                                                                               CH  0                                  Q-34 H      H       H     CH.sub.3                                                                             CH.sub.3                                                                               CH  0                                  Q-34 H      H       H     CH.sub.3                                                                             OCF.sub.2 H                                                                            CH  0                                  Q-34 H      H       H     CH.sub.3                                                                             OCH.sub.3                                                                              CH  1                                  Q-34 H      H       H     CH.sub.3                                                                             OCH.sub.3                                                                              N   1                                  Q-34 H      H       H     OCH.sub.3                                                                            OCH.sub.3                                                                              CH  1                                  Q-34 H      H       H     OCH.sub.3                                                                            OCH.sub.3                                                                              N   1                                  Q-34 H      2-CH.sub.3                                                                             H     CH.sub.3                                                                             CH.sub.3                                                                               CH  1                                  Q-34 H      4-CH.sub.3                                                                             H     CH.sub.3                                                                             CH.sub.3                                                                               N   1                                  Q-34 H      5-CH.sub.3                                                                             H     CH.sub.3                                                                             OCH.sub.3                                                                              CH  1                                  Q-34 H      6-CH.sub.3                                                                             H     CH.sub.3                                                                             OCH.sub.3                                                                              N   1                                  Q-34 H      2-CH.sub.3                                                                             6-CH.sub.3                                                                           OCH.sub.3                                                                            OCH.sub.3                                                                              CH  1                                  Q-34 H      4-CH.sub.3                                                                             6-CH.sub.3                                                                           OCH.sub.3                                                                            OCH.sub.3                                                                              N   1                                  Q-34 H      H       H     CH.sub.3                                                                             CH.sub.3                                                                               N   1                                  Q-34 CH.sub.3                                                                              H       H     CH.sub.3                                                                             CH.sub.3                                                                               CH  1                                  Q-34 H      H       H     CH.sub.3                                                                             CH.sub.3                                                                               CH  1                                  Q-34 H      H       H     CH.sub.3                                                                             OCF.sub.2 H                                                                            CH  1                                  Q-35 H      H       H     CH.sub.3                                                                             OCH.sub.3                                                                              CH  0                                  Q-35 H      H       H     CH.sub.3                                                                             OCH.sub.3                                                                              N   0                                  Q-35 H      H       H     OCH.sub.3                                                                            OCH.sub.3                                                                              CH  0                                  Q-35 H      H       H     OCH.sub.3                                                                            OCH.sub.3                                                                              N   0                                  Q-35 H      2-CH.sub.3                                                                             H     CH.sub.3                                                                             CH.sub.3                                                                               CH  0                                  Q-35 H      H       H     Cl    OCH.sub.3                                                                              CH  0                                  Q-35 H      3-CH.sub.3                                                                             H     CH.sub.3                                                                             CH.sub.3                                                                               N   0                                  Q-35 H      2-CH.sub.3                                                                             6-CH.sub.3                                                                           CH.sub.3                                                                             OCH.sub.3                                                                              CH  0                                  Q-35 H      2-CH.sub.3                                                                             3-CH.sub.3                                                                           CH.sub.3                                                                             OCH.sub.3                                                                              N   0                                  Q-35 H      3-CH.sub.3                                                                             5-CH.sub.3                                                                           CH.sub.3                                                                             OCH.sub.3                                                                              N   0                                  Q-35 H      H       H     CH.sub.3                                                                             CH.sub.3                                                                               N   0                                  Q-35 CH.sub.3                                                                              H       H     OCH.sub.3                                                                            OCH.sub.3                                                                              CH  0                                  Q-35 H      H       H     CH.sub.3                                                                             OCH.sub.2 CF.sub.3                                                                     CH  0                                  Q-35 H      H       H     CH.sub.3                                                                             CH.sub.3                                                                               CH  0                                  Q-35 H      H       H     CH.sub.3                                                                             OCH.sub.3                                                                              CH  1                                  Q-35 H      H       H     CH.sub.3                                                                             OCH.sub.3                                                                              N   1                                  Q-35 H      H       H     OCH.sub.3                                                                            OCH.sub.3                                                                              CH  1                                  Q-35 H      H       H     OCH.sub.3                                                                            OCH.sub.3                                                                              N   1                                  Q-35 H      2-CH.sub.3                                                                             H     CH.sub.3                                                                             CH.sub.3                                                                               CH  1                                  Q-35 H      H       H     Cl    OCH.sub.3                                                                              CH  1                                  Q-35 H      3-CH.sub.3                                                                             H     CH.sub.3                                                                             CH.sub.3                                                                               N   1                                  Q-35 H      2-CH.sub.3                                                                             6-CH.sub.3                                                                           CH.sub.3                                                                             OCH.sub.3                                                                              CH  1                                  Q-35 H      2-CH.sub.3                                                                             3-CH.sub.3                                                                           CH.sub.3                                                                             OCH.sub.3                                                                              N   1                                  Q-35 H      3-CH.sub.3                                                                             5-CH.sub.3                                                                           CH.sub.3                                                                             OCH.sub.3                                                                              N   1                                  Q-35 H      H       H     CH.sub.3                                                                             CH.sub.3                                                                               N   1                                  Q-35 CH.sub.3                                                                              H       H     OCH.sub.3                                                                            OCH.sub.3                                                                              CH  1                                  Q-35 H      H       H     CH.sub.3                                                                             OCH.sub.2 CF.sub.3                                                                     CH  1                                  Q-35 H      H       H     CH.sub.3                                                                             CH.sub.3                                                                               CH  1                                  ______________________________________                                    

                                      TABLE 7a                                     __________________________________________________________________________     General Structure 3 wherein Q is Q-1.                                          R   R.sub.1                                                                            R.sub.2                                                                              X         Y       Z m.p. °C.                              __________________________________________________________________________     H   H   H     CH.sub.3  CH.sub.3                                                                               CH                                             H   H   H     CH.sub.3  CH.sub.3                                                                               N                                              H   H   H     CH.sub.3  OCH.sub.3                                                                              CH                                             H   H   H     CH.sub.3  OCH.sub.3                                                                              N                                              H   H   H     OCH.sub.3 OCH.sub.3                                                                              CH                                             H   H   H     Cl        OCH.sub.3                                                                              CH                                             H   H   H     OCH.sub.3 OCH.sub.3                                                                              N                                              H   4-Cl                                                                               H     CH.sub.3  OCH.sub.3                                                                              CH                                             H   H   4-F   CH.sub.3  CH.sub.3                                                                               N                                              H   4-CH.sub.3                                                                         H     OCH.sub.3 OCH.sub.3                                                                              CH                                             H   H   4-OCH.sub.3                                                                          CH.sub.3  OCH.sub.3                                                                              N                                              H   H   4-CF.sub.3                                                                           CH.sub.3  OCH.sub.3                                                                              CH                                             CH.sub.3                                                                           3-CH.sub.3                                                                         5-CH.sub.3                                                                           CH.sub.3  CH.sub.3                                                                               N                                              H   H   H     OCH.sub.3 OCF.sub.2 H                                                                            CH                                             H   H   H     OCH.sub.3 cyclopropyl                                                                            N                                              H   H   H     OC.sub.2 H.sub.5                                                                         OCH.sub.3                                                                              N                                              H   H   H     O-- -n-C.sub.4 H.sub.9                                                                   CH.sub.3                                                                               CH                                             H   H   H     OCH.sub.2 CF.sub.3                                                                       OCH.sub.3                                                                              N                                              H   H   H     OCH.sub.2 CH.sub.2 CH.sub.2 F                                                            CH.sub.3                                                                               CH                                             H   H   H     SCH.sub.3 OCH.sub.3                                                                              CH                                             H   H   H     SCH(CH.sub.3).sub.2                                                                      CH.sub.3                                                                               N                                              H   H   H     CH.sub.2 CH.sub.2 OCH.sub.3                                                              CH.sub.3                                                                               CH                                             H   H   H     CH.sub.2 OCH.sub.2 CH.sub.3                                                              OCH.sub.3                                                                              N                                              H   H   H     N(CH.sub.2 CH.sub.3).sub.2                                                               CH.sub.3                                                                               CH                                             H   H   H     N(CH.sub.2 CH.sub.2 CH.sub.3)                                                            OCH.sub.3                                                                              N                                              H   H   H     CH.sub.3  OCH.sub.2 CH=CH.sub.2                                                                  CH                                             H   H   H     OCH.sub.3 OCH.sub.2 C.tbd.CCH.sub.3                                                              N                                              H   H   H     CH.sub.3  cyclopentyl                                                                            CH                                             H   H   H     OCH.sub.3 CH.sub.2 SCH.sub.3                                                                     N                                              H   H   H     CH.sub.3  C(O)CH.sub.3                                                                           CH                                             H   H   H     CH.sub.3  1,3-dioxan-2-yl                                                                        N                                              H   H   H     OCH.sub.3 N(OCH.sub.3)CH.sub.3                                                                   CH                                             H   H   H     OCH.sub.3 OCH.sub.3                                                                              CH                                                                               *                                            H   H   H     OCH.sub.3 CH.sub.3                                                                               N *                                            H   4-Cl                                                                               H     OCH.sub.3 OCH.sub.3                                                                              CH                                                                               *                                            __________________________________________________________________________      W is O, unless indicated by * where W is S in all Tables.                

                                      TABLE 7b                                     __________________________________________________________________________     General structure 3                                                                                                m.p.                                       Q  R  R.sub.3                                                                           R.sub.4                                                                           R.sub.5                                                                            X       Y      Z  W'                                                                               °C.                                 __________________________________________________________________________     Q-2                                                                               H  H  H  H   CH.sub.3                                                                               OCH.sub.3                                                                             CH O                                            Q-2                                                                               H  H  H  H   CH.sub.3                                                                               OCH.sub.3                                                                             N  O                                            Q-2                                                                               H  H  H  H   OCH.sub.3                                                                              OCH.sub.3                                                                             CH O                                            Q-2                                                                               H  H  H  H   OCH.sub.3                                                                              OCH.sub.3                                                                             N  O                                            Q-2                                                                               H  CH.sub.3                                                                          H  H   CH.sub.3                                                                               CH.sub.3                                                                              CH O                                            Q-2                                                                               H  H  CH.sub.3                                                                          H   CH.sub.3                                                                               OCH.sub.3                                                                             N  O                                            Q-2                                                                               H  H  H  CH.sub.3                                                                           CH.sub.3                                                                               OCH.sub.3                                                                             CH O                                            Q-2                                                                               CH.sub.3                                                                          H  H  H   CH      CH.sub.3                                                                              CH O                                            Q-2                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          H   OCH.sub.3                                                                              OCH.sub.3                                                                             N  O                                            Q-2                                                                               H  H  H  H   Cl      OCH.sub.3                                                                             CH S                                            Q-2                                                                               H  H  H  H   CH.sub.3                                                                               OCH.sub.3                                                                             CH S                                            Q-2                                                                               H  H  H  H   CH.sub.3                                                                               OCH.sub. 3                                                                            N  S                                            Q-2                                                                               H  H  H  H   OCH.sub.3                                                                              OCH.sub.3                                                                             CH S                                            Q-2                                                                               H  H  H  H   OCH.sub.3                                                                              OCH.sub.3                                                                             N  S                                            Q-2                                                                               H  H  H  H   CH.sub.3                                                                               CH.sub.3                                                                              CH S                                            Q-2                                                                               H  CH.sub.3                                                                          H  H   CH.sub.3                                                                               CH.sub.3                                                                              CH S                                            Q-2                                                                               H  H  CH.sub.3                                                                          H   CH.sub.3                                                                               CH.sub.3                                                                              N  S                                            Q-2                                                                               H  H  H  CH.sub.3                                                                           CH.sub.3                                                                               OCH.sub.3                                                                             CH S                                            Q-2                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          H   CH.sub.3                                                                               OCH.sub.3                                                                             N  S                                            Q-2                                                                               H  H  CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                              OCH.sub.3                                                                             CH S                                            Q-2                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                              OCH.sub.3                                                                             N  S                                            Q-2                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                               OCH.sub.3                                                                             CH S                                            Q-2                                                                               CH.sub.3                                                                          H  H  H   CH.sub.3                                                                               CH.sub.3                                                                              CH S                                            Q-2                                                                               H  H  H  H   Cl      OC.sub.2 H.sub.5                                                                      CH S                                            Q-3                                                                               H  H  H  H   CH.sub.3                                                                               CH.sub.3                                                                              CH O                                            Q-3                                                                               H  H  H  H   CH.sub.3                                                                               CH.sub.3                                                                              N  O                                            Q-3                                                                               H  H  H  H   CH.sub.3                                                                               OCH.sub.3                                                                             CH O                                            Q-3                                                                               H  H  H  H   CH.sub.3                                                                               OCH.sub.3                                                                             N  O                                            Q-3                                                                               H  H  H  H   OCH.sub.3                                                                              OCH.sub.3                                                                             CH O                                            Q-3                                                                               H  H  H  H   OCH.sub.3                                                                              OCH.sub.3                                                                             N  O                                            Q-3                                                                               H  CH.sub.3                                                                          H  H   CH.sub.3                                                                               CH.sub.3                                                                              CH O                                            Q-3                                                                               H  H  CH.sub.3                                                                          H   CH.sub.3                                                                               CH.sub.3                                                                              N  O                                            Q-3                                                                               H  H  H  CH.sub.3                                                                           CH.sub.3                                                                               OCH.sub.3                                                                             CH O                                            Q-3                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          H   CH.sub.3                                                                               OCH.sub.3                                                                             N  O                                            Q-3                                                                               H  H  CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                              OCH.sub.3                                                                             CH O                                            Q-3                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                              OCH.sub.3                                                                             N  O                                            Q-3                                                                               H  H  H  H   OCH.sub.3                                                                              OCH.sub.2 CF.sub.3                                                                    CH O                                            Q-3                                                                               H  H  H  H   OCH.sub.3                                                                              OCH.sub.2 CF.sub.3                                                                    CH O                                            Q-3                                                                               CH.sub.3                                                                          H  H  H   Cl      OCH.sub.3                                                                             CH O                                            Q-3                                                                               H  H  H  H   CH.sub.3                                                                               OCH.sub.3                                                                             CH S                                            Q-3                                                                               H  H  H  H   OCH.sub.3                                                                              OCH.sub.3                                                                             CH S                                            Q-3                                                                               H  H  H  H   OCH.sub.3                                                                              OCH.sub.3                                                                             N  S                                            Q-3                                                                               H  CH.sub.3                                                                          H  H   CH.sub.3                                                                               CH.sub.3                                                                              CH S                                            Q-3                                                                               H  H  CH.sub.3                                                                          H   CH.sub.3                                                                               OCH.sub. 3                                                                            N  S                                            Q-3                                                                               H  H  H  CH.sub.3                                                                           CH.sub.3                                                                               OCH.sub.3                                                                             CH S                                            Q-3                                                                               CH.sub.3                                                                          H  H  H   CH.sub.3                                                                               CH.sub.3                                                                              CH S                                            Q-3                                                                               H  H  CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                              OCH.sub.3                                                                             N  S                                            Q-3                                                                               H  H  H  H   OCH.sub.3                                                                              CF.sub.3                                                                              N  S                                            Q-4                                                                               H  H  H  H   CH.sub.3                                                                               OCH.sub.3                                                                             CH --                                           Q-4                                                                               H  H  H  H   OCH.sub.3                                                                              Cl     CH --                                           Q-4                                                                               H  H  H  H   CH.sub.3                                                                               OCH.sub.3                                                                             N  --                                           Q-4                                                                               H  H  H  H   CH.sub.3                                                                               CH.sub.3                                                                              CH --                                           Q-4                                                                               H  H  H  H   OCH.sub.3                                                                              OCH.sub.3                                                                             CH --                                           Q-4                                                                               H  H  H  H   OCH.sub.3                                                                              OCH.sub.3                                                                             N  --                                           Q-4                                                                               H  CH.sub.3                                                                          H  H   CH.sub.3                                                                               CH.sub.3                                                                              CH --                                           Q-4                                                                               H  H  CH.sub.3                                                                          H   CH.sub.3                                                                               OCH.sub.3                                                                             N  --                                           Q-4                                                                               H  H  H  CH.sub.3                                                                           CH.sub.3                                                                               OCH.sub.3                                                                             CH --                                           Q-4                                                                               CH.sub.3                                                                          H  H  H   OCH.sub.3                                                                              OCH.sub.3                                                                             CH --                                           Q-4                                                                               CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                               OCH.sub.3                                                                             N  --                                           Q-4                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                               OCH.sub. 3                                                                            CH --                                           Q-4                                                                               H  H  H  H   OCH.sub.3                                                                              OCH.sub.2 CF.sub.3                                                                    N  --                                           Q-4                                                                               H  H  H  H   CH.sub.3                                                                               NHCH.sub.3                                                                            CH --                                           Q-4                                                                               H  H  H  H   CH.sub.3                                                                               CH.sub.3                                                                              CH --                                           Q-4                                                                               H  H  H  H   CH.sub.3                                                                               CH.sub.3                                                                              N  --                                           Q-9                                                                               H  H  H  H   CH.sub.3                                                                               OCH.sub.3                                                                             CH --                                           Q-9                                                                               H  H  H  H   CH.sub.3                                                                               OCH.sub.3                                                                             N  --                                           Q-9                                                                               H  H  H  H   OCH.sub.3                                                                              OCH.sub.3                                                                             CH --                                           Q-9                                                                               H  H  H  H   OCH.sub.3                                                                              OCH.sub.3                                                                             N  --                                           Q-9                                                                               CH.sub.3                                                                          CH.sub.3                                                                          H  H   CH.sub.3                                                                               CH.sub.3                                                                              CH --                                           Q-9                                                                               H  H  CH.sub.3                                                                          H   CH.sub.3                                                                               OCH.sub.3                                                                             N  --                                           Q-9                                                                               H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                              OCH.sub.3                                                                             CH --                                           Q-9                                                                               H  H  CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                               OCH.sub.3                                                                             CH --                                           Q-9                                                                               H  H  H  H   Cl      OCH.sub.2 CH.sub.3                                                                    CH --                                           Q-9                                                                               H  H  H  H   OCH.sub.3                                                                              CH(OCH.sub.3).sub.2                                                                   CH --                                           Q-9                                                                               H  H  H  H   NH.sub.2                                                                               CH.sub.3                                                                              CH --                                           Q-9                                                                               H  H  H  H   NHCH(CH.sub.3).sub.2                                                                   CH.sub.3                                                                              CH --                                           Q-9                                                                               H  H  H  H   CH.sub.2 O-- -n-C.sub.4 H.sub.9                                                        CH.sub.3                                                                              CH --                                           Q-9                                                                               H  H  H  H   S-- -n-C.sub.4 H.sub.9                                                                 CH.sub.3                                                                              CH --                                           Q-9                                                                               H  H  H  H   S-- -n-CH.sub.2 CH.sub.2 F                                                             CH.sub.3                                                                              CH --                                           __________________________________________________________________________

                  TABLE 7c                                                         ______________________________________                                         General Structure 3                                                                                                        m.p.                               Q    R      R.sub.3 '                                                                             R.sub.4                                                                             X     Y        Z    W"°C.                       ______________________________________                                         Q-10 H      H      H    CH.sub.3                                                                             OCH.sub.3                                                                               CH   O                                  Q-10 H      H      H    CH.sub.3                                                                             CH.sub.3 CH   O                                  Q-10 H      H      H    OCH.sub.3                                                                            OCH.sub.3                                                                               N    O                                  Q-10 H      H      H    OCH.sub.3                                                                            Cl       CH   O                                  Q-10 H      H      H    OCH.sub.3                                                                            OCH.sub.3                                                                               CH   O                                  Q-10 H      H      H    OCH.sub.3                                                                            OCH.sub.3                                                                               N    O                                  Q-10 H      H      H    CH.sub.3                                                                             OCH.sub.3                                                                               CH   S                                  Q-10 H      H      H    CH.sub.3                                                                             OCH.sub.3                                                                               N    S                                  Q-10 H      H      H    OCH.sub.3                                                                            OCH.sub.3                                                                               CH   S                                  Q-10 H      H      H    OCH.sub.3                                                                            OCH.sub.3                                                                               N    S                                  Q-10 H      H      H    OCH.sub.3                                                                            Cl       CH   NCH.sub.3                          Q-10 H      H      H    CH.sub.3                                                                             CH.sub.3 CH   NCH.sub.3                          Q-10 H      H      H    CH.sub.3                                                                             OCH.sub.3                                                                               N    NCH.sub.3                          Q-10 H      H      H    CH.sub.3                                                                             CH.sub.3 N    NCH.sub.3                          Q-10 H      H      H    OCH.sub.3                                                                            OCH.sub.3                                                                               CH   NCH.sub.3                          Q-10 H      H      H    OCH.sub.3                                                                            OCH.sub.3                                                                               N    NCH.sub.3                          Q-10 H      CH.sub.3                                                                              H    CH.sub.3                                                                             CH.sub.3 CH   O                                  Q-10 H      H      CH.sub.3                                                                            CH.sub.3                                                                             OCH.sub.3                                                                               N    O                                  Q-10 H      CH.sub.3                                                                              CH.sub.3                                                                            CH.sub.3                                                                             OCH.sub.3                                                                               CH   O                                  Q-10 CH.sub.3                                                                              H      H    OCH.sub.3                                                                            OCH.sub.3                                                                               N    O                                  Q-10 H      H      H    CH.sub.3                                                                              ##STR147##                                                                             CH   O                                  Q-10 H      CH.sub.3                                                                              H    CH.sub.3                                                                             CH.sub.3 CH   S                                  Q-10 H      H      CH.sub.3                                                                            CH.sub.3                                                                             OCH.sub.3                                                                               N    S                                  Q-10 H      CH.sub.3                                                                              CH.sub.3                                                                            CH.sub.3                                                                             OCH.sub.3                                                                               CH   S                                  Q-10 CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            CH.sub.3                                                                             OCH.sub.3                                                                               CH   S                                  Q-10 CH.sub.3                                                                              H      H    OCH.sub.3                                                                            OCH.sub.3                                                                               N    S                                  Q-10 H      H      H    CH.sub.3                                                                             OC.sub.2 H.sub.5                                                                        CH   S                                  Q-10 H      H      CH.sub.3                                                                            CH.sub.3                                                                             CH.sub.3 N    NCH.sub.3                          Q-10 H      H      CH.sub.3                                                                            CH.sub.3                                                                             OCH.sub.3                                                                               CH   NCH.sub.3                          Q-10 H      CH.sub.3                                                                              CH.sub.3                                                                            OCH.sub.3                                                                            OCH.sub.3                                                                               N    NCH.sub.3                          Q-10 CH.sub.3                                                                              H      H    OCH.sub.3                                                                            OCH.sub. 3                                                                              N    NCH.sub.3                          Q-11 H      H      H    CH.sub.3                                                                             CH.sub.3 N    O                                  Q-11 H      H      H    CH.sub.3                                                                             CH.sub.3 CH   O                                  Q-11 H      H      H    CH.sub.3                                                                             OCH.sub.3                                                                               N    O                                  Q-11 H      H      H    CH.sub.3                                                                             OCH.sub.3                                                                               CH   O                                  Q-11 H      H      H    OCH.sub.3                                                                            OCH.sub.3                                                                               CH   O                                  Q-11 H      H      H    OCH.sub.3                                                                            OCH.sub.3                                                                               N    O                                  Q-11 H      H      H    CH.sub.3                                                                             CH.sub.3 CH   S                                  Q-11 H      H      H    CH.sub.3                                                                             OCH.sub.3                                                                               CH   S                                  Q-11 H      H      H    CH.sub.3                                                                             OCH.sub.3                                                                               CH   S                                  Q-11 H      H      H    OCH.sub.3                                                                            OCH.sub.3                                                                               CH   S                                  Q-11 H      H      H    CH.sub.3                                                                             CH.sub.3 CH   NCH.sub.3                          Q-11 H      H      H    CH.sub.3                                                                             OCH.sub.3                                                                               CH   NCH.sub.3                          Q-11 H      H      H    OCH.sub.3                                                                            OCH.sub.3                                                                               CH   NCH.sub.3                          Q-11 H      H      H    CH.sub.3                                                                             OCH.sub.3                                                                               N    NCH.sub.3                          Q-11 H      CH.sub.3                                                                              H    CH.sub.3                                                                             OCH.sub.3                                                                               N    O                                  Q-11 H      H      CH.sub.3                                                                            OCH.sub.3                                                                            OCH.sub.3                                                                               N    O                                  Q-11 H      CH.sub.3                                                                              CH.sub.3                                                                            CH.sub.3                                                                             OCH.sub.3                                                                               CH   O                                  Q-11 CH.sub.3                                                                              H      H    CH.sub.3                                                                             OCH.sub.3                                                                               CH   O                                  Q-11 H      H      H    CH.sub.3                                                                             C.sub. 2 H.sub.5                                                                        N    O                                  Q-11 H      H      H    CH.sub.3                                                                             CH.sub.2 OCH.sub.3                                                                      CH   O                                  Q-11 H      CH.sub.3                                                                              H    CH.sub.3                                                                             OCH.sub.3                                                                               N    S                                  Q-11 H      H      CH.sub.3                                                                            OCH.sub.3                                                                            OCH.sub.3                                                                               N    S                                  Q-11 H      CH.sub.3                                                                              CH.sub.3                                                                            CH.sub.3                                                                             OCH.sub.3                                                                               CH   S                                  Q-11 CH.sub.3                                                                              H      H    CH.sub.3                                                                             OCH.sub.3                                                                               CH   S                                  Q-11 H      H      H    CH.sub.3                                                                             C.sub.2 H.sub.5                                                                         N    S                                  Q-11 CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            CH.sub.3                                                                             OCH.sub.3                                                                               N    S                                  Q-11 H      H      H    Cl    OCH.sub.3                                                                               CH   S                                  Q-11 H      CH.sub.3                                                                              H    CH.sub.3                                                                             CH.sub.3 CH   NCH.sub.3                          Q-11 H      H      CH.sub.3                                                                            CH.sub.3                                                                             OCH.sub.3                                                                               N    NCH.sub.3                          Q-11 H      CH.sub.3                                                                              CH.sub.3                                                                            CH.sub.3                                                                             OCH.sub.3                                                                               CH   NCH.sub.3                          Q-11 CH.sub.3                                                                              H      H    OCH.sub.3                                                                            OCH.sub.3                                                                               N    NH                                 Q-11 H      H      H    CH.sub.3                                                                             OCH.sub.3                                                                               CH   NH                                 Q-11 H      H      H    OCH.sub.3                                                                            OCH.sub.3                                                                               CH   O*                                 Q-11 H      H      H    OCH.sub.3                                                                            CH       N    O*                                 Q-11 H      H      H    CH.sub.3                                                                             OCH.sub.3                                                                               N    NCH.sub.3                          Q-11 H      H      H    CH.sub.3                                                                             OCF.sub.3 H                                                                             CH   NCH.sub.3                          Q-11 H      CH.sub.3                                                                              H    OCH.sub.3                                                                            OCH.sub.2 CF.sub.3                                                                      N    NCH.sub.3                          Q-12 H      H      H    CH.sub.3                                                                             OCH.sub.3                                                                               CH   O                                  Q-12 H      H      H    CH.sub.3                                                                             OCH.sub.3                                                                               N    O                                  Q-12 H      H      H    OCH.sub.3                                                                            OCH.sub.3                                                                               CH   O                                  Q-12 H      H      H    OCH.sub.3                                                                            OCH.sub.3                                                                               N    O                                  Q-12 H      H      H    CH.sub.3                                                                             OCH.sub.3                                                                               CH   S                                  Q-12 H      H      H    CH.sub.3                                                                             OCH.sub.3                                                                               N    S                                  Q-12 H      H      H    OCH.sub.3                                                                            OCH.sub.3                                                                               CH   S                                  Q-12 H      H      H    OCH.sub.3                                                                            OCH.sub.3                                                                               N    S                                  Q-12 H      H      H    CH.sub.3                                                                             CH.sub.3 N    NCH.sub.3                          Q-12 H      H      H    CH.sub.3                                                                             OCH.sub.3                                                                               CH   NCH.sub.3                          Q-12 H      H      H    CH.sub.3                                                                             OCH.sub.3                                                                               N    NCH.sub.3                          Q-12 H      H      H    OCH.sub.3                                                                            OCH.sub.3                                                                               CH   NCH.sub.3                          Q-12 H      H      H    OCH.sub.3                                                                            OCH.sub.3                                                                               N    NCH.sub.3                          Q-12 H      H      H    OCH.sub.3                                                                            OCH.sub.3                                                                               N    NH                                 Q-12 H      CH.sub.3                                                                              H    CH.sub.3                                                                             CH.sub.3 CH   O                                  Q-12 H      H      CH.sub.3                                                                            CH.sub.3                                                                             OCH.sub.3                                                                               N    O                                  Q-12 H      CH.sub.3                                                                              CH.sub.3                                                                            CH.sub.3                                                                             OCH.sub.3                                                                               CH   O                                  Q-12 CH.sub.3                                                                              H      H    OCH.sub.3                                                                            OCH.sub.3                                                                               N    O                                  Q-12 CH.sub.3                                                                              H      H    CH.sub.3                                                                             CF.sub.3 CH   O                                  Q-12 H      H      H    OCH.sub.3                                                                            OCH.sub.2 CF.sub.3                                                                      N                                       Q-12 H      CH.sub.3                                                                              H    CH.sub.3                                                                             OCH.sub.3                                                                               CH   S                                  Q-12 H      H      CH.sub.3                                                                            CH.sub.3                                                                             OCH.sub.3                                                                               N    S                                  Q-12 H      CH.sub.3                                                                              CH.sub.3                                                                            OCH.sub.3                                                                            OCH.sub.3                                                                               CH   S                                  Q-12 CH.sub.3                                                                              H      H    OCH.sub.3                                                                            OCH.sub.3                                                                               N    S                                  Q-12 CH.sub.3                                                                              CH.sub.3                                                                              H    CH.sub.3                                                                             NHCH.sub.3                                                                              CH   S                                  Q-12 H      H      H    Br    OC.sub.2 H.sub.5                                                                        CH   S                                  Q-12 H      CH.sub.3                                                                              H    CH.sub.3                                                                             CH.sub.3 CH   NH                                 Q-12 H      CH.sub.3                                                                              H    CH.sub.3                                                                             CH.sub.3 CH   NCH.sub.3                          Q-12 H      H      CH.sub.3                                                                            CH.sub.3                                                                             OCH.sub.3                                                                               N    NCH.sub.3                          Q-12 H      CH.sub.3                                                                              CH.sub.3                                                                            CH.sub.3                                                                             CH.sub.3 CH.sub.3                                                                            NCH.sub.3                          Q-12 CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            CH.sub.3                                                                             OCH.sub.3                                                                               N    NCH.sub.3                          Q-12 CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            CH.sub.3                                                                             OCH.sub.3                                                                               CH   NCH.sub.3                          Q-12 H      H      H    Br    OCH.sub.3                                                                               CH   NCH.sub.3                          Q-12 H      H      H    OCH.sub.3                                                                            N(CH.sub.3).sub.2                                                                       CH   NCH.sub.3                          Q-13 H      H      H    CH.sub.3                                                                             OCH.sub.3                                                                               CH   O                                  Q-13 H      H      H    CH.sub.3                                                                             OCH.sub.3                                                                               CH   O                                  Q-13 H      H      H    CH.sub.3                                                                             CH.sub.3 CH   O                                  Q-13 H      H      H    CH.sub.3                                                                             OCH.sub.3                                                                               N    O                                  Q-13 H      H      H    OCH.sub.3                                                                            OCH.sub.3                                                                               CH   O                                  Q-13 H      H      H    CH.sub.3                                                                             CH.sub.3 N    O                                  Q-13 H      H      H    OCH.sub.3                                                                            OCH.sub.3                                                                               N    O                                  Q-13 H      H      H    CH.sub.3                                                                             OCH.sub.3                                                                               CH   S                                  Q-13 H      H      H    CH.sub.3                                                                             OCH.sub.3                                                                               N    S                                  Q-13 H      H      H    OCH.sub.3                                                                            OCH.sub.3                                                                               CH   S                                  Q-13 H      H      H    OCH.sub.3                                                                            OCH.sub.3                                                                               N    S                                  Q-13 H      H      H    CH.sub.3                                                                             OCH.sub.3                                                                               CH   NH                                 Q-13 H      H      H    CH.sub.3                                                                             OCH.sub.3                                                                               N    NH                                 Q-13 H      H      H    OCH.sub.3                                                                            OCH.sub.3                                                                               CH   NCH.sub.3                          Q-13 H      H      H    OCH.sub.3                                                                            OCH.sub.3                                                                               N    NH                                 Q-13 H      CH.sub.3                                                                              H    CH.sub.3                                                                             CH.sub.3 CH   O                                  Q-13 H      H      CH.sub.3                                                                            CH.sub.3                                                                             CH.sub.3 N    O                                  Q-13 H      CH.sub.3                                                                              CH.sub.3                                                                            CH.sub.3                                                                             OCH.sub.3                                                                               CH   O                                  Q-13 CH.sub.3                                                                              H      H    CH.sub.3                                                                             OCH.sub.3                                                                               N    O                                  Q-13 H      H      H    CH.sub.3                                                                             CH(OCH.sub.3).sub.2                                                                     CH   O                                  Q-13 H      CH.sub.3                                                                              H    CH.sub.3                                                                             OCH.sub.3                                                                               CH   S                                  Q-13 H      H      CH.sub.3                                                                            CH.sub.3                                                                             OCH.sub.3                                                                               CH   S                                  Q-13 H      CH.sub.3                                                                              CH.sub.3                                                                            CH.sub.3                                                                             OCH.sub.3                                                                               N    S                                  Q-13 CH.sub.3                                                                              H      CH.sub.3                                                                            OCH.sub.3                                                                            OCH.sub.3                                                                               N    S                                  Q-13 CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            CH.sub.3                                                                             CH.sub.3 N    S                                                                O                                                Q-13 H      H      H    OCH.sub.3                                                                            O        CH   S                                  Q-13 H      CH.sub.3                                                                              H    CH.sub.3                                                                             OCH.sub.3                                                                               N    NCH.sub.3                          Q-13 H      H      CH.sub.3                                                                            CH.sub.3                                                                             OCH.sub.3                                                                               N    NCH.sub.3                          Q-13 H      CH.sub.3                                                                              CH.sub.3                                                                            CH.sub.3                                                                             OCH.sub.3                                                                               CH   NCH.sub.3                          Q-13 CH.sub.3                                                                              H      H    OCH.sub.3                                                                            OCH.sub.3                                                                               CH   NCH.sub.3                          Q-13 H      H      H    CH.sub.3                                                                             OCH.sub.3                                                                               N    NH                                 Q-13 H      H      H    Br    OC.sub.2 H.sub.5                                                                        CH   NH                                 Q-13 H      H      H    OCH.sub.3                                                                            C.sub.2 H.sub.5                                                                         N    NH                                 Q-13 H      H      H    CH.sub.3                                                                             CH.sub.3 CH   NCH.sub.3                          Q-13 H      H      H    CH.sub.3                                                                             CH.sub.3 N    NCH.sub.3                          Q-13 H      H      H    Cl    OCH.sub.3                                                                               CH   NCH.sub.3                          Q-14 H      H      H    CH.sub.3                                                                             CH.sub.3 N    O                                  Q-14 H      H      H    CH.sub.3                                                                             CH.sub.3 CH   O                                  Q-14 H      H      H    CH.sub.3                                                                             OCH.sub.3                                                                               CH   O                                  Q-14 H      H      H    CH.sub.3                                                                             OCH.sub.3                                                                               CH   O                                  Q-14 H      H      H    CH.sub.3                                                                             OCH.sub.3                                                                               N    O                                  Q-14 H      H      H    OCH.sub.3                                                                            OCH.sub.3                                                                               CH   O                                  Q-14 H      H      H    CH.sub.3                                                                             OCH.sub.3                                                                               CH   S                                  Q-14 H      H      H    CH.sub.3                                                                             OCH.sub.3                                                                               N    S                                  Q-14 H      H      H    OCH.sub.3                                                                            OCH.sub.3                                                                               CH   S                                  Q-14 H      H      H    OCH.sub.3                                                                            OCH.sub.3                                                                               CH   S                                  Q-14 H      H      H    OCH.sub.3                                                                            OCH.sub.3                                                                               N    S                                  Q-14 H      H      H    CH.sub.3                                                                             OCH.sub.3                                                                               CH   NCH.sub.3                          Q-14 H      H      H    CH.sub.3                                                                             OCH.sub.3                                                                               N    NCH.sub.3                          Q-14 H      H      H    OCH.sub.3                                                                            OCH.sub.3                                                                               CH   NH                                 Q-14 H      H      H    OCH.sub.3                                                                            OCH.sub.3                                                                               N    NCH.sub.3                          Q-14 H      CH.sub.3                                                                              H    CH.sub.3                                                                             CH.sub.3 CH   O                                  Q-14 H      H      CH.sub.3                                                                            CH.sub.3                                                                             CH.sub.3 N    O                                  Q-14 H      CH.sub.3                                                                              CH.sub.3                                                                            CH.sub.3                                                                             OCH.sub.3                                                                               CH   O                                  Q-14 CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            CH.sub.3                                                                             OCH.sub.3                                                                               N    O                                  Q-14 H      H      H    CH.sub.3                                                                             C.sub.2 H.sub.5                                                                         N    O                                  Q-14 H      H      H    CH.sub.3                                                                             OC.sub.2 H.sub.5                                                                        N    O                                  Q-14 H      CH.sub.3                                                                              H    CH.sub.3                                                                             OCH.sub.3                                                                               CH   S                                  Q-14 H      H      CH.sub.3                                                                            CH.sub.3                                                                             OCH.sub.3                                                                               N    S                                  Q-14 H      CH.sub.3                                                                              CH.sub.3                                                                            OCH.sub.3                                                                            OCH.sub.3                                                                               CH   S                                  Q-14 CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            OCH.sub.3                                                                            OCH.sub.3                                                                               CH   S                                  Q-14 H      H      H    OCH.sub.3                                                                            C.sub.2 H.sub.5                                                                         N    S                                  Q-14 H      H      H    OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                        N    S                                  Q-14 H      CH.sub.3                                                                              H    CH.sub.3                                                                             OCH.sub.3                                                                               CH   NCH.sub.3                          Q-14 H      H      CH.sub.3                                                                            CH.sub.3                                                                             OCH.sub.3                                                                               N    NCH.sub.3                          Q-14 H      CH.sub.3                                                                              CH.sub.3                                                                            OCH.sub.3                                                                            OCH.sub.3                                                                               CH   NCH.sub.3                          Q-14 CH.sub.3                                                                              CH.sub.3                                                                              H    OCH.sub.3                                                                            OCH.sub.3                                                                               N    NCH.sub.3                          Q-14 H      CH.sub.3                                                                              CH.sub.3                                                                            CH.sub.3                                                                             OCH.sub.3                                                                               CH   NH                                 Q-14 H      H      H    CH.sub.3                                                                             OCH.sub.3                                                                               N    NH                                 Q-14 H      H      H    CH.sub.3                                                                             CH.sub.2 OCH.sub.3                                                                      CH   NCH.sub.3                          Q-15 H      H      H    CH.sub.3                                                                             OCH.sub.3                                                                               CH   O                                  Q-15 H      H      H    CH.sub.3                                                                             OCH.sub.3                                                                               N    O                                  Q-15 H      H      H    OCH.sub.3                                                                            OCH.sub.3                                                                               CH   O                                  Q-15 H      H      H    OCH.sub.3                                                                            OCH.sub.3                                                                               N    O                                  Q-15 H      C.sub.2 H.sub.5                                                                       H    OCH.sub.3                                                                            OCH.sub.3                                                                               CH   O                                  Q-15 H      CH.sub.3                                                                              H    CH.sub.3                                                                             OCH.sub.3                                                                               CH   O                                  Q-15 H      CH.sub.3                                                                              H    CH.sub.3                                                                             CH.sub.3 CH   O                                  Q-15 H      CH.sub.3                                                                              H    OCH.sub.3                                                                            OCH.sub.3                                                                               CH   O                                  Q-15 H      H      CH.sub.3                                                                            CH.sub.3                                                                             CH.sub.3 N    O                                  Q-15 H      CH.sub.3                                                                              H    CH.sub.3                                                                             OCH.sub.3                                                                               N    O                                  Q-15 H      CH.sub.3                                                                              CH.sub.3                                                                            CH.sub.3                                                                             OCH.sub.3                                                                               CH   O                                  Q-15 H      CH.sub.3                                                                              H    OCH.sub.3                                                                            OCH.sub.3                                                                               N    O                                  Q-15 CH.sub.3                                                                              H      H    CH.sub.3                                                                             OCH.sub.3                                                                               N    O                                  Q-15 H      CH.sub.3                                                                              H    OCH.sub.3                                                                            Cl       CH   O                                  Q-15 CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            OCH.sub.3                                                                            OCH.sub.3                                                                               CH   O                                  Q-15 H      H      H    CH.sub.3                                                                             CF.sub.3 CH   O                                  Q-15 H      H      H    CH.sub.3                                                                             CF.sub.3 N    O                                  Q-15 H      H      H    OCH.sub.3                                                                            OCF.sub.3 H                                                                             CH   O                                  Q-15 CH.sub.3                                                                              H      H    OCH.sub.3                                                                            OCF.sub.2 H                                                                             CH   O                                  Q-15 H      H      H    CH.sub.3                                                                             CH.sub.3 CH   O                                  Q-15 H      H      H    CH.sub.3                                                                             CH.sub.3 N    O                                  Q-15 H      H      H    OCH.sub.3                                                                            OCH.sub.3                                                                               CH   O*                                 Q-15 H      H      H    OCH.sub.3                                                                            CH.sub.3 N    O*                                 Q-15 H      H      H    CH.sub.3                                                                             CH.sub.3 N    S                                  Q-15 H      CH.sub.3                                                                              H    CH.sub.3                                                                             OCH.sub.3                                                                               CH   S                                  Q-15 H      CH.sub.3                                                                              H    CH.sub.3                                                                             OCH.sub.3                                                                               N    S                                  Q-15 H      CH.sub.3                                                                              H    OCH.sub.3                                                                            OCH.sub.3                                                                               CH   S                                  Q-15 H      CH.sub.3                                                                              H    OCH.sub.3                                                                            OCH.sub.3                                                                               N    S                                  Q-15 H      CH.sub.3                                                                              H    Cl    OCH.sub.3                                                                               CH   S                                  Q-15 H      H      H    CH.sub.3                                                                             OCH.sub.3                                                                               CH   NCH.sub.3                          Q-15 H      H      H    CH.sub.3                                                                             OCH.sub.3                                                                               N    NCH.sub.3                          Q-15 H      H      H    OCH.sub.3                                                                            OCH.sub.3                                                                               CH   NCH.sub.3                          Q-15 H      H      H    OCH.sub.3                                                                            OCH.sub.3                                                                               N    NCH.sub.3                          Q-15 H      CH.sub.3                                                                              H    CH.sub.3                                                                             CH.sub.3 CH   S                                  Q-15 H      H      CH.sub.3                                                                            CH.sub.3                                                                             CH.sub.3 N    S                                  Q-15 H      CH.sub.3                                                                              CH.sub.3                                                                            CH.sub.3                                                                             OCH.sub.3                                                                               CH   S                                  Q-15 CH.sub.3                                                                              H      H    CH.sub.3                                                                             OCH.sub.3                                                                               N    S                                  Q-15 CH.sub.3                                                                              H      CH.sub.3                                                                            OCH.sub.3                                                                            OCH.sub.3                                                                               CH   S                                  Q-15 H      H      H    Cl    OC.sub.2 H.sub.5                                                                        CH   S                                  Q-15 H      H      H    OCH.sub.3                                                                            OCH.sub.2 CF.sub.3                                                                      CH   S                                  Q-15 H      CH.sub.3                                                                              H    CH.sub.3                                                                             CH.sub.3 CH   NCH.sub.3                          Q-15 H      H      CH.sub.3                                                                            CH.sub.3                                                                             OCH.sub.3                                                                               CH   NCH.sub.3                          Q-15 H      CH.sub.3                                                                              CH.sub.3                                                                            CH.sub.3                                                                             OCH.sub.3                                                                               N    NCH.sub.3                          Q-15 CH.sub.3                                                                              CH.sub.3                                                                              CH.sub.3                                                                            CH.sub.3                                                                             OCH.sub.3                                                                               N    NCH.sub.3                          Q-15 CH.sub.3                                                                              H      H    CH.sub.3                                                                             OCH.sub.3                                                                               CH   NH                                 Q-15 H      H      H    OCH.sub.3                                                                            OCH.sub.3                                                                               N    NH                                 Q-15 H      H      H    CH.sub.3                                                                             NHCH.sub.3                                                                              CH   NCH.sub.3                          Q-15 H      H      H    OCH.sub.3                                                                            N(CH.sub.3).sub.2                                                                       CH   NCH.sub.3                          Q-15 H      H      H    CH.sub.3                                                                             OCH.sub.2 CCH                                                                           N    S                                  Q-15 H      H      H    CH.sub.3                                                                             CH.sub.2 CCH.sub.3                                                                      CH   S                                  Q-15 H      H      H    CH.sub.3                                                                             CCH      N    S                                  Q-15 H      C.sub.2 H.sub.5                                                                       H    OCH.sub.3                                                                            OCH.sub.3                                                                               CH   S                                  Q-15 H      H      H    OCH.sub.3                                                                            (CH.sub.2).sub.3 CH.sub.2 F                                                             CH   S                                  Q-15 H      H      H    OCH.sub.3                                                                            2-methyl-1,3,                                                                           N    S                                                                dioxolan-2-yl                                    Q-15 H      H      H    OCH.sub.3                                                                            2-methyl-1,3-                                                                           CH   S                                                                dithiolan-2-yl                                   Q-15 H      H      H    OCH.sub.3                                                                            2-methyl-1,3-                                                                           N    S                                                                dithian-2-yl                                     Q-15 H      H      H    OCH.sub.3                                                                            OCH.sub.3                                                                               CH   S*                                 Q-15 H      H      H    OCH.sub.3                                                                            CH.sub.3 N    S*                                 ______________________________________                                    

                  TABLE 7d                                                         ______________________________________                                         General Structure 3                                                                                                            m.p.                           Q    R      R.sub.3                                                                               R.sub.4                                                                             R.sub.5                                                                             X     Y        Z   °C.                     ______________________________________                                         Q-18 H      H      H    H    CH.sub.3                                                                             CH.sub.3 CH                                 Q-18 H      H      H    H    CH.sub.3                                                                             OCH.sub.3                                                                               CH                                 Q-18 H      H      H    H    CH.sub.3                                                                             OCH.sub.3                                                                               N                                  Q-18 CH.sub.3                                                                              H      H    H    CH.sub.3                                                                             OCH.sub.3                                                                               N                                  Q-18 H      H      H    H    OCH.sub.3                                                                            OCH.sub.3                                                                               CH                                 Q-18 H      H      H    H    CH.sub.3                                                                             CH.sub.3 CH                                 Q-18 H      H      H    H    OCH.sub.3                                                                            OCH.sub.3                                                                               N                                  Q-18 H      H      H    H    Cl    OCH.sub.3                                                                               CH                                 Q-18 H      CH.sub.3                                                                              H    H    CH.sub.3                                                                             OCH.sub.3                                                                               CH                                 Q-18 H      H      CH.sub.3                                                                            H    CH.sub.3                                                                             OCH.sub.3                                                                               N                                  Q-18 H      H      H    CH.sub.3                                                                            CH.sub.3                                                                             CH.sub.3 CH                                 Q-18 H      CH.sub.3                                                                              CH.sub.3                                                                            H    CH.sub.3                                                                             CH.sub.3 N                                  Q-18 H      H      CH.sub.3                                                                            CH.sub.3                                                                            OCH.sub.3                                                                            OCH.sub.3                                                                               CH                                 Q-18 H      CH.sub.3                                                                              H    CH.sub.3                                                                            OCH.sub.3                                                                            OCH.sub.3                                                                               N                                  Q-18 H      CH.sub.3                                                                              CH.sub.3                                                                            CH.sub.3                                                                            CH.sub.3                                                                             OCH.sub.3                                                                               CH                                 Q-18 H      H      H    H    OCH.sub.3                                                                            CH(OCH.sub.3).sub.2                                                                     CH                                 Q-19 CH.sub.3                                                                              H      H    H    Cl    OCH.sub.3                                                                               CH                                 Q-19 H      H      H    H    CH.sub.3                                                                             OCH.sub.3                                                                               CH                                 Q-19 H      H      H    H    CH.sub.3                                                                             OCH.sub.3                                                                               N                                  Q-19 H      H      H    H    OCH.sub.3                                                                            OCH.sub.3                                                                               CH                                 Q-19 H      H      H    H    OCH.sub.3                                                                            OCH.sub.3                                                                               N                                  Q-19 H      CH.sub.3                                                                              H    H    CH.sub.3                                                                             CH.sub.3 CH                                 Q-19 H      H      CH.sub.3                                                                            H    CH.sub.3                                                                             CH.sub.3 N                                  Q-19 H      H      H    CH.sub.3                                                                            CH.sub.3                                                                             OCH.sub.3                                                                               CH                                 Q-19 H      CH.sub.3                                                                              CH.sub.3                                                                            H    CH.sub.3                                                                             OCH.sub.3                                                                               N                                  Q-19 H      H      CH.sub.3                                                                            CH.sub.3                                                                            OCH.sub.3                                                                            OCH.sub.3                                                                               CH                                 Q-19 H      CH.sub.3                                                                              H    CH.sub.3                                                                            OCH.sub.3                                                                            OCH.sub.3                                                                               N                                  Q-19 H      H      H    H    CH.sub.3                                                                             CH.sub.3 CH                                 Q-19 H      CH.sub.3                                                                              CH.sub.3                                                                            CH.sub.3                                                                            CH.sub.3                                                                             OCH.sub.3                                                                               CH                                 Q-19 CH.sub.3                                                                              H      H    H    CH.sub.3                                                                             OCH.sub.3                                                                               N                                                                     O                                           Q-19 H      H      H    H    OCH.sub.3      CH                                                                    O                                           ______________________________________                                    

                                      TABLE 7e                                     __________________________________________________________________________     General Structure 3                                                                                                   m.p.                                    Q   R   R.sub.3 ',"                                                                             X    Y        Z   W'  °C.                              __________________________________________________________________________     Q-21                                                                               H   H        CH.sub.3                                                                            OCH.sub.3                                                                               CH  O                                           Q-21                                                                               H   H        CH.sub.3                                                                            OCH.sub.3                                                                               N   O                                           Q-21                                                                               H   H        OCH.sub.3                                                                           OCH.sub.3                                                                               CH  O                                           Q-21                                                                               CH.sub.3                                                                           H        OCH.sub.3                                                                           OCH.sub.3                                                                               CH  O                                           Q-21                                                                               H   H        OCH.sub.3                                                                           NHCH.sub.3                                                                              CH  O                                           Q-21                                                                               H   H        OCH.sub.3                                                                           OCH.sub.3                                                                               N   O                                           Q-21                                                                               H   CH.sub.3 CH.sub.3                                                                            OCH.sub.3                                                                               CH  O                                           Q-21                                                                               CH.sub.3                                                                           CH.sub.3 CH.sub.3                                                                            OCH.sub.3                                                                               CH  O                                           Q-21                                                                               H   H        CH.sub.3                                                                            CH.sub.3 CH  O                                           Q-21                                                                               H   H        CH.sub.3                                                                            CH.sub.3 N   O                                           Q-21                                                                               H   H        CH.sub.3                                                                            OCH.sub.3                                                                               CH  S                                           Q-21                                                                               H   H        CH.sub.3                                                                            OCH.sub.3                                                                               N   S                                           Q-21                                                                               H   H        OCH.sub.3                                                                           OCH.sub.3                                                                               CH  S                                           Q-21                                                                               H   H        OCH.sub.3                                                                           OCH.sub.3                                                                               N   S                                           Q-21                                                                               H   CH.sub.3 CH.sub.3                                                                            OCH.sub.3                                                                               CH  S                                           Q-21                                                                               CH.sub.3                                                                           H        CH.sub.3                                                                            OCH.sub.3                                                                               CH  S                                           Q-21                                                                               H   H        OCH.sub. 3                                                                          N(CH.sub.3).sub.2                                                                       N   S                                           Q-22                                                                               H   H        CH.sub.3                                                                            OCH.sub.3                                                                               CH  O                                           Q-22                                                                               H   H        CH.sub.3                                                                            OCH.sub.3                                                                               N   O                                           Q-22                                                                               H   H        OCH.sub.3                                                                           OCH.sub.3                                                                               CH  O                                           Q-22                                                                               H   H        OCH.sub.3                                                                           OCH.sub.3                                                                               N   O                                           Q-22                                                                               H   CH.sub.3 CH.sub.3                                                                            OCH.sub.3                                                                               CH  O                                           Q-22                                                                               H   CH.sub.3 CH.sub.3                                                                            OCH.sub.3                                                                               N   O                                           Q-22                                                                               CH.sub.3                                                                           CH.sub.3 CH.sub.3                                                                            CH.sub.3 CH  O                                           Q-22                                                                               H   H        CH.sub.3                                                                            CH(OCH.sub.3).sub.2                                                                     CH  O                                           Q-22                                                                               H   H        CH.sub.3                                                                            C.sub.2 H.sub.5                                                                         N   O                                           Q-22                                                                               H   H        CH.sub.3                                                                            CH.sub.3 CH  S                                           Q-22                                                                               H   H        CH.sub.3                                                                            CH.sub.3 N   S                                           Q-22                                                                               H   H        CH.sub.3                                                                            OCH.sub.3                                                                               CH  S                                           Q-22                                                                               H   H        CH.sub.3                                                                            OCH.sub.3                                                                               N   S                                           Q-22                                                                               H   H        OCH.sub.3                                                                           OCH.sub.3                                                                               CH  S                                           Q-22                                                                               H   H        OCH.sub.3                                                                           OCH.sub.3                                                                               N   S                                           Q-22                                                                               H   CH.sub.3 CH.sub.3                                                                            OCH.sub.3                                                                               CH  S                                           Q-22                                                                               CH.sub.3                                                                           CH.sub.3 CH.sub.3                                                                            OCH.sub.3                                                                               CH  S                                           Q-22                                                                               CH.sub.3                                                                           H        CH.sub.3                                                                            OCH.sub.3                                                                               N   S                                           Q-22                                                                               H   H        CH.sub.3                                                                             ##STR148##                                                                             CH  S                                           Q-22                                                                               H   H        OCH.sub.3                                                                           C.sub.2 H.sub.5                                                                         N   S                                           Q-23                                                                               H   H        CH.sub.3                                                                            OCH.sub.3                                                                               CH  --                                          Q-23                                                                               H   H        CH.sub.3                                                                            OCH.sub.3                                                                               N   --                                          Q-23                                                                               H   H        OCH.sub.3                                                                           OCH.sub.3                                                                               CH  --                                          Q-23                                                                               H   H        OCH.sub.3                                                                           OCH.sub.3                                                                               N   --                                          Q-23                                                                               H   CH.sub.3 CH.sub.3                                                                            CH.sub.3 CH  --                                          Q-23                                                                               H   CH.sub.3 CH.sub.3                                                                            OCH.sub.3                                                                               N   --                                          Q-23                                                                               CH.sub.3                                                                           H        CH.sub.3                                                                            OCH.sub.3                                                                               N   --                                          Q-23                                                                               CH.sub.3                                                                           CH.sub.3 CH.sub.3                                                                            OCH.sub.3                                                                               CH  --                                          Q-23                                                                               H   H        CH.sub.3                                                                            OC.sub.2 H.sub.5                                                                        N   --                                          Q-23                                                                               H   H        CH.sub.3                                                                            CH.sub.2 OCH.sub.3                                                                      CH  --                                          Q-24                                                                               H   H        CH.sub.3                                                                            OCH.sub.3                                                                               CH  --                                          Q-24                                                                               H   H        CH.sub.3                                                                            OCH.sub.3                                                                               N   --                                          Q-24                                                                               H   H        OCH.sub.3                                                                           OCH.sub.3                                                                               CH  --                                          Q-24                                                                               H   H        OCH.sub.3                                                                           OCH.sub.3                                                                               N   --                                          Q-24                                                                               H   CH.sub.3 CH.sub.3                                                                            OCH.sub.3                                                                               CH  --                                          Q-24                                                                               H   CH.sub.3 CH.sub.3                                                                            CH.sub.3 CH  --                                          Q-24                                                                               CH.sub.3                                                                           H        CH.sub.3                                                                            CH.sub.3 N   --                                          Q-24                                                                               H   H        CH.sub.3                                                                            CF.sub.3 CH  --                                          Q-24                                                                               H   H        OCH.sub.3                                                                           OCF.sub.2 H                                                                             N   --                                          Q-25                                                                               H   H        CH.sub.3                                                                            OCH.sub.3                                                                               CH  -- **                                       Q-25                                                                               H   H        CH.sub.3                                                                            OCH.sub.3                                                                               N   -- **                                       Q-25                                                                               H   H        OCH.sub.3                                                                           OCH.sub.3                                                                               CH  -- **                                       Q-25                                                                               H   H        OCH.sub.3                                                                           OCH.sub.3                                                                               N   -- **                                       Q-25                                                                               CH.sub.3                                                                           H        OCH.sub.3                                                                           OCH.sub.3                                                                               N   -- **                                       Q-25                                                                               H   H        CH.sub.3                                                                            CH.sub.3 CH  -- **                                       Q-25                                                                               H   H        CH.sub.3                                                                            CH.sub.3 N   -- **                                       Q-25                                                                               H   CH.sub.3 CH.sub.3                                                                            OCH.sub.3                                                                               CH  -- **                                       Q-25                                                                               H   CH.sub.3 CH.sub.3                                                                            OCH.sub.3                                                                               N   -- **                                       Q-25                                                                               CH.sub.3                                                                           CH.sub.3 OCH.sub.3                                                                           OCH.sub.3                                                                               N   -- **                                       Q-25                                                                               H   H        CH.sub.3                                                                            OCH.sub.2 CF.sub.3                                                                      CH  -- **                                       Q-25                                                                               H   H        CH.sub.3                                                                            NHCH.sub.3                                                                              N   -- **                                       Q-26                                                                               H   H        CH.sub.3                                                                            OCH.sub.3                                                                               CH  -- **                                       Q-26                                                                               H   H        CH.sub.3                                                                            OCH.sub.3                                                                               N   -- **                                       Q-26                                                                               H   H        OCH.sub.3                                                                           OCH.sub.3                                                                               CH  -- **                                       Q-26                                                                               H   CH.sub.3 CH.sub.3                                                                            CH.sub. 3                                                                               N   -- **                                       Q-26                                                                               H   CH.sub.3 CH.sub.3                                                                            CH.sub.3 CH  -- **                                       Q-26                                                                               H   CH.sub.3 CH.sub.3                                                                            OCH.sub.3                                                                               N   -- **                                       Q-26                                                                               H   CH.sub.3 CH.sub.3                                                                            OCH.sub.3                                                                               CH  -- **                                       Q-26                                                                               H   CH.sub.3 CH.sub.3                                                                            OCH.sub.3                                                                               N   -- **                                       Q-26                                                                               H   H        CH.sub.3                                                                            CH.sub.3 CH  -- **                                       Q-26                                                                               H   H        CH.sub.3                                                                            CH.sub.3 N   -- **                                       Q-26                                                                               H   CH.sub.3 OCH.sub.3                                                                           OCH.sub.3                                                                               CH  -- **                                       Q-26                                                                               H   CH.sub.3 OCH.sub.3                                                                           OCH.sub.3                                                                               N   -- **                                       Q-26                                                                               CH.sub.3                                                                           H        CH.sub.3                                                                            OCH.sub.3                                                                               CH  -- **                                       Q-26                                                                               H   H        CH.sub.3                                                                            N(CH.sub.3).sub.2                                                                       CH  -- **                                       Q-26                                                                               H   H        CH.sub.3                                                                            N(CH.sub.3).sub.2                                                                       N   -- **                                       Q-27                                                                               H   H        CH.sub.3                                                                            OCH.sub.3                                                                               CH  -- **                                       Q-27                                                                               H   H        CH.sub.3                                                                            OCH.sub.3                                                                               N   -- **                                       Q-27                                                                               H   H        OCH.sub.3                                                                           OCH.sub.3                                                                               CH  -- **                                       Q-27                                                                               H   H        OCH.sub.3                                                                           OCH.sub.3                                                                               N   -- **                                       Q-27                                                                               H   H        CH.sub.3                                                                            CH.sub.3 CH  -- **                                       Q-27                                                                               H   H        CH.sub.3                                                                            CH.sub.3 N   -- **                                       Q-27                                                                               H   CH.sub.3 CH.sub.3                                                                            CH.sub.3 CH  -- **                                       Q-27                                                                               H   H        Cl   OC.sub.2 H.sub.5                                                                        CH  -- **                                       Q-27                                                                               H   CH.sub.3 CH.sub.3                                                                            CH.sub.3 N   -- **                                       Q-27                                                                               H   CH.sub.3 CH.sub.3                                                                            OCH.sub.3                                                                               CH  -- **                                       Q-27                                                                               H   CH.sub.3 CH.sub.3                                                                            OCH.sub.3                                                                               N   -- **                                       Q-27                                                                               H   CH.sub.3 OCH.sub.3                                                                           OCH.sub.3                                                                               CH  -- **                                       Q-27                                                                               H   CH.sub.3 OCH.sub.3                                                                           OCH.sub.3                                                                               N   -- **                                       Q-27                                                                               CH.sub.3                                                                           CH.sub.3 CH.sub.3                                                                            OCH.sub.3                                                                               N   -- **                                       Q-27                                                                               CH.sub.3                                                                           H        CH.sub.3                                                                            OCH.sub.3                                                                               N   -- **                                       Q-27                                                                               H   H        CH.sub.3                                                                            CH(OCH.sub.3).sub.2                                                                     CH  -- **                                       Q-27                                                                               H   H        CH.sub.3                                                                            O(CH.sub.2).sub.3 CH.sub.2 Cl                                                           CH  -- **                                       Q-25                                                                               H   SH       CH.sub.3                                                                            CH.sub.3 CH  -- **                                       Q-25                                                                               H   SH       CH.sub.3                                                                            OCH.sub.3                                                                               CH  -- **                                       Q-25                                                                               H   SH       OCH.sub.3                                                                           OCH.sub.3                                                                               CH  -- **                                       Q-25                                                                               H   SH       OCH.sub.3                                                                           Cl       CH  -- **                                       Q-25                                                                               H   SH       CH.sub.3                                                                            OCH.sub.3                                                                               N   -- **                                       Q-25                                                                               H   SH       OCH.sub.3                                                                           OCH.sub.3                                                                               N   -- **                                       Q-25                                                                               H   SCH.sub.3                                                                               CH.sub.3                                                                            CH.sub.3 CH  -- **                                       Q-25                                                                               H   SCH.sub.3                                                                               CH.sub.3                                                                            OCH.sub.3                                                                               CH  -- **                                       Q-25                                                                               H   SCH.sub.3                                                                               OCH.sub.3                                                                           OCH.sub.3                                                                               CH  -- **                                       Q-25                                                                               H   SCH.sub.3                                                                               OCH.sub.3                                                                           Cl       CH  -- **                                       Q-25                                                                               H   SCH.sub.3                                                                               CH   OCH.sub.3                                                                               N   -- **                                       Q-25                                                                               H   SCH.sub.3                                                                               OCH.sub.3                                                                           OCH.sub.3                                                                               N   -- **                                       Q-25                                                                               H   SCH.sub.2 CHCH.sub.2                                                                    CH.sub.3                                                                            CH.sub.3 CH  -- **                                       Q-25                                                                               H   SCH.sub.2 CHCH.sub.2                                                                    CH.sub.3                                                                            OCH.sub.3                                                                               CH  -- **                                       Q-25                                                                               H   SCH.sub.2 CHCH.sub.2                                                                    OCH.sub.3                                                                           OCH.sub.3                                                                               CH  -- **                                       Q-25                                                                               H   SCH.sub.2 CHCH.sub.2                                                                    OCH.sub.3                                                                           Cl       CH  -- **                                       Q-25                                                                               H   SCH.sub.2 CHCH.sub.2                                                                    CH.sub.3                                                                            OCH.sub.3                                                                               N   -- **                                       Q-25                                                                               H   SCH.sub.2 CHCH.sub.2                                                                    OCH.sub.3                                                                           OCH.sub.3                                                                               N   -- **                                       Q-25                                                                               CH.sub.3                                                                           SCH.sub.3                                                                               OCH.sub.3                                                                           OCH.sub.3                                                                               CH  -- **                                       Q-25                                                                               CH.sub.3                                                                           SH       OCH.sub.3                                                                           OCH.sub.3                                                                               CH  -- **                                       Q-25                                                                               CH.sub.3                                                                           SCH.sub.2 CHCH.sub.2                                                                    OCH.sub.3                                                                           OCH.sub. 3                                                                              CH  -- **                                       __________________________________________________________________________      R.sub.11 is --, unless indicated by ** where R.sub.11 is CH.sub.3 in all       Tables.                                                                  

                  TABLE 7f                                                         ______________________________________                                         General Structure 3                                                                                                       m.p.                                Q    R         R.sub.3 R.sub.4                                                                        R.sub.5                                                                             X     Y        Z°C.                         ______________________________________                                         Q-29 HH        H       --   CH.sub.3                                                                             OCH.sub.3                                                                               CH                                  Q-29 HH        H       --   CH.sub.3                                                                             OCH.sub.3                                                                               N                                   Q-29 HH        H       --   CH.sub.3                                                                             OCH.sub.3                                                                               N                                   Q-29 HH        H       --   OCH.sub.3                                                                            OCH.sub.3                                                                               CH                                  Q-29 HH        H       --   OCH.sub.3                                                                            OCH.sub.3                                                                               N                                   Q-29 HH        H       --   CH.sub.3                                                                             CH.sub.3 CH                                  Q-29 HH        H       --   CH.sub.3                                                                             CH.sub.3 N                                   Q-29 HCH.sub.3 H       --   CH.sub.3                                                                             OCH.sub.3                                                                               CH                                  Q-29 HCH.sub.3 H       --   CH.sub.3                                                                             CH.sub.3 CH                                  Q-29 HCH.sub.3 CH.sub.3                                                                               --   CH.sub.3                                                                             OCH.sub.3                                                                               N                                   Q-29 CH.sub.3 CH.sub.3                                                                        CH.sub.3                                                                               --   CH.sub.3                                                                             CH.sub.3 N                                   Q-29 CH.sub.3 H                                                                               H       --   OCH.sub.3                                                                            OCH.sub.3                                                                               CH                                  Q-29 HH        H       --   CH.sub.3                                                                             OC.sub.2 H.sub.5                                                                        N                                   Q-29 HH        H       --   Cl    OCH.sub.3                                                                               CH                                  Q-36 HH        H       H    CH.sub.3                                                                             OCH.sub.3                                                                               CH                                  Q-36 CH.sub.3 H                                                                               H       H    CH.sub.3                                                                             OCH.sub.3                                                                               CH                                  Q-36 HH        H       H    CH.sub.3                                                                             OCH.sub.3                                                                               N                                   Q-36 HH        H       H    OCH.sub.3                                                                            OCH.sub.3                                                                               CH                                  Q-36 HH        H       H    OCH.sub.3                                                                            OCH.sub.3                                                                               N                                   Q-36 HH        H       H    OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                        CH                                  Q-36 HH        H       H    CH.sub.3                                                                             CH.sub.3 CH                                  Q-36 HH        H       H    CH.sub.3                                                                             CH.sub.3 N                                   Q-36 HCH.sub.3 H       H    CH.sub.3                                                                             CH.sub.3 CH                                  Q-36 HH        CH.sub.3                                                                               H    CH.sub.3                                                                             CH.sub.3 N                                   Q-36 HCH.sub.3 H       CH.sub.3                                                                            CH.sub.3                                                                             OCH.sub.3                                                                               CH                                  Q-36 HCH.sub.3 CH.sub.3                                                                               H    CH.sub.3                                                                             OCH.sub.3                                                                               N                                   Q-36 HCH.sub.3 CH.sub.3                                                                               CH.sub.3                                                                            OCH.sub.3                                                                            OCH.sub.3                                                                               CH                                  Q-36 CH.sub.3 H                                                                               H       H    OCH.sub.3                                                                            OCH.sub.3                                                                               N                                   Q-36 HH        H       H    CH.sub.3                                                                             NHCH.sub.3                                                                              CH                                  Q-36 HH        H       H    CH.sub.3                                                                             N(CH.sub.3).sub.2                                                                       CH                                  Q-37 HH        H       --   CH.sub.3                                                                             OCH.sub.3                                                                               CH                                  Q-37 HH        H       --   CH.sub.3                                                                             OCH.sub.3                                                                               N                                   Q-37 HH        H       --   OCH.sub.3                                                                            OCH.sub.3                                                                               CH                                  Q-37 HH        H       --   CH.sub.3                                                                             OCH.sub.3                                                                               CH                                  Q-37 HH        H       --   CH.sub.3                                                                             OCH.sub.3                                                                               N                                   Q-37 HH        H       --   OCH.sub.3                                                                            OCH.sub.3                                                                               CH                                  Q-37 HH        H       --   OCH.sub.3                                                                            OCH.sub.3                                                                               N                                   Q-37 HH        H       --   CH.sub.3                                                                             CH.sub.3 CH                                  Q-37 H2-CH.sub.3                                                                              H       --   CH.sub.3                                                                             CH.sub.3 CH                                  Q-37 H4-CH.sub.3                                                                              H       --   CH.sub.3                                                                             CH.sub.3 N                                   Q-37 H5-CH.sub.3                                                                              H       --   CH.sub.3                                                                             OCH      CH                                  Q-37 HH        H       --   CH.sub.3                                                                             CH.sub.3 N                                   Q-37 H2-CH.sub.3                                                                              4-CH.sub.3                                                                             --   CH.sub.3                                                                             OCH.sub.3                                                                               N                                   Q-37 H2-CH.sub.3                                                                              5-CH.sub.3                                                                             --   OCH.sub.3                                                                            OCH.sub.3                                                                               CH                                  Q-37 H4-CH.sub.3                                                                              5-CH.sub.3                                                                             --   OCH.sub.3                                                                            OCH.sub.3                                                                               N                                   Q-37 CH.sub.3 H                                                                               H       --   CH.sub.3                                                                             OCH.sub.3                                                                               CH                                  Q-37 HH        H       --   CH.sub.3                                                                             CH(OCH.sub.3).sub.2                                                                     CH                                  Q-37 HH        H       --   Cl    OCH.sub.3                                                                               CH                                  Q-38 HH        H       --   CH.sub.3                                                                             OCH.sub.3                                                                               CH                                  Q-38 HH        H       --   CH.sub.3                                                                             OCH.sub.3                                                                               N                                   Q-38 HH        H       --   OCH.sub.3                                                                            OCH.sub.3                                                                               CH                                  Q-38 HH        H       --   OCH.sub.3                                                                            OCH.sub.3                                                                               N                                   Q-38 H2-CH.sub.3                                                                              H       --   CH.sub.3                                                                             CH.sub.3 CH                                  Q-38 H4-CH.sub.3                                                                              H       --   CH.sub.3                                                                             CH.sub.3 N                                   Q-38 H2-CH.sub.3                                                                              4-CH.sub.3                                                                             --   CH.sub.3                                                                             OCH.sub.3                                                                               CH                                  Q-38 H4-CH.sub.3                                                                              4-CH.sub.3                                                                             --   CH.sub.3                                                                             OCH.sub.3                                                                               N                                   Q-38 HH        H       --   CH.sub.3                                                                             CH.sub.3 N                                   Q-38 CH.sub.3 4-CH.sub.3                                                                      6-CH.sub.3                                                                             --   OCH.sub.3                                                                            OCH.sub.3                                                                               CH                                  Q-38 HH        H       --   CH.sub.3                                                                              ##STR149##                                                                             CH                                  Q-38 HH        H       --   CH.sub.3                                                                             CH.sub.3 CH                                  Q-38 HH        H       --   OCH.sub.3                                                                            C.sub.2 H.sub.5                                                                         N                                   Q-39 HH        H       --   CH.sub.3                                                                             OCH.sub.3                                                                               CH                                  Q-39 HH        H       --   CH.sub.3                                                                             OCH.sub.3                                                                               N                                   Q-39 HH        H       --   CH.sub.3                                                                             CH.sub.3 N                                   Q-39 HH        H       --   OCH.sub.3                                                                            OCH.sub.3                                                                               CH                                  Q-39 HH        H       --   OCH.sub.3                                                                            OCH.sub.3                                                                               N                                   Q-39 CH.sub.3 H                                                                               H       --   OCH.sub.3                                                                            OCH.sub.3                                                                               N                                   Q-39 H3-CH.sub.3                                                                              H       --   CH.sub.3                                                                             CH.sub.3 CH                                  Q-39 HH        H       --   CH.sub.3                                                                             CH.sub.3 CH                                  Q-39 H5-CH.sub.3                                                                              H       --   CH.sub.3                                                                             CH.sub.3 N                                   Q-39 HH        H       --   Cl    OC.sub.2 H.sub.5                                                                        CH                                  Q-39 H6-CH.sub.3                                                                              H       --   CH.sub.3                                                                             OCH.sub.3                                                                               CH                                  Q-39 H3-CH.sub.3                                                                              5-CH.sub.3                                                                             --   CH.sub.3                                                                             OCH.sub.3                                                                               N                                   Q-39 H3-CH.sub.3                                                                              6-CH.sub.3                                                                             OCH.sub.3                                                                           OCH.sub.3                                                                            CH                                           Q-39 H5-CH.sub.3                                                                              6-CH.sub.3                                                                             --   OCH.sub.3                                                                            OCH.sub.3                                                                               N                                   Q-39 HH        H       --   OCH.sub.3                                                                            OC.sub.2 H.sub.5                                                                        N                                   Q-39 HH        H       --   OCH.sub.3                                                                            CH.sub.2 OCH.sub.3                                                                      N                                   Q-40 HH        H       --   CH.sub.3                                                                             CH.sub.3 CH                                  Q-40 HH        H       --   CH.sub.3                                                                             OCH.sub.3                                                                               CH                                  Q-40 HH        H       --   CH.sub.3                                                                             OCH.sub.3                                                                               N                                   Q-40 HH        H       --   OCH.sub.3                                                                            OCH.sub. 3                                                                              CH                                  Q-40 HH        H       --   OCH.sub.3                                                                            OCH.sub.3                                                                               N                                   Q-40 HH        H       --   CH.sub.3                                                                             CH.sub.3 N                                   Q-40 H4-CH.sub.3                                                                              H       --   CH.sub.3                                                                             CH.sub.3 CH                                  Q-40 H5-CH.sub.3                                                                              H       --   CH.sub.3                                                                             CH.sub.3 N                                   Q-40 H6-CH.sub.3                                                                              H       --   CH.sub.3                                                                             OCH.sub.3                                                                               CH                                  Q-40 H4-CH.sub.3                                                                              5-CH.sub.3                                                                             --   CH.sub.3                                                                             OCH.sub.3                                                                               N                                   Q-40 H4-CH.sub.3                                                                              6-CH.sub.3                                                                             OCH.sub.3                                                                           OCH.sub.3                                                                            CH                                           Q-40 H5-CH.sub.3                                                                              6-CH.sub.3                                                                             --   OCH.sub.3                                                                            OCH.sub.3                                                                               N                                   Q-40 CH.sub.3 H                                                                               H       --   CH.sub.3                                                                             CH.sub.3 CH                                  Q-40 HH        H       --   CH.sub.3                                                                             CF.sub.3 N                                   Q-40 HH        H       --   OCH.sub.3                                                                            OCF.sub.2 H                                                                             N                                   Q-43 HH        H       --   CH.sub.3                                                                             CH.sub.3 CH                                  Q-43 HH        H       --   CH.sub.3                                                                             OCH.sub.3                                                                               CH                                  Q-43 HH        H       --   CH.sub.3                                                                             OCH.sub.3                                                                               N                                   Q-43 HH        H       --   OCH.sub.3                                                                            OCH.sub.3                                                                               CH                                  Q-43 HH        H       --   OCH.sub.3                                                                            OCH.sub.3                                                                               N                                   Q-43 CH.sub.3 H                                                                               H       --   OCH.sub.3                                                                            OCH.sub.3                                                                               CH                                  Q-43 HCH.sub.3 CH.sub.3                                                                               --   CH.sub.3                                                                             OCH.sub.3                                                                               CH                                  Q-43 HCH.sub.3 H       --   CH.sub.3                                                                             CH.sub.3 CH                                  Q-43 HH        H       --   CH.sub.3                                                                             CH.sub.3 N                                   Q-43 HH        H       --   OCH.sub.3                                                                            OCH.sub.2 CF.sub.3                                                                      N                                   Q-43 HH        H       --   OCH.sub.3                                                                            NHCH.sub.3                                                                              N                                   Q-44 HH        H       --   CH.sub.3                                                                             OCH.sub.3                                                                               CH                                  Q-44 HH        H       --   CH.sub.3                                                                             OCH.sub.3                                                                               N                                   Q-44 HH        H       --   OCH.sub.3                                                                            OCH.sub.3                                                                               CH                                  Q-44 HH        H       --   OCH.sub.3                                                                            OCH.sub.3                                                                               N                                   Q-44 HCH.sub.3 H       --   CH.sub.3                                                                             CH.sub.3 CH                                  Q-44 HH        CH.sub.3                                                                               --   CH.sub.3                                                                             CH.sub.3 N                                   Q-44 HCH.sub.3 CH.sub.3                                                                               --   CH.sub.3                                                                             OCH.sub.3                                                                               N                                   Q-44 CH.sub.3 H                                                                               H       --   CH.sub.3                                                                             OCH.sub.3                                                                               N                                   Q-44 HH        H       --   OCH.sub.3                                                                            N(CH.sub.3).sub.2                                                                       N                                   Q-44 HH        H       --   Br    OCH.sub.3                                                                               CH                                  Q-44 HH        H       --   CH.sub.3                                                                             CH.sub.3 CH                                  Q-44 HH        H       --   CH.sub.3                                                                             CH.sub.3 N                                   Q-45 HH        --      --   CH.sub.3                                                                             OCH.sub.3                                                                               CH                                  Q-45 HH        --      --   CH.sub.3                                                                             OCH.sub.3                                                                               N                                   Q-45 HH        --      --   OCH.sub.3                                                                            OCH.sub.3                                                                               CH                                  Q-45 HH        --      --   OCH.sub.3                                                                            OCH.sub.3                                                                               N                                   Q-45 HCH.sub.3 --      --   CH.sub.3                                                                             CH.sub.3 CH                                  Q-45 CH.sub.3 H                                                                               --      --   CH.sub.3                                                                             CH.sub.3 N                                   Q-45 HH        --      --   OCH.sub.3                                                                            CH(OCH.sub.3).sub.2                                                                     N                                   Q-45 HH        --      --   CH.sub.3                                                                             CH.sub.3 CH                                  Q-45 HH        --      --   CH.sub.3                                                                             CH.sub.3 N                                   Q-45 HH        --      --   Cl    OCH.sub.3                                                                               CH                                  ______________________________________                                          wherein W' is O.                                                         

                                      TABLE 8a                                     __________________________________________________________________________     General Structure 3 wherein Q is Q-5.                                                                             m.p.                                        R  R.sub.3                                                                           R.sub.4                                                                           R.sub.5                                                                           R.sub.6                                                                           R.sub.7                                                                           R.sub.8                                                                           X   Y      Z  °C.                                  __________________________________________________________________________     H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              N                                              H  H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             CH                                             H  H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N                                              H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH                                             H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             N                                              CH.sub.3                                                                          H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH                                             H  CH.sub.3                                                                          H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              CH                                             H  H  H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              N                                              H  H  H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                             CH                                             H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                             N                                              H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             CH                                             H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                             N                                              H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                              CH                                             H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                              N                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             CH                                             H  H  H  H  CH.sub.3                                                                          H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N                                              H  H  H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                             CH                                             H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                             N                                              H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH                                                        H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                              N                                              H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                             CH                                             H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                             N                                              H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                             CH                                             H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                              CH                                             H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                              CH                                             H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                              N                                              H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                             CH                                             CH.sub.3                                                                          H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                             N                                              H  H  H  H  H  H  H  OCH.sub.3                                                                          CH(OCH.sub.3).sub.2                                                                   N                                              H  H  H  H  H  H  H  OCH.sub.3                                                                           ##STR150##                                                                           N                                              H  H  H  H  H  H  H  Cl  OCH.sub.3                                                                             CH                                             H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                              CH                                             __________________________________________________________________________      Wherein W" is O.                                                         

                                      TABLE 8b                                     __________________________________________________________________________     General Structure 3 wherein Q is Q-6.                                                                                 m.p.                                    Q  R  R.sub.3                                                                           R.sub.4                                                                           R.sub.5                                                                           R.sub.6                                                                           R.sub.7                                                                           R.sub.8                                                                           X   Y     Z W" °C.                              __________________________________________________________________________     Q-6                                                                               H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                                                               O                                          Q-6                                                                               H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             N O                                          Q-6                                                                               H  CH.sub.3                                                                          H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                                                               O                                          Q-6                                                                               H  H  H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N O                                          Q-6                                                                               H  H  H  H  H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                                                               O                                          Q-6                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N O                                          Q-6                                                                               H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                                                               O                                          Q-6                                                                               H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             N O                                          Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                                                               O                                          Q-6                                                                               H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N O                                          Q-6                                                                               H  H  H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                                                               O                                          Q-6                                                                               H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            N O                                          Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                                                               O                                          Q-6                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                             N O                                          Q-6                                                                               H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                                                               O                                          Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N O                                          Q-6                                                                               H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                                                               O                                          Q-6                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                            N O                                          Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                                                               O                                          Q-6                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                             N O                                          Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                                                               O                                          Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            N O                                          Q-6                                                                               H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                                                               O                                          Q-6                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            N O                                          Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                             CH                                                                               O                                          Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             N O                                          Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            CH                                                                               O                                          Q-6                                                                               CH.sub.3                                                                          H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N O                                          Q-6                                                                               H  H  H  H  H  H  H  Br  OCH.sub.3                                                                            CH                                                                               O                                          Q-6                                                                               H  H  H  H  H  H  H  Cl  OC.sub.2 H.sub.5                                                                     CH                                                                               O                                          Q-6                                                                               H  H  H  H  H  H  H  OCH.sub.3                                                                          C.sub.2 H.sub.5                                                                      CH                                                                               O                                          Q-6                                                                               H  H  H  H  H  H  H  OCH.sub.3                                                                          OC.sub.2 H.sub.5                                                                     CH                                                                               O                                          Q-6                                                                               H  H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                                                               O                                          Q-6                                                                               H  H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N O                                          Q-6                                                                               H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                                                               O                                          Q-6                                                                               H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N O                                          Q-6                                                                               CH.sub.3                                                                          H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                                                               O                                          Q-6                                                                               H  H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                                                               S                                          Q-6                                                                               H  H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N S                                          Q-6                                                                               H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                                                               S                                          Q-6                                                                               H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N S                                          Q-6                                                                               H  H  H  H  H  H  H  OCH.sub.3                                                                          C.sub.2 H.sub.5                                                                      CH                                                                               S                                          Q-6                                                                               H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                                                               S                                          Q-6                                                                               H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             N S                                          Q-6                                                                               H  CH.sub.3                                                                          H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                                                               S                                          Q-6                                                                               H  H  H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N S                                          Q-6                                                                               H  H  H  H  H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                                                               S                                          Q-6                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N S                                          Q-6                                                                               H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                                                               S                                          Q-6                                                                               H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             N S                                          Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                                                               S                                          Q-6                                                                               H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N S                                          Q-6                                                                               H  H  H  H  H  H  H  OCH.sub.3                                                                          CH.sub.2 OCH.sub.3                                                                   CH                                                                               S                                          Q-6                                                                               H  H  H  H  H  H  H  OCH.sub.3                                                                          CF.sub.3                                                                             CH                                                                               S                                          Q-6                                                                               H  H  H  H  H  H  H  OCH.sub.3                                                                          OCF.sub.2 H                                                                          CH                                                                               S                                          Q-6                                                                               H  H  H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                                                               S                                          Q-6                                                                               H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            N S                                          Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                                                               S                                          Q-6                                                                               H  CH.sub. 3                                                                         H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                             N S                                          Q-6                                                                               H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                                                               S                                          Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N S                                          Q-6                                                                               H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                                                               S                                          Q-6                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                            N S                                          Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                                                               S                                          Q-6                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                             N S                                          Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                                                               S                                          Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            N S                                          Q-6                                                                               H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                                                               S                                          Q-6                                                                               H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            N S                                          Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                             CH                                                                               S                                          Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             N S                                          Q-6                                                                               H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            CH                                                                               S                                          Q-6                                                                               CH.sub.3                                                                          H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N S                                          __________________________________________________________________________

                                      TABLE 8c                                     __________________________________________________________________________     General Structure 3                                                                                                 m.p.                                      Q  R   R.sub.3                                                                           R.sub.4                                                                            R.sub.5                                                                           R.sub.6                                                                           X   Y       Z  W'                                                                               °C.                                __________________________________________________________________________     Q-7                                                                               H   H  H   H  H  CH.sub.3                                                                           OCH.sub.3                                                                              CH --                                          Q-7                                                                               H   H  H   H  H  CH.sub.3                                                                           OCH.sub.3                                                                              N  --                                          Q-7                                                                               H   H  H   H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              CH --                                          Q-7                                                                               H   H  H   H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              N  --                                          Q-7                                                                               H   H  H   H  H  CH.sub.3                                                                           CH.sub.3                                                                               CH --                                          Q-7                                                                               H   H  H   H  H  CH.sub.3                                                                           CH.sub.3                                                                               N  --                                          Q-7                                                                               H   CH.sub.3                                                                          H   H  H  CH.sub.3                                                                           OCH.sub.3                                                                              CH --                                          Q-7                                                                               H   H  CH.sub.3                                                                           H  H  CH.sub.3                                                                           OCH.sub.3                                                                              N  --                                          Q-7                                                                               H   CH.sub.3                                                                          H   H  CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                              CH --                                          Q-7                                                                               H   H  CH.sub.3                                                                           CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                              N  --                                          Q-7                                                                               H   CH.sub.3                                                                          CH.sub.3                                                                           H  H  CH.sub.3                                                                           CH.sub.3                                                                               CH --                                          Q-7                                                                               H   CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                               N  --                                          Q-7                                                                               H   CH.sub.3                                                                          H   CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                              CH --                                          Q-7                                                                               H   CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                              N  --                                          Q-7                                                                               CH.sub.3                                                                           H  H   H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              CH --                                          Q-7                                                                               CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                              CH --                                          Q-7                                                                               H   H  H   H  H  OCH.sub.3                                                                          OCH.sub.2 CF.sub.3                                                                     CH --                                          Q-7                                                                               H   H  H   H  H  OCH.sub.3                                                                          NHCH.sub.3                                                                             CH --                                          Q-7                                                                               H   H  H   H  H  Cl  OCH.sub.3                                                                              CH --                                          Q-7                                                                               H   H  H   H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              CH --                                                                               *                                         Q-7                                                                               H   H  H   H  H  OCH.sub.3                                                                          CH.sub.3                                                                               N  --                                                                               *                                         Q-7                                                                               H   H  H   H  H  OCH.sub.3                                                                          CH      CH --                                                                               *                                         Q-16                                                                              H   CH.sub.3                                                                          CH.sub.3                                                                           H  H  CH.sub.3                                                                           OCH.sub.3                                                                              CH O                                           Q-16                                                                              H   CH.sub.3                                                                          CH.sub.3                                                                           H  H  CH.sub.3                                                                           OCH.sub.3                                                                              N  O                                           Q-16                                                                              H   CH.sub.3                                                                          CH.sub.3                                                                           H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              CH O                                           Q-16                                                                              H   CH.sub.3                                                                          CH.sub.3                                                                           H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              N  O                                           Q-16                                                                              CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                           H  H  CH.sub.3                                                                           OCH.sub.3                                                                              N  O                                           Q-16                                                                              CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                           H  H  Cl  OCH.sub.3                                                                              CH O                                           Q-16                                                                              H   CH.sub.3                                                                          CH.sub.3                                                                           H  H  CH.sub.3                                                                           CH.sub.3                                                                               CH O                                           Q-16                                                                              H   CH.sub.3                                                                          CH.sub.3                                                                           H  H  CH.sub.3                                                                           CH.sub.3                                                                               N  O                                           Q-16                                                                              H   H  H   H  H  CH.sub.3                                                                           OCH.sub.3                                                                              CH O                                           Q-16                                                                              H   H  H   H  H  CH.sub.3                                                                           OCH.sub.3                                                                              N  O                                           Q-16                                                                              H   H  H   H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              CH O                                           Q-16                                                                              H   H  H   H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              N  O                                           Q-16                                                                              H   CH.sub.3                                                                          CH.sub.3                                                                           H  H  OCH.sub.3                                                                          N(CH.sub.3).sub.2                                                                      CH O                                           Q-16                                                                              H   CH.sub.3                                                                          CH.sub.3                                                                           H  H  OCH.sub.3                                                                          CH(OCH.sub.3).sub.2                                                                    CH O                                           Q-16                                                                              H   CH.sub.3                                                                          CH.sub.3                                                                           H  H  Cl  OCH.sub.3                                                                              CH O                                           Q-16                                                                              H   CH.sub.3                                                                          CH.sub.3                                                                           H  H  CH.sub.3                                                                           CH.sub.2 OCH.sub.3                                                                     N  O                                           Q-16                                                                              H   CH.sub.3                                                                          H   H  H  CH.sub.3                                                                           CH.sub.3                                                                               CH O                                           Q-16                                                                              H   H  H   CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                               N  O                                           Q-16                                                                              H   CH.sub.3                                                                          H   CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                              N  O                                           Q-16                                                                              H   H  H   CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                              CH O                                           Q-16                                                                              H   CH.sub.3                                                                          H   CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                              CH O                                           Q-16                                                                              H   CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                              N  O                                           Q-16                                                                              H   CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                               CH O                                           Q-16                                                                              H   CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                               N  O                                           Q-16                                                                              H   CH.sub.3                                                                          CH.sub.3                                                                           H  H  CH.sub.3                                                                           CH.sub.3                                                                               CH S                                           Q-16                                                                              H   CH.sub.3                                                                          CH.sub.3                                                                           H  H  CH.sub.3                                                                           CH.sub.3                                                                               N  S                                           Q-16                                                                              H   CH.sub.3                                                                          CH.sub.3                                                                           H  H  CH.sub.3                                                                           OCH.sub.3                                                                              CH S                                           Q-16                                                                              H   CH.sub.3                                                                          CH.sub.3                                                                           H  H  CH.sub.3                                                                           OCH.sub.3                                                                              N  S                                           Q-16                                                                              H   CH.sub.3                                                                          CH.sub.3                                                                           H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              CH S                                           Q-16                                                                              H   CH.sub.3                                                                          CH.sub.3                                                                           H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              N  S                                           Q-16                                                                              H   CH.sub.3                                                                          CH.sub. 3                                                                          H  H  Cl  OCH.sub.3                                                                              CH S                                           Q-16                                                                              H   CH.sub.3                                                                          CH.sub.3                                                                           H  H  CH.sub.3                                                                           NHCH.sub.3                                                                             N  S                                           Q-16                                                                              H   CH.sub.3                                                                          CH.sub.3                                                                           H  H  CH.sub.3                                                                           N(CH.sub.3).sub.2                                                                      N  S                                           Q-16                                                                              H   H  H   H  H  CH.sub.3                                                                           OCH.sub.3                                                                              CH S                                           Q-16                                                                              H   H  H   H  H  CH.sub.3                                                                           OCH.sub.3                                                                              N  S                                           Q-16                                                                              H   H  H   H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              CH S                                           Q-16                                                                              H   H  H   H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              N  S                                           Q-16                                                                              CH.sub.3                                                                           H  H   H  H  CH.sub.3                                                                           CH.sub.3                                                                               CH S                                           Q-16                                                                              H   CH.sub.3                                                                          H   H  H  CH.sub.3                                                                           CH.sub.3                                                                               N  S                                           Q-16                                                                              H   H  H   CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                              N  S                                           Q-16                                                                              H   CH.sub.3                                                                          H   CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                              CH S                                           Q-16                                                                              H   H  H   CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                              CH S                                           Q-16                                                                              H   CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                              N  S                                           Q-16                                                                              H   CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                               CH S                                           Q-16                                                                              H   CH.sub.3                                                                          H   CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                               N  S                                           Q-16                                                                              H   CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                              CH S                                           Q-17                                                                              H   H  H   H  H  Cl  OCH.sub.3                                                                              CH --                                          Q-17                                                                              H   H  H   H  H  CH.sub.3                                                                           CH.sub.3                                                                               CH --                                          Q-17                                                                              H   H  H   H  H  Cl  OC.sub.2 H.sub.5                                                                       CH --                                          Q-17                                                                              H   H  H   H  H  CH.sub.3                                                                           CH.sub.3                                                                               N  --                                          Q-17                                                                              H   H  H   H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              CH --                                          Q-17                                                                              H   H  H   H  H  OCH.sub.3                                                                          OCH.sub.3                                                                              N  --                                          Q-17                                                                              H   H  H   H  H  OCH.sub.3                                                                          OC.sub.2 H.sub.5                                                                       CH --                                          Q-17                                                                              H   H  H   H  H  OCH.sub.3                                                                          OC.sub.2 H.sub.5                                                                       N  --                                          Q-17                                                                              H   CH.sub.3                                                                          H   H  H  CH.sub.3                                                                           CH.sub.3                                                                               CH --                                          Q-17                                                                              H   H  H   H  H  CH.sub.3                                                                           CH(OCH.sub.3).sub.2                                                                    N  --                                          Q-17                                                                              H   H  H   H  H  CH.sub.3                                                                            ##STR151##                                                                            N  --                                          Q-17                                                                              H   H  H   CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                               N  --                                          Q-17                                                                              H   CH.sub.3                                                                          CH.sub.3                                                                           H  H  CH.sub.3                                                                           OCH.sub.3                                                                              CH --                                          Q-17                                                                              H   CH.sub.3                                                                          CH.sub.3                                                                           H  H  CH.sub.3                                                                           OCH.sub.3                                                                              N  --                                          Q-17                                                                              H   H  H   CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                              CH --                                          Q-17                                                                              H   CH.sub.3                                                                          H   CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                              N  --                                          Q-17                                                                              H   CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                               CH --                                          Q-17                                                                              H   CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                               N  --                                          Q-17                                                                              H   CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                              CH --                                          Q-17                                                                              CH.sub.3                                                                           H  H   H  H  CH.sub.3                                                                           OCH.sub.3                                                                              N  --                                          __________________________________________________________________________

                                      TABLE 8d                                     __________________________________________________________________________     General Structure 3 wherein Q is Q-30                                                                                m.p.                                     R  R.sub.3                                                                           R.sub.4                                                                           R.sub.5                                                                           R.sub.6                                                                             R.sub.7                                                                           R.sub.8                                                                           R.sub.9                                                                           X   Y     Z °C.                               __________________________________________________________________________     H  H  H  H  H    H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                         H  H  H  H  H    H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N                                          H  H  H  H  H    H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                         H  H  H  H  H    H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N                                          H  H  H  H  H    H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             N                                          H  H  H  H  H    H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                         CH.sub.3                                                                          H  H  H  H    H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                         H  CH.sub.3                                                                          H  H  H    H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N                                          H  H  H  H  H    H  H  H  Cl  OCH.sub.3                                                                            CH                                         H  H  CH.sub.3                                                                          H  H    H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                         H  H  H  H  CH.sub.3                                                                            H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N                                          H  H  H  H  H    H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                         H  CH.sub.3                                                                          CH.sub.3                                                                          H  H    H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             N                                          H  CH.sub.3                                                                          H  H  CH.sub.3                                                                            H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                         H  CH.sub.3                                                                          H  H  H    H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            N                                          H  H  CH.sub.3                                                                          CH.sub.3                                                                          H    H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                         H  H  CH.sub.3                                                                          H  CH.sub.3                                                                            H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N                                          H  H  CH.sub.3                                                                          H  H    H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                         H  H  H  H  CH.sub.3                                                                            CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                             N                                          H  H  H  H  CH.sub.3                                                                            H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                         H  H  H  H  H    H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            N                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H    H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                         H  CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                            H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N                                          H  CH.sub.3                                                                          CH.sub.3                                                                          H  H    H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                         H  CH.sub.3                                                                          H  H  H    CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                             N                                          H  CH.sub.3                                                                          H  H  CH.sub.3                                                                            H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                         H  CH.sub.3                                                                          H  H  H    H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            N                                          H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                            H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                         H  H  CH.sub.3                                                                          CH.sub.3                                                                          H    H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                            N                                          H  H  CH.sub.3                                                                          H  CH.sub.3                                                                            CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                         H  H  CH.sub.3                                                                          H  CH.sub.3                                                                            H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             N                                          H  H  CH.sub.3                                                                          H  H    H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            CH                                         H  H  H  H  CH.sub.3                                                                            CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            N                                          H  H  H  H  CH.sub.3                                                                            H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub. 3                                                                         OCH.sub.3                                                                            CH                                         H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                            H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N                                          H  CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                            H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                         H  CH.sub.3                                                                          H  H  CH.sub.3                                                                            CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            N                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H    H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                         H  CH.sub.3                                                                          H  H  CH.sub.3                                                                            H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            N                                          H  CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                            CH.sub.3                                                                          H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                         H  CH.sub.3                                                                          CH.sub.3                                                                          H  H    H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            N                                          H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                            CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                         H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                            H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             N                                          H  H  CH.sub.3                                                                          H  CH.sub.3                                                                            CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                         H  H  CH.sub.3                                                                          H  CH.sub.3                                                                            H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub. 3                                                                           N                                          H  H  H  H  CH.sub.3                                                                            CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                         H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                            CH.sub.3                                                                          H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N                                          H  CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                            CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                         H  CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                            H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                             N                                          H  CH.sub.3                                                                          H  H  CH.sub.3                                                                            CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            CH                                         H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H    H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            N                                          H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                            H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                         H  H  CH.sub.3                                                                          H  CH.sub.3                                                                            CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            N                                          H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                            CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                         H  CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                            CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                             N                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                            H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            CH                                         H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                            CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            N                                          H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                            CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                         H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                            CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            N                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                            CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                             CH                                         H  H  H  H  H    H  H  H  CH.sub.3                                                                           OC.sub.2 H.sub.5                                                                     CH                                         H  H  H  H  H    H  H  H  CH.sub.3                                                                           CH.sub.2 OCH.sub.3                                                                   CH                                         __________________________________________________________________________

                                      TABLE 8e                                     __________________________________________________________________________     General Structure 3 wherein Q is Q-31.                                                                                m.p.                                    R  R.sub.3                                                                           R.sub.4                                                                           R.sub.5                                                                           R.sub.6                                                                           R.sub.7                                                                           R.sub.8                                                                           R.sub.9                                                                           R.sub.10                                                                          X   Y     Z °C.                              __________________________________________________________________________     H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                        H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N                                         H  H  H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                        H  H  H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N                                         H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                        H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             N                                         H  H  H  H  H  H  H  H  H  Cl  OCH.sub.3                                                                            CH                                        H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           C.sub.2 H.sub.5                                                                      CH                                        H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           CF.sub.3                                                                             CH                                        H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           OCF.sub.2 H                                                                          CH                                        H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.2 CF.sub.3                                                                   CH                                        H  CH.sub.3                                                                          H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                        H  H  H  CH.sub.3                                                                          H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             N                                         H  H  H  H  H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                        H  H  H  H  H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            N                                         H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                        H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N                                         H  H  H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                        H  H  H  H  H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                             N                                         H  H  H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                        H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N                                         H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                        H  H  H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                            N                                         H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                        H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                             N                                         H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                        H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N                                         H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                        H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            N                                         H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                        H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             N                                         H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub. 3                                                                         CH.sub.3                                                                          H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                        H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            N                                         H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                        H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                            N                                         H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                        H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             N                                         H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            CH                                        H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            N                                         H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                        CH.sub.3                                                                          H  H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N                                         H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                                                               *                                       H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N *                                       H  H  H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                                                               *                                       H  H  H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N *                                       H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                                                               *                                       H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             N *                                       H  H  H  H  H  H  H  H  H  Cl  OCH.sub.3                                                                            CH                                                                               *                                       __________________________________________________________________________      ***Wherein W" is O, unless indicated by **** where W" is S in all Tables.

                                      TABLE 8f                                     __________________________________________________________________________     General Structure 3 wherein Q is Q-32.                                         R  R.sub.3                                                                           R.sub.4                                                                           R.sub.5                                                                           R.sub.6                                                                           R.sub.7                                                                           R.sub.8                                                                           R.sub.9                                                                           R.sub.10                                                                          X   Y     Z  W"                                     __________________________________________________________________________     H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             CH O                                      H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             N  O                                      H  H  H  H  H  H  H  H  H  Cl  OCH.sub.3                                                                            CH O                                      H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           NHCH.sub.3                                                                           CH O                                      H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           N(CH.sub.3).sub.2                                                                    CH O                                      H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           CH(OCH.sub.3).sub.2                                                                  CH O                                      H  H  H  H  H  H  H  H  H  Br  OCH.sub.3                                                                            CH O                                      H  CH.sub.3                                                                          H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             CH O                                      H  H  H  CH.sub.3                                                                          H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             N  O                                      H  H  H  H  H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH O                                      H  H  H  H  H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            N  O                                      H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH O                                      H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N  O                                      H  H  H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                             CH O                                      H  H  H  H  H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                             N  O                                      H  H  H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            CH O                                      H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N  O                                      H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH O                                      H  H  H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                            N  O                                      H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             CH O                                      H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                             N  O                                      H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            CH O                                      H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N  O                                      H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH O                                      H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            N  O                                      H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             CH O                                      H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             N  O                                      H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH O                                      H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            N  O                                      H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH O                                      H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                            N  O                                      H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub. 3                                                                         H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             CH O                                      H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             N  O                                      H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            CH O                                      H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            N  O                                      H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH O                                      CH.sub.3                                                                          H  H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N  O                                      H  CH.sub.3                                                                          H  H  H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            CH O                                      H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH O                                      H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N  O                                      H  H  H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH O                                      H  H  H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N  O                                      H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH S                                      H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N  S                                      H  H  H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH S                                      H  H  H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N  S                                      H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             CH S                                      H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             N  S                                      H  H  H  H  H  H  H  H  H  Cl  OCH.sub.3                                                                            CH S                                      H  H  H  H  H  H  H  H  H  CH.sub.3                                                                            ##STR152##                                                                          CH S                                      H  H  H  H  H  H  H  H  H  Cl  OC.sub.2 H.sub.5                                                                     CH S                                      H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           C.sub.2 H.sub.5                                                                      N  S                                      H  H  H  H  H  H  H  H  H  CH.sub.3                                                                           OC.sub.2 H.sub.5                                                                     N  S                                      H  CH.sub.3                                                                          H  H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             CH S                                      H  H  H  CH.sub.3                                                                          H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             N  S                                      H  H  H  H  H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH S                                      H  H  H  H  H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            N  S                                      H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH S                                      H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N  S                                      H  H  H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                             CH S                                      H  H  H  H  H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                             N  S                                      H  H  H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            CH S                                      H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N  S                                      H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH S                                      H  H  H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                            N  S                                      H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             CH S                                      H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                             N  S                                      H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            CH S                                      H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N  S                                      H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH S                                      H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            N  S                                      H  CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             CH S                                      H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             N  S                                      H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N  S                                      H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            N  S                                      H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH S                                      H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  OCH.sub. 3                                                                         OCH.sub.3                                                                            N  S                                      H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             CH S                                      H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             N  S                                      H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            CH S                                      H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            N  S                                      H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH S                                      CH.sub.3                                                                          H  H  H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N  S                                      H  CH.sub.3                                                                          H  H  H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            CH S                                      __________________________________________________________________________

                                      TABLE 8g                                     __________________________________________________________________________     General Structure 3                                                                                                m.p.                                       Q  R  R.sub.3                                                                           R.sub.4                                                                           R.sub.5                                                                           R.sub.6                                                                           R.sub.7                                                                           X   Y     Z  W °C.                                 __________________________________________________________________________     Q-41                                                                              H  H  H  H  H  H  Cl  OCH.sub.3                                                                            CH                                              Q-41                                                                              H  H  H  H  H  H  Br  OCH.sub.3                                                                            CH                                              Q-41                                                                              H  H  H  H  H  H  Cl  OC.sub.2 H.sub.5                                                                     CH                                              Q-41                                                                              H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             N                                               Q-41                                                                              H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                              Q-41                                                                              H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N                                               Q-41                                                                              H  H  H  H  H  H  OCH.sub.3                                                                          OC.sub.2 H.sub.5                                                                     CH                                              Q-41                                                                              H  H  H  H  H  H  OCH.sub.3                                                                          OC.sub.2 H.sub.5                                                                     N                                               Q-41                                                                              H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                              Q-41                                                                              H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N                                               Q-41                                                                              H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                              Q-41                                                                              H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.2 OCH.sub.3                                                                   CH                                              Q-41                                                                              H  H  H  H  H  H  CH.sub.3                                                                           CF.sub.3                                                                             N                                               Q-41                                                                              H  H  H  H  H  H  CH.sub.3                                                                           OCF.sub.2 H                                                                          N                                               Q-41                                                                              H  CH.sub.3                                                                          H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                              Q-41                                                                              H  H  H  CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                             N                                               Q-41                                                                              H  H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                              Q-41                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N                                               Q-41                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                              Q-41                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N                                               Q-41                                                                              H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                              Q-41                                                                              H  CH.sub.3                                                                          H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             N                                               Q-41                                                                              H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                              Q-41                                                                              H  H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            N                                               Q-41                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                              Q-41                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                            N                                               Q-41                                                                              H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                              Q-41                                                                              H  CH.sub.3                                                                          H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                             N                                               Q-41                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                              Q-41                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            N                                               Q-42                                                                              H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N  O                                            Q-42                                                                              H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH O                                            Q-42                                                                              H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N  O                                            Q-42                                                                              H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH S                                            Q-42                                                                              H  H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N  S                                            Q-42                                                                              H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH S                                            Q-42                                                                              H  H  H  H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N  S                                            Q-42                                                                              H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             CH S                                            Q-42                                                                              H  H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             N  S                                            Q-42                                                                              H  H  H  H  H  H  CH.sub.3                                                                            ##STR153##                                                                          N  S                                            Q-42                                                                              H  H  H  H  H  H  Br  OC.sub.2 H.sub.5                                                                     CH S                                            Q-42                                                                              H  H  H  H  H  H  OCH.sub.3                                                                          CH.sub.2 OCH.sub.3                                                                   N  S                                            Q-42                                                                              CH.sub.3                                                                          H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH S                                            Q-42                                                                              CH.sub.3                                                                          H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N  S                                            Q-42                                                                              H  CH.sub.3                                                                          H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             CH S                                            Q-42                                                                              H  H  H  CH.sub.3                                                                          H  H  CH.sub.3                                                                           CH.sub.3                                                                             N  S                                            Q-42                                                                              H  H  H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            CH S                                            Q-42                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N  S                                            Q-42                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH S                                            Q-42                                                                              H  CH.sub.3                                                                          H  CH.sub.3                                                                          H  H  OCH.sub.3                                                                          OCH.sub.3                                                                            N  S                                            Q-42                                                                              H  CH.sub.3                                                                          H  H  CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             CH S                                            Q-42                                                                              H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           CH.sub.3                                                                             N  S                                            Q-42                                                                              H  H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            CH S                                            Q-42                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  H  CH.sub.3                                                                           OCH.sub.3                                                                            N  S                                            Q-42                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                            CH S                                            Q-42                                                                              H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          H  OCH.sub.3                                                                          OCH.sub.3                                                                            N  S                                            Q-42                                                                              H  H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                             CH S                                            Q-42                                                                              H  CH.sub.3                                                                          H  H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                                                                             N  S                                            Q-42                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                           OCH.sub.3                                                                            CH S                                            Q-42                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                           OCH.sub.3                                                                            N  S                                            Q-42                                                                              H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            CH S                                            Q-42                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            N  S                                            Q-41                                                                              H  CH.sub.3                                                                          H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            CH                                              Q-41                                                                              H  CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          OCH.sub.3                                                                          OCH.sub.3                                                                            N                                               Q-41                                                                              CH.sub.3                                                                          H  H  H  H  H  CH.sub.3                                                                           CH.sub.3                                                                             CH                                              Q-41                                                                              CH.sub.3                                                                          H  H  H  H  H  CH.sub.3                                                                           OCH.sub.3                                                                            CH                                              __________________________________________________________________________

                                      TABLE 9a                                     __________________________________________________________________________     General Structure 3 wherein Q is Q-20.                                                                            m.p.                                        R   R'.sub.3     X    Y      Z   W'                                                                               °C.                                  __________________________________________________________________________     H   H            CH.sub.3                                                                            OCH.sub.3                                                                             CH  O                                             H   H            CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   H            OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   H            OCH.sub.3                                                                           Cl     CH  O                                             H   H            OCH.sub.3                                                                           OCH.sub.3                                                                             N   O                                             H   H            CH.sub.3                                                                            CH.sub.3                                                                              CH  O                                             H   CH.sub.3     CH.sub.3                                                                            OCH.sub.3                                                                             CH  O                                             CH.sub.3                                                                           H            CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             CH.sub.3                                                                           CH.sub.3     OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   H            CH.sub.3                                                                            OC.sub.2 H.sub.5                                                                      N   O                                             H   H            CH.sub.3                                                                            CH.sub.3                                                                              CH  S                                             H   H            CH.sub.3                                                                            CH.sub.3                                                                              N   S                                             H   H            CH.sub.3                                                                            OCH.sub.3                                                                             CH  S                                             H   H            CH.sub.3                                                                            OCH.sub.3                                                                             N   S                                             H   H            OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   H            OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             CH.sub.3                                                                           H            CH.sub.3                                                                            OCH.sub.3                                                                             CH  S                                             H   CH.sub.3     CH.sub.3                                                                            OCH.sub.3                                                                             N   S                                             H   CH.sub.3     CH.sub.3                                                                            CH.sub.2 OCH.sub.3                                                                    N   S                                             H   C.sub.2 H.sub.5                                                                             CH.sub.3                                                                            CH.sub.3                                                                              CH  O                                             H   C.sub.2 H.sub.5                                                                             CH.sub.3                                                                            CH.sub.3                                                                              N   O                                             H   C.sub.2 H.sub.5                                                                             CH.sub.3                                                                            OCH.sub.3                                                                             CH  O                                             H   C.sub.2 H.sub.5                                                                             CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   C.sub.2 H.sub.5                                                                             OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   C.sub.2 H.sub.5                                                                             OCH.sub.3                                                                           OCH.sub.3                                                                             N   O                                             H   C.sub.2 H.sub.5                                                                             OCH.sub.3                                                                           Cl     CH  O                                             H   C.sub.2 H.sub.5                                                                             CH.sub.3                                                                            CH.sub.3                                                                              CH  S                                             H   C.sub.2 H.sub.5                                                                             CH.sub.3                                                                            CH.sub.3                                                                              N   S                                             H   C.sub.2 H.sub.5                                                                             CH.sub.3                                                                            OCH.sub.3                                                                             CH  S                                             H   C.sub.2 H.sub.5                                                                             CH.sub.3                                                                            OCH.sub.3                                                                             N   S                                             H   C.sub.2 H.sub.5                                                                             OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   C.sub.2 H.sub.5                                                                             OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             H   C.sub.2 H.sub.5                                                                             OCH.sub.3                                                                           Cl     CH  S                                             H   C.sub.2 H.sub.5                                                                             OCH.sub.3                                                                           N(CH.sub.3).sub.2                                                                     N   S                                             CH.sub.3                                                                            -n-C.sub.3 H.sub.7                                                                         OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             CH.sub.3                                                                            -n-C.sub.3 H.sub.7                                                                         CH.sub.3                                                                            CH.sub. 3                                                                             CH  O                                             CH.sub.3                                                                            -n-C.sub.3 H.sub.7                                                                         CH.sub.3                                                                            OCH.sub.3                                                                             CH  O                                             CH.sub.3                                                                            -n-C.sub.3 H.sub.7                                                                         OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             CH.sub.3                                                                            -n-C.sub.3 H.sub.7                                                                         OCH.sub.3                                                                           OCH.sub.3                                                                             N   O                                             CH.sub.3                                                                            -n-C.sub.3 H.sub.7                                                                         OCH.sub.3                                                                           Cl     CH  O                                             CH.sub.3                                                                            -n-C.sub.3 H.sub.7                                                                         CH.sub.3                                                                            OCH.sub.2 CF.sub.3                                                                    CH  O                                             H    -n-C.sub.3 H.sub.7                                                                         CH.sub.3                                                                            CH.sub.3                                                                              CH  S                                             H    -n-C.sub.3 H.sub.7                                                                         CH.sub.3                                                                            OCH.sub.3                                                                             CH  S                                             H    -n-C.sub.3 H.sub.7                                                                         CH.sub.3                                                                            OCH.sub.3                                                                             N   S                                             H    -n-C.sub.3 H.sub.7                                                                         OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H    -n-C.sub.3 H.sub.7                                                                         OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             H    -n-C.sub.3 H.sub.7                                                                         OCH.sub.3                                                                           Cl     CH  S                                             H    -n-C.sub.3 H.sub.7                                                                         CH.sub.3                                                                            CH(OCH.sub.3).sub.2                                                                   CH  S                                             H    .sub.-i-C.sub.3 H.sub.7                                                                    CH.sub.3                                                                            CH.sub.3                                                                              CH  O                                             H    .sub.-i-C.sub.3 H.sub.7                                                                    CH.sub.3                                                                            OCH.sub.3                                                                             CH  O                                             H    .sub.-i-C.sub.3 H.sub.7                                                                    CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H    .sub.-i-C.sub.3 H.sub.7                                                                    OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H    .sub.-i-C.sub.3 H.sub.7                                                                    OCH.sub.3                                                                           OCH.sub.3                                                                             N   O                                             H    .sub.-i-C.sub.3 H.sub.7                                                                    OCH.sub.3                                                                           Cl     CH  O                                             H    .sub.-i-C.sub.3 H.sub.7                                                                    CH.sub.3                                                                            CH.sub.3                                                                              N   O                                             H    .sub.-i-C.sub.3 H.sub.7                                                                    OCH.sub.3                                                                            ##STR154##                                                                           CH  O                                             CH.sub.3                                                                            .sub.-i-C.sub.3 H.sub.7                                                                    OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H    .sub.-i-C.sub.3 H.sub.7                                                                    CH.sub.3                                                                            CH.sub.3                                                                              CH  S                                             H    .sub.-i-C.sub.3 H.sub.7                                                                    CH.sub.3                                                                            OCH.sub.3                                                                             CH  S                                             H    .sub.-i-C.sub.3 H.sub.7                                                                    CH.sub.3                                                                            OCH.sub.3                                                                             N   S                                             H    .sub.-i-C.sub.3 H.sub.7                                                                    OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H    .sub.-i-C.sub.3 H.sub.7                                                                    OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             H    .sub.-i-C.sub.3 H.sub.7                                                                    OCH.sub.3                                                                           Cl     CH  S                                             H    .sub.-i-C.sub.3 H.sub.7                                                                    CH.sub.3                                                                            OC.sub.2 H.sub.5                                                                      N   S                                             H   SCH.sub.3    CH.sub.3                                                                            CH.sub.3                                                                              CH  O                                             H   SCH.sub.3    CH.sub.3                                                                            OCH.sub.3                                                                             CH  O                                             H   SCH.sub.3    CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   SCH.sub.3    OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   SCH.sub.3    OCH.sub.3                                                                           OCH.sub.3                                                                             N   O                                             H   SCH.sub.3    OCH.sub.3                                                                           Cl     CH  O                                             H   SCH.sub.3    OCH.sub.3                                                                           NHCH.sub.3                                                                            CH  O                                             CH.sub.3                                                                           SCH.sub.3    OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   SCH.sub.3    CH.sub.3                                                                            CH.sub.3                                                                              CH  S                                             H   SCH.sub.3    CH.sub.3                                                                            CH.sub.3                                                                              N   S                                             H   SCH.sub.3    CH.sub.3                                                                            OCH.sub.3                                                                             CH  S                                             H   SCH.sub.3    CH.sub.3                                                                            OCH.sub.3                                                                             N   S                                             H   SCH.sub.3    OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   SCH.sub.3    OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             H   SCH.sub.3    OCH.sub.3                                                                           Cl     CH  S                                             CH.sub.3                                                                           SC.sub.2 H.sub.5                                                                            OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   SC.sub.2 H.sub.5                                                                            CH.sub.3                                                                            CH.sub.3                                                                              CH  O                                             H   SC.sub.2 H.sub.5                                                                            CH.sub.3                                                                            CH.sub.3                                                                              N   O                                             H   SC.sub.2 H.sub.5                                                                            CH.sub.3                                                                            OCH.sub.3                                                                             CH  O                                             H   SC.sub.2 H.sub.5                                                                            CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   SC.sub.2 H.sub.5                                                                            OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   SC.sub.2 H.sub.5                                                                            OCH.sub.3                                                                           OCH.sub.3                                                                             N   O                                             H   SC.sub.2 H.sub.5                                                                            OCH.sub.3                                                                           Cl     CH  O                                             H   SC.sub.2 H.sub.5                                                                            CH.sub.3                                                                            CH.sub.3                                                                              CH  S                                             H   SC.sub.2 H.sub.5                                                                            CH.sub.3                                                                            OCH.sub.3                                                                             CH  S                                             H   SC.sub.2 H.sub.5                                                                            CH.sub.3                                                                            OCH.sub.3                                                                             N   S                                             H   SC.sub.2 H.sub.5                                                                            OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   SC.sub.2 H.sub.5                                                                            CH.sub.3                                                                            OCH.sub.3                                                                             N   S                                             H   SC.sub.2 H.sub.5                                                                            OCH.sub.3                                                                           Cl     CH  S                                             H   SC.sub.2 H.sub.5                                                                            CH.sub.3                                                                            OC.sub.2 H.sub.5                                                                      N   S                                             H   S -n-C.sub.3 H.sub.7                                                                        CH.sub.3                                                                            CH.sub.3                                                                              CH  O                                             H   S -n-C.sub.3 H.sub.7                                                                        CH.sub.3                                                                            CH.sub.2 OCH.sub.3                                                                    CH  O                                             H   S  -n-C.sub.3 H.sub.7                                                                       CH.sub.3                                                                            OCH.sub.3                                                                             CH  O                                             H   S -n-C.sub.3 H.sub.7                                                                        CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   S -n-C.sub.3 H.sub.7                                                                        OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   S -n-C.sub.3 H.sub.7                                                                        OCH.sub.3                                                                           OCH.sub.3                                                                             N   O                                             H   S -n-C.sub.3 H.sub.7                                                                        OCH.sub.3                                                                           Cl     CH  O                                             CH.sub.3                                                                           S -n-C.sub.3 H.sub.7                                                                        OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   S -n-C.sub.3 H.sub.7                                                                        CH.sub.3                                                                            CH.sub.3                                                                              CH  S                                             H   S -n-C.sub.3 H.sub.7                                                                        CH.sub.3                                                                            CH.sub.3                                                                              N   S                                             H   S -n-C.sub.3 H.sub.7                                                                        CH.sub.3                                                                            OCH.sub.3                                                                             CH  S                                             H   S -n-C.sub.3 H.sub.7                                                                        OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   S -n-C.sub.3 H.sub.7                                                                        OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             H   S -n-C.sub.3 H.sub.7                                                                        CH.sub.3                                                                            Cl     CH  S                                             H   S -n-C.sub.3 H.sub.7                                                                        CH.sub.3                                                                            OCH.sub.3                                                                             CH  O                                             H   S -n-C.sub.3 H.sub.7                                                                        OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   S -n-C.sub.3 H.sub.7                                                                        CH.sub.3                                                                            OCH.sub.3                                                                             N   S                                             CH.sub.3                                                                           S -n-C.sub.4 H.sub.9                                                                        OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   S -n-C.sub.4 H.sub.9                                                                        CH.sub.3                                                                            CH.sub.3                                                                              CH  O                                             H   S -n-C.sub.4 H.sub.9                                                                        CH.sub.3                                                                            CH.sub.3                                                                              N   O                                             H   S -n-C.sub.4 H.sub.9                                                                        CH.sub.3                                                                            OCH.sub.3                                                                             CH  O                                             H   S -n-C.sub.4 H.sub.9                                                                        CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   S -n-C.sub.4 H.sub.9                                                                        OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   S -n-C.sub.4 H.sub.9                                                                        OCH.sub.3                                                                           OCH.sub.3                                                                             N   O                                             H   S -n-C.sub.4 H.sub.9                                                                        OCH.sub.3                                                                           Cl     CH  O                                             H   S -n-C.sub.4 H.sub.9                                                                        CH.sub.3                                                                            CH.sub.3                                                                              CH  S                                             H   S -n-C.sub.4 H.sub.9                                                                        CH.sub.3                                                                            OCH.sub.3                                                                             N   S                                             H   S - n-C.sub.4 H.sub.9                                                                       CH.sub.3                                                                            OCH.sub.3                                                                             CH  S                                             H   S -n-C.sub.4 H.sub.9                                                                        OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             H   S -n-C.sub.4 H.sub.9                                                                        OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   S -n-C.sub.4 H.sub.9                                                                        OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             H   S -n-C.sub.4 H.sub.9                                                                        OCH.sub.3                                                                           OCF.sub.2 H                                                                           N   S                                             H   S -n-C.sub.4 H.sub.9                                                                        OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   S -n-C.sub.4 H.sub.9                                                                        CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   S -n-C.sub.4 H.sub.9                                                                        OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   S -n-C.sub.4 H.sub.9                                                                        CH.sub.3                                                                            OCH.sub.3                                                                             CH  S                                             H   S -n-C.sub.4 H.sub.9                                                                        CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   S -n-C.sub.4 H.sub.9                                                                        CH.sub.3                                                                            OCH.sub.3                                                                             CH  O                                             H   S -n-C.sub.4 H.sub.9                                                                        OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   S -n-C.sub.4 H.sub.9                                                                        OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             H   S -n-C.sub.4 H.sub.9                                                                        CH.sub.3                                                                            OCH.sub.3                                                                             CH  O                                             H   S -n-C.sub.4 H.sub.9                                                                        OCH.sub.3                                                                           OCH.sub.3                                                                             N   O                                             H   S -n-C.sub.4 H.sub.9                                                                        OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   S -n-C.sub.4 H.sub.9                                                                        CH.sub.3                                                                            OCH.sub.3                                                                             N   S                                             H   SCH.sub.2 CHCH.sub.2                                                                        CH.sub.3                                                                            CH.sub.3                                                                              CH  O                                             H   SCH.sub.2 CHCH.sub.2                                                                        CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   SCH.sub.2 CHCH.sub.2                                                                        CH.sub.3                                                                            OCH.sub.3                                                                             CH  O                                             H   SCH.sub.2 CHCH.sub.2                                                                        OCH.sub.3                                                                           OCH.sub.3                                                                             N   O                                             H   SCH.sub.2 CHCH.sub.2                                                                        OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   SCH.sub.2 CHCH.sub.2                                                                        OCH.sub.3                                                                           OCH.sub.3                                                                             N   O                                             H   SCH.sub.2 CHCH.sub.2                                                                        OCH.sub.3                                                                           Cl     CH  O                                             H   SCH.sub.2 CHCH.sub.2                                                                        CH.sub.3                                                                            OCH.sub.2 CF.sub.3                                                                    CH  O                                             CH.sub.3                                                                           SCH.sub.2 CHCH.sub.2                                                                        OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   SCH.sub.2 CHCH.sub.2                                                                        CH.sub.3                                                                            CH.sub.3                                                                              CH  S                                             H   SCH.sub.2 CHCH.sub.2                                                                        CH.sub.3                                                                            CH.sub.3                                                                              N   S                                             H   SCH.sub.2 CHCH.sub.2                                                                        CH.sub.3                                                                            OCH.sub.3                                                                             CH  S                                             H   SCH.sub.2 CHCH.sub.2                                                                        CH.sub.3                                                                            OCH.sub.3                                                                             N   S                                             H   SCH.sub.2 CHCH.sub.2                                                                        OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   SCH.sub.2 CHCH.sub.2                                                                        OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             H   SCH.sub.2 CHCH.sub.2                                                                        OCH.sub.3                                                                           Cl     CH  S                                             H    .sub.--ESCHCHCH.sub.3                                                                      CH.sub.3                                                                            OCH.sub.3                                                                             CH  O                                             H    .sub.--ESCHCHCH.sub.3                                                                      CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H    .sub.--ESCHCHCH.sub.3                                                                      OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H    .sub.--ESCHCHCH.sub.3                                                                      OCH.sub.3                                                                           OCH.sub.3                                                                             N   O                                             H    .sub.--ESCHCHCH.sub.3                                                                      CH.sub.3                                                                            OCH.sub.3                                                                             N   S                                             H    .sub.--ESCHCHCH.sub.3                                                                      CH.sub.3                                                                            OCH.sub.3                                                                             CH  S                                             H    .sub.--ESCHCHCH.sub.3                                                                      OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H    .sub.--ESCHCHCH.sub.3                                                                      OCH.sub.3                                                                           Cl     CH  S                                             H    .sub.--ZSCHCHCH.sub.3                                                                      CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H    .sub.--ZSCHCHCH.sub.3                                                                      OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H    .sub.--ZSCHCHCH.sub.3                                                                      OCH.sub.3                                                                           OCH.sub.3                                                                             N   O                                             H    .sub.--ZSCHCHCH.sub.3                                                                      OCH.sub.3                                                                           Cl     CH  O                                             H    .sub.--ZSCHCHCH.sub.3                                                                      CH.sub.3                                                                            CH.sub.3                                                                              CH  S                                             H    .sub.--ZSCHCHCH.sub.3                                                                      OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H    .sub.--ZSCHCHCH.sub.3                                                                      CH.sub.3                                                                            OCH.sub.3                                                                             N   S                                             H    .sub.--ZSCHCHCH.sub.3                                                                      OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             H   S(CH.sub.2).sub.2 CHCH.sub.2                                                                OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   S(CH.sub.2).sub.2 CHCH.sub.2                                                                OCH.sub.3                                                                           OCH.sub.3                                                                             N   O                                             H   S(CH.sub.2).sub.2 CHCH.sub.2                                                                CH.sub.3                                                                            OCH.sub.3                                                                             CH  O                                             H   S(CH.sub.2).sub.2 CHCH.sub.2                                                                OCH.sub.3                                                                           Cl     CH  O                                             H   S(CH.sub.2).sub.2 CHCH.sub.2                                                                OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   S(CH.sub.2).sub.2 CHCH.sub.2                                                                CH.sub.3                                                                            OCH.sub.3                                                                             N   S                                             H   S(CH.sub. 2).sub.2 CHCH.sub.2                                                               OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             H   S(CH.sub.2).sub.2 CHCH.sub.2                                                                CH.sub.3                                                                            CH.sub.3                                                                              CH  S                                             H    .sub.--ESCH.sub.2 CHCHCH.sub.3                                                             OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H    .sub.--ESCH.sub.2 CHCHCH.sub.3                                                             OCH.sub.3                                                                           OCH.sub.3                                                                             N   O                                             H    .sub.--ESCH.sub.2 CHCHCH.sub.3                                                             CH.sub.3                                                                            OCH.sub.3                                                                             CH  O                                             H    .sub.--ESCH.sub.2 CHCHCH.sub.3                                                             OCH.sub.3                                                                           Cl     CH  O                                             H    .sub.--ESCH.sub.2 CHCHCH.sub.3                                                             OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H    .sub.--ESCH.sub.2 CHCHCH.sub.3                                                             CH.sub.3                                                                            OCH.sub.3                                                                             N   S                                             H    .sub.--ESCH.sub.2 CHCHCH.sub.3                                                             CH.sub.3                                                                            OCH.sub.3                                                                             CH  S                                             H    .sub.--ESCH.sub.2 CHCHCH.sub.3                                                             CH.sub.3                                                                            CH.sub.3                                                                              CH  S                                             H    .sub.--ZSCH.sub.2 CHCHCH.sub.3                                                             CH.sub.3                                                                            OCH.sub.3                                                                             CH  O                                             H    .sub.--ZSCH.sub.2 CHCHCH.sub.3                                                             CH.sub. 3                                                                           OCH.sub.3                                                                             N   O                                             H    .sub.--ZSCH.sub.2 CHCHCH.sub.3                                                             OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H    .sub.--ZSCH.sub.2 CHCHCH.sub.3                                                             OCH.sub.3                                                                           Cl     CH  O                                             H    .sub.--ZSCH.sub.2 CHCHCH.sub.3                                                             CH.sub.3                                                                            OCH.sub.3                                                                             CH  S                                             H    .sub.--ZSCH.sub.2 CHCHCH.sub.3                                                             CH.sub.3                                                                            OCH.sub.3                                                                             N   S                                             H    .sub.--ZSCH.sub.2 CHCHCH.sub.3                                                             OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H    .sub.--ZSCH.sub.2 CHCHCH.sub.3                                                             OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             H    .sub.--ESCHCHC.sub.2 H.sub.5                                                               OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H    .sub.--ESCHCHC.sub.2 H.sub.5                                                               OCH.sub.3                                                                           OCH.sub.3                                                                             N   O                                             H    .sub.--ESCHCHC.sub.2 H.sub.5                                                               CH.sub.3                                                                            OCH.sub.3                                                                             CH  O                                             H    .sub.--ESCHCHC.sub.2 H.sub.5                                                               OCH.sub.3                                                                           Cl     CH  O                                             H    .sub.--ESCHCHC.sub.2 H.sub.5                                                               OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H    .sub.--ESCHCHC.sub.2 H.sub.5                                                               CH.sub.3                                                                            CH.sub.3                                                                              CH  S                                             H    .sub.--ESCHCHC.sub.2 H.sub.5                                                               CH.sub.3                                                                            OCH.sub.3                                                                             N   S                                             H    .sub.--ESCHCHC.sub.2 H.sub.5                                                               CH.sub.3                                                                            OCH.sub.3                                                                             CH  S                                             H    .sub.--ZSCHCHC.sub.2 H.sub.5                                                               OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H    .sub.--ZSCHCHC.sub.2 H.sub.5                                                               OCH.sub.3                                                                           OCH.sub.3                                                                             N   O                                             H    .sub.--ZSCHCHC.sub.2 H.sub.5                                                               CH.sub.3                                                                            CH.sub.3                                                                              CH  O                                             H    .sub.--ZSCHCHC.sub.2 H.sub.5                                                               CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H    .sub.--ZSCHCHC.sub.2 H.sub.5                                                               OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H    .sub.--ZSCHCHC.sub.2 H.sub.5                                                               CH.sub.3                                                                            OCH.sub.3                                                                             CH  S                                             H    .sub.--ZSCHCHC.sub.2 H.sub.5                                                               CH.sub.3                                                                            OCH.sub.3                                                                             N   S                                             H    .sub.--ZSCHCHC.sub.2 H.sub.5                                                               OCH.sub.3                                                                           Cl     CH  S                                             H   SCH.sub. 2 CCH                                                                              CH.sub.3                                                                            OCH.sub.3                                                                             CH  O                                             H   SCH.sub.2 CCH                                                                               CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   SCH.sub.2 CCH                                                                               OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   SCH.sub.2 CCH                                                                               OCH.sub.3                                                                           OCH.sub.3                                                                             N   O                                             H   SCH.sub.2 CCH                                                                               CH.sub.3                                                                            OCH.sub.3                                                                             CH  S                                             H   SCH.sub.2 CCH                                                                               OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             H   SCH.sub.2 CCH                                                                               OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   SCH.sub.2 CCH                                                                               OCH.sub.3                                                                           Cl     CH  S                                             CH.sub.3                                                                           SCH.sub.2 CCH                                                                               OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   SCCCH.sub.3  CH.sub.3                                                                            CH.sub.3                                                                              CH  O                                             H   SC CCH.sub.3 CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   SCCCH.sub.3  CH.sub.3                                                                            OCH.sub.3                                                                             CH  O                                             H   SCCCH.sub.3  OCH.sub.3                                                                           OCH.sub.3                                                                             N   O                                             H   SCCCH.sub.3  OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   SCCCH.sub.3  CH.sub.3                                                                            OCH.sub.3                                                                             N   S                                             H   SCCCH.sub.3  CH.sub.3                                                                            OCH.sub.3                                                                             CH  S                                             H   SCCCH.sub.3  OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             H   S(CH.sub.2).sub.2 CCH                                                                       CH.sub.3                                                                            OCH.sub.3                                                                             CH  O                                             H   S(CH.sub.2).sub.2 CCH                                                                       CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   S(CH.sub.2).sub.2 CCH                                                                       OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   S(CH.sub.2).sub. 2 CCH                                                                      OCH.sub.3                                                                           OCH.sub.3                                                                             N   O                                             H   S(CH.sub.2).sub.2 CCH                                                                       CH.sub.3                                                                            OCH.sub.3                                                                             CH  S                                             H   S(CH.sub.2).sub.2 CCH                                                                       CH.sub.3                                                                            OCH.sub.3                                                                             N   S                                             H   S(CH.sub.2).sub.2 CCH                                                                       OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   S(CH.sub.2).sub.2 CCH                                                                       OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             H   SCH.sub.2 CCCH.sub.3                                                                        CH.sub.3                                                                            CH.sub.3                                                                              CH  O                                             H   SCH.sub.2 CCCH.sub.3                                                                        CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   SCH.sub.2 CCCH.sub.3                                                                        CH.sub.3                                                                            OCH.sub.3                                                                             CH  O                                             H   SCH.sub.2 CCCH.sub.3                                                                        OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   SCH.sub.2 C CCH.sub.3                                                                       OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   SCH.sub.2 CCCH.sub.3                                                                        OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             H   SCH.sub.2 CCCH.sub.3                                                                        CH.sub.3                                                                            OCH.sub.3                                                                             CH  S                                             H   SCH.sub.2 CCCH.sub.3                                                                        OCH.sub.3                                                                           Cl     CH  S                                             H   SCCC.sub.2 H.sub.5                                                                          CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   SCCC.sub.2 H.sub.5                                                                          OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   SCCC.sub.2 H.sub.5                                                                          OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   SCCC.sub.2 H.sub.5                                                                          CH.sub.3                                                                            CH.sub.3                                                                              CH  S                                             CH.sub.3                                                                           SCCC.sub.2 H.sub.5                                                                          CH.sub.3                                                                            OCH.sub.3                                                                             CH  O                                             H   CH.sub.2 CN  CH.sub.3                                                                            CH.sub.3                                                                              CH  O                                             H   CH.sub.2 CN  CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   CH.sub.2 CN  CH.sub.3                                                                            OCH.sub.3                                                                             CH  O                                             H   CH.sub.2 CN  OCH.sub.3                                                                           OCH.sub.3                                                                             N   O                                             H   CH.sub.2 CN  OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   CH.sub.2 CN  OCH.sub.3                                                                           Cl     CH  O                                             H   CH.sub.2 CN  CH.sub.3                                                                            NHCH.sub.3                                                                            N   O                                             CH.sub.3                                                                           CH.sub.2 CN  OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   CH.sub.2 CN  CH.sub.3                                                                            CH.sub.3                                                                              CH  S                                             H   CH.sub.2 CN  CH.sub.3                                                                            CH.sub.3                                                                              N   S                                             H   CH.sub.2 CN  CH.sub.3                                                                            OCH.sub.3                                                                             CH  S                                             H   CH.sub.2 CN  CH.sub.3                                                                            OCH.sub.3                                                                             N   S                                             H   CH.sub.2 CN  OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   CH.sub.2 CN  OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             H   CH.sub.2 CN  OCH.sub.3                                                                           Cl     CH  S                                             CH.sub.3                                                                           CH.sub.2 CO.sub.2 CH.sub.3                                                                  CH.sub.3                                                                            OCH.sub.3                                                                             CH  O                                             H   CH.sub.2 CO.sub.2 CH.sub.3                                                                  CH.sub.3                                                                            CH.sub.3                                                                              CH  O                                             H   CH.sub.2 CO.sub.2 CH.sub.3                                                                  CH.sub.3                                                                            OCH.sub.3                                                                             CH  O                                             H   CH.sub.2 CO.sub.2 CH.sub.3                                                                  CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   CH.sub.2 CO.sub.2 CH.sub.3                                                                  OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   CH.sub.2 CO.sub.2 CH.sub. 3                                                                 OCH.sub.3                                                                           OCH.sub.3                                                                             N   O                                             H   CH.sub.2 CO.sub.2 CH.sub.3                                                                  OCH.sub.3                                                                           Cl     CH  O                                             H   CH.sub.2 CO.sub.2 CH.sub.3                                                                  CH.sub.3                                                                            CH.sub.3                                                                              CH  S                                             H   CH.sub.2 CO.sub.2 CH.sub.3                                                                  CH.sub.3                                                                            OCH.sub.3                                                                             N   S                                             H   CH.sub.2 CO.sub.2 CH.sub.3                                                                  CH.sub.3                                                                            OCH.sub.3                                                                             CH  S                                             H   CH.sub.2 CO.sub.2 CH.sub.3                                                                  OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             H   CH.sub.2 CO.sub.2 CH.sub.3                                                                  OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   CH.sub.2 CO.sub.2 CH.sub.3                                                                  OCH.sub.3                                                                           Cl     CH  S                                             H   CH.sub.2 CO.sub.2 CH.sub.3                                                                  CH.sub.3                                                                            N(CH.sub.3).sub.2                                                                     N   S                                             H   CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                                                           CH.sub.3                                                                            CH.sub.3                                                                              CH  O                                             H   CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                                                           CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                                                           CH.sub.3                                                                            OCH.sub.3                                                                             CH  O                                             H   CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                                                           OCH.sub.3                                                                           OCH.sub.3                                                                             N   O                                             H   CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                                                           OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                                                           OCH.sub.3                                                                           Cl     CH  O                                             H   CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                                                           OC.sub.2 H.sub.5                                                                    Cl     CH  O                                             CH.sub.3                                                                           CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                                                           OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                                                           CH.sub.3                                                                            CH.sub.3                                                                              CH  S                                             H   CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                                                           CH.sub.3                                                                            CH.sub.3                                                                              N   S                                             H   CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                                                           CH.sub.3                                                                            OCH.sub.3                                                                             CH  S                                             H   CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                                                           CH.sub.3                                                                            OCH.sub.3                                                                             N   S                                             H   CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                                                           OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                                                           OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             H   CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                                                           OCH.sub.3                                                                           Cl     CH  S                                             CH.sub.3                                                                           CH.sub.2 OCH.sub.3                                                                          OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   CH.sub.2 OCH.sub.3                                                                          CH.sub.3                                                                            CH.sub.3                                                                              CH  O                                             H   CH.sub.2 OCH.sub.3                                                                          CH.sub.3                                                                            CH.sub.3                                                                              N   O                                             H   CH.sub.2 OCH.sub.3                                                                          CH.sub.3                                                                            OCH.sub.3                                                                             CH  O                                             H   CH.sub.2 OCH.sub.3                                                                          CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   CH.sub.2 OCH.sub.3                                                                          OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   CH.sub.2 OCH.sub.3                                                                          OCH.sub.3                                                                           OCH.sub.3                                                                             N   O                                             H   CH.sub.2 OCH.sub.3                                                                          OCH.sub.3                                                                           Cl     CH  O                                             H   CH.sub.2 OCH.sub.3                                                                          CH.sub.3                                                                            CH.sub.3                                                                              CH  S                                             H   CH.sub.2 OCH.sub.3                                                                          CH.sub.3                                                                            OCH.sub.3                                                                             N   S                                             H   CH.sub.2 OCH.sub.3                                                                          CH.sub.3                                                                            OCH.sub.3                                                                             CH  S                                             H   CH.sub.2 OCH.sub.3                                                                          OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             H   CH.sub.2 OCH.sub.3                                                                          OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   CH.sub.2 OCH.sub.3                                                                          OCH.sub.3                                                                           Cl     CH  S                                             H   CH.sub.2 OCH.sub.3                                                                          CH.sub.3                                                                            CH(OCH.sub.3).sub.2                                                                   CH  S                                             H   CH.sub.2 OC.sub.2 H.sub.5                                                                   CH.sub.3                                                                            CH.sub.3                                                                              CH  O                                             H   CH.sub.2 OC.sub.2 H.sub.5                                                                   CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   CH.sub.2 OC.sub.2 H.sub.5                                                                   CH.sub.3                                                                            OCH.sub.3                                                                             CH  O                                             H   CH.sub.2 OC.sub.2 H.sub.5                                                                   OCH.sub.3                                                                           OCH.sub.3                                                                             N   O                                             H   CH.sub.2 OC.sub.2 H.sub.5                                                                   OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   CH.sub.2 OC.sub.2 H.sub.5                                                                   OCH.sub.3                                                                           Cl     CH  O                                             H   CH.sub.2 OC.sub.2 H.sub.5                                                                   OCH.sub.3                                                                           Br     CH  O                                             CH.sub.3                                                                           CH.sub.2 OC.sub.2 H.sub.5                                                                   CH.sub.3                                                                            OCH.sub.3                                                                             CH  S                                             H   CH.sub.2 OC.sub.2 H.sub.5                                                                   CH.sub.3                                                                            CH.sub.3                                                                              CH  S                                             H   CH.sub.2 OC.sub.2 H.sub.5                                                                   CH.sub.3                                                                            CH.sub.3                                                                              N   S                                             H   CH.sub.2 OC.sub.2 H.sub.5                                                                   CH.sub.3                                                                            OCH.sub.3                                                                             CH  S                                             H   CH.sub.2 OC.sub.2 H.sub.5                                                                   CH.sub.3                                                                            OCH.sub.3                                                                             N   S                                             H   CH.sub.2 OC.sub.2 H.sub.5                                                                   OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   CH.sub.2 OC.sub.2 H.sub.5                                                                   OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             H   CH.sub.2 OC.sub.2 H.sub.5                                                                   OCH.sub.3                                                                           Cl     CH  S                                             CH.sub.3                                                                           (CH.sub.2).sub.2 COCH.sub.3                                                                 OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   (CH.sub.2).sub.2 COCH.sub.3                                                                 CH.sub.3                                                                            CH.sub.3                                                                              CH  O                                             H   (CH.sub.2).sub.2 COCH.sub.3                                                                 CH.sub.3                                                                            CH.sub.3                                                                              N   O                                             H   (CH.sub.2).sub.2 COCH.sub.3                                                                 CH.sub.3                                                                            OCH.sub.3                                                                             CH  O                                             H   (CH.sub.2).sub.2 COCH.sub.3                                                                 CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   (CH.sub.2).sub.2 COCH.sub.3                                                                 OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   (CH.sub.2).sub.2 COCH.sub.3                                                                 OCH.sub.3                                                                           OCH.sub.3                                                                             N   O                                             H   (CH.sub.2).sub.2 COCH.sub.3                                                                 OCH.sub.3                                                                           Cl     CH  O                                             H   (CH.sub.2).sub.2 COCH.sub.3                                                                 CH.sub.3                                                                            CH.sub.3                                                                              CH  S                                             H   (CH.sub.2).sub.2 COCH.sub.3                                                                 CH.sub.3                                                                            OCH.sub.3                                                                             N   S                                             H   (CH.sub.2).sub.2 COCH.sub.3                                                                 CH.sub.3                                                                            OCH.sub.3                                                                             CH  S                                             H   (CH.sub.2).sub.2 COCH.sub.3                                                                 OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             H   (CH.sub.2).sub.2 COCH.sub.3                                                                 OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   (CH.sub.2).sub.2 COCH.sub.3                                                                 OCH.sub.3                                                                           Cl     CH  S                                             H   (CH.sub.2).sub.2 COCH.sub.3                                                                 CH.sub.3                                                                             ##STR155##                                                                           CH  S                                             H   (CH.sub.2).sub.2 CN                                                                         CH.sub.3                                                                            OCH.sub.3                                                                             CH  O                                             H   (CH.sub.2).sub.2 CN                                                                         CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   (CH.sub.2).sub.2 CN                                                                         OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   (CH.sub.2).sub.2 CN                                                                         OCH.sub.3                                                                           OCH.sub.3                                                                             N   O                                             H   (CH.sub.2).sub.2 CN                                                                         CH.sub.3                                                                            CH.sub.3                                                                              CH  S                                             H   (CH.sub.2).sub.2 CN                                                                         CH.sub.3                                                                            OCH.sub.3                                                                             N   S                                             H   (CH.sub.2).sub.2 CN                                                                         OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   (CH.sub.2).sub.2 CN                                                                         OCH.sub.3                                                                           Cl     CH  S                                             H   CH(CH.sub.3)CN                                                                              OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   CH(CH.sub.3)CN                                                                              OCH.sub.3                                                                           OCH.sub.3                                                                             N   O                                             H   CH(CH.sub.3)CN                                                                              CH.sub.3                                                                            OCH.sub.3                                                                             CH  S                                             H   CH(CH.sub.3)CN                                                                              CH.sub.3                                                                            OCH.sub.3                                                                             N   S                                             H   (CH.sub.2).sub.3 CN                                                                         CH.sub.3                                                                            OCH.sub.3                                                                             CH  O                                             H   (CH.sub.2).sub.3 CN                                                                         CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   (CH.sub.2).sub.3 CN                                                                         OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   (CH.sub.2).sub.3 CN                                                                         OCH.sub.3                                                                           OCH.sub.3                                                                             N   O                                             H   (CH.sub.2).sub.3 CN                                                                         CH.sub.3                                                                            CH.sub.3                                                                              CH  S                                             H   (CH.sub.2).sub.3 CN                                                                         CH.sub.3                                                                            OCH.sub.3                                                                             N   S                                             H   (CH.sub.2).sub.3 CN                                                                         OCH.sub.3                                                                           OCH.sub.3                                                                             CH.sub.3                                                                           S                                             H   (CH.sub.2).sub.3 CN                                                                         OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             H   CH.sub.2 CH(CH.sub.3)CN                                                                     CH.sub.3                                                                            OCH.sub.3                                                                             CH  O                                             H   CH.sub.2 CH(CH.sub.3)CN                                                                     CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   CH.sub.2 CH(CH.sub.3)CN                                                                     OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   CH.sub.2 CH(CH.sub.3)CN                                                                     OCH.sub.3                                                                           Cl     CH  S                                             H   CH.sub.2 CH(CH.sub.3)CN                                                                     CH.sub.3                                                                            CH.sub.3                                                                              CH  O                                             H   CH.sub. 2 CH(CH.sub.3)CN                                                                    CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   CH.sub.2 CH(CH.sub.3)CN                                                                     OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   CH.sub.2 CH(CH.sub.3)CN                                                                     OCH.sub.3                                                                           CH.sub.3                                                                              CH  S                                             CH.sub.3                                                                           CH.sub.2 CH(CH.sub.3)CN                                                                     OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   CH(CN)C.sub.2 H.sub.5                                                                       CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   CH(CN)C.sub.2 H.sub.5                                                                       OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   CH(CN)C.sub.2 H.sub.5                                                                       OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             H   CH(CN)C.sub.2 H.sub.5                                                                       OCH.sub.3                                                                           Cl     CH  S                                             H   C(CH.sub.3).sub.2 CN                                                                        CH.sub.3                                                                            CH.sub.3                                                                              CH  O                                             H   C(CH.sub.3).sub.2 CN                                                                        OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   C(CH.sub.3).sub.2 CN                                                                        OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             H   C(CH.sub.3).sub.2 CN                                                                        OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   CH(CH.sub.3)CO.sub.2 CH.sub.3                                                               OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   CH(CH.sub.3)CO.sub.2 CH.sub.3                                                               OCH.sub.3                                                                           OCH.sub.3                                                                             N   O                                             H   CH(CH.sub.3)CO.sub.2 CH.sub.3                                                               CH.sub.3                                                                            OCH.sub.3                                                                             CH  S                                             H   CH(CH.sub.3)CO.sub.2 CH.sub.3                                                               CH.sub.3                                                                            OCH.sub.3                                                                             N   S                                             H   (CH.sub.2).sub.3 CO.sub.2 CH.sub.3                                                          CH.sub. 3                                                                           OCH.sub.3                                                                             CH  O                                             H   (CH.sub.2).sub.3 CO.sub.2 CH.sub.3                                                          CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   (CH.sub.2).sub.3 CO.sub.2 CH.sub.3                                                          OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   (CH.sub.2).sub.3 CO.sub.2 CH.sub.3                                                          OCH.sub.3                                                                           OCH.sub.3                                                                             N   O                                             H   (CH.sub.2).sub.3 CO.sub.2 CH.sub.3                                                          CH.sub.3                                                                            OCH.sub.3                                                                             CH  S                                             H   (CH.sub.2).sub.3 CO.sub.2 CH.sub.3                                                          CH.sub.3                                                                            OCH.sub.3                                                                             N   S                                             H   (CH.sub.2).sub.3 CO.sub.2 CH.sub.3                                                          OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   (CH.sub.2).sub.3 CO.sub.2 CH.sub.3                                                          OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             H   CH.sub.2 CH(CH.sub.3)CO.sub.2 CH.sub.3                                                      CH.sub.3                                                                            OCH.sub.3                                                                             CH  O                                             H   CH.sub.2 CH(CH.sub.3)CO.sub.2 CH.sub.3                                                      CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   CH.sub.2 CH(CH.sub.3)CO.sub.2 CH.sub.3                                                      OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   CH.sub.2 CH(CH.sub.3)CO.sub.2 CH.sub.3                                                      OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             H   CH.sub.2 CH(CH.sub.3)CO.sub.2 CH.sub.3                                                      CH.sub.3                                                                            OCH.sub.3                                                                             CH  O                                             H   CH.sub.2 CH(CH.sub.3)CO.sub.2 CH.sub.3                                                      CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   CH.sub.2 CH(CH.sub.3)CO.sub.2 CH.sub.3                                                      OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   CH.sub.2 CH(CH.sub.3)CO.sub.2 CH.sub.3                                                      OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             H   CH(CO.sub.2 CH.sub.3)C.sub.2 H.sub.5                                                        CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   CH(CO.sub.2 CH.sub.3)C.sub.2 H.sub.5                                                        OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   CH(CO.sub.2 CH.sub.3)C.sub.2 H.sub.5                                                        OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             H   CH(CO.sub.2 CH.sub.3)C.sub.2 H.sub.5                                                        OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   C(CH.sub.3).sub.2 CO.sub.3 CH.sub.3                                                         CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   C(CH.sub.3).sub.2 CO.sub.3 CH.sub.3                                                         OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   C(CH.sub.3).sub.2 CO.sub.3 CH.sub.3                                                         CH.sub.3                                                                            OCH.sub.3                                                                             N   S                                             H   C(CH.sub.3).sub.2 CO.sub.3 CH.sub.3                                                         OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   (CH.sub.2).sub.2 CO.sub.2 C.sub.2 H.sub.5                                                   CH.sub.3                                                                            CH.sub.3                                                                              CH  O                                             H   (CH.sub.2).sub.2 CO.sub.2 C.sub.2 H.sub.5                                                   CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   (CH.sub.2).sub.2 CO.sub.2 C.sub.2 H.sub.5                                                   OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   (CH.sub.2).sub.2 CO.sub.2 C.sub.2 H.sub.5                                                   OCH.sub.3                                                                           OCH.sub.3                                                                             N   O                                             H   (CH.sub.2).sub.2 CO.sub.2 C.sub.2 H.sub.5                                                   OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   (CH.sub.2).sub.2 CO.sub.2 C.sub.2 H.sub.5                                                   CH.sub.3                                                                            OCH.sub.3                                                                             N   S                                             H   (CH.sub.2).sub.2 CO.sub.2 C.sub.2 H.sub.5                                                   OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   (CH.sub.2).sub.2 CO.sub.2 C.sub.2 H.sub.5                                                   OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             H   CH(CH.sub.3)CO.sub.2 C.sub.2 H.sub.5                                                        OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   CH(CH.sub.3)CO.sub.2 C.sub.2 H.sub.5                                                        OCH.sub.3                                                                           OCH.sub.3                                                                             N   O                                             H   CH(CH.sub.3)CO.sub.2 C.sub.2 H.sub.5                                                        CH.sub.3                                                                            OCH.sub.3                                                                             CH  S                                             H   CH(CH.sub.3)CO.sub.2 C.sub.2 H.sub.5                                                        CH.sub.3                                                                            OCH.sub.3                                                                             N   S                                             H   (CH.sub.2).sub.3 CO.sub.2 C.sub.2 H.sub.5                                                   CH.sub.3                                                                            OCH.sub.3                                                                             CH  O                                             H   (CH.sub.2).sub.3 CO.sub.2 C.sub.2 H.sub.5                                                   CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   (CH.sub.2).sub.3 CO.sub.2 C.sub.2 H.sub.5                                                   OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   (CH.sub.2 ).sub.3 CO.sub.2 C.sub.2 H.sub.5                                                  OCH.sub.3                                                                           OCH.sub.3                                                                             N   O                                             H   (CH.sub.2).sub.3 CO.sub.2 C.sub.2 H.sub.5                                                   CH.sub.3                                                                            OCH.sub.3                                                                             CH  S                                             H   (CH.sub.2).sub.3 CO.sub.2 C.sub.2 H.sub.5                                                   CH.sub.3                                                                            OCH.sub.3                                                                             N   S                                             H   (CH.sub.2).sub.3 CO.sub.2 C.sub.2 H.sub.5                                                   OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   (CH.sub.2).sub.3 CO.sub.2 C.sub.2 H.sub.5                                                   OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             H   CH.sub.2 CH(CH.sub.3)CO.sub.2 C.sub.2 H.sub.5                                               CH.sub.3                                                                            OCH.sub.3                                                                             CH  O                                             H   CH.sub.2 CH(CH.sub.3)CO.sub.2 C.sub.2 H.sub.5                                               CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   CH.sub.2 CH(CH.sub.3)CO.sub.2 C.sub.2 H.sub.5                                               OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   CH.sub.2 CH(CH.sub.3)CO.sub.2 C.sub.2 H.sub.5                                               OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             H   CH.sub.2 CH(CH.sub.3)CO.sub.2 C.sub.2 H.sub.5                                               CH.sub.3                                                                            OCH.sub.3                                                                             CH  O                                             H   CH.sub.2 CH(CH.sub.3)CO.sub.2 C.sub.2 H.sub.5                                               CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   CH.sub.2 CH(CH.sub.3)CO.sub.2 C.sub.2 H.sub.5                                               CH.sub.3                                                                            OCH.sub.3                                                                             CH  S                                             H   CH.sub.2 CH(CH.sub.3)CO.sub.2 C.sub.2 H.sub.5                                               OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             H   CH(CO.sub.2 C.sub.2 H.sub.5)C.sub.2 H.sub.5                                                 CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   CH(CO.sub.2 C.sub.2 H.sub.5)C.sub.2 H.sub.5                                                 OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   CH(CO.sub.2 C.sub.2 H.sub.5)C.sub.2 H.sub.5                                                 OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             H   CH(CO.sub.2 C.sub.2 H.sub.5)C.sub.2 H.sub.5                                                 OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   C(CH.sub.3).sub.2 CO.sub.2 C.sub.2 H.sub.5                                                  CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   C(CH.sub.3).sub.2 CO.sub.2 C.sub.2 H.sub.5                                                  OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   C(CH.sub.3).sub.2 CO.sub.2 C.sub.2 H.sub.5                                                  CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   C(CH.sub.3).sub.2 CO.sub.2 C.sub.2 H.sub.5                                                  OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   (CH.sub.2).sub.2 OCH.sub.3                                                                  CH.sub.3                                                                            CH.sub.3                                                                              CH  O                                             H   (CH.sub.2).sub.2 OCH.sub.3                                                                  CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   (CH.sub.2).sub.2 OCH.sub.3                                                                  OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   (CH.sub.2).sub.2 OCH.sub.3                                                                  OCH.sub.3                                                                           OCH.sub.3                                                                             N   O                                             H   (CH.sub.2).sub.2 OCH.sub.3                                                                  OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   (CH.sub.2).sub.2 OCH.sub.3                                                                  CH.sub.3                                                                            OCH.sub.3                                                                             N   S                                             H   (CH.sub.2).sub.2 OCH.sub.3                                                                  OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   (CH.sub.2).sub.2 OCH.sub.3                                                                  OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             H   CH(CH.sub.3)OCH.sub.3                                                                       OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   CH(CH.sub.3)OCH.sub.3                                                                       OCH.sub.3                                                                           OCH.sub.3                                                                             N   O                                             H   CH(CH.sub.3)OCH.sub.3                                                                       CH.sub.3                                                                            OCH.sub.3                                                                             CH  S                                             H   CH(CH.sub.3)OCH.sub.3                                                                       CH.sub.3                                                                            OCH.sub.3                                                                             N   S                                             H   (CH.sub.2).sub.3 OCH.sub.3                                                                  CH.sub.3                                                                            OCH.sub.3                                                                             CH  O                                             H   (CH.sub.2).sub.3 OCH.sub.3                                                                  CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   (CH.sub.2).sub.3 OCH.sub.3                                                                  OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   (CH.sub.2).sub.3 OCH.sub.3                                                                  OCH.sub.3                                                                           OCH.sub.3                                                                             N   O                                             H   (CH.sub.2).sub.3 OCH.sub.3                                                                  CH.sub.3                                                                            OCH.sub.3                                                                             CH  S                                             H   (CH.sub.2).sub.3 OCH.sub.3                                                                  CH.sub.3                                                                            OCH.sub.3                                                                             N   S                                             H   (CH.sub.2).sub.3 OCH.sub.3                                                                  OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   (CH.sub.2).sub.3 OCH.sub.3                                                                  OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             H   CH.sub.2 CH(CH.sub.3)OCH.sub.3                                                              CH.sub.3                                                                            OCH.sub.3                                                                             CH  O                                             H   CH.sub.2 CH(CH.sub.3)OCH.sub.3                                                              CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   CH.sub.2 CH(CH.sub.3)OCH.sub.3                                                              OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   CH.sub.2 CH(CH.sub.3)OCH.sub.3                                                              OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             H   CH.sub.2 CH(CH.sub.3)OCH.sub.3                                                              CH.sub.3                                                                            OCH.sub.3                                                                             CH  O                                             H   CH.sub.2 CH(CH.sub.3)OCH.sub.3                                                              CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   CH.sub.2 CH(CH.sub.3)OCH.sub.3                                                              CH.sub.3                                                                            OCH.sub.3                                                                             CH  S                                             H   CH.sub.2 CH(CH.sub.3)OCH.sub.3                                                              OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             H   CH(OCH.sub.3)C.sub.2 H.sub.5                                                                CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   CH(OCH.sub.3)C.sub.2 H.sub.5                                                                OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   CH(OCH.sub.3)C.sub.2 H.sub.5                                                                OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             H   CH(OCH.sub.3)C.sub.2 H.sub.5                                                                OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   C(CH.sub.3).sub.2 OCH.sub.3                                                                 CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   C(CH.sub.3).sub.2 OCH.sub.3                                                                 OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   C(CH.sub.3).sub.2 OCH.sub.3                                                                 CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   C(CH.sub.3).sub.2 OCH.sub.3                                                                 OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   (CH.sub.2).sub.2 OC.sub.2 H.sub.5                                                           CH.sub.3                                                                            CH.sub.3                                                                              CH  O                                             H   (CH.sub.2).sub.2 OC.sub.2 H.sub.5                                                           CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   (CH.sub.2).sub.2 OC.sub.2 H.sub.5                                                           OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   (CH.sub.2).sub.2 OC.sub.2 H.sub.5                                                           OCH.sub.3                                                                           OCH.sub.3                                                                             N   O                                             H   (CH.sub.2).sub.2 OC.sub.2 H.sub.5                                                           OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   (CH.sub.2).sub.2 OC.sub.2 H.sub.5                                                           CH.sub.3                                                                            OCH.sub.3                                                                             N   S                                             H   (CH.sub.2).sub.2 OC.sub.2 H.sub.5                                                           OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   (CH.sub.2).sub.2 OC.sub.2 H.sub.5                                                           OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             H   CH(CH.sub.3)OC.sub.2 H.sub.5                                                                OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   CH(CH.sub.3)OC.sub.2 H.sub.5                                                                OCH.sub.3                                                                           OCH.sub.3                                                                             N   O                                             H   CH(CH.sub.3)OC.sub.2 H.sub.5                                                                CH.sub.3                                                                            OCH.sub.3                                                                             CH  S                                             H   CH(CH.sub.3)OC.sub.2 H.sub.5                                                                CH.sub.3                                                                            OCH.sub.3                                                                             N   S                                             H   (CH.sub.2).sub.3 OC.sub.2 H.sub.5                                                           CH.sub.3                                                                            OCH.sub.3                                                                             CH  O                                             H   (CH.sub.2).sub.3 OC.sub.2 H.sub.5                                                           CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   (CH.sub.2).sub.3 OC.sub.2 H.sub.5                                                           OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   (CH.sub.2).sub.3 OC.sub.2 H.sub.5                                                           OCH.sub.3                                                                           OCH.sub.3                                                                             N   O                                             H   (CH.sub.2).sub.3 OC.sub.2 H.sub.5                                                           CH.sub.3                                                                            OCH.sub.3                                                                             CH  S                                             H   (CH.sub.2).sub.3 OC.sub.2 H.sub.5                                                           CH.sub.3                                                                            OCH.sub.3                                                                             N   S                                             H   (CH.sub.2).sub.3 OC.sub.2 H.sub.5                                                           OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   (CH.sub.2).sub.3 OC.sub.2 H.sub.5                                                           OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             H   CH.sub.2 CH(CH.sub.3)OC.sub.2 H.sub.5                                                       CH.sub.3                                                                            OCH.sub.3                                                                             CH  O                                             H   CH.sub.2 CH(CH.sub.3)OC.sub.2 H.sub.5                                                       CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   CH.sub.2 CH(CH.sub.3)OC.sub.2 H.sub.5                                                       OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   CH.sub.2 CH(CH.sub.3)OC.sub.2 H.sub.5                                                       OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             H   CH(CH.sub.3)CH.sub.2 OC.sub.2 H.sub.5                                                       CH.sub.3                                                                            OCH.sub.3                                                                             CH  O                                             H   CH(CH.sub.3)CH.sub.2 OC.sub.2 H.sub.5                                                       CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   CH(CH.sub.3)CH.sub. 2 OC.sub.2 H.sub.5                                                      CH.sub.3                                                                            OCH.sub.3                                                                             CH  S                                             H   CH(CH.sub.3)CH.sub.2 OC.sub.2 H.sub.5                                                       OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             H   CH(OC.sub.2 H.sub.5)C.sub.2 H.sub.5                                                         CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   CH(OC.sub.2 H.sub.5)C.sub.2 H.sub.5                                                         OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   CH(OC.sub.2 H.sub.5)C.sub.2 H.sub.5                                                         OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             H   CH(OC.sub.2 H.sub.5)C.sub.2 H.sub.5                                                         OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   CH(CH.sub.3).sub.2 OC.sub.2 H.sub.5                                                         CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   CH(CH.sub.3).sub.2 OC.sub.2 H.sub.5                                                         OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   CH(CH.sub.3).sub.2 OC.sub.2 H.sub.5                                                         CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   C(CH.sub.3).sub.2 OC.sub.2 H.sub.5                                                          OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   (CH.sub.2)CH.sub.2 COCH.sub.3                                                               CH.sub.3                                                                            CH.sub.3                                                                              CH  O                                             H   (CH.sub.2)CH.sub.2 COCH.sub.3                                                               CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   (CH.sub.2)CH.sub.2 COCH.sub.3                                                               OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   (CH.sub.2)CH.sub.2 COCH.sub.3                                                               OCH.sub.3                                                                           OCH.sub.3                                                                             N   O                                             H   (CH.sub. 2)CH.sub.2 COCH.sub.3                                                              OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   (CH.sub.2)CH.sub.2 COCH.sub.3                                                               CH.sub.3                                                                            OCH.sub.3                                                                             N   S                                             H   (CH.sub.2)CH.sub.2 COCH.sub.3                                                               OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   (CH.sub.2)CH.sub.2 COCH.sub.3                                                               OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             H   CH(CH.sub.3)CH.sub.2 COCH.sub.3                                                             OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   CH(CH.sub.3)CH.sub.2 COCH.sub.3                                                             OCH.sub.3                                                                           OCH.sub.3                                                                             N   O                                             H   CH(CH.sub.3)CH.sub.2 COCH.sub.3                                                             CH.sub.3                                                                            OCH.sub.3                                                                             CH  S                                             H   CH(CH.sub.3)CH.sub.2 COCH.sub.3                                                             CH.sub.3                                                                            OCH.sub.3                                                                             N   S                                             H   (CH.sub.2).sub.3 CH.sub.2 COCH.sub.3                                                        CH.sub.3                                                                            OCH.sub.3                                                                             CH  O                                             H   (CH.sub.2).sub.3 CH.sub.2 COCH.sub.3                                                        CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   (CH.sub.2).sub.3 CH.sub.2 COCH.sub.3                                                        OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   (CH.sub.2).sub.3 CH.sub.2 COCH.sub.3                                                        OCH.sub.3                                                                           OCH.sub.3                                                                             N   O                                             H   (CH.sub.2).sub.3 CH.sub.2 COCH.sub.3                                                        CH.sub.3                                                                            OCH.sub.3                                                                             CH  S                                             H   (CH.sub.2).sub.3 CH.sub.2 COCH.sub.3                                                        CH.sub.3                                                                            OCH.sub.3                                                                             N   S                                             H   (CH.sub.2).sub.3 CH.sub.2 COCH.sub. 3                                                       OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   (CH.sub.2).sub.3 CH.sub.2 COCH.sub.3                                                        OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             H   CH.sub.2 CH(CH.sub.3)CH.sub.2 COCH.sub.3                                                    CH.sub.3                                                                            OCH.sub.3                                                                             CH  O                                             H   CH.sub.2 CH(CH.sub.3)CH.sub.2 COCH.sub.3                                                    CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   CH.sub.2 CH(CH.sub.3)CH.sub.2 COCH.sub.3                                                    OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   CH.sub.2 CH(CH.sub.3)CH.sub.2 COCH.sub.3                                                    OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             H   CH(CH.sub.3)CH.sub.2 CH.sub.2 COCH.sub.3                                                    CH.sub.3                                                                            OCH.sub.3                                                                             CH  O                                             H   CH(CH.sub.3)CH.sub.2 CH.sub.2 COCH.sub.3                                                    CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   CH(CH.sub.3)CH.sub.2 CH.sub.2 COCH.sub.3                                                    CH.sub.3                                                                            OCH.sub.3                                                                             CH  S                                             H   CH(CH.sub.3)CH.sub.2 CH.sub.2 COCH.sub.3                                                    OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             H   CH(C.sub.2 H.sub.5)CH.sub.2 COCH.sub.3                                                      CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   CH(C.sub.2 H.sub.5)CH.sub.2 OCH.sub.3                                                       OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   CH(C.sub.2 H.sub.5)CH.sub.2 OCH.sub.3                                                       OCH.sub.3                                                                           OCH.sub.3                                                                             N   S                                             H   CH(C.sub.2 H.sub.5)CH.sub.2 OCH.sub.3                                                       OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   CH(CH.sub.3).sub.2 CH.sub.2 COCH.sub.3                                                      CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   CH(CH.sub.3).sub.2 CH.sub.2 COCH.sub.3                                                      OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O                                             H   CH(CH.sub.3).sub.2 CH.sub.2 COCH.sub.3                                                      CH.sub.3                                                                            OCH.sub.3                                                                             N   O                                             H   C(CH.sub.3).sub.2 CH.sub.2 COCH.sub.3                                                       OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S                                             H   H            OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O *                                           H   H            OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S *                                           H   CH.sub.3     OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O *                                           H   CH.sub.3     OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S *                                           H   SCH.sub.3    OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O *                                           H   SCH.sub.3    OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S *                                           H   SCH.sub.2 CHCH.sub.2                                                                        OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O *                                           H   SCH.sub.3 CHCH.sub.2                                                                        OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S *                                           H   SH           OCH.sub.3                                                                           OCH.sub.3                                                                             CH  O *                                           H   SH           OCH.sub.3                                                                           OCH.sub.3                                                                             CH  S *                                           __________________________________________________________________________      W is O, unless indicated by * where W is S in all Tables.                

                  TABLE 9b                                                         ______________________________________                                         General Structure 3 wherein Q is Q-28.                                                                                     m.p.                               R     R.sub.3                                                                               R.sub.4 X     Y       Z        °C.                         ______________________________________                                         H     H      H       CH.sub.3                                                                             OCH.sub.3                                                                              CH       172-174                            H     H      H       CH.sub.3                                                                             OCH.sub.3                                                                              N        206-208                            H     H      H       OCH.sub.3                                                                            OCH.sub.3                                                                              CH       207-209                            H     H      H       OCH.sub.3                                                                            OCH.sub.3                                                                              N        169-174                            H     H      H       CH.sub.3                                                                             CH.sub.3                                                                               CH       231-232                            H     H      H       CH.sub.3                                                                             CH.sub.3                                                                               N                                           H     CH.sub.3                                                                              H       CH.sub.3                                                                             OCH.sub.3                                                                              CH                                          H     H      H       Cl    OCH.sub.3                                                                              CH       208-210                            H     H      CH.sub.3                                                                               CH.sub.3                                                                             OCH.sub.3                                                                              N                                           H     CH.sub.3                                                                              CH.sub.3                                                                               OCH.sub.3                                                                            OCH.sub.3                                                                              CH                                          CH.sub.3                                                                             CH.sub.3                                                                              CH.sub.3                                                                               OCH.sub.3                                                                            OCH.sub.3                                                                              N                                           H     H      H       CH.sub.3                                                                              ##STR156##                                                                            CH                                          H     H      H       CH.sub.3                                                                             C.sub.2 H.sub.5                                                                        CH                                          H     CH.sub.3                                                                              H       CH.sub. 3                                                                            CH.sub.3                                                                               CH                                          H     CH.sub.3                                                                              H       CH.sub.3                                                                             OCH.sub.3                                                                              N                                           H     CH.sub.3                                                                              H       OCH.sub.3                                                                            OCH.sub.3                                                                              CH                                          H     CH.sub.3                                                                              H       OCH.sub.3                                                                            OCH.sub.3                                                                              N                                           H     CH.sub.3                                                                              H       OCH.sub.3                                                                            Cl      CH                                          H     CH.sub.3                                                                              H       CH.sub.3                                                                             CH.sub.3                                                                               N                                           H     Cl     H       CH.sub.3                                                                             CH.sub.3                                                                               CH                                          H     Cl     H       CH.sub.3                                                                             CH.sub.3                                                                               N                                           H     Cl     H       CH.sub.3                                                                             OCH.sub.3                                                                              CH                                          H     Cl     H       CH.sub.3                                                                             OCH.sub.3                                                                              N                                           H     Cl     H       OCH.sub.3                                                                            OCH.sub.3                                                                              CH                                          H     Cl     H       OCH.sub.3                                                                            OCH.sub.3                                                                              N                                           H     Cl     H       OCH.sub.3                                                                            Cl      CH                                          H     Cl     CH.sub.3                                                                               CH.sub.3                                                                             OCH.sub.3                                                                              CH                                          H     Cl     CH.sub.3                                                                               CH.sub.3                                                                             OCH.sub.3                                                                              N                                           H     Cl     CH.sub.3                                                                               OCH.sub.3                                                                            OCH.sub.3                                                                              CH                                          H     Cl     CH.sub.3                                                                               OCH.sub.3                                                                            OCH.sub.3                                                                              N                                           H     Br     H       OCH.sub.3                                                                            OCH.sub.3                                                                              CH                                          H     Br     H       CH.sub.3                                                                             CH.sub.3                                                                               CH                                          H     Br     H       CH.sub.3                                                                             OCH.sub.3                                                                              N                                           H     Br     H       CH.sub.3                                                                             OCH.sub.3                                                                              CH                                          H     Br     H       OCH.sub.3                                                                            OCH.sub.3                                                                              N                                           H     Br     H       OCH.sub.3                                                                            OCH.sub.3                                                                              CH                                          H     Br     H       OCH.sub.3                                                                            Cl      CH                                          H     H      H       OCH.sub.3                                                                            OCH.sub. 3                                                                             CH   *                                      H     CH.sub.3                                                                              H       OCH.sub.3                                                                            OCH.sub.3                                                                              CH   *                                      H     H      CH.sub.3                                                                               OCH.sub.3                                                                            OCH.sub.3                                                                              CH   *                                      H     CH.sub.3                                                                              CH.sub.3                                                                               OCH.sub.3                                                                            OCH.sub.3                                                                              CH   *                                      H     Cl     H       OCH.sub.3                                                                            OCH.sub.3                                                                              CH   *                                      H     Cl     CH.sub.3                                                                               OCH.sub.3                                                                            OCH.sub.3                                                                              CH   *                                      H     Br     H       OCH.sub.3                                                                            OCH.sub.3                                                                              CH   *                                      H     Br     CH.sub.3                                                                               OCH.sub.3                                                                            OCH.sub.3                                                                              CH   *                                      ______________________________________                                          *Wherein W is O, unless indicated by * where W is S in all Tables.       

                  TABLE 9c                                                         ______________________________________                                         General Structure 3                                                                                                            m.p.                           Q    R      R.sub.3 R.sub.4                                                                              X     Y       Z   n'  °C.                     ______________________________________                                         Q-33 H      H       H     CH.sub.3                                                                             OCH.sub.3                                                                              CH  0                                  Q-33 H      H       H     CH.sub.3                                                                             OCH.sub.3                                                                              N   0                                  Q-33 H      H       H     OCH.sub.3                                                                            OCH.sub.3                                                                              CH  0                                  Q-33 H      H       H     OCH.sub.3                                                                            OCH.sub.3                                                                              N   0                                  Q-33 H      H       H     CH.sub.3                                                                             CH.sub.3                                                                               CH  0                                  Q-33 H      3-CH.sub.3                                                                             H     CH.sub.3                                                                             OCH.sub.3                                                                              CH  0                                  Q-33 H      4-CH.sub.3                                                                             H     CH.sub.3                                                                             OCH.sub.3                                                                              CH  0                                  Q-33 H      5-CH.sub.3                                                                             H     CH.sub.3                                                                             OCH.sub.3                                                                              CH  0                                  Q-33 H      H       H     CH.sub.3                                                                             CH.sub.3                                                                               N   0                                  Q-33 H      6-CH.sub.3                                                                             H     CH.sub.3                                                                             OCH.sub.3                                                                              CH  0                                  Q-33 H      3-CH.sub.3                                                                             5-CH.sub.3                                                                           CH.sub.3                                                                             OCH.sub.3                                                                              N   0                                  Q-33 H      4-CH.sub.3                                                                             6-CH.sub.3                                                                           CH.sub.3                                                                             OCH.sub.3                                                                              N   0                                  Q-33 CH.sub.3                                                                              H       H     OCH.sub.3                                                                            OCH.sub.3                                                                              CH  0                                  Q-33 H      H       H     CH.sub.3                                                                             CH.sub.2 OCH.sub.3                                                                     CH  0                                  Q-33 H      H       H     Cl    OC.sub.2 H.sub.5                                                                       CH  0                                  Q-33 H      H       H     CH.sub.3                                                                             CF.sub.3                                                                               CH  0                                  Q-33 H      H       H     Cl    OCH.sub.3                                                                              CH  1                                  Q-33 H      H       H     CH.sub.3                                                                             OCH.sub.3                                                                              CH  1                                  Q-33 H      H       H     CH.sub.3                                                                             OCH.sub.3                                                                              N   1                                  Q-33 H      H       H     OCH.sub.3                                                                            OCH.sub.3                                                                              CH  1                                  Q-33 H      H       H     OCH.sub.3                                                                            OCH.sub.3                                                                              N   1                                  Q-33 H      H       H     CH.sub.3                                                                             CH.sub.3                                                                               CH  1                                  Q-33 H      3-CH.sub.3                                                                             H     CH.sub.3                                                                             OCH.sub.3                                                                              CH  1                                  Q-33 H      4-CH.sub.3                                                                             H     CH.sub.3                                                                             OCH.sub.3                                                                              CH  1                                  Q-33 H      5-CH.sub.3                                                                             H     CH.sub.3                                                                             OCH.sub.3                                                                              CH  1                                  Q-33 H      H       H     CH.sub.3                                                                             CH.sub.3                                                                               N   1                                  Q-33 H      6-CH.sub.3                                                                             H     CH.sub.3                                                                             OCH.sub.3                                                                              CH  1                                  Q-33 H      3-CH.sub.3                                                                             5-CH.sub.3                                                                           CH.sub.3                                                                             OCH.sub.3                                                                              N   1                                  Q-33 H      4-CH.sub.3                                                                             6-CH.sub.3                                                                           CH.sub.3                                                                             OCH.sub.3                                                                              N   1                                  Q-33 CH.sub.3                                                                              H       H     OCH.sub.3                                                                            OCH.sub.3                                                                              CH  1                                  Q-33 H      H       H     CH.sub.3                                                                             CH.sub.2 OCH.sub.3                                                                     CH  1                                  Q-33 H      H       H     Cl    OC.sub.2 H.sub.5                                                                       CH  1                                  Q-33 H      H       H     CH.sub.3                                                                             CF.sub.3                                                                               CH  1                                  Q-34 H      H       H     CH.sub.3                                                                             OCH.sub.3                                                                              CH  0                                  Q-34 H      H       H     CH.sub.3                                                                             OCH.sub.3                                                                              N   0                                  Q-34 H      H       H     OCH.sub.3                                                                            OCH.sub.3                                                                              CH  0                                  Q-34 H      H       H     OCH.sub.3                                                                            OCH.sub.3                                                                              N   0                                  Q-34 H      2-CH.sub.3                                                                             H     CH.sub.3                                                                             CH.sub.3                                                                               CH  0                                  Q-34 H      4-CH.sub.3                                                                             H     CH.sub.3                                                                             CH.sub.3                                                                               N   0                                  Q-34 H      5-CH.sub.3                                                                             H     CH.sub.3                                                                             OCH.sub.3                                                                              CH  0                                  Q-34 H      6-CH.sub.3                                                                             H     CH.sub.3                                                                             OCH.sub.3                                                                              N   0                                  Q-34 H      2-CH.sub.3                                                                             6-CH.sub.3                                                                           OCH.sub.3                                                                            OCH.sub.3                                                                              CH  0                                  Q-34 H      4-CH.sub.3                                                                             6-CH.sub.3                                                                           OCH.sub.3                                                                            OCH.sub.3                                                                              N   0                                  Q-34 H      H       H     CH.sub.3                                                                             CH.sub.3                                                                               N   0                                  Q-34 CH.sub.3                                                                              H       H     CH.sub.3                                                                             CH.sub.3                                                                               CH  0                                  Q-34 H      H       H     CH.sub.3                                                                             CH.sub.3                                                                               CH  0                                  Q-34 H      H       H     CH.sub.3                                                                             OCF.sub.2 H                                                                            CH  0                                  Q-34 H      H       H     CH.sub.3                                                                             OCH.sub.3                                                                              CH  1                                  Q-34 H      H       H     CH.sub.3                                                                             OCH.sub.3                                                                              N   1                                  Q-34 H      H       H     OCH.sub.3                                                                            OCH.sub.3                                                                              CH  1                                  Q-34 H      H       H     OCH.sub.3                                                                            OCH.sub.3                                                                              N   1                                  Q-34 H      2-CH.sub.3                                                                             H     CH.sub.3                                                                             CH.sub.3                                                                               CH  1                                  Q-34 H      4-CH.sub.3                                                                             H     CH.sub.3                                                                             CH.sub.3                                                                               N   1                                  Q-34 H      5-CH.sub.3                                                                             H     CH.sub.3                                                                             OCH.sub.3                                                                              CH  1                                  Q-34 H      6-CH.sub.3                                                                             H     CH.sub.3                                                                             OCH.sub.3                                                                              N   1                                  Q-34 H      2-CH.sub.3                                                                             6-CH.sub.3                                                                           OCH.sub.3                                                                            OCH.sub.3                                                                              CH  1                                  Q-34 H      4-CH.sub.3                                                                             6-CH.sub.3                                                                           OCH.sub.3                                                                            OCH.sub.3                                                                              N   1                                  Q-34 H      H       H     CH.sub.3                                                                             CH.sub.3                                                                               N   1                                  Q-34 CH.sub.3                                                                              H       H     CH.sub.3                                                                             CH.sub.3                                                                               CH  1                                  Q-34 H      H       H     CH.sub.3                                                                             CH.sub.3                                                                               CH  1                                  Q-34 H      H       H     CH.sub.3                                                                             OCF.sub.2 H                                                                            CH  1                                  Q-35 H      H       H     CH.sub.3                                                                             OCH.sub.3                                                                              CH  0                                  Q-35 H      H       H     CH.sub.3                                                                             OCH.sub.3                                                                              N   0                                  Q-35 H      H       H     OCH.sub.3                                                                            OCH.sub.3                                                                              CH  0                                  Q-35 H      H       H     OCH.sub.3                                                                            OCH.sub.3                                                                              N   0                                  Q-35 H      2-CH.sub.3                                                                             H     CH.sub.3                                                                             CH.sub.3                                                                               CH  0                                  Q-35 H      H       H     Cl    OCH.sub.3                                                                              CH  0                                  Q-35 H      3-CH.sub.3                                                                             H     CH.sub.3                                                                             CH.sub.3                                                                               N   0                                  Q-35 H      2-CH.sub.3                                                                             6-CH.sub.3                                                                           CH.sub.3                                                                             OCH.sub.3                                                                              CH  0                                  Q-35 H      2-CH.sub.3                                                                             3-CH.sub.3                                                                           CH.sub.3                                                                             OCH.sub.3                                                                              N   0                                  Q-35 H      3-CH.sub.3                                                                             5-CH.sub.3                                                                           CH.sub.3                                                                             OCH.sub.3                                                                              N   0                                  Q-35 H      H       H     CH.sub.3                                                                             CH.sub.3                                                                               N   0                                  Q-35 CH.sub.3                                                                              H       H     OCH.sub.3                                                                            OCH.sub.3                                                                              CH  0                                  Q-35 H      H       H     CH.sub.3                                                                             OCH.sub.2 CF.sub.3                                                                     CH  0                                  Q-35 H      H       H     CH.sub.3                                                                             CH.sub.3                                                                               CH  0                                  Q-35 H      H       H     CH.sub.3                                                                             OCH.sub.3                                                                              CH  1                                  Q-35 H      H       H     CH.sub.3                                                                             OCH.sub.3                                                                              N   1                                  Q-35 H      H       H     OCH.sub.3                                                                            OCH.sub.3                                                                              CH  1                                  Q-35 H      H       H     OCH.sub.3                                                                            OCH.sub.3                                                                              N   1                                  Q-35 H      2-CH.sub.3                                                                             H     CH.sub.3                                                                             CH.sub.3                                                                               CH  1                                  Q-35 H      H       H     Cl    OCH.sub.3                                                                              CH  1                                  Q-35 H      3-CH.sub.3                                                                             H     CH.sub.3                                                                             CH.sub.3                                                                               N   1                                  Q-35 H      2-CH.sub.3                                                                             6-CH.sub.3                                                                           CH.sub.3                                                                             OCH.sub.3                                                                              CH  1                                  Q-35 H      2-CH.sub.3                                                                             3-CH.sub.3                                                                           CH.sub.3                                                                             OCH.sub.3                                                                              N   1                                  Q-35 H      3-CH.sub.3                                                                             5-CH.sub.3                                                                           CH.sub.3                                                                             OCH.sub.3                                                                              N   1                                  Q-35 H      H       H     CH.sub.3                                                                             CH.sub.3                                                                               N   1                                  Q-35 CH.sub.3                                                                              H       H     OCH.sub.3                                                                            OCH.sub.3                                                                              CH  1                                  Q-35 H      H       H     CH.sub.3                                                                             OCH.sub.2 CF.sub.3                                                                     CH  1                                  Q-35 H      H       H     CH.sub.3                                                                             CH.sub.3                                                                               CH  1                                  ______________________________________                                    

                                      TABLE 10                                     __________________________________________________________________________     General Structure 4                                                            Q             R  W'                                                                               W" A                                                        __________________________________________________________________________     Q-1                                                                               (R.sub.1, R.sub.2 = H)                                                                    H  --                                                                               -- A-2 (X.sub.1 = OCH.sub.3, Y.sub.1 = O)                   Q-1                                                                               (R.sub.1, R.sub.2 = H)                                                                    H  --                                                                               -- A-2 (X.sub.1 = CH.sub.3, Y.sub.1 = O)                    Q-1                                                                               (R.sub.1, R.sub.2 = H)                                                                    H  --                                                                               -- A-3 (X.sub.1 = OCH.sub.3)                                Q-1                                                                               (R.sub.1, R.sub.2 = H)                                                                    H  --                                                                               -- A-4 (X.sub.1, Y.sub.2 = CH.sub.3)                        Q-1                                                                               (R.sub.1, R.sub.2 = H)                                                                    H  --                                                                               -- A-5 (X.sub.2 = OCH.sub.3, Y.sub.3 = CH.sub.3)            Q-1                                                                               (R.sub.1, R.sub.2 = H)                                                                    H  --                                                                               -- A-6 (X.sub.3 = CH.sub. 3)                                Q-2                                                                               (R.sub.3, R.sub.4, R.sub.5 = H)                                                           H  S -- A-2 (X.sub.1 = CH.sub.3, Y.sub.1 = O)                    Q-2                                                                               (R.sub.3, R.sub.4, R.sub.5 = H)                                                           H  S -- A-3 (X.sub.1 = OCH.sub.3)                                Q-2                                                                               (R.sub.3, R.sub.4, R.sub.5 = H)                                                           H  O -- A-4 (X.sub.1, Y.sub.2 = CH.sub.3)                        Q-3                                                                               (R.sub.3, R.sub.4, R.sub.5 = H)                                                           H  S -- A-2 (X.sub.1 = OCH.sub.3, Y.sub.1 = CH.sub.2)            Q-3                                                                               (R.sub.3, R.sub.4, R.sub.5 = H)                                                           H  S -- A-3 (X.sub.1 = CH.sub.3)                                 Q-3                                                                               (R.sub.3, R.sub.4, R.sub.5 = H)                                                           H  O -- A-4 (X.sub.1 = CH.sub.3, Y.sub.2 = H)                    Q-4                                                                               (R.sub.3, R.sub.4, R.sub.5 =  H)                                                          H  --                                                                               -- A-2 (X.sub.1 = OCH.sub.3, Y.sub.1 = O)                   Q-4                                                                               (R.sub.3, R.sub.4, R.sub.5 = H)                                                           H  --                                                                               -- A-5 (X.sub.2 = OCH.sub.3, Y.sub.3 = CH.sub.3)            Q-4                                                                               (R.sub.3, R.sub.4, R.sub.5 = H)                                                           H  --                                                                               -- A-6 (X.sub.3 = OCH.sub.3)                                Q-7                                                                               (R.sub.3, R.sub.4, R.sub.5, R.sub.6 = H)                                                  H  --                                                                               -- A-2 (X.sub.1 = OCF.sub.2 H, Y.sub.1 = O)                 Q-7                                                                               (R.sub.3, R.sub.4, R.sub.5, R.sub.6 = H)                                                  H  --                                                                               -- A-3 (X.sub.1 = OCH.sub.2 CH.sub.3)                       Q-7                                                                               (R.sub.3, R.sub.4, R.sub.5, R.sub.6 = H)                                                  H  --                                                                               -- A-4 (X.sub.1 = OCH.sub.3, Y.sub.2 = CH.sub.3)            Q-7                                                                               (R.sub.3, R.sub.4 , R.sub.5, R.sub.6 = H)                                                 H  --                                                                               -- A-5 (X.sub.2 = SCH.sub.3, Y.sub.3 = CH.sub.3)            Q-7                                                                               (R.sub.3, R.sub.4, R.sub.5, R.sub.6 = H)                                                  H  --                                                                               -- A-6 (X.sub.3 = OCH.sub.3)                                Q-10                                                                              (R.sub.3, R.sub.4 = H)                                                                    H  --                                                                               O  A-2 (X.sub.1 = OCH.sub.3, Y.sub.1 = O)                   Q-10                                                                              (R.sub.3, R.sub.4 = H)                                                                    H  --                                                                               O  A-3 (X.sub.1 = OCH.sub.3)                                Q-10                                                                              (R.sub.3, R.sub.4 = H)                                                                    H  --                                                                               S  A-4 (X.sub.1 = CH.sub.3, Y.sub.2 = CH.sub.3)             Q-11                                                                              (R.sub.3, R.sub.4 = H)                                                                    H  --                                                                               O  A-2 (X.sub.1 = OCH.sub.3, Y.sub.1 = CH.sub.2)            Q-11                                                                              (R.sub.3, R.sub.4 = H)                                                                    H  --                                                                               O  A-3 (X.sub.1  = CH.sub.3)                                Q-11                                                                              (R.sub.3, R.sub.4 = H)                                                                    H  --                                                                               S  A-4 (X.sub.1 = OCH.sub.3, Y.sub.2 = H)                   Q-16                                                                              (R.sub.3, R.sub.4, R.sub.5, R.sub.6 = H)                                                  H  O -- A-2 (X.sub.1 = CH.sub.3, Y.sub.1 = O)                    Q-16                                                                              (R.sub.3, R.sub.4, R.sub.5, R.sub.6 = H)                                                  H  O -- A-3 (X.sub.1 = CH.sub.3)                                 Q-16                                                                              (R.sub.3, R.sub.4, R.sub.5, R.sub.6 = H)                                                  H  O -- A-5 (X.sub.2 = OCH.sub.3, Y.sub.3 = CH.sub.3)            Q-16                                                                              (R.sub.3, R.sub.4, R.sub.5, R.sub.6 = H)                                                  H  S -- A-4 (X.sub.1 = CH.sub.3, Y.sub.2 = CH.sub.3)             Q-16                                                                              (R.sub.3, R.sub.4, R.sub.5, R.sub.6 = H)                                                  H  S -- A-5 (X.sub.2 = OCH.sub.3, Y.sub.3 = CH.sub.2                                   CH.sub.3)                                                Q-16                                                                              (R.sub.3, R.sub.4, R.sub.5, R.sub.6 = H)                                                  H  S -- A-6 (X.sub.3 = OCH.sub.3)                                Q-20                                                                              (R.sub.3 ' = H)                                                                           H  S -- A-2 (X.sub.1 = OCH.sub.3, Y.sub.1 = O)                   Q-20                                                                              (R.sub.3 ' = H)                                                                           H  O -- A-2 (X.sub.1 = OCH.sub.3)                                Q-20                                                                              (R.sub.3 ' = CH.sub.3)                                                                    H  S -- A-4 (X.sub.1 = OCH.sub.3, Y.sub.2 = H)                   Q-20                                                                              (R.sub.3 ' = CH.sub.3)                                                                    H  O -- A-2 (X.sub.1 = OCH.sub.3, Y.sub.1 = O)                   Q-20                                                                              (R.sub.3 ' = SCH.sub.3)                                                                   H  S -- A-3 (X.sub.1 = OCH.sub.3)                                Q-20                                                                              (R.sub.3 ' = SCH.sub.3)                                                                   H  O -- A-4 (X.sub.1 = OCH.sub.3, Y.sub.2 = CH.sub.3)            Q-23                                                                              (R.sub.3 = H)                                                                             H  --                                                                               -- A-3 (X.sub.1 = CH.sub.3)                                 Q-23                                                                              (R.sub.3 = H)                                                                             H  --                                                                               -- A-4 (X.sub.1 = OCH.sub.3, Y.sub.2 = CH.sub.3)            Q-23                                                                              (R.sub.3 = CH.sub.3)                                                                      H  --                                                                               -- A-6 (X.sub.3 = OCH.sub.3)                                Q-28                                                                              (R.sub.3 " = H, R.sub.4 = H)                                                              H  --                                                                               -- A-2 (X.sub.1 = CH.sub.3, Y.sub.1 = O)                    Q-28                                                                              (R.sub.3 " = Cl, R.sub.4 = H)                                                             H  --                                                                               -- A-3 (X.sub.1 = OCH.sub.3)                                Q-28                                                                              (R.sub.3 " = CH.sub.3, R.sub.4 = H)                                                       H  --                                                                               -- A-4 (X.sub.1 = OCH.sub.3, Y.sub.2 = CH.sub.3)            Q-28                                                                              (R.sub.3 " =  H, R.sub.4 = H)                                                             H  --                                                                               -- A-5 (X.sub.2 = CH.sub.3, Y.sub.2 = CH.sub.3)             Q-28                                                                              (R.sub.3 " = H, R.sub.4 = H)                                                              H  --                                                                               -- A-6 (X.sub.3 = CH.sub.3)                                 Q-33                                                                              (R.sub.3, R.sub.4 = H, n = O)                                                             H  --                                                                               -- A-2 (X.sub.1 = OCH.sub.3, Y.sub.1 = CH.sub.2)            Q-33                                                                              (R.sub.3, R.sub.4 = H, n = O)                                                             H  --                                                                               -- A-3 (X.sub.1 = CH.sub.3)                                 Q-33                                                                              (R.sub.3, R.sub.4 = H, n = O)                                                             H  --                                                                               -- A-4 (X.sub.1 = OCH.sub.3, Y.sub.2 = CH.sub.3)            Q-36                                                                              (R.sub.3, R.sub.4, R.sub.5 = H)                                                           H  --                                                                               -- A-2 (X.sub.1 = OCH.sub.3, Y.sub.1 = O)                   Q-36                                                                              (R.sub.3 , R.sub.4, R.sub.5 = H)                                                          H  --                                                                               -- A-3 (X.sub.1 = OCH.sub.3)                                Q-36                                                                              (R.sub.3, R.sub.4, R.sub.5 = H)                                                           H  --                                                                               -- A-4 (X.sub.1 = OCH.sub.3, Y.sub.2 = CH.sub.3)            Q-39                                                                              (R.sub.3, R.sub.4 = H)                                                                    H  --                                                                               -- A-2 (X.sub.1 = CH.sub.3, Y.sub.1 = CH.sub.2)             Q-39                                                                              (R.sub.3, R.sub.4 = H)                                                                    H  --                                                                               -- A-3 (X.sub.1 = CH.sub.3)                                 Q-39                                                                              (R.sub.3, R.sub.4 = H)                                                                    H  --                                                                               -- A-4 (X.sub.1 = OCH.sub.3, Y.sub.2 = H)                   Q-1                                                                               (R.sub.1, R.sub.2 = H)                                                                    H  --                                                                               -- A-2 (X.sub.1 = OCH.sub.3, Y.sub.1 = O)*                  Q-7                                                                               (R.sub.3, R.sub.4, R.sub.5,R.sub.6 = H)                                                   H  --                                                                               -- A-3 (X.sub.1 = OCH.sub.2 CH.sub.3)*                      Q-15                                                                              (R.sub.3 ', R.sub.4 = H)                                                                  H  --                                                                               O  A-2 (X.sub.1 = OCH.sub.3, Y.sub.1 = O)*                  Q-15                                                                              (R.sub.3 ', R.sub.4 = H)                                                                  H  --                                                                               S  A-2 (X.sub.1 = OCH.sub.3, Y.sub.1 = O)*                  Q-20                                                                              (R.sub.3 ' = SH)                                                                          H  O -- A-2 (X.sub.1 = OCH.sub.3, Y.sub.1 = O)*                  Q-20                                                                              (R.sub.3 ' = SH)                                                                          H  S -- A-2 (X.sub.1 = OCH.sub.3, Y.sub.1 = O)*                  Q-28                                                                              (R.sub.3 ' = Cl, R.sub.4 = H)                                                             H  --                                                                               -- A-2 (X.sub.1 = OCH.sub.3, Y.sub.1                        __________________________________________________________________________                           = O)*                                                     W is O, unless indicated by * where W is S in all Tables.                

                                      TABLE 11                                     __________________________________________________________________________     General Structure 5                                                            Q             R  W'                                                                               W" A                                                        __________________________________________________________________________     Q-1                                                                               (R.sub.1, R.sub.2 = H)                                                                    H  --                                                                               -- A-2 (X.sub.1 = OCH.sub.3, Y.sub.1 = O)                   Q-1                                                                               (R.sub.1, R.sub.2 = H)                                                                    H  --                                                                               -- A-2 (X.sub.1 = CH.sub.3, Y.sub.1 = O)                    Q-1                                                                               (R.sub.1, R.sub.2 = H)                                                                    H  --                                                                               -- A-3 (X.sub.1 = OCH.sub.3)                                Q-1                                                                               (R.sub.1, R.sub.2 = H)                                                                    H  --                                                                               -- A-4 (X.sub.1, Y.sub.2 = CH.sub.3)                        Q-1                                                                               (R.sub.1, R.sub.2 = H)                                                                    H  --                                                                               -- A-5 (X.sub.2 = OCH.sub.3, Y.sub.3 = CH.sub.3)            Q-1                                                                               (R.sub.1, R.sub.2 = H)                                                                    H  --                                                                               -- A-6 (X.sub.3 = CH.sub. 3)                                Q-2                                                                               (R.sub.3, R.sub.4, R.sub.5 = H)                                                           H  S -- A-2 (X.sub.1 = CH.sub.3, Y.sub.1 = O)                    Q-2                                                                               (R.sub.3, R.sub.4, R.sub.5 = H)                                                           H  S -- A-3 (X.sub.1 = OCH.sub.3)                                Q-2                                                                               (R.sub.3, R.sub.4, R.sub.5 = H)                                                           H  O -- A-4 (X.sub.1, Y.sub.2 = CH.sub.3)                        Q-3                                                                               (R.sub.3, R.sub.4, R.sub.5 = H)                                                           H  S -- A-2 (X.sub.1 = OCH.sub.3, Y.sub.1 = CH.sub.2)            Q-3                                                                               (R.sub.3, R.sub.4, R.sub.5 = H)                                                           H  S -- A-3 (X.sub.1 = CH.sub.3)                                 Q-3                                                                               (R.sub.3, R.sub.4, R.sub.5 = H)                                                           H  O -- A-4 (X.sub.1 = CH.sub.3, Y.sub.2 = H)                    Q-4                                                                               (R.sub.3, R.sub.4, R.sub.5 =  H)                                                          H  --                                                                               -- A-2 (X.sub.1 = OCH.sub.3, Y.sub.1 = O)                   Q-4                                                                               (R.sub.3, R.sub.4, R.sub.5 = H)                                                           H  --                                                                               -- A-5 (X.sub.2 = OCH.sub.3, Y.sub.3 = CH.sub.3)            Q-4                                                                               (R.sub.3, R.sub.4, R.sub.5 = H)                                                           H  --                                                                               -- A-6 (X.sub.3 = OCH.sub.3)                                Q-7                                                                               (R.sub.3, R.sub.4, R.sub.5, R.sub.6 = H)                                                  H  --                                                                               -- A-2 (X.sub.1 = OCF.sub.2 H, Y.sub.1 = O)                 Q-7                                                                               (R.sub.3, R.sub.4, R.sub.5, R.sub.6 = H)                                                  H  --                                                                               -- A-3 (X.sub.1 = OCH.sub.2 CH.sub.3)                       Q-7                                                                               (R.sub.3, R.sub.4, R.sub.5, R.sub.6 = H)                                                  H  --                                                                               -- A-4 (X.sub.1 = OCH.sub.3, Y.sub.2 = CH.sub.3)            Q-7                                                                               (R.sub.3, R.sub. 4, R.sub.5, R.sub.6 = H)                                                 H  --                                                                               -- A-5 (X.sub.2 = SCH.sub.3, Y.sub.3 = CH.sub.3)            Q-7                                                                               (R.sub.3, R.sub.4, R.sub.5, R.sub.6 = H)                                                  H  --                                                                               -- A-6 (X.sub.3 = OCH.sub.3)                                Q-10                                                                              (R.sub.3, R.sub.4 = H)                                                                    H  --                                                                               O  A-2 (X.sub.1 = OCH.sub.3, Y.sub.1 = O)                   Q-10                                                                              (R.sub.3, R.sub.4 = H)                                                                    H  --                                                                               O  A-3 (X.sub.1 = OCH.sub.3)                                Q-10                                                                              (R.sub.3, R.sub.4 = H)                                                                    H  --                                                                               S  A-4 (X.sub.1 = CH.sub.3, Y.sub.2 = CH.sub.3)             Q-11                                                                              (R.sub.3, R.sub.4 = H)                                                                    H  --                                                                               O  A-2 (X.sub.1 = OCH.sub.3, Y.sub.1 = CH.sub.2)            Q-11                                                                              (R.sub.3, R.sub.4 = H)                                                                    H  --                                                                               O  A-3 (X.sub.1 = CH.sub.3)                                 Q-11                                                                              (R.sub.3, R.sub.4 = H)                                                                    H  --                                                                               S  A-4 (X.sub.1 = OCH.sub.3, Y.sub.2 = H)                   Q-16                                                                              (R.sub.3, R.sub.4, R.sub.5, R.sub.6 = H)                                                  H  O -- A-2 (X.sub.1 = CH.sub.3, Y.sub.1 = O)                    Q-16                                                                              (R.sub.3, R.sub.4, R.sub.5, R.sub.6 = H)                                                  H  O -- A-3 (X.sub.1 = CH.sub.3)                                 Q-16                                                                              (R.sub.3, R.sub.4, R.sub.5, R.sub.6 = H)                                                  H  O -- A-5 (X.sub.2 = OCH.sub.3, Y.sub.3 = CH.sub.3)            Q-16                                                                              (R.sub.3, R.sub.4, R.sub.5, R.sub.6 = H)                                                  H  S -- A-4 (X.sub.1 = CH.sub.3, Y.sub.2 = CH.sub.3)             Q-16                                                                              (R.sub.3, R.sub.4, R.sub.5, R.sub.6 = H)                                                  H  S -- A-5 (X.sub.2 = OCH.sub.3, Y.sub.3 = CH.sub.2                                   CH.sub.3)                                                Q-16                                                                              (R.sub.3, R.sub.4, R.sub.5, R.sub.6 = H)                                                  H  S -- A-6 (X.sub.3 = OCH.sub.3)                                Q-20                                                                              (R.sub.3 ' = H)                                                                           H  S -- A-2 (X.sub.1 = OCH.sub.3, Y.sub.1 = O)                   Q-20                                                                              (R.sub.3 ' = H)                                                                           H  O -- A-2 (X.sub.1 = OCH.sub.3)                                Q-20                                                                              (R.sub.3 ' = CH.sub.3)                                                                    H  S -- A-4 (X.sub.1 = OCH.sub.3, Y.sub.2 = H)                   Q-20                                                                              (R.sub.3 ' = CH.sub.3)                                                                    H  O -- A-2 (X.sub.1 = OCH.sub.3, Y.sub.1 = O)                   Q-20                                                                              (R.sub.3 ' = SCH.sub.3)                                                                   H  S -- A-3 (X.sub.1 = OCH.sub.3)                                Q-20                                                                              (R.sub.3 ' = SCH.sub.3)                                                                   H  O -- A-4 (X.sub.1 = OCH.sub.3, Y.sub.2 = CH.sub.3)            Q-23                                                                              (R.sub.3 = H)                                                                             H  --                                                                               -- A-3 (X.sub.1 = CH.sub.3)                                 Q-23                                                                              (R.sub.3 = H)                                                                             H  --                                                                               -- A-4 (X.sub.1 = OCH.sub.3, Y.sub.2 = CH.sub.3)            Q-23                                                                              (R.sub.3 = CH.sub.3)                                                                      H  --                                                                               -- A-6 (X.sub.3 = OCH.sub.3)                                Q-28                                                                              (R.sub.3 " = H, R.sub.4 = H)                                                              H  --                                                                               -- A-2 (X.sub.1 = CH.sub.3, Y.sub.1 = O)                    Q-28                                                                              (R.sub.3 " = Cl, R.sub.4 = H)                                                             H  --                                                                               -- A-3 (X.sub.1 = OCH.sub.3)                                Q-28                                                                              (R.sub.3 " = CH.sub.3, R.sub.4 = H)                                                       H  --                                                                               -- A-4 (X.sub.1 = OCH.sub.3, Y.sub.2 = CH.sub.3)            Q-28                                                                              (R.sub.3 " =  H, R.sub.4 = H)                                                             H  --                                                                               -- A-5 (X.sub.2 = CH.sub.3, Y.sub.2 = CH.sub.3)             Q-28                                                                              (R.sub.3 " = H, R.sub.4 = H)                                                              H  --                                                                               -- A-6 (X.sub.3 = CH.sub.3)                                 Q-33                                                                              (R.sub.3, R.sub.4 = H, n = O)                                                             H  --                                                                               -- A-2 (X.sub.1 = OCH.sub.3, Y.sub.1 = CH.sub.2)            Q-33                                                                              (R.sub.3, R.sub.4 = H, n = O)                                                             H  --                                                                               -- A-3 (X.sub.1 = CH.sub.3)                                 Q-33                                                                              (R.sub.3, R.sub.4 = H, n = O)                                                             H  --                                                                               -- A-4 (X.sub.1 = OCH.sub.3, Y.sub.2 = CH.sub.3)            Q-36                                                                              (R.sub.3, R.sub.4, R.sub.5 = H)                                                           H  --                                                                               -- A-2 (X.sub.1 = OCH.sub.3, Y.sub.1 = O)                   Q-36                                                                              (R.sub.3 , R.sub.4, R.sub.5 = H)                                                          H  --                                                                               -- A-3 (X.sub.1 = OCH.sub.3)                                Q-36                                                                              (R.sub.3, R.sub.4, R.sub.5 = H)                                                           H  --                                                                               -- A-4 (X.sub.1 = OCH.sub.3, Y.sub.2 = CH.sub.3)            Q-39                                                                              (R.sub.3, R.sub.4 = H)                                                                    H  --                                                                               -- A-2 (X.sub.1 = CH.sub.3, Y.sub.1 = CH.sub.2)             Q-39                                                                              (R.sub.3, R.sub.4 = H)                                                                    H  --                                                                               -- A-3 (X.sub.1 = CH.sub.3)                                 Q-39                                                                              (R.sub.3, R.sub.4 = H)                                                                    H  --                                                                               -- A-4 (X.sub.1 = OCH.sub.3, Y.sub.2                        __________________________________________________________________________                           = H)                                                

                                      TABLE 12                                     __________________________________________________________________________     General Structure 6                                                            Q             R  W'                                                                               W" A                                                        __________________________________________________________________________     Q-1                                                                               (R.sub.1, R.sub.2 = H)                                                                    H  --                                                                               -- A-2 (X.sub.1 = OCH.sub.3, Y.sub.1 = O)                   Q-1                                                                               (R.sub.1, R.sub.2 = H)                                                                    H  --                                                                               -- A-2 (X.sub.1 = CH.sub.3, Y.sub.1 = O)                    Q-1                                                                               (R.sub.1, R.sub.2 = H)                                                                    H  --                                                                               -- A-3 (X.sub.1 = OCH.sub.3)                                Q-1                                                                               (R.sub.1, R.sub.2 = H)                                                                    H  --                                                                               -- A-4 (X.sub.1, Y.sub.2 = CH.sub.3)                        Q-1                                                                               (R.sub.1, R.sub.2 = H)                                                                    H  --                                                                               -- A-5 (X.sub.2 = OCH.sub.3, Y.sub.3 = CH.sub.3)            Q-1                                                                               (R.sub.1, R.sub.2 = H)                                                                    H  --                                                                               -- A-6 (X.sub.3 = CH.sub.3 )                                Q-2                                                                               (R.sub.3, R.sub.4, R.sub.5 = H)                                                           H  S -- A-2 (X.sub.1 = CH.sub.3, Y.sub.1 = O)                    Q-2                                                                               (R.sub.3, R.sub.4, R.sub.5 = H)                                                           H  S -- A-3 (X.sub.1 = OCH.sub.3)                                Q-2                                                                               (R.sub.3, R.sub.4, R.sub.5 = H)                                                           H  O -- A-4 (X.sub.1, Y.sub.2 = CH.sub.3)                        Q-3                                                                               (R.sub.3, R.sub.4, R.sub.5 = H)                                                           H  S -- A-2 (X.sub.1 = OCH.sub.3, Y.sub.1 = CH.sub.2)            Q-3                                                                               (R.sub.3, R.sub.4, R.sub.5 = H)                                                           H  S -- A-3 (X.sub.1 = CH.sub.3)                                 Q-3                                                                               (R.sub.3, R.sub.4, R.sub.5 = H)                                                           H  O -- A-4 (X.sub.1 = CH.sub.3, Y.sub.2 = H)                    Q-4                                                                               (R.sub.3, R.sub.4, R.sub.5 = H)                                                           H  --                                                                               -- A-2 (X.sub.1 = OCH.sub.3, Y.sub.1 = O)                   Q-4                                                                               (R.sub.3, R.sub.4, R.sub.5 = H)                                                           H  --                                                                               -- A-5 (X.sub.2 = OCH.sub.3, Y.sub.3 = CH.sub.3)            Q-4                                                                               (R.sub.3, R.sub.4, R.sub.5 = H)                                                           H  --                                                                               -- A-6 (X.sub.3 = OCH.sub.3)                                Q-7                                                                               (R.sub.3, R.sub.4, R.sub.5, R.sub.6 = H)                                                  H  --                                                                               -- A-2 (X.sub.1 = OCF.sub.2 H, Y.sub.1 = O)                 Q-7                                                                               (R.sub.3, R.sub.4, R.sub.5, R.sub.6 = H)                                                  H  --                                                                               -- A-3 (X.sub.1 = OCH.sub.2 CH.sub.3)                       Q-7                                                                               (R.sub.3, R.sub.4, R.sub.5, R.sub.6 = H)                                                  H  --                                                                               -- A-4 (X.sub.1 = OCH.sub.3, Y.sub.2 = CH.sub.3)            Q-7                                                                               (R.sub.3, R.sub.4 , R.sub.5, R.sub.6 = H)                                                 H  --                                                                               -- A-5 (X.sub.2 = SCH.sub.3, Y.sub.3 = CH.sub.3)            Q-7                                                                               (R.sub.3, R.sub.4, R.sub.5, R.sub.6 = H)                                                  H  --                                                                               -- A-6 (X.sub.3 = OCH.sub.3)                                Q-10                                                                              (R.sub.3, R.sub.4 = H)                                                                    H  --                                                                               O  A-2 (X.sub.1 = OCH.sub.3, Y.sub.1 = O)                   Q-10                                                                              (R.sub.3, R.sub.4 = H)                                                                    H  --                                                                               O  A-3 (X.sub.1 = OCH.sub.3)                                Q-10                                                                              (R.sub.3, R.sub.4 = H)                                                                    H  --                                                                               S  A-4 (X.sub.1 = CH.sub.3, Y.sub.2 = CH.sub.3)             Q-11                                                                              (R.sub.3, R.sub.4 = H)                                                                    H  --                                                                               O  A-2 (X.sub.1 = OCH.sub.3, Y.sub.1 = CH.sub.2)            Q-11                                                                              (R.sub.3, R.sub.4 = H)                                                                    H  --                                                                               O  A-3 (X.sub.1  = CH.sub.3)                                Q-11                                                                              (R.sub.3, R.sub.4 = H)                                                                    H  --                                                                               S  A-4 (X.sub.1 = OCH.sub.3, Y.sub.2 = H)                   Q-16                                                                              (R.sub.3, R.sub.4, R.sub.5, R.sub.6 = H)                                                  H  O -- A-2 (X.sub.1 = CH.sub.3, Y.sub.1 = O)                    Q-16                                                                              (R.sub.3, R.sub.4, R.sub.5, R.sub.6 = H)                                                  H  O -- A-3 (X.sub.1 = CH.sub.3)                                 Q-16                                                                              (R.sub.3, R.sub.4, R.sub.5, R.sub.6 = H)                                                  H  O -- A-5 (X.sub.2 = OCH.sub.3, Y.sub.3 = CH.sub.3)            Q-16                                                                              (R.sub.3, R.sub.4, R.sub.5, R.sub.6 = H)                                                  H  S -- A-4 (X.sub.1 = CH.sub.3, Y.sub.2 = CH.sub.3)             Q-16                                                                              (R.sub.3, R.sub.4, R.sub.5, R.sub.6 = H)                                                  H  S -- A-5 (X.sub. 2 = OCH.sub.3, Y.sub.3 = CH.sub.2                                  CH.sub.3)                                                Q-16                                                                              (R.sub.3, R.sub.4, R.sub.5, R.sub.6 = H)                                                  H  S -- A-6 (X.sub.3 = OCH.sub.3)                                Q-20                                                                              (R.sub.3 ' = H)                                                                           H  S -- A-2 (X.sub.1 = OCH.sub.3, Y.sub.1 = O)                   Q-20                                                                              (R.sub.3 ' = H)                                                                           H  O -- A-2 (X.sub.1 = OCH.sub.3)                                Q-20                                                                              (R.sub.3 ' = CH.sub.3)                                                                    H  S -- A-4 (X.sub.1 = OCH.sub.3, Y.sub.2 = H)                   Q-20                                                                              (R.sub.3 ' = CH.sub.3)                                                                    H  O -- A-2 (X.sub.1 = OCH.sub.3, Y.sub.1 = O)                   Q-20                                                                              (R.sub.3 ' = SCH.sub.3)                                                                   H  S -- A-3 (X.sub.1 = OCH.sub.3)                                Q-20                                                                              (R.sub.3 ' = SCH.sub.3)                                                                   H  O -- A-4 (X.sub.1  = OCH.sub.3, Y.sub.2 = CH.sub.3)           Q-23                                                                              (R.sub.3 = H)                                                                             H  --                                                                               -- A-3 (X.sub.1 = CH.sub.3)                                 Q-23                                                                              (R.sub.3 = H)                                                                             H  --                                                                               -- A-4 (X.sub.1 = OCH.sub.3, Y.sub.2 = CH.sub.3)            Q-23                                                                              (R.sub.3 = CH.sub.3)                                                                      H  --                                                                               -- A-6 (X.sub.3 = OCH.sub.3)                                Q-28                                                                              (R.sub.3 " = H, R.sub.4 = H)                                                              H  --                                                                               -- A-2 (X.sub.1 = CH.sub.3, Y.sub.1 = O)                    Q-28                                                                              (R.sub.3 " = Cl, R.sub.4 = H)                                                             H  --                                                                               -- A-3 (X.sub.1 = OCH.sub.3)                                Q-28                                                                              (R.sub.3 " = CH.sub.3, R.sub.4 = H)                                                       H  --                                                                               -- A-4 (X.sub.1 = OCH.sub.3, Y.sub.2 = CH.sub.3)            Q-28                                                                              (R.sub.3 " =  H, R.sub.4 = H)                                                             H  --                                                                               -- A-5 (X.sub.2 = CH.sub.3, Y.sub.2 = CH.sub.3)             Q-28                                                                              (R.sub.3 " = H, R.sub.4 = H)                                                              H  --                                                                               -- A-6 (X.sub.3 = CH.sub.3)                                 Q-33                                                                              (R.sub.3, R.sub.4 = H, n = O)                                                             H  --                                                                               -- A-2 (X.sub.1 = OCH.sub.3, Y.sub.1 = CH.sub.2)            Q-33                                                                              (R.sub.3, R.sub.4 = H, n = O)                                                             H  --                                                                               -- A-3 (X.sub.1 = CH.sub.3)                                 Q-33                                                                              (R.sub.3, R.sub.4 = H, n = O)                                                             H  --                                                                               -- A-4 (X.sub.1 = OCH.sub.3, Y.sub.2 = CH.sub.3)            Q-36                                                                              (R.sub.3, R.sub.4, R.sub.5 = H)                                                           H  --                                                                               -- A-2 (X.sub.1 = OCH.sub.3, Y.sub.1 = O)                   Q-36                                                                              (R.sub.3, R.sub.4, R.sub.5 = H)                                                           H  --                                                                               -- A-3 (X.sub.1 = OCH.sub.3)                                Q-36                                                                              (R.sub.3, R.sub.4, R.sub.5 = H)                                                           H  --                                                                               -- A-4 (X.sub.1 = OCH.sub.3, Y.sub.2 = CH.sub.3)            Q-39                                                                              (R.sub.3, R.sub.4 = H)                                                                    H  --                                                                               -- A-2 (X.sub.1 = CH.sub.3, Y.sub.1 = CH.sub.2)             Q-39                                                                              (R.sub.3, R.sub.4 = H)                                                                    H  --                                                                               -- A-3 (X.sub.1 = CH.sub.3)                                 Q-39                                                                              (R.sub.3, R.sub.4 = H)                                                                    H  --                                                                               -- A-4 (X.sub.1 = OCH.sub.3, Y.sub.2                        __________________________________________________________________________                           = H)                                                

                                      TABLE 13                                     __________________________________________________________________________     General Structure 7                                                                                      W'                                                                             or                                                   Q  n R  R.sub.1                                                                          R.sub.2                                                                          R.sub.3                                                                          R.sub.3'                                                                           R.sub.4                                                                          R.sub.5                                                                          R.sub.6                                                                          W W" X   Y   Z                                         __________________________________________________________________________     Q-1                                                                               1 H  H H --                                                                               --  --                                                                               --                                                                               --                                                                               O -- CH.sub.3                                                                           CH.sub.3                                                                           CH                                        Q-1                                                                               1 H  H H --                                                                               --  --                                                                               --                                                                               --                                                                               O -- CH.sub.3                                                                           OCH.sub.3                                                                          CH                                        Q-1                                                                               1 H  H H --                                                                               --  --                                                                               --                                                                               --                                                                               O -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-1                                                                               1 H  H H --                                                                               --  --                                                                               --                                                                               --                                                                               O -- OCH.sub.3                                                                          CH  N                                         Q-1                                                                               1 H  H H --                                                                               --  --                                                                               --                                                                               --                                                                               O -- OCH.sub.3                                                                          OCH.sub.3                                                                          N                                         Q-1                                                                               1 H  H H --                                                                               --  --                                                                               --                                                                               --                                                                               O -- OCH.sub.3                                                                          Cl  CH                                        Q-1                                                                               1 H  H H --                                                                               --  --                                                                               --                                                                               --                                                                               S -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-1                                                                               2 H  H H --                                                                               --  --                                                                               --                                                                               --                                                                               O -- CH.sub.3                                                                           CH.sub.3                                                                           CH                                        Q-1                                                                               2 H  H H --                                                                               --  --                                                                               --                                                                               --                                                                               O -- CH.sub.3                                                                           OCH.sub.3                                                                          CH                                        Q-1                                                                               2 H  H H --                                                                               --  --                                                                               --                                                                               --                                                                               O -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-1                                                                               2 H  H H --                                                                               --  --                                                                               --                                                                               --                                                                               O -- CH.sub.3                                                                           OCH.sub.3                                                                          N                                         Q-1                                                                               2 H  H H --                                                                               --  --                                                                               --                                                                               --                                                                               O -- OCH.sub.3                                                                          OCH.sub.3                                                                          N                                         Q-1                                                                               2 H  H H --                                                                               --  --                                                                               --                                                                               --                                                                               O -- OCH.sub.3                                                                          Cl  CH                                        Q-1                                                                               2 H  H H --                                                                               --  --                                                                               --                                                                               --                                                                               S -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-7                                                                               1 H  --                                                                               --                                                                               H --  H H H O -- CH.sub.3                                                                           CH.sub.3                                                                           CH                                        Q-7                                                                               1 H  --                                                                               --                                                                               H --  H H H O -- CH.sub.3                                                                           OCH.sub.3                                                                          CH                                        Q-7                                                                               1 H  --                                                                               --                                                                               H --  H H H O -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-7                                                                               1 H  --                                                                               --                                                                               H --  H H H O -- CH.sub.3                                                                           OCH.sub.3                                                                          N                                         Q-7                                                                               1 H  --                                                                               --                                                                               H --  H H H O -- OCH.sub.3                                                                          OCH.sub.3                                                                          N                                         Q-7                                                                               1 H  --                                                                               --                                                                               H --  H H H O -- OCH.sub.3                                                                          Cl  CH                                        Q-7                                                                               1 H  --                                                                               --                                                                               H --  H H H S -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-7                                                                               2 H  --                                                                               --                                                                               H --  H H H O -- CH.sub.3                                                                           CH.sub.3                                                                           CH                                        Q-7                                                                               2 H  --                                                                               --                                                                               H --  H H H O -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-7                                                                               2 H  --                                                                               --                                                                               H --  H H H O -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-7                                                                               2 H  --                                                                               --                                                                               H --  H H H O -- OCH.sub.3                                                                          CH  N                                         Q-7                                                                               2 H  --                                                                               --                                                                               H --  H H H O -- OCH.sub.3                                                                          OCH.sub.3                                                                          N                                         Q-7                                                                               2 H  --                                                                               --                                                                               H --  H H H O -- OCH.sub.3                                                                          Cl  CH                                        Q-7                                                                               2 H  --                                                                               --                                                                               H --  H H H S -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-11                                                                              1 H  --                                                                               --                                                                               H --  H --                                                                               --                                                                               O O  CH.sub.3                                                                           CH.sub.3                                                                           CH                                        Q-11                                                                              1 H  --                                                                               --                                                                               H --  H --                                                                               --                                                                               O O  CH.sub.3                                                                           OCH.sub.3                                                                          CH                                        Q-11                                                                              1 H  --                                                                               --                                                                               H --  H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-11                                                                              1 H  --                                                                               --                                                                               H --  H --                                                                               --                                                                               O O  CH.sub.3                                                                           OCH.sub.3                                                                          N                                         Q-11                                                                              1 H  --                                                                               --                                                                               H --  H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          N                                         Q-11                                                                              1 H  --                                                                               --                                                                               H --  H --                                                                               --                                                                               O O  OCH.sub.3                                                                          Cl  CH                                        Q-11                                                                              1 H  --                                                                               --                                                                               H --  H --                                                                               --                                                                               S O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-11                                                                              2 H  --                                                                               --                                                                               H --  H --                                                                               --                                                                               O O  CH.sub.3                                                                           CH.sub.3                                                                           CH                                        Q-11                                                                              2 H  --                                                                               --                                                                               H --  H --                                                                               --                                                                               O O  CH.sub.3                                                                           OCH.sub.3                                                                          CH                                        Q-11                                                                              2 H  --                                                                               --                                                                               H --  H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-11                                                                              2 H  --                                                                               --                                                                               H --  H --                                                                               --                                                                               O O  OCH.sub.3                                                                          CH.sub.3                                                                           N                                         Q-11                                                                              2 H  --                                                                               --                                                                               H --  H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          N                                         Q-11                                                                              2 H  --                                                                               --                                                                               H --  H --                                                                               --                                                                               O O  OCH.sub.3                                                                          Cl  CH                                        Q-11                                                                              2 H  --                                                                               --                                                                               H --  H --                                                                               --                                                                               S O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-15                                                                              1 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O O  CH.sub.3                                                                           CH.sub.3                                                                           CH                                        Q-15                                                                              1 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O O  CH.sub.3                                                                           OCH.sub.3                                                                          CH                                        Q-15                                                                              1 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-15                                                                              1 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O O  CH.sub.3                                                                           OCH.sub.3                                                                          N                                         Q-15                                                                              1 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          N                                         Q-15                                                                              1 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O O  OCH.sub.3                                                                          Cl  CH                                        Q-15                                                                              1 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               S O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-15                                                                              2 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O O  CH.sub.3                                                                           CH.sub.3                                                                           CH                                        Q-15                                                                              2 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O O  OCH.sub.3                                                                          CH.sub.3                                                                           CH                                        Q-15                                                                              2 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-15                                                                              2 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O O  OCH.sub.3                                                                          CH.sub.3                                                                           N                                         Q-15                                                                              2 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          N                                         Q-15                                                                              2 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O O  OCH.sub.3                                                                          Cl  CH                                        Q-15                                                                              2 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               S O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-15                                                                              1 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O S  CH.sub.3                                                                           CH.sub.3                                                                           CH                                        Q-15                                                                              1 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O S  CH.sub.3                                                                           OCH.sub.3                                                                          CH                                        Q-15                                                                              1 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O S  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-15                                                                              1 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O S  CH.sub.3                                                                           OCH.sub.3                                                                          N                                         Q-15                                                                              1 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O S  OCH.sub.3                                                                          OCH.sub.3                                                                          N                                         Q-15                                                                              1 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O S  OCH.sub.3                                                                          Cl  CH                                        Q-15                                                                              1 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               S S  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-15                                                                              2 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O S  CH.sub.3                                                                           CH.sub.3                                                                           CH                                        Q-15                                                                              2 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O S  CH.sub.3                                                                           OCH.sub.3                                                                          CH                                        Q-15                                                                              2 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O S  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-15                                                                              2 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O S  CH.sub.3                                                                           OCH.sub.3                                                                          N                                         Q-15                                                                              2 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O S  OCH.sub.3                                                                          OCH.sub.3                                                                          N                                         Q-15                                                                              2 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O S  OCH.sub.3                                                                          Cl  CH                                        Q-15                                                                              2 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               S S  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-20                                                                              1 H  --                                                                               --                                                                               --                                                                               SCH.sub.3                                                                          H --                                                                               --                                                                               O O  CH.sub.3                                                                           CH.sub.3                                                                           CH                                        Q-20                                                                              1 H  --                                                                               --                                                                               --                                                                               SCH.sub.3                                                                          H --                                                                               --                                                                               O O  CH.sub.3                                                                           OCH.sub.3                                                                          CH                                        Q-20                                                                              1 H  --                                                                               --                                                                               --                                                                               SCH.sub.3                                                                          H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-20                                                                              1 H  --                                                                               --                                                                               --                                                                               SCH.sub.3                                                                          H --                                                                               --                                                                               O O  CH.sub.3                                                                           OCH.sub.3                                                                          N                                         Q-20                                                                              1 H  --                                                                               --                                                                               --                                                                               SCH.sub.3                                                                          H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          N                                         Q-20                                                                              1 H  --                                                                               --                                                                               --                                                                               SCH.sub.3                                                                          H --                                                                               --                                                                               O O  OCH.sub.3                                                                          Cl  CH                                        Q-20                                                                              1 H  --                                                                               --                                                                               --                                                                               SCH.sub.3                                                                          H --                                                                               --                                                                               S O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-20                                                                              2 H  --                                                                               --                                                                               --                                                                               SCH.sub.3                                                                          H --                                                                               --                                                                               O O  CH.sub.3                                                                           CH.sub.3                                                                           CH                                        Q-20                                                                              2 H  --                                                                               --                                                                               --                                                                               SCH.sub.3                                                                          H --                                                                               --                                                                               O O  CH.sub.3                                                                           OCH.sub.3                                                                          CH                                        Q-20                                                                              2 H  --                                                                               --                                                                               --                                                                               SCH.sub.3                                                                          H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-20                                                                              2 H  --                                                                               --                                                                               --                                                                               SCH.sub.3                                                                          H --                                                                               --                                                                               O O  CH.sub.3                                                                           OCH.sub.3                                                                          N                                         Q-20                                                                              2 H  --                                                                               --                                                                               --                                                                               SCH.sub.3                                                                          H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          N                                         Q-20                                                                              2 H  --                                                                               --                                                                               --                                                                               SCH.sub.3                                                                          H --                                                                               --                                                                               O O  OCH.sub.3                                                                          Cl  CH                                        Q-20                                                                              2 H  --                                                                               --                                                                               --                                                                               SCH.sub.3                                                                          H --                                                                               --                                                                               S O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-28                                                                              1 H  --                                                                               --                                                                               --                                                                               Cl  H --                                                                               --                                                                               O -- CH.sub.3                                                                           CH.sub.3                                                                           CH                                        Q-28                                                                              1 H  --                                                                               --                                                                               --                                                                               Cl  H --                                                                               --                                                                               O -- CH.sub.3                                                                           OCH.sub.3                                                                          CH                                        Q-28                                                                              1 H  --                                                                               --                                                                               --                                                                               Cl  H --                                                                               --                                                                               O -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-28                                                                              1 H  --                                                                               --                                                                               --                                                                               Cl  H --                                                                               --                                                                               O -- OCH.sub.3                                                                          CH  N                                         Q-28                                                                              1 H  --                                                                               --                                                                               --                                                                               Cl  H --                                                                               --                                                                               O -- OCH.sub.3                                                                          OCH.sub.3                                                                          N                                         Q-28                                                                              1 H  --                                                                               --                                                                               --                                                                               Cl  H --                                                                               --                                                                               O -- OCH.sub.3                                                                          Cl  CH                                        Q-28                                                                              1 H  --                                                                               --                                                                               --                                                                               Cl  H --                                                                               --                                                                               S -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-28                                                                              2 H  --                                                                               --                                                                               --                                                                               Cl  H --                                                                               --                                                                               O -- CH.sub.3                                                                           CH.sub.3                                                                           CH                                        Q-28                                                                              2 H  --                                                                               --                                                                               --                                                                               Cl  H --                                                                               --                                                                               O -- CH.sub.3                                                                           OCH.sub.3                                                                          CH                                        Q-28                                                                              2 H  --                                                                               --                                                                               --                                                                               Cl  H --                                                                               --                                                                               O -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-28                                                                              2 H  --                                                                               --                                                                               --                                                                               Cl  H --                                                                               --                                                                               O -- OCH.sub.3                                                                          CH  N                                         Q-28                                                                              2 H  --                                                                               --                                                                               --                                                                               Cl  H --                                                                               --                                                                               O -- OCH.sub.3                                                                          OCH.sub.3                                                                          N                                         Q-28                                                                              2 H  --                                                                               --                                                                               --                                                                               Cl  H --                                                                               --                                                                               O -- OCH.sub.3                                                                          Cl  CH                                        Q-28                                                                              2 H  --                                                                               --                                                                               --                                                                               Cl  H --                                                                               --                                                                               S -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-1                                                                               1 CH.sub.3                                                                          H H --                                                                               --  --                                                                               --                                                                               --                                                                               O -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-1                                                                               2 CH.sub.3                                                                          H H --                                                                               --  --                                                                               --                                                                               --                                                                               O -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-7                                                                               1 CH.sub.3                                                                          --                                                                               --                                                                               H --  H H H O -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-7                                                                               2 CH.sub.3                                                                          --                                                                               --                                                                               H --  H H H O -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-11                                                                              1 CH.sub.3                                                                          --                                                                               --                                                                               H --  H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-11                                                                              2 CH.sub.3                                                                          --                                                                               --                                                                               H --  H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-15                                                                              1 CH.sub.3                                                                          --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-15                                                                              2 CH.sub.3                                                                          --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-15                                                                              1 CH.sub.3                                                                          --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O S  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-15                                                                              2 CH.sub.3                                                                          --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O S  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-20                                                                              1 CH.sub.3                                                                          --                                                                               --                                                                               --                                                                               SCH.sub.3                                                                          H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-20                                                                              2 CH.sub.3                                                                          --                                                                               --                                                                               --                                                                               SCH.sub.3                                                                          H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-28                                                                              1 CH.sub.3                                                                          --                                                                               --                                                                               --                                                                               Cl  H --                                                                               --                                                                               O -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-28                                                                              2 CH.sub.3                                                                          --                                                                               --                                                                               --                                                                               Cl  H --                                                                               --                                                                               O -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        __________________________________________________________________________

                                      TABLE 14                                     __________________________________________________________________________     General Structure 8                                                                                      W'                                                                             or                                                   Q  n R  R.sub.1                                                                          R.sub.2                                                                          R.sub.3                                                                          R.sub.3'                                                                           R.sub.4                                                                          R.sub.5                                                                          R.sub.6                                                                          W W" X   Y   Z                                         __________________________________________________________________________     Q-1                                                                               1 H  H H --                                                                               --  --                                                                               --                                                                               --                                                                               O -- CH.sub.3                                                                           CH.sub.3                                                                           CH                                        Q-1                                                                               1 H  H H --                                                                               --  --                                                                               --                                                                               --                                                                               O -- CH.sub.3                                                                           OCH.sub.3                                                                          CH                                        Q-1                                                                               1 H  H H --                                                                               --  --                                                                               --                                                                               --                                                                               O -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-1                                                                               1 H  H H --                                                                               --  --                                                                               --                                                                               --                                                                               O -- OCH.sub.3                                                                          CH  N                                         Q-1                                                                               1 H  H H --                                                                               --  --                                                                               --                                                                               --                                                                               O -- OCH.sub.3                                                                          OCH.sub.3                                                                          N                                         Q-1                                                                               1 H  H H --                                                                               --  --                                                                               --                                                                               --                                                                               O -- OCH.sub.3                                                                          Cl  CH                                        Q-1                                                                               1 H  H H --                                                                               --  --                                                                               --                                                                               --                                                                               S -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-1                                                                               2 H  H H --                                                                               --  --                                                                               --                                                                               --                                                                               O -- CH.sub.3                                                                           CH.sub.3                                                                           CH                                        Q-1                                                                               2 H  H H --                                                                               --  --                                                                               --                                                                               --                                                                               O -- CH.sub.3                                                                           OCH.sub.3                                                                          CH                                        Q-1                                                                               2 H  H H --                                                                               --  --                                                                               --                                                                               --                                                                               O -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-1                                                                               2 H  H H --                                                                               --  --                                                                               --                                                                               --                                                                               O -- CH.sub.3                                                                           OCH.sub.3                                                                          N                                         Q-1                                                                               2 H  H H --                                                                               --  --                                                                               --                                                                               --                                                                               O -- OCH.sub.3                                                                          OCH.sub.3                                                                          N                                         Q-1                                                                               2 H  H H --                                                                               --  --                                                                               --                                                                               --                                                                               O -- OCH.sub.3                                                                          Cl  CH                                        Q-1                                                                               2 H  H H --                                                                               --  --                                                                               --                                                                               --                                                                               S -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-7                                                                               1 H  --                                                                               --                                                                               H --  H H H O -- CH.sub.3                                                                           CH.sub.3                                                                           CH                                        Q-7                                                                               1 H  --                                                                               --                                                                               H --  H H H O -- CH.sub.3                                                                           OCH.sub.3                                                                          CH                                        Q-7                                                                               1 H  --                                                                               --                                                                               H --  H H H O -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-7                                                                               1 H  --                                                                               --                                                                               H --  H H H O -- CH.sub.3                                                                           OCH.sub.3                                                                          N                                         Q-7                                                                               1 H  --                                                                               --                                                                               H --  H H H O -- OCH.sub.3                                                                          OCH.sub.3                                                                          N                                         Q-7                                                                               1 H  --                                                                               --                                                                               H --  H H H O -- OCH.sub.3                                                                          Cl  CH                                        Q-7                                                                               1 H  --                                                                               --                                                                               H --  H H H S -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-7                                                                               2 H  --                                                                               --                                                                               H --  H H H O -- CH.sub.3                                                                           CH.sub.3                                                                           CH                                        Q-7                                                                               2 H  --                                                                               --                                                                               H --  H H H O -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-7                                                                               2 H  --                                                                               --                                                                               H --  H H H O -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-7                                                                               2 H  --                                                                               --                                                                               H --  H H H O -- OCH.sub.3                                                                          CH  N                                         Q-7                                                                               2 H  --                                                                               --                                                                               H --  H H H O -- OCH.sub.3                                                                          OCH.sub.3                                                                          N                                         Q-7                                                                               2 H  --                                                                               --                                                                               H --  H H H O -- OCH.sub.3                                                                          Cl  CH                                        Q-7                                                                               2 H  --                                                                               --                                                                               H --  H H H S -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-11                                                                              1 H  --                                                                               --                                                                               H --  H --                                                                               --                                                                               O O  CH.sub.3                                                                           CH.sub.3                                                                           CH                                        Q-11                                                                              1 H  --                                                                               --                                                                               H --  H --                                                                               --                                                                               O O  CH.sub.3                                                                           OCH.sub.3                                                                          CH                                        Q-11                                                                              1 H  --                                                                               --                                                                               H --  H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-11                                                                              1 H  --                                                                               --                                                                               H --  H --                                                                               --                                                                               O O  CH.sub.3                                                                           OCH.sub.3                                                                          N                                         Q-11                                                                              1 H  --                                                                               --                                                                               H --  H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          N                                         Q-11                                                                              1 H  --                                                                               --                                                                               H --  H --                                                                               --                                                                               O O  OCH.sub.3                                                                          Cl  CH                                        Q-11                                                                              1 H  --                                                                               --                                                                               H --  H --                                                                               --                                                                               S O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-11                                                                              2 H  --                                                                               --                                                                               H --  H --                                                                               --                                                                               O O  CH.sub.3                                                                           CH.sub.3                                                                           CH                                        Q-11                                                                              2 H  --                                                                               --                                                                               H --  H --                                                                               --                                                                               O O  CH.sub.3                                                                           OCH.sub.3                                                                          CH                                        Q-11                                                                              2 H  --                                                                               --                                                                               H --  H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-11                                                                              2 H  --                                                                               --                                                                               H --  H --                                                                               --                                                                               O O  OCH.sub.3                                                                          CH.sub.3                                                                           N                                         Q-11                                                                              2 H  --                                                                               --                                                                               H --  H --                                                                               --                                                                               O O  OCH.sub. 3                                                                         OCH.sub.3                                                                          N                                         Q-11                                                                              2 H  --                                                                               --                                                                               H --  H --                                                                               --                                                                               O O  OCH.sub.3                                                                          Cl  CH                                        Q-11                                                                              2 H  --                                                                               --                                                                               H --  H --                                                                               --                                                                               S O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-15                                                                              1 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O O  CH.sub.3                                                                           CH.sub.3                                                                           CH                                        Q-15                                                                              1 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O O  CH.sub.3                                                                           OCH.sub.3                                                                          CH                                        Q-15                                                                              1 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-15                                                                              1 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O O  CH.sub.3                                                                           OCH.sub.3                                                                          N                                         Q-15                                                                              1 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          N                                         Q-15                                                                              1 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O O  OCH.sub.3                                                                          Cl  CH                                        Q-15                                                                              1 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               S O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-15                                                                              2 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O O  CH.sub.3                                                                           CH.sub.3                                                                           CH                                        Q-15                                                                              2 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O O  OCH.sub.3                                                                          CH.sub.3                                                                           CH                                        Q-15                                                                              2 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-15                                                                              2 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O O  OCH.sub.3                                                                          CH.sub.3                                                                           N                                         Q-15                                                                              2 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          N                                         Q-15                                                                              2 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O O  OCH.sub.3                                                                          Cl  CH                                        Q-15                                                                              2 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               S O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-15                                                                              1 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O S  CH.sub.3                                                                           CH.sub.3                                                                           CH                                        Q-15                                                                              1 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O S  CH.sub.3                                                                           OCH.sub.3                                                                          CH                                        Q-15                                                                              1 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O S  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-15                                                                              1 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O S  CH.sub.3                                                                           OCH.sub.3                                                                          N                                         Q-15                                                                              1 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O S  OCH.sub.3                                                                          OCH.sub.3                                                                          N                                         Q-15                                                                              1 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O S  OCH.sub.3                                                                          Cl  CH                                        Q-15                                                                              1 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               S S  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-15                                                                              2 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O S  CH.sub.3                                                                           CH.sub.3                                                                           CH                                        Q-15                                                                              2 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O S  CH.sub.3                                                                           OCH.sub.3                                                                          CH                                        Q-15                                                                              2 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O S  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-15                                                                              2 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O S  CH.sub.3                                                                           OCH.sub.3                                                                          N                                         Q-15                                                                              2 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O S  OCH.sub.3                                                                          OCH.sub.3                                                                          N                                         Q-15                                                                              2 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O S  OCH.sub.3                                                                          Cl  CH                                        Q-15                                                                              2 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               S S  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-20                                                                              1 H  --                                                                               --                                                                               --                                                                               SCH.sub.3                                                                          H --                                                                               --                                                                               O O  CH.sub.3                                                                           CH.sub.3                                                                           CH                                        Q-20                                                                              1 H  --                                                                               --                                                                               --                                                                               SCH.sub.3                                                                          H --                                                                               --                                                                               O O  CH.sub.3                                                                           OCH.sub.3                                                                          CH                                        Q-20                                                                              1 H  --                                                                               --                                                                               --                                                                               SCH.sub.3                                                                          H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-20                                                                              1 H  --                                                                               --                                                                               --                                                                               SCH.sub. 3                                                                         H --                                                                               --                                                                               O O  CH.sub.3                                                                           OCH.sub.3                                                                          N                                         Q-20                                                                              1 H  --                                                                               --                                                                               --                                                                               SCH.sub.3                                                                          H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          N                                         Q-20                                                                              1 H  --                                                                               --                                                                               --                                                                               SCH.sub.3                                                                          H --                                                                               --                                                                               O O  OCH.sub.3                                                                          Cl  CH                                        Q-20                                                                              1 H  --                                                                               --                                                                               --                                                                               SCH.sub.3                                                                          H --                                                                               --                                                                               S O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-20                                                                              2 H  --                                                                               --                                                                               --                                                                               SCH.sub.3                                                                          H --                                                                               --                                                                               O O  CH.sub.3                                                                           CH.sub.3                                                                           CH                                        Q-20                                                                              2 H  --                                                                               --                                                                               --                                                                               SCH.sub.3                                                                          H --                                                                               --                                                                               O O  CH.sub.3                                                                           OCH.sub.3                                                                          CH                                        Q-20                                                                              2 H  --                                                                               --                                                                               --                                                                               SCH.sub.3                                                                          H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-20                                                                              2 H  --                                                                               --                                                                               --                                                                               SCH.sub.3                                                                          H --                                                                               --                                                                               O O  CH.sub.3                                                                           OCH.sub.3                                                                          N                                         Q-20                                                                              2 H  --                                                                               --                                                                               --                                                                               SCH.sub.3                                                                          H --                                                                               --                                                                               O O  OCH.sub. 3                                                                         OCH.sub.3                                                                          N                                         Q-20                                                                              2 H  --                                                                               --                                                                               --                                                                               SCH.sub.3                                                                          H --                                                                               --                                                                               O O  OCH.sub.3                                                                          Cl  CH                                        Q-20                                                                              2 H  --                                                                               --                                                                               --                                                                               SCH.sub.3                                                                          H --                                                                               --                                                                               S O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-28                                                                              1 H  --                                                                               --                                                                               --                                                                               Cl  H --                                                                               --                                                                               O -- CH.sub.3                                                                           CH.sub.3                                                                           CH                                        Q-28                                                                              1 H  --                                                                               --                                                                               --                                                                               Cl  H --                                                                               --                                                                               O -- CH.sub.3                                                                           OCH.sub.3                                                                          CH                                        Q-28                                                                              1 H  --                                                                               --                                                                               --                                                                               Cl  H --                                                                               --                                                                               O -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-28                                                                              1 H  --                                                                               --                                                                               --                                                                               Cl  H --                                                                               --                                                                               O -- OCH.sub.3                                                                          CH  N                                         Q-28                                                                              1 H  --                                                                               --                                                                               --                                                                               Cl  H --                                                                               --                                                                               O -- OCH.sub.3                                                                          OCH.sub.3                                                                          N                                         Q-28                                                                              1 H  --                                                                               --                                                                               --                                                                               Cl  H --                                                                               --                                                                               O -- OCH.sub.3                                                                          Cl  CH                                        Q-28                                                                              1 H  --                                                                               --                                                                               --                                                                               Cl  H --                                                                               --                                                                               S -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-28                                                                              2 H  --                                                                               --                                                                               --                                                                               Cl  H --                                                                               --                                                                               O -- CH.sub.3                                                                           CH.sub.3                                                                           CH                                        Q-28                                                                              2 H  --                                                                               --                                                                               --                                                                               Cl  H --                                                                               --                                                                               O -- CH.sub.3                                                                           OCH.sub.3                                                                          CH                                        Q-28                                                                              2 H  --                                                                               --                                                                               --                                                                               Cl  H --                                                                               --                                                                               O -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-28                                                                              2 H  --                                                                               --                                                                               --                                                                               Cl  H --                                                                               --                                                                               O -- OCH.sub.3                                                                          CH  N                                         Q-28                                                                              2 H  --                                                                               --                                                                               --                                                                               Cl  H --                                                                               --                                                                               O -- OCH.sub.3                                                                          OCH.sub.3                                                                          N                                         Q-28                                                                              2 H  --                                                                               --                                                                               --                                                                               Cl  H --                                                                               --                                                                               O -- OCH.sub.3                                                                          Cl  CH                                        Q-28                                                                              2 H  --                                                                               --                                                                               --                                                                               Cl  H --                                                                               --                                                                               S -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-1                                                                               1 CH.sub.3                                                                          H H --                                                                               --  --                                                                               --                                                                               --                                                                               O -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-1                                                                               2 CH.sub.3                                                                          H H --                                                                               --  --                                                                               --                                                                               --                                                                               O -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-7                                                                               1 CH.sub.3                                                                          --                                                                               --                                                                               H --  H H H O -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-7                                                                               2 CH.sub.3                                                                          --                                                                               --                                                                               H --  H H H O -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-11                                                                              1 CH.sub.3                                                                          --                                                                               --                                                                               H --  H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-11                                                                              2 CH.sub.3                                                                          --                                                                               --                                                                               H --  H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-15                                                                              1 CH.sub.3                                                                          --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-15                                                                              2 CH.sub.3                                                                          --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-15                                                                              1 CH.sub.3                                                                          --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O S  OCH.sub.3                                                                          OCH.sub. 3                                                                         CH                                        Q-15                                                                              2 CH.sub.3                                                                          --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O S  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-20                                                                              1 CH.sub.3                                                                          --                                                                               --                                                                               --                                                                               SCH.sub.3                                                                          H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-20                                                                              2 CH.sub.3                                                                          --                                                                               --                                                                               --                                                                               SCH.sub.3                                                                          H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-28                                                                              1 CH.sub.3                                                                          --                                                                               --                                                                               --                                                                               Cl  H --                                                                               --                                                                               O -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-28                                                                              2 CH.sub.3                                                                          --                                                                               --                                                                               --                                                                               Cl  H --                                                                               --                                                                               O -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        __________________________________________________________________________

                                      TABLE 15                                     __________________________________________________________________________     General Structure 9                                                                                      W'                                                                             or                                                   Q  n R  R.sub.1                                                                          R.sub.2                                                                          R.sub.3                                                                          R.sub.3 '                                                                          R.sub.4                                                                          R.sub.5                                                                          R.sub.6                                                                          W W" X   Y   Z                                         __________________________________________________________________________     Q-1                                                                               1 H  H H --                                                                               --  --                                                                               --                                                                               --                                                                               O -- CH.sub.3                                                                           CH.sub.3                                                                           CH                                        Q-1                                                                               1 H  H H --                                                                               --  --                                                                               --                                                                               --                                                                               O -- CH.sub.3                                                                           OCH.sub.3                                                                          CH                                        Q-1                                                                               1 H  H H --                                                                               --  --                                                                               --                                                                               --                                                                               O -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-1                                                                               1 H  H H --                                                                               --  --                                                                               --                                                                               --                                                                               O -- OCH.sub.3                                                                          CH  N                                         Q-1                                                                               1 H  H H --                                                                               --  --                                                                               --                                                                               --                                                                               O -- OCH.sub.3                                                                          OCH.sub.3                                                                          N                                         Q-1                                                                               1 H  H H --                                                                               --  --                                                                               --                                                                               --                                                                               O -- OCH.sub.3                                                                          Cl  CH                                        Q-1                                                                               1 H  H H --                                                                               --  --                                                                               --                                                                               --                                                                               S -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-1                                                                               2 H  H H --                                                                               --  --                                                                               --                                                                               --                                                                               O -- CH.sub.3                                                                           CH.sub.3                                                                           CH                                        Q-1                                                                               2 H  H H --                                                                               --  --                                                                               --                                                                               --                                                                               O -- CH.sub.3                                                                           OCH.sub.3                                                                          CH                                        Q-1                                                                               2 H  H H --                                                                               --  --                                                                               --                                                                               --                                                                               O -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-1                                                                               2 H  H H --                                                                               --  --                                                                               --                                                                               --                                                                               O -- CH.sub.3                                                                           OCH.sub.3                                                                          N                                         Q-1                                                                               2 H  H H --                                                                               --  --                                                                               --                                                                               --                                                                               O -- OCH.sub.3                                                                          OCH.sub.3                                                                          N                                         Q-1                                                                               2 H  H H --                                                                               --  --                                                                               --                                                                               --                                                                               O -- OCH.sub.3                                                                          Cl  CH                                        Q-1                                                                               2 H  H H --                                                                               --  --                                                                               --                                                                               --                                                                               S -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-7                                                                               1 H  --                                                                               --                                                                               H --  H H H O -- CH.sub.3                                                                           CH.sub.3                                                                           CH                                        Q-7                                                                               1 H  --                                                                               --                                                                               H --  H H H O -- CH.sub.3                                                                           OCH.sub.3                                                                          CH                                        Q-7                                                                               1 H  --                                                                               --                                                                               H --  H H H O -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-7                                                                               1 H  --                                                                               --                                                                               H --  H H H O -- CH.sub.3                                                                           OCH.sub.3                                                                          N                                         Q-7                                                                               1 H  --                                                                               --                                                                               H --  H H H O -- OCH.sub.3                                                                          OCH.sub.3                                                                          N                                         Q-7                                                                               1 H  --                                                                               --                                                                               H --  H H H O -- OCH.sub.3                                                                          Cl  CH                                        Q-7                                                                               1 H  --                                                                               --                                                                               H --  H H H S -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-7                                                                               2 H  --                                                                               --                                                                               H --  H H H O -- CH.sub.3                                                                           CH.sub.3                                                                           CH                                        Q-7                                                                               2 H  --                                                                               --                                                                               H --  H H H O -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-7                                                                               2 H  --                                                                               --                                                                               H --  H H H O -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-7                                                                               2 H  --                                                                               --                                                                               H --  H H H O -- OCH.sub.3                                                                          CH  N                                         Q-7                                                                               2 H  --                                                                               --                                                                               H --  H H H O -- OCH.sub.3                                                                          OCH.sub.3                                                                          N                                         Q-7                                                                               2 H  --                                                                               --                                                                               H --  H H H O -- OCH.sub.3                                                                          Cl  CH                                        Q-7                                                                               2 H  --                                                                               --                                                                               H --  H H H S -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-11                                                                              1 H  --                                                                               --                                                                               H --  H --                                                                               --                                                                               O O  CH.sub.3                                                                           CH.sub.3                                                                           CH                                        Q-11                                                                              1 H  --                                                                               --                                                                               H --  H --                                                                               --                                                                               O O  CH.sub.3                                                                           OCH.sub.3                                                                          CH                                        Q-11                                                                              1 H  --                                                                               --                                                                               H --  H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-11                                                                              1 H  --                                                                               --                                                                               H --  H --                                                                               --                                                                               O O  CH.sub.3                                                                           OCH.sub.3                                                                          N                                         Q-11                                                                              1 H  --                                                                               --                                                                               H --  H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          N                                         Q-11                                                                              1 H  --                                                                               --                                                                               H --  H --                                                                               --                                                                               O O  OCH.sub.3                                                                          Cl  CH                                        Q-11                                                                              1 H  --                                                                               --                                                                               H --  H --                                                                               --                                                                               S O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-11                                                                              2 H  --                                                                               --                                                                               H --  H --                                                                               --                                                                               O O  CH.sub.3                                                                           CH.sub.3                                                                           CH                                        Q-11                                                                              2 H  --                                                                               --                                                                               H --  H --                                                                               --                                                                               O O  CH.sub.3                                                                           OCH.sub.3                                                                          CH                                        Q-11                                                                              2 H  --                                                                               --                                                                               H --  H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-11                                                                              2 H  --                                                                               --                                                                               H --  H --                                                                               --                                                                               O O  OCH.sub.3                                                                          CH.sub.3                                                                           N                                         Q-11                                                                              2 H  --                                                                               --                                                                               H --  H --                                                                               --                                                                               O O  OCH.sub. 3                                                                         OCH.sub.3                                                                          N                                         Q-11                                                                              2 H  --                                                                               --                                                                               H --  H --                                                                               --                                                                               O O  OCH.sub.3                                                                          Cl  CH                                        Q-11                                                                              2 H  --                                                                               --                                                                               H --  H --                                                                               --                                                                               S O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-15                                                                              1 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O O  CH.sub.3                                                                           CH.sub.3                                                                           CH                                        Q-15                                                                              1 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O O  CH.sub.3                                                                           OCH.sub.3                                                                          CH                                        Q-15                                                                              1 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-15                                                                              1 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O O  CH.sub.3                                                                           OCH.sub.3                                                                          N                                         Q-15                                                                              1 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          N                                         Q-15                                                                              1 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O O  OCH.sub.3                                                                          Cl  CH                                        Q-15                                                                              1 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               S O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-15                                                                              2 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O O  CH.sub.3                                                                           CH.sub.3                                                                           CH                                        Q-15                                                                              2 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O O  OCH.sub.3                                                                          CH.sub.3                                                                           CH                                        Q-15                                                                              2 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-15                                                                              2 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O O  OCH.sub.3                                                                          CH.sub.3                                                                           N                                         Q-15                                                                              2 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          N                                         Q-15                                                                              2 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O O  OCH.sub.3                                                                          Cl  CH                                        Q-15                                                                              2 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               S O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-15                                                                              1 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O S  CH.sub.3                                                                           CH.sub.3                                                                           CH                                        Q-15                                                                              1 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O S  CH.sub.3                                                                           OCH.sub.3                                                                          CH                                        Q-15                                                                              1 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O S  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-15                                                                              1 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O S  CH.sub.3                                                                           OCH.sub.3                                                                          N                                         Q-15                                                                              1 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O S  OCH.sub.3                                                                          OCH.sub.3                                                                          N                                         Q-15                                                                              1 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O S  OCH.sub.3                                                                          Cl  CH                                        Q-15                                                                              1 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               S S  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-15                                                                              2 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O S  CH.sub.3                                                                           CH.sub.3                                                                           CH                                        Q-15                                                                              2 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O S  CH.sub.3                                                                           OCH.sub.3                                                                          CH                                        Q-15                                                                              2 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O S  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-15                                                                              2 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O S  CH.sub.3                                                                           OCH.sub.3                                                                          N                                         Q-15                                                                              2 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O S  OCH.sub.3                                                                          OCH.sub.3                                                                          N                                         Q-15                                                                              2 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O S  OCH.sub.3                                                                          Cl  CH                                        Q-15                                                                              2 H  --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               S S  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-20                                                                              1 H  --                                                                               --                                                                               --                                                                               SCH.sub.3                                                                          H --                                                                               --                                                                               O O  CH.sub.3                                                                           CH.sub.3                                                                           CH                                        Q-20                                                                              1 H  --                                                                               --                                                                               --                                                                               SCH.sub.3                                                                          H --                                                                               --                                                                               O O  CH.sub.3                                                                           OCH.sub.3                                                                          CH                                        Q-20                                                                              1 H  --                                                                               --                                                                               --                                                                               SCH.sub.3                                                                          H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-20                                                                              1 H  --                                                                               --                                                                               --                                                                               SCH.sub. 3                                                                         H --                                                                               --                                                                               O O  CH.sub.3                                                                           OCH.sub.3                                                                          N                                         Q-20                                                                              1 H  --                                                                               --                                                                               --                                                                               SCH.sub.3                                                                          H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          N                                         Q-20                                                                              1 H  --                                                                               --                                                                               --                                                                               SCH.sub.3                                                                          H --                                                                               --                                                                               O O  OCH.sub.3                                                                          Cl  CH                                        Q-20                                                                              1 H  --                                                                               --                                                                               --                                                                               SCH.sub.3                                                                          H --                                                                               --                                                                               S O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-20                                                                              2 H  --                                                                               --                                                                               --                                                                               SCH.sub.3                                                                          H --                                                                               --                                                                               O O  CH.sub.3                                                                           CH.sub.3                                                                           CH                                        Q-20                                                                              2 H  --                                                                               --                                                                               --                                                                               SCH.sub.3                                                                          H --                                                                               --                                                                               O O  CH.sub.3                                                                           OCH.sub.3                                                                          CH                                        Q-20                                                                              2 H  --                                                                               --                                                                               --                                                                               SCH.sub.3                                                                          H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-20                                                                              2 H  --                                                                               --                                                                               --                                                                               SCH.sub.3                                                                          H --                                                                               --                                                                               O O  CH.sub.3                                                                           OCH.sub.3                                                                          N                                         Q-20                                                                              2 H  --                                                                               --                                                                               --                                                                               SCH.sub.3                                                                          H --                                                                               --                                                                               O O  OCH.sub. 3                                                                         OCH.sub.3                                                                          N                                         Q-20                                                                              2 H  --                                                                               --                                                                               --                                                                               SCH.sub.3                                                                          H --                                                                               --                                                                               O O  OCH.sub.3                                                                          Cl  CH                                        Q-20                                                                              2 H  --                                                                               --                                                                               --                                                                               SCH.sub.3                                                                          H --                                                                               --                                                                               S O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-28                                                                              1 H  --                                                                               --                                                                               --                                                                               Cl  H --                                                                               --                                                                               O -- CH.sub.3                                                                           CH.sub.3                                                                           CH                                        Q-28                                                                              1 H  --                                                                               --                                                                               --                                                                               Cl  H --                                                                               --                                                                               O -- CH.sub.3                                                                           OCH.sub.3                                                                          CH                                        Q-28                                                                              1 H  --                                                                               --                                                                               --                                                                               Cl  H --                                                                               --                                                                               O -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-28                                                                              1 H  --                                                                               --                                                                               --                                                                               Cl  H --                                                                               --                                                                               O -- OCH.sub.3                                                                          CH  N                                         Q-28                                                                              1 H  --                                                                               --                                                                               --                                                                               Cl  H --                                                                               --                                                                               O -- OCH.sub.3                                                                          OCH.sub.3                                                                          N                                         Q-28                                                                              1 H  --                                                                               --                                                                               --                                                                               Cl  H --                                                                               --                                                                               O -- OCH.sub.3                                                                          Cl  CH                                        Q-28                                                                              1 H  --                                                                               --                                                                               --                                                                               Cl  H --                                                                               --                                                                               S -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-28                                                                              2 H  --                                                                               --                                                                               --                                                                               Cl  H --                                                                               --                                                                               O -- CH.sub.3                                                                           CH.sub.3                                                                           CH                                        Q-28                                                                              2 H  --                                                                               --                                                                               --                                                                               Cl  H --                                                                               --                                                                               O -- CH.sub.3                                                                           OCH.sub.3                                                                          CH                                        Q-28                                                                              2 H  --                                                                               --                                                                               --                                                                               Cl  H --                                                                               --                                                                               O -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-28                                                                              2 H  --                                                                               --                                                                               --                                                                               Cl  H --                                                                               --                                                                               O -- OCH.sub.3                                                                          CH  N                                         Q-28                                                                              2 H  --                                                                               --                                                                               --                                                                               Cl  H --                                                                               --                                                                               O -- OCH.sub.3                                                                          OCH.sub.3                                                                          N                                         Q-28                                                                              2 H  --                                                                               --                                                                               --                                                                               Cl  H --                                                                               --                                                                               O -- OCH.sub.3                                                                          Cl  CH                                        Q-28                                                                              2 H  --                                                                               --                                                                               --                                                                               Cl  H --                                                                               --                                                                               S -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-1                                                                               1 CH.sub.3                                                                          H H --                                                                               --  --                                                                               --                                                                               --                                                                               O -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-1                                                                               2 CH.sub.3                                                                          H H --                                                                               --  --                                                                               --                                                                               --                                                                               O -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-7                                                                               1 CH.sub.3                                                                          --                                                                               --                                                                               H --  H H H O -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-7                                                                               2 CH.sub.3                                                                          --                                                                               --                                                                               H --  H H H O -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-11                                                                              1 CH.sub.3                                                                          --                                                                               --                                                                               H --  H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-11                                                                              2 CH.sub.3                                                                          --                                                                               --                                                                               H --  H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-15                                                                              1 CH.sub.3                                                                          --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-15                                                                              2 CH.sub.3                                                                          --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-15                                                                              1 CH.sub.3                                                                          --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O S  OCH.sub.3                                                                          OCH.sub. 3                                                                         CH                                        Q-15                                                                              2 CH.sub.3                                                                          --                                                                               --                                                                               --                                                                               CH.sub.3                                                                           H --                                                                               --                                                                               O S  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-20                                                                              1 CH.sub.3                                                                          --                                                                               --                                                                               --                                                                               SCH.sub.3                                                                          H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-20                                                                              2 CH.sub.3                                                                          --                                                                               --                                                                               --                                                                               SCH.sub.3                                                                          H --                                                                               --                                                                               O O  OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-28                                                                              1 CH.sub.3                                                                          --                                                                               --                                                                               --                                                                               Cl  H --                                                                               --                                                                               O -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        Q-28                                                                              2 CH.sub.3                                                                          --                                                                               --                                                                               --                                                                               Cl  H --                                                                               --                                                                               O -- OCH.sub.3                                                                          OCH.sub.3                                                                          CH                                        __________________________________________________________________________

FORMULATIONS

Useful formulations of the compounds of Formula I can be prepared in conventional ways. They include dusts, granules, pellets, solutions, suspensions, emulsions, wettable powders, emulsifiable concentrates and the like. Many of these may be applied directly. Sprayable formulations can be extended in suitable media and used at spray volumes of from a few liters to several hundred liters per hectare. High strength compositions are primarily used as intermediates for further formulation. The formulations, broadly, contain about 0.1% to 99% by weight of active ingredient(s) and at least one of (a) about 0.1% to 20% surfactant(s) and (b) about 1% to 99.9% solid or liquid inert diluent(s). More specifically, they will contain these ingredients in the following approximate proportions:

                  TABLE 16                                                         ______________________________________                                                     Active  Weight Percent*                                                        Ingredient                                                                             Diluent(s)                                                                               Surfactant(s)                                    ______________________________________                                         Wettable Powders                                                                             20-90      0-74      1-10                                        Oil Suspensions,                                                                              3-50     40-95      0-15                                        Emulsions, Solutions,                                                          (including Emulsifiable                                                        Concentrates)                                                                  Aqueous Suspension                                                                           10-50     40-84      1-20                                        Dusts          1-25     70-99     0-5                                          Granules and Pellets                                                                         0.1-95      5-99.9   0-15                                        High Strength 90-99      0-10     0-2                                          Compositions                                                                   ______________________________________                                          *Active ingredient plus at least one of a Surfactant or a Diluent equals       100 weight percent.                                                      

Lower or higher levels of active ingredient can, of course, be present depending on the intended use and the physical properties of the compound. Higher ratios of surfactant to active ingredient are sometimes desirable, and are achieved by incorporation into the formulation or by tank mixing.

Typical solid diluents are described in Watkins, et al., "Handbook of Insecticide Dust Diluents and Carriers", 2nd Ed., Dorland Books, Caldwell, N.J., but other solids, either mined or manufactured, may be used. The more absorptive diluents are preferred for wettable powders and the denser ones for dusts. Typical liquid diluents and solvents are described in Marsden, "Solvents Guide," 2nd Ed., Interscience, New York, 1950. Solubility under 0.1% is preferred for suspension concentrates; solution concentrates are preferably stable against phase separation at 0° C. "McCutcheon's Detergents and Emulsifiers Annual", MC Publishing Corp., Ridgewood, N.J., as well as Sisely and Wood, "Encyclopedia of Surface Active Agents", Chemical Publishing Co., Inc., New York, 1964, list surfactants and recommended uses. All formulations can contain minor amounts of additives to reduce foaming, caking, corrosion, microbiological growth, etc.

The methods of making such compositions are well known. Solutions are prepared by simply mixing the ingredients. Fine solid compositions are made by blending and, usually, grinding as in a hammer or fluid energy mill. Suspensions are prepared by wet milling (see, for example, Littler, U.S. Pat. No. 3,060,084). Granules and pellets may be made by spraying the active material upon preformed granular carriers or by agglomeration techniques. See J. E. Browning, "Agglomeration", Chemical Engineering, Dec. 4, 1967, pp. 147ff. and "Perry's Chemical Engineer's Handbook", 5th Ed, McGraw-Hill, New York, 1973, pp. 8-57ff.

In the following examples, all parts are by weight unless otherwise indicated.

EXAMPLE 7 Wettable Powder

    ______________________________________                                         N--[(4,6-dimethylpyrimidin-2-yl)aminocarbonyl]-                                                           80%                                                 3-(isoxazol-3-yl)-2-thiophenesulfonamide                                       sodium alkylnaphthalenesulfonate                                                                          2%                                                  sodium ligninsulfonate     2%                                                  synthetic amorphous silica 3%                                                  kaolinite                  13%                                                 ______________________________________                                    

The ingredients are blended, hammer-milled until all the solids are essentially under 50 microns, reblended, and packaged.

EXAMPLE 8 Wettable Powder

    ______________________________________                                         3-(isoxazol-3-yl)-N--[(4-methoxy-6-methyl-                                                              50%                                                   pyrimidin-2-yl)-aminocarbonyl]-2-                                              thiophenesulfonamide                                                           sodium alkylnaphthalenesulfonate                                                                         2%                                                   low viscosity methyl cellulose                                                                           2%                                                   diatomaceous earth       46%                                                   ______________________________________                                    

The ingredients are blended, coarsely hammer-milled and then air-milled to produce particles essentially all below 10 microns in diameter. The product is reblended before packaging.

EXAMPLE 9 Granule

    ______________________________________                                         Wettable Powder of Example 8                                                                           5%                                                     attapulgite granules   95%                                                     (U.S.S. 20-40 mesh: 0.84-0.42 mm)                                              ______________________________________                                    

A slurry of wettable powder containing 25% solids is sprayed on the surface of attapulgite granules in a double-cone blender. The granules are dried and packaged.

EXAMPLE 10 Extruded Pellet

    ______________________________________                                         N--[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-                                                           25%                                                3-(isoxazol-3-yl)-2-thiophenesulfonamide                                       anhydrous sodium sulfate    10%                                                crude calcium ligninsulfonate                                                                               5%                                                sodium alkylnaphthalenesulfonate                                                                            1%                                                calcium/magnesium bentonite 59%                                                ______________________________________                                    

The ingredients are blended, hammer-milled and then moistened with about 12% water. The mixture is extruded as cylinders about 3 mm diameter which are cut to produce pellets about 3 mm long. These may be used directly after drying, or the dried pellets may be crushed to pass a U.S.S. No. 20 sieve (0.84 mm openings). The granules held on a U.S.S. No. 40 sieve (0.42 mm openings) may be packaged for use and the fines recycled.

EXAMPLE 11 Low Strength Granule

    ______________________________________                                         N--[(4,6-dimethylpyrimidin-2-yl)aminocarbonyl]-                                                            0.1%                                               3-(isoxazol-3-yl)-2-thiophenesulfonamide                                       attapulgite granules       99.9%                                               (U.S.S. 20-40 mesh)                                                            ______________________________________                                    

The active ingredient is dissolved in a solvent and the solution is sprayed upon dedusted granules in a double-cone blender. After spraying of the solution has been completed, the material is warmed to evaporate the solvent. The material is allowed to cool and then packaged.

EXAMPLE 12 Granule

    ______________________________________                                         3-(isoxazol-3-yl)-N--[(4-methoxy-6-methyl-                                                              80%                                                   pyrimidin-2-yl)-aminocarbonyl]-2-                                              thiophenesulfonamide                                                           wetting agent            1%                                                    crude ligninsulfonate salt (containing                                                                  10%                                                   5-20% of the natural sugars)                                                   attapulgite clay         9%                                                    ______________________________________                                    

The ingredients are blended and milled to pass through a 100 mesh screen. This material is then added to a fluid bed granulator, the air flow is adjusted to gently fluidize the material, and a fine spray of water is sprayed onto the fluidized material. The fluidization and spraying are continued until granules of the desired size range are made. The spraying is stopped, but fluidization is continued, optionally with heat, until the water content is reduced to the desired level, generally less than 1%. The material is then discharged, screened to the desired size range, generally 14-100 mesh (1410-149 microns), and packaged for use.

EXAMPLE 13 Low Strength Granule

    ______________________________________                                         N--[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-                                                         1%                                                   3-(isoxazol-3-yl)-2-thiophenesulfonamide                                       N,N--dimethylformamide    9%                                                   attapulgite granules      90%                                                  (U.S.S. 20-40 sieve)                                                           ______________________________________                                    

The active ingredient is dissolved in the solvent and the solution is sprayed upon dedusted granules in a double cone blender. After spraying of the solution has been completed, the blender is allowed to run for a short period and then the granules are packaged.

EXAMPLE 14 Aqueous Suspension

    ______________________________________                                         N--[(4,6-dimethylpyrimidin-2-yl)aminocarbonyl]-                                                            40%                                                3-(isoxazol-3-yl)-2-thiophenesulfonamide                                       polyacrylic acid thickener 0.3%                                                dodecylphenol polyethylene glycol ether                                                                   0.5%                                                disodium phosphate           1%                                                monosodium phosphate       0.5%                                                polyvinyl alcohol          1.0%                                                water                      56.7%                                               ______________________________________                                    

The ingredients are blended and ground together in a sand mill to produce particles essentially all under 5 microns in size.

EXAMPLE 15 Solution

    ______________________________________                                         3-(isoxazol-3-yl)-N--[(4-methoxy-6-methyl-                                                               5%                                                   pyrimidin-2-yl)-aminocarbonyl]-2-                                              thiophenesulfonamide, sodium salt                                              water                    95%                                                   ______________________________________                                    

The salt is added directly to the water with stirring to produce the solution, which may then be packaged for use.

EXAMPLE 16 High Strength Concentrate

    ______________________________________                                         N--[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-                                                            99%                                               3-(isoxazol-3-yl)-2-thiophenesulfonamide                                       silica aerogel              0.5%                                               synthetic amorphous silica  0.5%                                               ______________________________________                                    

The ingredients are blended and ground in a hammer-mill to produce a material essentially all passing a U.S.S. No. 50 screen (0.3 mm opening). The concentrate may be formulated further if necessary.

EXAMPLE 17 Wettable Powder

    ______________________________________                                         N--[(4,6-dimethylpyrimidin-2-yl)aminocarbonyl]-                                                            90%                                                3-(isoxazol-3-yl)-2-thiophenesulfonamide                                       dioctyl sodium sulfosuccinate                                                                             0.1%                                                synthetic fine silica      9.9%                                                ______________________________________                                    

The ingredients are blended and ground in a hammer-mill to produce particles essentially all below 100 microns. The material is sifted through a U.S.S. No. 50 screen and then packaged.

EXAMPLE 18 Wettable Powder

    ______________________________________                                         3-(isoxazol-3-yl)-N--[(4-methoxy-6-methyl-                                                              40%                                                   pyrimidin-2-yl)-aminocarbonyl]-2-                                              thiophenesulfonamide                                                           sodium ligninsulfonate   20%                                                   montmorillonite clay     40%                                                   ______________________________________                                    

The ingredients are throughly blended, coarsely hammer-milled and then air-milled to produce particles essentially all below 10 microns in size. The material is reblended and then packaged.

EXAMPLE 19 Oil Suspension

    ______________________________________                                         N--[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-                                                           35%                                                3-(isoxazol-3-yl)-2-thiophenesulfonamide                                       blend of polyalcohol carboxylic                                                                             6%                                                esters and oil soluble petroleum                                               sulfonates                                                                     xylene                      59%                                                ______________________________________                                    

The ingredients are combined and ground together in a sand mill to produce particles essentially all below 5 microns. The product can be used directly, extended with oils, or emulsified in water.

EXAMPLE 20 Dust

    ______________________________________                                         N--[(4,6-dimethylpyrimidin-2-yl)aminocarbonyl]-                                                           10%                                                 3-(isoxazol-3-yl)-2-thiophenesulfonamide                                       attapulgite                10%                                                 Pyrophyllite               80%                                                 ______________________________________                                    

The active ingredient is blended with attapulgite and then passed through a hammer-mill to produce particles substantially all below 200 microns. The ground concentrate is then blended with powdered pyrophyllite until homogeneous.

EXAMPLE 21 Oil Suspension

    ______________________________________                                         3-(isoxazol-3-yl)-N--[(4-methoxy-6-methyl-                                                              25%                                                   pyrimidin-2-yl)-aminocarbonyl]-2-                                              thiophenesulfonamide                                                           polyoxyethylene sorbitol hexaoleate                                                                      5%                                                   highly aliphatic hydrocarbon oil                                                                        70%                                                   ______________________________________                                    

The ingredients are ground together in a sand mill until the solid particles have been reduced to under about 5 microns. The resulting thick suspension may be applied directly, but preferably after being extended with oils or emulsified in water.

EXAMPLE 22 Wettable Powder

    ______________________________________                                         N--[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-                                                           20%                                                3-(isoxazol-3-yl)-2-thiophenesulfonamide                                       sodium alkylnaphthalenesulfonate                                                                            4%                                                sodium ligninsulfonate       4%                                                low viscosity methyl cellulose                                                                              3%                                                attapulgite                 69%                                                ______________________________________                                    

The ingredients are thoroughly blended. After grinding in a hammer-mill to produce particles essentially all below 100 microns, the material is reblended and sifted through a U.S.S. No. 50 sieve (0.3 mm opening) and packaged.

EXAMPLE 23 Wettable Powder

    ______________________________________                                         N--[(4-chloro-6-methoxypyrimidin-2-yl)amino-                                                             80%                                                  carbonyl]-3-(1H--pyrrol-1-yl)-2-thiophene-                                     sulfonamide                                                                    sodium alkylnaphthalenesulfonate                                                                         2%                                                   sodium ligninsulfonate    2%                                                   synthetic amorphous silica                                                                               3%                                                   kaolinite                 13%                                                  ______________________________________                                    

The ingredients are blended, hammer-milled until all the solids are essentially under 50 microns, reblended, and packaged.

EXAMPLE 24 Wettable Powder

    ______________________________________                                         N--[(4,6-dimethoxy-1,3,5-triazin-2-yl)amino-                                                            50%                                                   carbonyl]-3-(1H--pyrrol-1-yl)-2-thiophene-                                     sulfonamide                                                                    sodium alkylnaphthalenesulfonate                                                                         2%                                                   low viscosity methyl cellulose                                                                           2%                                                   diatomaceous earth       46%                                                   ______________________________________                                    

The ingredients are blended, coarsely hammer-milled and then air-milled to produce particles essentially all below 10 microns in diameter. The product is reblended before packaging.

EXAMPLE 25 Extruded Pellet

    ______________________________________                                         N--[(4,6-dimethyl-1,3,5-triazin-2-yl)amino-                                                             25%                                                   carbonyl]-3-(1H--pyrrol-1-yl)-2-thiophene-                                     sulfonamide                                                                    anhydrous sodium sulfate 10%                                                   crude calcium ligninsulfonate                                                                            5%                                                   sodium alkylnaphthalenesulfonate                                                                         1%                                                   calcium/magnesium bentonite                                                                             59%                                                   ______________________________________                                    

The ingredients are blended, hammer-milled and then moistened with about 12% water. The mixture is extruded as cylinders about 3 mm diameter which are cut to produce pellets about 3 mm long. These may be used directly after drying, or the dried pellets may be crushed to pass a U.S.S. No. 20 sieve (0.84 mm openings). The granules held on a U.S.S. No. 40 sieve (0.42 mm openings) may be packaged for use and the fines recycled.

EXAMPLE 26 Low Strength Granule

    ______________________________________                                         N--[(4,6-dimethylpyrimidin-2-yl)aminocarbonyl]-                                                            0.1%                                               3-(isoxazol-3-yl)-2-thiophenesulfonamide                                       attapulgite granules       99.9%                                               (U.S.S. 20-40 mesh)                                                            ______________________________________                                    

The active ingredient is dissolved in a solvent and the solution is sprayed upon dedusted granules in a double-cone blender. After spraying of the solution has been completed, the material is warmed to evaporate the solvent. The material is allowed to cool and then packaged.

EXAMPLE 27 Granule

    ______________________________________                                         N--[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-                                                           80%                                                3-(1H--pyrrol-1-yl)-2-thiophenesulfonamide                                     wetting agent                1%                                                crude ligninsulfonate salt (containing                                                                     10%                                                5-20% of the natural sugars)                                                   attapulgite clay             9%                                                ______________________________________                                    

The ingredients are blended and milled to pass through a 100 mesh screen. This material is then added to a fluid bed granulator, the air flow is adjusted to gently fluidize the material, and a fine spray of water is sprayed onto the fluidized material. The fluidization and spraying are continued until granules of the desired size range are made. The spraying is stopped, but fluidization is continued, optionally with heat, until the water content is reduced to the desired level, generally less than 1%. The material is then discharged, screened to the desired size range, generally 14-100 mesh (1410-149 microns), and packaged for use.

EXAMPLE 28 Low Strength Granule

    ______________________________________                                         N--[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino-                                                        1%                                                   carbonyl]-3-(1H--pyrrol-1-yl)-2-thiophene-                                     sulfonamide                                                                    N,N--dimethylformamide    9%                                                   attapulgite granules      90%                                                  (U.S.S. 20-40 sieve)                                                           ______________________________________                                    

The active ingredient is dissolved in the solvent and the solution is sprayed upon dedusted granules in a double cone blender. After spraying of the solution has been completed, the blender is allowed to run for a short period and then the granules are packaged.

EXAMPLE 29 Aqueous Suspension

    ______________________________________                                         N--[(4-methoxy-6-methylpyrimidin-2-yl)amino-                                                              40%                                                 carbonyl]-3-(1H--pyrrol-1-yl)-2-thiophene-                                     sulfonamide                                                                    polyacrylic acid thickener                                                                               0.3%                                                 dodecylphenol polyethylene glycol ether                                                                  0.5%                                                 disodium phosphate          1%                                                 monosodium phosphate      0.5%                                                 polyvinyl alcohol         1.0%                                                 water                     56.7%                                                ______________________________________                                    

The ingredients are blended and ground together in a sand mill to produce particles essentially all under 5 microns in size.

EXAMPLE 30 Solution

    ______________________________________                                         3-(5-chloro-1H--1,2,4-triazol-1-yl)-N--[(4,6-dimethoxy-                                                     5%                                                pyrimidin-2-yl)aminocarbonyl]-2-thiophene-                                     sulfonamide, sodium salt                                                       water                       95%                                                ______________________________________                                    

The salt is added directly to the water with stirring to produce the solution, which may then be packaged for use.

UTILITY

Test results indicate that the compounds of the present invention are active herbicides. They have utility for broad-spectrum pre- and/or post-emergence weed control in areas where complete control of all vegetation is desired, such as around fuel storage tanks, ammunition depots, industrial storage areas, parking lots, drive-in theaters, around billboards, highway and railroad structures. Alternatively, many of the subject compounds should be useful for the selective pre- or post-emergence weed control in crops, especially wheat, barley and soybeans.

The rates of application for the compounds of the invention are determined by a number of factors, including their use as selective or general herbicides, the crop species involved, the types of weeds to be controlled, weather and climate, formulations selected, mode of application, amount of foliage present, etc. In general use, the subject compounds should be applied at levels of around 0.01 to 5 kg/ha, the lower rates being suggested for use on lighter soils and/or those having a low organic matter content, for selective weed control or for situations where only short-term persistence is required.

The compounds of the invention may be used in combination with any other commercial herbicide, examples of which are those of the triazine, triazole, uracil, urea, amide, diphenylether, carbamate and bipyridylium types. The compounds may also be used in combination with mefluidide.

The herbicidal properties of the subject compounds were discovered in a number of greenhouse tests. The test procedures and results follow.

TEST A

Seeds of crabgrass (Digitaria sp.), barnyardgrass (Echinochloa crusgalli), wild oats (Avena fatua), sicklepod (Cassia obtusifolia), morningglory (Ipomoea sp.), cocklebur (Xanthium sp.), sorghum, corn, soybean, cotton, sugar beet, rice, wheat and nutsedge tubers (Cyperus rotundus) were planted in a growth medium and treated pre-emergence with the chemicals dissolved in a non-phytotoxic solvent. At the same time, these crops and weed species were treated with a soil/foliage application. At the time of treatment, the plants ranged in height from 2 to 18 cm. Treated plants and controls were maintained in a greenhouse for sixteen days, after which all species were compared to controls and visually rated for response to treatment. The ratings are based on a numerical scale extending from 0=no injury, to 10=complete kill. The accompanying descriptive symbols have the following meanings:

C=chlorosis or necrosis;

G=growth retardation;

H=formative effects;

U=unusual pigmentation.

The compounds are highly active herbicides. Wheat exhibits tolerance.

COMPOUNDS ##STR157##

    TABLE A        Cmpd. Cmpd. Cmpd. Cmpd. Cmpd. Cmpd. Cmpd. Cmpd. Cmpd.            1 2 3      4 5 4 5 6 7 Cmpd. 8 Cmpd. 9 Cmpd. 10 Cmpd. 11 Cmpd. 12 Cmpd. 13 Cmpd. 14      Cmpd. 15 Cmpd. 16 Cmpd. 17 Rate kg/ha 0.05 0.05 0.05 0.05 0.05 2 2 0.05      0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05        POST-EMERGENCE Morningglory 2C,5G 4C,9G 10C 0 0 2C,5G 1C 0 1C,3G 3C,8H 5      C,8H 2C,5G 10C 10C 9C 9C 2C,6G 10C  10C Cocklebur 4C,9G 9C 10C 0 0 1C 1C      2C,3H 6G 4C,9G 2G 2C,6H 2C,7G 4C,9G 9C 3C,8G 2C,5G 5C,9G 9C Sicklepod      2C,8H 9C 9C 0 0 2C,6G 1C 1C 5C,9G 3C,3H 4C,5G 3C,3H 2C,7G 4C,8G 4C,7G      4C,8G 1C 4C,8G 5C,9G Nutsedge 9C 9C 10C 0 0 0 0 0 9G 0 0 7G 8G 10C 3G 3G      2C,9G 3C,9G 9C Crabgrass 0 2C,6G 2C,6G 0 0 0 0 0 0 0 0 0 1H 0 0 0 0 0 3G      Barnyardgrass 10C 9C 9C 0 0 0 0 0 4G 0 0 3G 8H 3C,8H 0 0 0 4C,9H 4C,8H      Wild Oats 2G 2C,6G 0 0 0 0 0 0 0 0 0 2C,3G 0 0 0 0 0 3C,9G 0 Wheat 0 1C      0 0 0 0 0 0 0 0 0 3G 0 0 0 0 0 0 0 Corn 5U,9G 9C 5C,9G 0 0 0 0 0 3G 0 0      1C,4H 3C,9H 2C,6H 2G 3G 0 3C,9H 1C,3H Soybean 5C,9G 9C 9C 3G 1H 2C,7G 0      1C,4H 5C,9G 3C,8H 3C,7H 3C,9G 4C,9G 4C,9G 4C,9G 4C,9G 1C 5C,9G 5C,9G      Rice 2C,8G 3C,9G 5G 0 0 0 0 2C,4G 3G 4G 2G 6G 2C,5G 1C,4G 0 0 0 4C,9G 3G      Sorghum 9C 3C,9H 4C,9G 0 0 0 0 2C,4G 2C,5G 3G 0 3C,7G 5C,9H 3C,7H 0 0 1C      3C,9H 2C,7G Sugar beet 5C,9G 9C 9C 0 0 5C,9G 3C,5G 3C,8H 9C 9C 9C 2C,7G      3C,8G 9C 9C 10C 0 3C,8G 9C Cotton 4C,9G 6C,9G 9C 0 0 2C,9G 1C 2C,8H 9C      4C,9H 4C,8H 3C,9H 9C 9C 5C,9G 4C,9H 4C,8G 5C,9H 9C Bush bean      -- --      -- -- -- -- -- -- -- -- -- -- -- -- Velvetleaf Cheatgrass PRE-EMERGENCE      Morningglory 2G 9C 9G 0 0 5G 0 2G 7G 8G 9G 5G 9G 9G 6G 9G 7G 8G 9G      Cocklebur 9G 9H 9H 0 0 5G 0 -- 7G 5G 5H -- 8H 8H 4G 8H 0 7H 8H Sicklepod      8G 9C 9C 0 0 2C 0 2C 7G 3C,8G 5C,9G 2C 7G 8G 2C,3H 8G 0 5G 7G Nutsedge      10E 10E 10E 0 0 0 0 0 10E 0 5G 0 0 2G 0 0 0 0 6G Crabgrass 0 4G 4G 0 0 0      0 0 2G 0 0 0 0 0 0 0 0 0 0 Barnyardgrass 5G 3C,9H 3C,9H 0 0 0 0 0 2C,4G      0 0 0 2C,8H 2C,5G 0 0 0 5G 3C,9H Wild Oats 2C,7G 3C,8G 2C,7G 0 0 0 0 0      2C 0 0 0 2C,4G 0 0 0 0 4G 0 Wheat 5G 6G 0 0 0 0 0 0 0 0 2G 0 0 0 0 0 0 0      0 Corn 2C,9H 3C,9H 2C,9H 0 0 5G 0 0 4G 3G 5G 2G 4C,9H 2C,7G 4G 4G 0 2G      3G Soybean 3C,6H 9H 2C,8H 0 0 2C,3G 0 3G 2C,7H 3C,5H 4C,7G 2C,3H 8H      2C,5H 3C,6G 2C,6G 0 2H 3C,6H Rice 8H 9G 8G 0 0 1C 0 5G 2C,5G 3G 5G 0 7G      1C 0 0 0 5G 4G Sorghum 2C,9G 6C,9H 2C,9H 0 0 2G 0 5G 3C,7H 2G 0 2C,4H      3C,9H 5G 0 0 0 2C,5G 3C,7H Suqar beet 5C,9G 10C 9C 0 0 4C,9G 0 3C,6G 9C      9C 5C,9G 4G 5C,9G 8G 3C,7G 4C,7G 0 8G 5C,9G Cotton 9G 10C 9G 0 0 2C,5G 0      6G 9G 6G 3C,7H 6G 8G 8G 2C,7G 8G 6G 4G 9G Velvetleaf Cheatgrass          Cmpd.  Cmpd.  Cmpd.              Cmpd. 18 19 Cmpd. 20 21 Cmpd. 22 23      Cmpd. 24 Cmpd. 25 Cmpd. 26 Cmpd. 27 Cmpd. 28 Cmpd. 29 Cmpd. 30 Cmpd. 31      Cmpd. 32 Cmpd. 33 Cmpd. 34 Cmpd. 35 Rate kg/ha 0.05 0.05 0.05 0.05 0.05      0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05        POST-EMERGENCE Morningglory 5C,9G 5C,9G 10C 9C 4C,9G 10C 2C,8H 10C      4C,9G 4C,7H 4C,9G 1C,2H 2C,7G 9C 4C,8G 0 10C 9C Cocklebur 10C 9C 9C 9C      9C 10C 5G 5C,9G 5C,9G 4C,9H 4C,8H 2C,5H 2C,7H 9C 4C,9H 0 9C 10C Sicklepod       5C,9G 6C,9G 2C,4G 9C 2C 5C,8H Nutsedge 0 2C,3G 2C,8G 9C 0 0 0 5G 3C,9G      0 0 0 2G 6C,9G 4G 0 5G 0 Crabgrass 0 0 0 0 0 0 0 5G 3G 0 0 0 0 3G 0 0 3G      0 Barnyardgrass 2H 0 3C,8H 3H 3G 0 0 3C,8H 3C,9H 0 0 2C,5H 7H 3C,7G 2H 0      3C,7H 0 Wild Oats 0 0 3C,3G 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Wheat 0 0 2G 0      0 0 0 0 2G 0 0 0 0 0 0 0 0 0 Corn 0 0 2C,7H 2G 2C,3H 0 0 4C,9G 3C,9H 0 0      0 0 3C,8H 0 0 2H,5G 0 Soybean 5C,9G 5C,9G 4C,9H 4C,9G 4C,9G 4C,9G 2C,7G      4C,9G 4C,9G 3C,8H 3C,8G 0 2H 4C,9G 3C,7H 2G 4C,9G 5C,9G Rice 0 0 2C,8G 0      0 0 2G 3C,8G 3C,8G 0 0 0 5C,9G 5G 0 0 4G 0 Sorghum 0 0 3C,9H 3C,5H 0 0      2C 4C,9H 3C,8H 0 0 1C,2H 2C,6H 3C,9H 0 0 2C,5G 0 Sugar beet 9C 9C 9C 9C      9C 9C 0 9C 9C 4C,8H 4C,9H 0 5C,9H 10C 4C,8H 2H 2C,6G 9C Cotton 5C,9H 9C      9C 9C 4C,9H 4C,9H 2G 5C,9H 5C,9G 3C,6G 3C,7G 0 5C,9G 9C 4C,8G 2G 9C 10C      Bush bean -- -- -- -- -- -- Velvetleaf       2C,5H 9C 5C,9G 3C,7H 0 3G      2G 10C 3C,9G 0 10C 10C Cheatgrass       0 3C,8G 5G 0 0 0 0 6G 0 0 5G 0      PRE-EMERGENCE Morningglory 4C,9G 9G 8G 9G 8H 8G  0 9G 8G 3C,3H 0 0 7G 9G 8      G 0 9H 9G Cocklebur 7H 3C,7H 5H 8H 2C 5H 0 3C,5H 9H 0 0 0 4H 9H 3G 0 --      -- Sicklepod 4C,7G 4C,8G 5G 8G 2C,4G 5G Nutsedge 0 0 0 10E 0 0 0 0 0 0 0      0 7G 8G 0 0 10E 0 Crabgrass 0 0 0 0 0 0 0 1C 0 0 0 0 0 0 0 0 0 0      Barnyardgrass 0 0 0 2H 0 0 0 1C 3H 0 0 0 0 2C,5H 0 0 7G 0 Wild Oats 0 0      0 0 0 0 0 0 0 0 0 0 0 2G 0 0 3C 0 Wheat 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0      2G 0 Corn 0 0 2C,8H 7G 2C,5G 2C,4G 0 5C,8G 4C,3G 0 0 0 2C,7G 3C,9H 0 0      2C,8G 3G Soybean 2C,5G 3C,6H 4C,5G 2C,6H 4C,5H 4C,6G 0 4C,7H 3C,4G 0 2C      0 1H 4C,8H 6H 0 4C,8H 9H Rice 0 0 2C,5G 5G 3G 0 0 5G 2C 2H 4G 0 2C,4G      4C,8G 0 0 5G 0 Sorghum 0 0 3C,9H 5H 0 0 0 4C,7G 3C,7G 2G 0 0 3C,6H 4C,9H      1C 0 2C,5G 0 Sugar beet 5C,9G 5C,9G 5C,9G 4C,9G 4C,9G 4C,9G 0 4C,9G      4C,8G 0 0 0 8G 9C 9C 4G 9C 9C Cotton 5G 2C,6G 8G 9G 2C,7G 6G 0 3C,7H 7G      0 0 0 9G 9G 8G 0 9G 9G Velvetleaf       0 3C,6H 5H 0 0 0 8G 10E 4G 0 9C      9C Cheatgrass       0 4G 0 0 0 0 2G 9G 0 0 8G 0          Cmpd.  Cmpd.             Cmpd.   Cmpd. 36 37 Cmpd. 38 39 Cmpd. 40      Cmpd. 41 Cmpd. 42 Cmpd. 43 Cmpd. 44 Cmpd. 45 Cmpd. 46 Cmpd. 47 Cmpd. 48      Cmpd. 49 Cmpd. 50 Cmpd. 51 52 Cmpd. 53 Rate kg/ha 0.05 0.05 0.05 0.05      0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05      0.05      POST-EMERGENCE Morningglory 9C 5G 9C 4H 5C,9G 10C 9C 4C,9G      4C,9G 2C,4G 7G 5C,9G 4C,8G 4C,9H 10C 3C,7H 0 5C,9G Cocklebur 10C 2C,8G      10C 0 4C,9G 9C 9C 5C,9G 5C,9G 2C,5G 5C,9H 10C 4C,9H 10C 10C 4C,9H 2C,7G      8H Sickelpod Nutsedge 2G 0 5C,9G 0 3C,5G 4C,8G 5C,9G 0 0 0 4C,9G,8X 0      4C,9G 2C,9G 5C,9G 2C,5G 0 2G Crabgrass 0 0 4C,5G 0 0 2G 2G 0 0 0 0 2C,6H      0 0 8G 0 0 0 Barnyardgrass 0 0 9C 0 4G 4C,9H 4C,9H 0 0 0 3C,9H 3C,9H 2H      4C,8H 9C 3C,9H 2C,4H 2C,7H Wild Oats 0 0 2C,2G 0 0 0 0 0 0 0 2G 0 0 0      3C,5G 0 0 0 Wheat 0 0 8G 0 0 0 0 0 0 0 2G 0 0 0 2C,4G 0 0 0 Corn 0 0      5C,9H 0 1H 3C,7H 3H 0 0 0 3C,9H 5C,8G 0 2C,7H 5C,9H 9G 3C,6H 2C,8G      Soybean 5C,9G 2G 5C,9G 0 4H 4C,8H 2C,7H 2G 0 0 4C,9G 5C,9G 4C,9G 3C,8G      5C,9G 2C,9G 3C,5G 4C,9G Rice 0 0 9C 0 8G 8G 6G 0 0 0 9C 5C,9G 0 5C,9G      6C,9G 2C,9G 2C,8G 3C,8G Sorghum 0 0 4C,9G 0 2C,8G 4C,8H 3C,8H 0 0 0      3C,9H 2C,8H 2G 3C,7H 5C,9H 3C,9H 2C,5G 3C,7H Sugar beet 9C 4G 9C 2H      3C,8H 9C 9C 9C 9C 2C,3H 10C 4C,9H 3C,6G 5C,9G 9C 3C,8H 5C,9H 9C Cotton      10C 5G 9C 0 4C,9H 10C 10C 3C,9G 4C,9G 6G 10C 9C 10C 10C 9C 3C,7H 0 5C,9G      Bush bean Velvetleaf 3C,7G 7G 9C 0 9C 10C 10C 5C,8G 2C,5G 3C,8G 5C,9H      5C,9G 4C 4C,9G 10C 5C,9G 2C,4G 4C,9G Cheatgrass 0 0 9C 0 2C,6G 3C,5G 8G      0 0 0 4C,9G 4G 0 1C 9C 2C,6G 0 0 PRE-EMERGENCE Morningglory 9G 0 9C 0 3C 6      G 7G 2C,6G 7H 5G 8H 7G 9G 9G 9G 5G 4H 6G Cocklebur -- 0 9H 0 4H 4G 5G 2G      0 0 8H 8G 7H 7G 9H 5H 3H 2C,5G Sicklepod Nutsedge 3G 0 5C,9H 0 0 0 0 0 0      0 0 0 10E 9G 8G 0 0 5G Crabgrass 0 0 5G 0 0 0 2G 0 0 0 0 0 0 0 7G 0 4G 0      Barnyardgrass 0 0 4C,9H 0 0 1C,3H 4C,7G 0 0 0 2C,6H 5G 2C 3C,8H 2C,9H 6G      1H 0 Wild Oats 0 0 3G 0 0 0 0 0 0 0 6G 0 0 0 6G 0 0 0 Wheat 0 0 8H 0 0 0      0 0 0 0 5G 0 0 0 6G 0 0 0 Corn 0 0 9H 0 0 3G 6G 0 0 0 2C,9H 5G 3G 3C,5G      2C,9H 2C,8H 2G 2C,5G Soybean 8H 0 4C,8H 0 0 4G 2C,5G 2G 0 0 2C,6G 5G      2H,4G 4G 9H 1C,3G 0 2C Rice 0 0 10E 0 0 5G 8G 0 2C 0 3C,5G 5G 3G 0 10E      3C,5G 0 3G Sorghum 0 0 5C,9H 0 0 2C,5G 4C,9G 0 1C 2C,4G 3C,8H 2G 2C,5G      2C,8H 6C,9G 3C,8H 0 1C Sugar beet 9C 4G 5C,9G 0 4G 8G 5C,9G 4C,8G 7G 8G      9C 5C,9G 8G 8G 5C,9G 2C,9G 5G 4C,9G Cotton 9G 0 2C,9G 0 4G 8G 8G 7G 3G      5G 8G 6G 8G 8G 9G 8G 3G 8G Velvetleaf 8G 0 9H,9G 0 3G 8H -- 3G 2H 3G 9G      7G 8G 8G 5C,9G 6G 5G 4G Cheatgrass 0 0 5C,9H 0 0 5G 8G 0 0 0 2C,8G 0 5G      3G 8G 3C,7G 0 0                       Cmpd.  Cmpd. Cmpd.  Cmpd. 54 Cmpd. 55 Cmpd. 56 Cmpd. 57      Cmpd. 58 Cmpd. 59 Cmpd. 60 Cmpd. 61 Cmpd. 62 Cmpd. 63 Cmpd. 64 Cmpd. 65      Cmpd. 66 Cmpd. 67 68 Cmpd. 69 70 71 Rate kg/ha 0.05 0.05 0.05 0.05 0.05      0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05        POST-EMERGENCE Morningglory 5C,9G 0 5C,9G 10C 9C 4C,9G 9C 4C,9G 2C,8G      10C 10C 9C 5C,9G 2C,9G 5G 9C 2C,7G 5G Cocklebur 4C,9G 0 5C,9G 9C 10C 9C      10C 5C,9G 10C 10C 10C 9C 4C,9G 5C,9G 5G 6G 5G 4G Sicklepod Nutsedge 0 0      9G 2C,9G 8G 0 0 3C,8G 5G 2C,9G 9C 0 0 3C,9G 2C,8G 2C,9G 9G 0 Crabgrass      4G 0 0 3C,7G 5G 2G 0 0 4G 5G 5G 0 2G 2G 0 2C,6G 3C,8G 0 Barnyardgrass      4C,8H 4H 4C,9H 9C 5C,9H 4H 2H 5H 3C,5H 3C,9H 9H 3H 2H 8H 2C,5G 3C,9H 9H      0 Wild Oats 0 0 3G 2C,5G 3C,5G 0 0 0 0 0 0 0 0 0 0 2G 0 0 Wheat 0 0 2G      2C,8G 9G 0 0 0 0 0 0 0 0 0 0 2G 0 0 Corn 0 0 3C,9H 5C,9G 3C,9H 5H 0 3H      2C,9G 2U,9G 3C,9H 6H 6H 5H 1C,2G 2C,9H 1C,4G 0 Soybean 3C,9G 0 4C,9G 9C      9C 4C,8G 4C,9G 2C,3G 4C,9G 9C 9C 5C,9G 4C,9G 2C,7G 3H,8G 4C,9G 2C,8H 3H      Rice 2C,3G 0 2C,8G 5C,9G 5C,9G 0 0 3G 3C,9G 4C,9G 2C,8G 3G 0 3G 2C,6G      2C,8G 3C,9G 0 Sorghum 2C,6G 3G 3C,9H 5C,9G 4C,9H 0 0 2C,7G 3C,8H 4C,9H      3C,9H 5G 3G 2C,8G 2C,8H 3C,9G 3C,9G 0 Sugar beet 5C,9G 1H 3C,7G 4C,9H      5C,9H 3C,7G 9C 4G 9C 9C 9C 9C 9C 9C 9C 9C 9C 5C,9G Cotton 5C,9G 0 3C,5G      4C,9H 5C,9G 3C,4G 3C,7G 2G 5C,9G 10C 10C 2C,8G 2C,3G 5C,9G 3C,9H 2C,9G      9C 2C,9G Bush bean Velvetleaf 4C,8G 0 4C,8H 5C,9G 9C 4C,8H 2C,4G 3C,6G      5C,9G 10C 10C 9C 4C,9G 3C,9G 2C,8G 9C 9C 2C,6G Cheatgrass 5G 0 2C,8G      2C,9G 3C,9G 0 0 2G 6G 2C,8G 8G 0 0 0 2C,9G 3C,9G 3C,9G 0 PRE-EMERGENCE      Morningglory 7H 0 2C 3C,7H 3C,7H 2H 3H 2C,5G 2C,6G 8G 8G 2C,5G 2C,5H 0      2G 2C,7G 9G 5G Cocklebur 0 0 1C 3C,3H 3C,6H 0 0 2C 3C,7H 6G 8H 2C,5H 2H      0 0 6G 7G 0 Sicklepod Nutsedge 0 0 0 0 4G 0 0 0 4G 10E 5G 0 0 0 0 6G      2C,9G 0 Crabgrass 0 0 0 0 0 0 0 0 3G 5G 0 0 0 0 3G 4G 5G 0 Barnyardgrass      0 0 0 0 4G 0 0 0 0 3C,8H 5G 2C 0 2C 0 3C,7H 2C,9H 0 Wild Oats 0 0 0 0 0      0 0 0 0 0 0 0 0 0 0 2C,7G 4G 0 Wheat 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 5G 2G      0 Corn 0 0 2C 3C,5G 3C,4G 3G 0 0 2C,7G 3C,9G 2C,5G 2C,6G 2G 2G 2C,5G      2C,8H 2C,8G 0 Soybean 0 0 0 3C,3H 3C,5G 0 0 0 2C,2H 3C,8H 4H 2C,4G 6G 3G      1C 2C,6G 6G 0 Rice 0 0 0 0 3C 0 2G 0 3G 7G 2G 0 0 2G 2C,5G 3C,8H 3C,9H 0      Sorghum 0 0 0 3C 3C,4G 0 0 2C 3G 3C,9H 2C,9G 2C,8G 2G 3C,6G 3C,8G 3C,9G      2C,9H 3G Sugar beet 7G 0 0 3C,6G 4C,7G 0 0 0 7G 5C,9G 3C,9G 5C,9G 4C,9G      7G 2C,8G 9G 3C,8G 5G Cotton 2G 0 0 2C 6G 0 3G 2C 8G 9G 9G 8G 7G 6G 6G 8G      9G 0 Velvetleaf 0 0 0 4C,5G 3C,5G 0 0 0 6G 4C,9G 8G 3C,3H 2C,4G 0 5G      4C,9G 5C,9G 0 Cheatgrass 0 0 0 0 0 0 0 0 4G 8H 0 0 0 0 5G 2C,8G 9H      0        Cmpd. 72 Cmpd. 73 Cmpd. 74 Cmpd. 75 Cmpd. 76 Cmpd. 77 Cmpd. 78      Cmpd. 79 Cmpd. 80 Cmpd. 81 Cmpd. 82 Cmpd. 83 Cmpd. 84 Cmpd. 85 Cmpd. 86      Rate kg/ha 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05      0.05 0.05 0.05        POST-EMERGENCE Morningglory 2C,5G 2C,6G 2C,6G 10C 5C,9H 2C,5G 10C 9C      2C,8H 4C,9G 10C 7G 2C,5G 10C 2C,3G Cocklebur 2G 0 5G 2C,6G 3C,8G 3C,9H      10C 9C 2H 4C,9H 10C 3C,9G 3C,9H 5C,9G 6G Sicklepod Nutsedge 0 0 8G 5G      2C,6G 8G 4G 4G 0 2C,5G 7G 0 4G 0 5G Crabgrass 0 1C 2G 2G 3G 2G 2G 0 0 0      4G 0 0 5G 3G Barnyardgrass 0 2C,8H 4C,9H 3G 3C,7H 0 0 0 0 9H 4C,9H 2H 5H      2H 3C,8H Wild Oats 0 0 3C,8G 0 0 0 0 0 0 0 0 0 0 0 0 Wheat 0 0 3G 0 0 0      0 0 0 0 0 0 0 0 0 Corn 0 0 9H 0 3C,8H 0 0 0 0 3C,9H 0 0 3C,8H 0 0      Soybean 1H 3H 4C,9G 4C,9G 4C,9G 5C,9G 5C,9G 5C,9G 1C,4G 5C,9G 4C,9G      4C,9G 4C,8G 4C,9G 0 Rice 0 5G 5C,9G 5G 8G 0 1C 0 0 2G 2G 0 4G 0 0      Sorghum 1C 2C,9H 5C,9G 2G 3C,8H 0 0 0 0 3C,4H 2C,5H 2H 3C,7G 2G 3C,6H      Sugar beet 2C,7G 3C,7G 5C,9H 1H 2C,5G 5G 9C 9C 0 4C,9H 9C 4C,9G 3C,6G      5C,9G 0 Cotton 2C,5G 3C,7H 4C,9H 9C 9C 9C 5C,9G 9C 9C 4C,9G 9C 2C,5G      2C,5G 2G 0 Bush bean Velvetleaf 2G 5G 5C,9G 4C,9G 10C 9C 10C 2C,7G 10C      10C 10C 4C,9G 4C,9G 4C,8H 4G Cheatgrass 0 0 2C,9G 4G 8G 0 0 0 0 2C,5G 3G      0 5G 0 0 PRE-EMERGENCE Morningglory 2G 6H 4G 10C 9G 2C,8G 9G 9G 9G 3G 7H 0       7G 5H 5G Cocklebur 0 0 0 2C,8G -- 7H 9H 8H 5G 3C,6H -- 0 0 0 0 Sicklepod       Nutsedge 0 0 0 0 7G 4G 0 3G 5G 5G 0 0 0 0 0 Crabrass 0 0 0 1C 2G 2G 0 0      0 0 0 0 4G 0 0 Barnyardgrass 0 0 1C 3C,5G 3C,7H 4H 1H 0 0 3C,7G 3H 0 2G      2G 0 Wild Oats 0 0 0 0 3G 0 0 0 0 0 0 0 0 0 0 Wheat 0 0 4G 2G 4G 2G 0 0      0 0 0 0 0 0 0 Corn 0 0 2C,4G 4G 3C,7G 4G 0 0 0 3C,9H 2C,5G 0 2C,5G 0 2G      Soybean 0 0 5G 3C,3H 3C,6H 0 4G 2C,6H 0 3C,2H 2C 0 2C,5G 0 0 Rice 0 5G      9H 2G 5G 5G 0 0 0 4G 0 0 0 0 0 Sorghum 0 2C,8G 3C,8H 2G 5G 2G 0 0 0      3C,8H 3C,8H 0 3C,7H 2G 2C,8G Sugar beet 0 3C,6G 4C,8G 3C,7H 9G 8G 9C 10C      10C 4C,9G 8G 5G 7G 5G 7G Cotton 0 3C,6G 8G 8G 8G 6G 9G 9G 5G 8G 6G 0 6G      5G 7G Velvetleaf 0 3G 2G 5C,9G 5C,9G 8G 10C 7G 6G 9C 4C,8G 2G 2C,5G 0 0      Cheatgrass 0 0 6G 3C,6G 8G 5G 0 0 2G 7G 0 0 0 0 0                  CL TEST B

Postemergence

Two round pans (25 cm diameter by 12.5 cm deep) were filled with Woodstown sandy loam soil. One pan was planted with blackgrass (Alopacurus myosuroides), sugar beets, nutsedge (Cyperus rotundus) tubers, crabgrass (Digitaria sanquinalis), sicklepod (Cassia obtusifolia), teaweed (Sida spinosa), jimsonweed (Datura stramonium), velvetleaf (Abutilon theophrasti), and giant foxtail (Setaria faberii). The other pan was planted with wheat, cotton, rice, corn, soybean, wild oats (Avena fatua), cocklebur (Xantium pensylvanicum), morningglory (Ipomoea hederacea), johnsongrass (Sorghum halepense) and barnyardgrass (Echinochloa crusgalli). The plants were grown for approximately fourteen days, then sprayed post-emergence with the chemicals dissolved in a non-phytotoxic solvent.

Pre-emergence

Two round pans (25 cm diameter by 12.5 cm deep) were filled with Woodstown sandy loam soil. One pan was planted with blackgrass (Alopacurus myosuroides), sugar beets, nutsedge, crabgrass, sicklepod, teaweed, jimsonweed, velvetleaf, and giant foxtail. The other pan was planted with wheat, cotton, rice, corn, soybeans, wild oats, cocklebur, morningglory, johnsongrass, and barnyardgrass. The two pans were sprayed pre-emergence with the chemicals dissolved in a non-phytotoxic solvent.

Treated plants and controls were maintained in the greenhouse for 28 days, then all treated plants were compared to controls and visually rated for plant response utilizing the rating system as described for Test A. The data are summarized in Table B.

The high herbicidal activity and the tolerance of wheat as observed in Test A were confirmed.

                                      TABLE B                                      __________________________________________________________________________             Compound 1                                                                               Compound 2 Compound 3                                        Rate g/ha                                                                              62 16 4 1 62 16 4  1 62 16 4  1                                        __________________________________________________________________________     POST-EMERGENCE                                                                 Corn    10G                                                                               8G 2G                                                                               0 10G                                                                               9G 7G 2G                                                                               8G 4G 0  0                                        Wheat   2G 0  0 0 2G 0  0  0 0  0  0  0                                        Rice    10G                                                                               7G 3G                                                                               0 9G 5G 2G 0 2G 0  0  0                                        Soybean 10G                                                                               10G                                                                               8G                                                                               2G                                                                               10G                                                                               10G                                                                               10G                                                                               8G                                                                               10G                                                                               10G                                                                               10G                                                                               4G                                       Cotton  10G                                                                               10G                                                                               4G                                                                               0 10G                                                                               10G                                                                               10G                                                                               5G                                                                               10G                                                                               10G                                                                               9G 2G                                       Sugar beet                                                                             10G                                                                               10G                                                                               7G                                                                               3G                                                                               10G                                                                               10G                                                                               10G                                                                               6G                                                                               10G                                                                               10G                                                                               10G                                                                               8G                                       Crabgrass                                                                              6G 5G 2G                                                                               0 5G 4G 3G 0 6G 2G 0  0                                        Johnsongrass                                                                           10G                                                                               6G 3G                                                                               0 10G                                                                               8G 5G 0 8G 4G 2G 0                                        Blackgrass                                                                             7G 4G 0 0 5G 0  0  0 0  0  0  0                                        Barnyardgrass                                                                          10G                                                                               9G 3G                                                                               0 9G 8G 3G 0 9G 4G 2G 0                                        Nutsedge                                                                               10G                                                                               10G                                                                               4G                                                                               0 10G                                                                               10G                                                                               10G                                                                               9G                                                                               10G                                                                               10G                                                                               10G                                                                               9G                                       Giant Foxtail                                                                          10G                                                                               5G 2G                                                                               0 7G 3G 0  0 5G 2G 0  0                                        Wild Oats                                                                              2G 0  0 0 2G 0  0  0 0  0  0  0                                        Cocklebur                                                                              10G                                                                               9G 4G                                                                               0 10G                                                                               10G                                                                               7G 2G                                                                               10G                                                                               6G 2G 0                                        Morningglory                                                                           9G 2G 0 0 10G                                                                               10G                                                                               6G 2G                                                                               9G 7G 3G 0                                        Teaweed 10G                                                                               10G                                                                               3G                                                                               0 6G 3G 0  0 6G 4G 0  0                                        Sicklepod                                                                              10G                                                                               5G 2G                                                                               0 10G                                                                               10G                                                                               6G 0 10G                                                                               8G 4G 0                                        Jimsonweed                                                                             7G 4G 0 0 9G 4G 2G 0 7G 4G 0  0                                        Velvetleaf                                                                             10G                                                                               10G                                                                               4G                                                                               2G                                                                               10G                                                                               10G                                                                               9G 2G                                                                               10G                                                                               10G                                                                               9G 3G                                       __________________________________________________________________________     Rate g/ha                                                                              250                                                                               62 16                                                                               4 250                                                                               62 16 4 250                                                                               62 16 4                                        __________________________________________________________________________     PRE-EMERGENCE                                                                  Corn    10G                                                                               7G 3G                                                                               0 10G                                                                               8G 5G 0 10G                                                                               4G 0  0                                        Wheat   3G 0  0 0 3G 0  0  0 0  0  0  0                                        Rice    10E                                                                               10G                                                                               8G                                                                               7G                                                                               10G                                                                               9G 7G 4G                                                                               10G                                                                               8G 6G 3G                                       Soybean 10G                                                                               8G 7G                                                                               3G                                                                               10G                                                                               9G 5G 2C                                                                               10G                                                                               8G 4G 2C                                       Cotton  10G                                                                               9G 5G                                                                               2G                                                                               10G                                                                               10G                                                                               9G 6G                                                                               9G 10G                                                                               8G 2G                                       Sugar beet                                                                             10G                                                                               10G                                                                               7G                                                                               4G                                                                               10G                                                                               10G                                                                               8G 4G                                                                               10G                                                                               10G                                                                               8G 5G                                       Crabgrass                                                                              6G 2G 0 0 7G 3G 0  0 6G 3G 2G 0                                        Johnsongrass                                                                           10G                                                                               9G 8G                                                                               3G                                                                               10G                                                                               10G                                                                               8G 3G                                                                               9G 10G                                                                               4G 0                                        Blackgrass                                                                             10G                                                                               8G 4G                                                                               2G                                                                               10G                                                                               8G 4G 0 5G 2G 0  0                                        Barnyardgrass                                                                          9G 7G 2G                                                                               0 10G                                                                               6G 5G 2G                                                                               9G 6G 4G 0                                        Nutsedge                                                                               10E                                                                               9G 6G                                                                               2G                                                                               10E                                                                               9G 4G 0 10G                                                                               9G 8G 3G                                       Giant Foxtail                                                                          -- 6G 2G                                                                               0 10G                                                                               6G -- 2G                                                                               9G 6G -- 0                                        Wild Oats                                                                              5G 2G 0 0 2G 0  0  0 0  0  0  0                                        Cocklebur                                                                              10G                                                                               8G 3G                                                                               0 9G 8G 5G 2G                                                                               8G 5G 4G 2G                                       Morningglory                                                                           5G 3G 0 0 8G 4G 0  0 9G 3G 0  0                                        Teaweed 10G                                                                               5G 2G                                                                               0 10G                                                                               7G 3G 0 10G                                                                               9G 5G 2G                                       Sicklepod                                                                              9G 4G 2G                                                                               0 8G 5G 0  0 9G 3G 0  0                                        Jimsonweed                                                                             10G                                                                               5G 2G                                                                               0 10G                                                                               8G 3G 0 10G                                                                               9G 6G 2G                                       Velvetleaf                                                                             10G                                                                               8G 3G                                                                               0 10G                                                                               9G 6G 3G                                                                               10G                                                                               10G                                                                               5G 0                                        __________________________________________________________________________

TEST C

Two plastic pans with polyethylene liners were filled with prepared Sassafras sandy loam soil. One pan was planted with seeds of wheat (Triticum aestivum), barley (Hordeum vulgare), wild oats (Avena fatua), cheatgrass (Bromus secalinus), blackgrass (Alopecurus myosuroides), annual bluegrass (Poa annua), green foxtail (Setaria viridis), Italian ryegrass (Lolium multiflorum) and rapeseed (Brassia napus). The other pan was planted with seeds of Russian thistle (Salsola kali), cleavers (Galium aparine), speedwell (Veronica persica), kochia (Kochia scoparia), shepherspurse (Capsella bursa-pastoris), (Matricaria inodora), black nightshade (Solanum nigrum), wild buckwheat (Polygonum convolvulus) and sugar beets (Beta vulgaris). The above two pans were treated pre-emergence. At the same time two pans in which the above plant species were already growing were treated post-emergence. Plant heights at the time of treatment ranged from 1-20 cm depending on plant species.

Compound #3 was diluted with a non-phytotoxic solvent and sprayed over the top of the pans. An untreated control and a solvent alone control were included for comparison. All treatments were maintained in the greenhouse for 19-22 days at which time the treatments were compared to the controls and the effects visually rated. The recorded data are presented in Table C. Compound #3 has high herbicidal activity at rates of application which are non-injurious to wheat and barley.

                  TABLE C                                                          ______________________________________                                         POST-EMERGENCE ON                                                              SASSAFRAS SANDY LOAM SOIL                                                                 Compound 3                                                          Rate kg/ha   0.125    0.06     0.03   0.015                                    ______________________________________                                         Wheat        0        0        0      0                                        Barley       0        0        0      0                                        Wild Oats    0        0        0      0                                        Cheatgrass   6G       3G       2G     0                                        Blackgrass   0        0        0      0                                        Annual Bluegrass                                                                            2G       2G       0      0                                        Green Foxtail                                                                               8G       8G       6G     6G                                       Italian Ryegrass                                                                            3G       2G       0      0                                        Rapeseed     10C      10C      9G     8G                                       Matricaria inodora                                                                          9G       9G       9G     9G                                       Galium       10C      10C      10C    10C                                      Russian Thistle                                                                             10C      10C      10C    7G                                       Shepherdspurse                                                                              8G       8G       8G     6G                                       Kochia       7G       4G       0      0                                        Black Nightshade                                                                            4G       3G       2G     0                                        Speedwell    7G       6G       0      0                                        Wild Buckwheat                                                                              10G      10C      10C    7G                                       Sugarbeet    10C      10C      10C    9G                                       ______________________________________                                         PRE-EMERGENCE ON                                                               SASSAFRAS SANDY LOAM SOIL                                                                 Compound 3                                                          Rate kg/ha   0.125    0.06     0.03   0.015                                    ______________________________________                                         Wheat        0        0        0      0                                        Barley       1G       0        0      0                                        Wild Oats    3G       3G       0      0                                        Cheatgrass   9G       8G       7G     5G                                       Blackgrass   6G       5G       5G     4G                                       Annual Bluegrass                                                                            5G       4G       4G     3G                                       Green Foxtail                                                                               9G       8G       7G     7G                                       Italian Ryegrass                                                                            6G       6G       6G     4G                                       Rapeseed     10C      10C      10C    9G                                       Matricaria inodora                                                                          9G       8G,5C    8G,5C  8G,5C                                    Galium       10C      9G       8G     7G                                       Russian Thistle                                                                             10C      10C      10C    10C                                      Shepherdspurse                                                                              9G,8C    9G,8C    9G,3C  9G,3C                                    Kochia       10C      10C      10C    10C                                      Black Nightshade                                                                            8G       7G       7G     7G                                       Speedwell    9G       8G,5C    7G     6G,3C                                    Wild Buckwheat                                                                              8G       8G       7G     6G                                       Sugarbeet    10C      10C      10C    9G,7C                                    ______________________________________                                     

What is claimed is:
 1. A compound of Formula Ia, Ib, or Ic ##STR158## wherein R is H or CH₃ ;n is 0, 1 or 2; W is O or S; Q is a saturated 5- or 6-membered ring containing 1 heteroatom selected from sulfur, nitrogen or oxygen or an unsaturated 5- or 6-membered ring containing 1-3 heteroatoms selected from 0-1 sulfur, 0-1 oxygen or 0-3 nitrogen and Q may optionally be substituted by one or more groups selected from SH, C₁ -C₄ alkyl, C₃ -C₄ alkenyl, C₁ -C₃ haloalkyl, halogen, C₁ -C₃ alkoxy, C₁ -C₄ alkylthio, C₃ -C₄ alkenylthio, C₃ -C₄ alkenyloxy, C₁ -C₂ haloalkoxy, C₁ -C₂ haloalkylthio, C₃ -C₄ alkynylthio, C₁ -C₄ cyanoalkylthio, C₁ -C₂ alkylcarbonylmethythio or C₁ -C₂ alkoxycarbonylmethylthio; E is H, C₁ -C₂ alkyl, C₁ -C₂ alkoxy, halogen, NO₂, C₁ -C₂ haloalkyl, C₁ -C₂ alkylthio, C₁ -C₂ alkylsulfonyl, C₁ -C₂ alkoxycarbonyl, C₁ -C₂ dialkylaminosulfamoyl; ##STR159## X is H, C₁ -C₄ alkyl, C₁ -C₄ alkoxy, C₁ -C₄ haloalkoxy, C₁ -C₄ haloalkyl, C₁ -C₄ haloalkylthio, C₁ -C₄ alkylthio, C₂ -C₅ alkoxyalkyl, C₂ -C₅ alkoxyalkoxy, amino, C₁ -C₃ alkylamino or di(C₁ -C₃ alkyl)amino; Y is H, C₁ -C₄ alkyl, C₁ -C₄ alkoxy, C₁ -C₄ haloalkoxy, C₁ -C₄ haloalkylthio, C₁ -C₄ alkylthio, halogen, C₂ -C₅ alkoxyalkyl, C₂ -C₅ alkoxyalkoxy, amino, C₁ -C₃ alkylamino, di(C₁ -C₃ alkyl)amino, C₃ -C₄ alkenyloxy, C₃ -C₄ alkynyloxy, C₂ -C₅ alkylthioalkyl, C₂ -C₅ alkylsulfinylalkyl, C₂ -C₅ alkylsulfonylalkyl, C₁ -C₄ haloalkyl, C₃ -C₅ cycloalkyl, C₂ -C₄ alkynyl, C(O)R_(c), ##STR160## m is 2 or 3; L₁ and L₂ are independently O or S; R_(a) and R_(b) are independently C₁ -C₂ alkyl; R_(c) is H or CH₃ ; Z is N; and X is CH₃ or OCH₃ ;and their agriculturally suitable salts; provided that
 1. the total number of carbon atoms of Q must be less than or equal to 8;2. X or Y is other than OCF₂ H;
 3. when Q is a saturated 5- or 6-membered ring containing one nitrogen atom, it is bonded to the thiophene ring through carbon; and
 4. when W is S, then R is H, A is A-1 and Y is CH₃, OCH₃, OC₂ H₅, CH₂ OCH₃, C₂ H₅, CF₃, SCH₃, OCH₂ CH═CH₂, OCH₂ C.tbd.CH, OCH₂ CH₂ OCH₃, CH(OCH₃)₂ or ##STR161##
 2. A compound of claim 1 wherein ##STR162## R₁ is H, Cl, CH₃ or OCH₃ ; R₂ is H, F, Cl, CH₃, OCH₃ or CF₃ ;R₃, R₄, R₅, R₆, R₇, R₈, R₉ and R₁₀ are independently H or CH₃ ; n' is 0 or 1; R₃ ' is H, SH, C₁ -C₃ alkyl, C₁ -C₄ alkylthio, C₃ -C₄ alkenylthio, C₃ -C₄ alkynylthio, C₁ -C₃ cyanoalkylthio, SCH₂ CO₂ CH₃, SCH₂ CO₂ C₂ H₅, SCH₂ C(O)CH₃, halogen, C₁ -C₃ alkoxy or OCH₂ CH═CH₂ ; R₃ " is H, CH₃, Cl or Br; W' is O or S; W" is O, S or NR₁₁ ; R₁₁ is H, C₁ -C₃ alkyl or CH₂ CH═CH₂.
 3. A compound of claim 2 wherein E is H; A is A-1; X is CH₃, OCH₃, or OC₂ H₅ ; Y is H, CH₃, OCH₃, C₂ H₅, OC₂ H₅, CH₂ OCH₃, CF₃, cyclopropyl, OCH₂ CF₃, NHCH₃, N(CH₃)₂, CH(OCH₃)₂ or ##STR163## n' is 0; and R₃ ' and R₃ " are independently H, CH₃ or Cl; R is H; and W is O.
 4. A compound of claim 3 wherein n is
 0. 5. A compound of claim 4 wherein Y is C₁ -C₂ alkyl or OCH₃.
 6. A compound of claim 5 of Formula Ia.
 7. A compound of claim 5 of Formula Ib.
 8. A compound of claim 5 of Formula Ic.
 9. A compound of claim 6 where Q is Q-1, Q-2, Q-3, Q-5, Q-7, Q-10, Q-11, Q-15, Q-16, Q-20, Q-23, Q-28, Q-36 or Q-39.
 10. A compound of claim 7 where Q is Q-1, Q-2, Q-3, Q-5, Q-7, Q-10, Q-11, Q-15, Q-16, Q-20, Q-23, Q-28, Q-36 or Q-39.
 11. A compound of claim 8 where Q is Q-1, Q-2, Q-3, Q-5, Q-7, Q-10, Q-11, Q-15, Q-16, Q-20, Q-23, Q-28, Q-36 or Q-39.
 12. The compound of claim 1 which is N-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)aminocarbonyl]-3-(1H-pyrrol-1-yl)-2-thiophenesulfonamide.
 13. The compound of claim 1 which is N-[(4,6-dimethyl-1,3,5-triazin-2-yl)aminocarbonyl]-3-(1H-pyrrol-1-yl)-2-thiophenesulfonamide.
 14. The compound of claim 1 which is N-[(4,6-dimethoxy-1,3,5-triazin-2-yl)aminocarbonyl]-3-(1H-pyrrol-1-yl)-2-thiophenesulfonamide.
 15. A composition suitable for controlling the growth of undesired vegetation which comprises an effective amount of a compound of claim 1 and at least one of the following: surfactant, solid or liquid diluent.
 16. A composition suitable for controlling the growth of undesired vegetation which comprises an effective amount of a compound of claim 9 and at least one of the following: surfactant, solid or liquid diluent.
 17. A composition suitable for controlling the growth of undesired vegetation which comprises an effective amount of a compound of claim 10 and at least one of the following: surfactant, solid or liquid diluent.
 18. A composition suitable for controlling the growth of undesired vegetation which comprises an effective amount of a compound of claim 11 and at least one of the following: surfactant, solid or liquid diluent.
 19. A method for controlling the growth of undesired vegetation which comprises applying to the locus to be protected an effective amount of a compound of claim
 1. 20. A method for controlling the growth of undesired vegetation which comprises applying to the locus to be protected an effective amount of a compound of claim
 9. 21. A method for controlling the growth of undesired vegetation which comprises applying to the locus to be protected an effective amount of a compound of claim
 10. 22. A method for controlling the growth of undesired vegetation which comprises applying to the locus to be protected an effective amount of a compound of claim
 11. 